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<title>SDGtalks.ai | News, Content &amp;amp; Communication &#45; : 12. Responsible Consumption and Production</title>
<link>https://sdgtalks.ai/rss/category/12-responsible-consumption-and-production</link>
<description>SDGtalks.ai | News, Content &amp;amp; Communication &#45; : 12. Responsible Consumption and Production</description>
<dc:language>en</dc:language>
<dc:rights>Copyright 2021 sdgtalks.ai &#45; All Rights Reserved.</dc:rights>

<item>
<title>Corporate responsibility budgets steady despite ‘challenging year’: ACCP – ESG Dive</title>
<link>https://sdgtalks.ai/corporate-responsibility-budgets-steady-despite-challenging-year-accp-esg-dive</link>
<guid>https://sdgtalks.ai/corporate-responsibility-budgets-steady-despite-challenging-year-accp-esg-dive</guid>
<description><![CDATA[ Corporate responsibility budgets steady despite ‘challenging year’: ACCP  ESG Dive ]]></description>
<enclosure url="https://www.esgdive.com/static/img/play.svg" length="49398" type="image/jpeg"/>
<pubDate>Mon, 06 Apr 2026 00:00:12 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Corporate, responsibility, budgets, steady, despite, ‘challenging, year’:, ACCP, –, ESG, Dive</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Corporate Social Responsibility Budgets Remain Steady Amid Challenges: Emphasis on Sustainable Development Goals</h2>
<h3>Overview of Corporate Social Responsibility Budget Trends in 2026</h3>
<p>Despite political shifts and policy changes under the Trump administration, particularly regarding social initiatives such as diversity, equity, and inclusion, corporate social responsibility (CSR) teams anticipate stable budgets for 2026. According to a recent survey conducted by the Association of Corporate Citizenship Professionals (ACCP),</p>
<ol>
<li>62% of CSR professionals expect their corporate impact budgets to remain unchanged.</li>
<li>17% anticipate budget increases.</li>
<li>21% foresee budget decreases.</li>
</ol>
<p>This stability underscores a continued corporate commitment to social impact initiatives aligned with the United Nations Sustainable Development Goals (SDGs), particularly those related to quality education (SDG 4), decent work and economic growth (SDG 8), and reduced inequalities (SDG 10).</p>
<h3>ACCP’s Role and Membership</h3>
<ul>
<li>ACCP is a trade association representing over 260 companies across more than 20 industries.</li>
<li>Member companies include American Express, Boeing, The Coca-Cola Company, eBay, Target, 3M, Pfizer, and FedEx.</li>
<li>The organization supports CSR and Environmental, Social, and Governance (ESG) professionals through research, programming, and professional development.</li>
</ul>
<h3>Leadership Perspective: Andrea Wood, ACCP President and CEO</h3>
<p>Andrea Wood, who assumed the dual roles of CEO and president in January 2025, emphasizes the importance of CSR as a fundamental business strategy. She states:</p>
<blockquote><p>
    “The proof of why CSR is important is there, if anybody wants to know how or why it positively affects the business and the community. This is really table stakes now; companies should be doing this. If they don’t have a CSR function, if they don’t have a plan, they need one.”
</p></blockquote>
<h3>Strategic Focus and Professional Development</h3>
<p>Under Wood’s leadership, ACCP is adopting a comprehensive approach to enhance corporate social impact by:</p>
<ul>
<li>Engaging members through research and collective knowledge sharing.</li>
<li>Providing programming for CSR professionals at all career stages.</li>
<li>Facilitating webinars, member discussions, and an online forum for ongoing support.</li>
</ul>
<p>This approach supports SDG 17 (Partnerships for the Goals) by fostering collaboration and knowledge exchange among CSR professionals.</p>
<h3>Challenges and Opportunities in CSR Amid Economic Headwinds</h3>
<p>While the majority of ACCP members have maintained their CSR budgets, economic uncertainties pose potential risks. Key challenges include:</p>
<ul>
<li>Economic headwinds affecting overall business performance.</li>
<li>Increased scrutiny from stakeholders including investors, communities, employees, and executive leadership.</li>
<li>Potential need to realign CSR strategies with evolving business priorities.</li>
</ul>
<p>Despite these challenges, companies are largely maintaining long-term CSR strategies, ensuring continued progress toward SDGs such as decent work and economic growth (SDG 8) and reduced inequalities (SDG 10).</p>
<h3>Alignment of CSR Strategies with Business Objectives</h3>
<p>ACCP highlights the critical importance of aligning CSR initiatives with core business strategies to maximize impact. This alignment supports the concept of “shared value,” which integrates corporate success with community benefits. Examples include:</p>
<ol>
<li><strong>STEM Education Initiatives:</strong> Many companies focus on science, technology, engineering, and mathematics (STEM) education to prepare future workforces, addressing SDG 4 (Quality Education) and SDG 8 (Decent Work and Economic Growth).</li>
<li><strong>Workforce Development:</strong> Investments in internships, career coaching, scholarships, and volunteering support the development of skilled labor pipelines, crucial amid demographic shifts and labor market challenges.</li>
<li><strong>Employee Engagement and Strategic Volunteerism:</strong> Encouraging employees to volunteer in ways that build relevant skills aligns with both business needs and community development, advancing SDG 8 and SDG 11 (Sustainable Cities and Communities).</li>
</ol>
<h3>Conclusion</h3>
<p>The ACCP survey and leadership insights reveal that despite external challenges, corporate social responsibility remains a strategic priority. Companies are committed to sustaining and evolving their CSR efforts in alignment with the Sustainable Development Goals, ensuring mutual benefits for business and society. Continued focus on strategic alignment, workforce development, and stakeholder engagement will be essential for advancing global sustainability agendas in the coming years.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 4: Quality Education</strong>
<ul>
<li>The article discusses corporate investments in STEM education for young people, aiming to prepare them for future jobs.</li>
</ul>
</li>
<li><strong>SDG 8: Decent Work and Economic Growth</strong>
<ul>
<li>Focus on workforce development, employee engagement, and strategic volunteerism to support employment and economic participation.</li>
</ul>
</li>
<li><strong>SDG 10: Reduced Inequalities</strong>
<ul>
<li>Emphasis on diversity, equity, and inclusion initiatives despite political challenges.</li>
</ul>
</li>
<li><strong>SDG 17: Partnerships for the Goals</strong>
<ul>
<li>Collaboration among companies, CSR professionals, and communities to align strategies and maximize social impact.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs</h2>
<ol>
<li><strong>SDG 4: Quality Education</strong>
<ul>
<li>Target 4.4: Increase the number of youth and adults with relevant skills, including technical and vocational skills, for employment.</li>
</ul>
</li>
<li><strong>SDG 8: Decent Work and Economic Growth</strong>
<ul>
<li>Target 8.5: Achieve full and productive employment and decent work for all women and men.</li>
<li>Target 8.6: Reduce the proportion of youth not in employment, education or training.</li>
</ul>
</li>
<li><strong>SDG 10: Reduced Inequalities</strong>
<ul>
<li>Target 10.2: Empower and promote the social, economic and political inclusion of all.</li>
</ul>
</li>
<li><strong>SDG 17: Partnerships for the Goals</strong>
<ul>
<li>Target 17.17: Encourage and promote effective public, public-private and civil society partnerships.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Budget Allocation and Changes</strong>
<ul>
<li>Percentage of companies maintaining or increasing corporate social responsibility (CSR) budgets (e.g., 62% expect budgets to remain the same, 17% anticipate increases).</li>
</ul>
</li>
<li><strong>Employee Engagement Metrics</strong>
<ul>
<li>Levels of employee participation in volunteering and community engagement activities aligned with company strategy.</li>
</ul>
</li>
<li><strong>Workforce Development Outcomes</strong>
<ul>
<li>Number of young people receiving STEM education support, internships, scholarships, and career coaching.</li>
<li>Employment rates of youth and readiness for STEM-related jobs.</li>
</ul>
</li>
<li><strong>Stakeholder Alignment and Strategy Implementation</strong>
<ul>
<li>Degree of alignment between CSR strategies and business goals as well as stakeholder support.</li>
</ul>
</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 4: Quality Education</td>
<td>Target 4.4: Increase youth and adults with relevant skills for employment.</td>
<td>
<ul>
<li>Number of youth supported through STEM education programs.</li>
<li>Participation rates in internships, scholarships, and career coaching.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 8: Decent Work and Economic Growth</td>
<td>
<ul>
<li>Target 8.5: Achieve full and productive employment.</li>
<li>Target 8.6: Reduce youth not in employment, education or training.</li>
</ul>
</td>
<td>
<ul>
<li>Employment rates of youth in STEM-related fields.</li>
<li>Employee engagement in strategic volunteerism.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 10: Reduced Inequalities</td>
<td>Target 10.2: Promote social, economic and political inclusion of all.</td>
<td>
<ul>
<li>Implementation and impact of diversity, equity, and inclusion initiatives.</li>
<li>Stakeholder scrutiny and response to social inclusion efforts.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 17: Partnerships for the Goals</td>
<td>Target 17.17: Promote effective public, public-private and civil society partnerships.</td>
<td>
<ul>
<li>Number and quality of partnerships among companies, CSR professionals, and communities.</li>
<li>Alignment of CSR strategies with business and community needs.</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.esgdive.com/news/corporate-responsibility-budgets-steady-despite-challenging-year-accp/816616/">esgdive.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<item>
<title>Unlocking Resources for Resilience and Energy Savings Join Us for a C&#45;PACE Info Session on March 18! – The City of Asheville (.gov)</title>
<link>https://sdgtalks.ai/unlocking-resources-for-resilience-and-energy-savings-join-us-for-a-c-pace-info-session-on-march-18-the-city-of-asheville-gov</link>
<guid>https://sdgtalks.ai/unlocking-resources-for-resilience-and-energy-savings-join-us-for-a-c-pace-info-session-on-march-18-the-city-of-asheville-gov</guid>
<description><![CDATA[ Unlocking Resources for Resilience and Energy Savings Join Us for a C-PACE Info Session on March 18!  The City of Asheville (.gov) ]]></description>
<enclosure url="https://www.ashevillenc.gov/wp-content/uploads/2026/03/CPACE-session-flyer-732x1024.png" length="49398" type="image/jpeg"/>
<pubDate>Thu, 12 Mar 2026 19:00:15 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Unlocking, Resources, for, Resilience, and, Energy, Savings, Join, for, C-PACE, Info, Session, March, 18, –, The, City, Asheville, .gov</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on the Launch of North Carolina C-PACE Program by City of Asheville and Buncombe County</h2>
<p>The City of Asheville and Buncombe County have introduced the North Carolina Commercial Property Assessed Capital Expenditure (C-PACE) program. This innovative financing mechanism aims to support commercial property owners and developers in implementing upgrades that promote energy efficiency, water conservation, and resiliency. The initiative aligns closely with several Sustainable Development Goals (SDGs), including SDG 7 (Affordable and Clean Energy), SDG 11 (Sustainable Cities and Communities), and SDG 13 (Climate Action).</p>
<h2>Information Session Details</h2>
<p>To facilitate understanding and utilization of the C-PACE program, a free information session will be held with no registration required:</p>
<ul>
<li><strong>Date and Time:</strong> March 18, 2026, from 9:00 to 10:00 AM</li>
<li><strong>Location:</strong> 200 College St, Asheville, 1st Floor Conference Room</li>
<li><strong>Parking:</strong> Validated parking available at 164 College St. parking deck</li>
</ul>
<h2>Overview of C-PACE Financing</h2>
<p>C-PACE provides long-term, private capital financing secured by a voluntary assessment and lien on commercial, industrial, agricultural, and multi-family properties. This financing tool addresses a critical barrier to sustainable development by reducing upfront costs associated with building improvements.</p>
<h3>Key Benefits of C-PACE Financing</h3>
<ol>
<li><strong>100% Financing:</strong> Covers both hard and soft costs, including audits and engineering, minimizing initial investment requirements.</li>
<li><strong>Improved Cash Flow:</strong> Financing terms extend 20–30 years, corresponding to the lifespan of improvements, often resulting in energy savings that exceed repayment amounts.</li>
<li><strong>Transferability:</strong> The repayment obligation is tied to the property and transfers automatically to new owners upon sale.</li>
<li><strong>Increased Property Value:</strong> Enhancements in energy efficiency, resiliency, renewable energy, and water conservation improve building longevity and attract tenants by lowering utility costs.</li>
</ol>
<h3>Eligible Improvements Under C-PACE</h3>
<p>The program supports a broad range of sustainable property improvements that contribute to multiple SDGs:</p>
<ul>
<li><strong>Energy Efficiency:</strong> Installation of high-efficiency lighting, HVAC systems, insulation, and energy-efficient windows (supports SDG 7).</li>
<li><strong>Renewable Energy:</strong> Deployment of solar photovoltaic (PV), wind, and geothermal systems (supports SDG 7 and SDG 13).</li>
<li><strong>Resiliency:</strong> Flood mitigation, stormwater management, wind resistance enhancements such as roof reinforcements, and indoor air quality improvements (supports SDG 11 and SDG 13).</li>
<li><strong>Water Conservation:</strong> Implementation of water-saving fixtures and measures to ensure safe drinking water (supports SDG 6).</li>
</ul>
<h3>Program Administration and Eligibility</h3>
<p>The Economic Development Partnership of North Carolina (EDPNC) administers the C-PACE program, with local government authorization and funding from private capital providers.</p>
<ul>
<li><strong>Eligibility Criteria:</strong> Property owners must be current on taxes and mortgages.</li>
<li><strong>Lienholder Consent:</strong> Written consent from all existing mortgage holders is mandatory prior to financing.</li>
<li><strong>Financing Limits:</strong> Financing is available up to 35% of the property’s assessed value.</li>
</ul>
<h2>Additional Resources and Contact</h2>
<p>For stakeholders unable to attend the information session, comprehensive program details and toolkits are accessible via the <a href="https://edpnc.com/nc-cpace/" target="_blank" rel="noopener noreferrer">EDPNC website</a>. The City of Asheville and Buncombe County encourage participation to advance sustainable development goals and support clean energy initiatives within the community.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses financing for energy efficiency and renewable energy upgrades, directly contributing to clean energy access and use.</li>
</ul>
</li>
<li><strong>SDG 6: Clean Water and Sanitation</strong>
<ul>
<li>Water conservation and safe drinking water improvements are part of the qualifying projects under C-PACE.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Resiliency upgrades such as flood mitigation and stormwater management enhance urban sustainability and safety.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Energy efficiency, renewable energy, and resiliency measures support climate change mitigation and adaptation efforts.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong>
<ul>
<li>The program promotes innovative financing tools and infrastructure improvements in commercial properties.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs</h2>
<ol>
<li><strong>SDG 7 Targets</strong>
<ul>
<li>Target 7.3: By 2030, double the global rate of improvement in energy efficiency.</li>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
</ul>
</li>
<li><strong>SDG 6 Targets</strong>
<ul>
<li>Target 6.4: By 2030, substantially increase water-use efficiency across all sectors.</li>
<li>Target 6.1: Achieve universal and equitable access to safe and affordable drinking water.</li>
</ul>
</li>
<li><strong>SDG 11 Targets</strong>
<ul>
<li>Target 11.5: Reduce the number of deaths and the number of people affected by disasters, including water-related disasters.</li>
<li>Target 11.6: Reduce the adverse per capita environmental impact of cities.</li>
</ul>
</li>
<li><strong>SDG 13 Targets</strong>
<ul>
<li>Target 13.1: Strengthen resilience and adaptive capacity to climate-related hazards and natural disasters.</li>
</ul>
</li>
<li><strong>SDG 9 Targets</strong>
<ul>
<li>Target 9.4: Upgrade infrastructure and retrofit industries to make them sustainable.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied in the Article</h2>
<ol>
<li><strong>Energy Efficiency and Renewable Energy Indicators</strong>
<ul>
<li>Percentage of commercial properties upgraded with energy-efficient lighting, HVAC, insulation, and renewable energy systems (solar, wind, geothermal).</li>
<li>Energy savings exceeding financing payments, implying measurement of energy consumption reductions.</li>
</ul>
</li>
<li><strong>Water Conservation Indicators</strong>
<ul>
<li>Implementation rate of water-saving fixtures and measures ensuring safe drinking water in commercial properties.</li>
</ul>
</li>
<li><strong>Resiliency Indicators</strong>
<ul>
<li>Number of properties with flood mitigation, stormwater management, and wind resistance improvements.</li>
<li>Improvement in indoor air quality measures.</li>
</ul>
</li>
<li><strong>Financial and Programmatic Indicators</strong>
<ul>
<li>Amount of private capital invested through C-PACE financing.</li>
<li>Percentage of property value financed (up to 35%).</li>
<li>Number of commercial property owners utilizing C-PACE financing.</li>
</ul>
</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.3: Double the rate of improvement in energy efficiency by 2030</li>
<li>7.2: Increase the share of renewable energy in the global energy mix</li>
</ul>
</td>
<td>
<ul>
<li>% of commercial properties upgraded with energy-efficient and renewable energy systems</li>
<li>Energy savings exceeding financing payments</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 6: Clean Water and Sanitation</td>
<td>
<ul>
<li>6.4: Increase water-use efficiency across all sectors</li>
<li>6.1: Achieve access to safe and affordable drinking water</li>
</ul>
</td>
<td>
<ul>
<li>Implementation rate of water-saving fixtures and safe drinking water measures</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>
<ul>
<li>11.5: Reduce deaths and people affected by disasters</li>
<li>11.6: Reduce adverse environmental impact of cities</li>
</ul>
</td>
<td>
<ul>
<li>Number of properties with flood mitigation, stormwater management, and wind resistance improvements</li>
<li>Indoor air quality improvements</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.1: Strengthen resilience and adaptive capacity to climate hazards</li>
</ul>
</td>
<td>
<ul>
<li>Number of resiliency upgrades implemented</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation and Infrastructure</td>
<td>
<ul>
<li>9.4: Upgrade infrastructure and retrofit industries for sustainability</li>
</ul>
</td>
<td>
<ul>
<li>Amount of private capital invested through C-PACE</li>
<li>Percentage of property value financed</li>
<li>Number of commercial properties utilizing C-PACE</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.ashevillenc.gov/news/unlocking-resources-for-resilience-and-energy-savings-join-us-for-a-c-pace-info-session-on-march-18/">ashevillenc.gov</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Advisory services and capacity building – energy.ec.europa.eu</title>
<link>https://sdgtalks.ai/advisory-services-and-capacity-building-energyeceuropaeu</link>
<guid>https://sdgtalks.ai/advisory-services-and-capacity-building-energyeceuropaeu</guid>
<description><![CDATA[ Advisory services and capacity building  energy.ec.europa.eu ]]></description>
<enclosure url="https://energy.ec.europa.eu/profiles/contrib/ewcms/modules/ewcms_seo/assets/images/ec-socialmedia-fallback.png" length="49398" type="image/jpeg"/>
<pubDate>Tue, 10 Mar 2026 19:00:18 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Advisory, services, and, capacity, building, –, energy.ec.europa.eu</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>One-Stop Shops for Energy Renovation: Advancing Sustainable Development Goals</h2>
<h3>Introduction to One-Stop Shops</h3>
<p>One-stop shops serve as essential hubs that simplify the energy renovation process for various stakeholders, including private citizens and enterprises. These centers provide comprehensive support and information throughout the different stages of energy renovation projects. Services typically encompass technical, administrative, legal, and financial assistance, accessible via online platforms, telephone consultations, in-person counters, or on-site visits.</p>
<h3>Alignment with Sustainable Development Goals (SDGs)</h3>
<p>The establishment and operation of one-stop shops directly contribute to several Sustainable Development Goals:</p>
<ul>
<li><strong>SDG 7: Affordable and Clean Energy</strong> – By facilitating energy-efficient renovations, one-stop shops promote access to clean and sustainable energy solutions.</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong> – Supporting innovative renovation methods and infrastructure upgrades.</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong> – Enhancing the energy performance of buildings contributes to sustainable urban development.</li>
<li><strong>SDG 13: Climate Action</strong> – Reducing energy consumption and greenhouse gas emissions through improved building efficiency.</li>
</ul>
<h3>Regulatory Framework Supporting One-Stop Shops</h3>
<p>The <em>Energy Efficiency Directive</em> and the <em>Energy Performance of Buildings Directive</em> establish key principles that underpin the creation and operation of one-stop shops across the European Union. These directives ensure that one-stop shops are equipped to provide integrated support services that align with EU energy and climate objectives.</p>
<h3>European Commission Initiatives</h3>
<p>As part of the <a href="https://ec.europa.eu/commission/presscorner/detail/en/ip_26_555">Energy Package</a> published on 10 March 2026, the European Commission issued a <a href="https://energy.ec.europa.eu/publications/recommendation-guidance-one-stop-shops-energy-efficiency-and-energy-performance-buildings_en">Recommendation with practical guidance on the establishment of one-stop shops</a>. This guidance outlines various models of one-stop shop services tailored to different contexts, recognizing that no single solution fits all scenarios.</p>
<h3>Objectives and Support for Authorities</h3>
<ol>
<li>Enable reflection on effective one-stop shop models suitable for national, regional, and local contexts.</li>
<li>Support authorities in establishing networks of one-stop shops that enhance energy efficiency and building performance.</li>
<li>Promote collaboration among stakeholders to accelerate energy renovation and contribute to the EU’s climate goals.</li>
</ol>
<h3>Additional Resources</h3>
<ul>
<li><a href="https://energy.ec.europa.eu/topics/energy-efficiency/energy-performance-buildings/energy-performance-buildings-directive/one-stop-shops-building-renovation-and-energy-efficiency_en">Facts on One-Stop Shops</a></li>
</ul>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article focuses on energy efficiency and energy performance of buildings, which directly relates to ensuring access to affordable, reliable, sustainable, and modern energy for all.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>By promoting energy renovations and improving building performance, the article supports making cities and human settlements inclusive, safe, resilient, and sustainable.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Energy efficiency improvements contribute to reducing greenhouse gas emissions, thus supporting urgent action to combat climate change and its impacts.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs</h2>
<ol>
<li><strong>SDG 7 Targets</strong>
<ul>
<li><strong>Target 7.3:</strong> By 2030, double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 11 Targets</strong>
<ul>
<li><strong>Target 11.6:</strong> By 2030, reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.</li>
</ul>
</li>
<li><strong>SDG 13 Targets</strong>
<ul>
<li><strong>Target 13.2:</strong> Integrate climate change measures into national policies, strategies, and planning.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Energy Efficiency Directive and Energy Performance of Buildings Directive Indicators</strong>
<ul>
<li>Number and effectiveness of one-stop shops established to support energy renovation projects.</li>
<li>Percentage improvement in energy performance of buildings undergoing renovation.</li>
<li>Reduction in energy consumption and greenhouse gas emissions from renovated buildings.</li>
</ul>
</li>
<li><strong>Commission Recommendation Indicators</strong>
<ul>
<li>Extent of adoption of recommended models of one-stop shops at national, regional, and local levels.</li>
<li>Stakeholder satisfaction and accessibility of technical, administrative, legal, and financial assistance.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>Target 7.3: Double the global rate of improvement in energy efficiency by 2030.</td>
<td>
<ul>
<li>Number and effectiveness of one-stop shops for energy renovation.</li>
<li>Percentage improvement in energy performance of renovated buildings.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>Target 11.6: Reduce adverse per capita environmental impact of cities by 2030.</td>
<td>
<ul>
<li>Reduction in energy consumption and emissions from buildings.</li>
<li>Accessibility and usage rates of one-stop shops supporting sustainable urban renovation.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>Target 13.2: Integrate climate change measures into national policies and planning.</td>
<td>
<ul>
<li>Adoption of one-stop shop models recommended by the Commission.</li>
<li>Stakeholder engagement and support levels in energy efficiency initiatives.</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://energy.ec.europa.eu/topics/energy-efficiency/financing/advisory-services-and-capacity-building_en">energy.ec.europa.eu</a></strong></p>
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<title>General Mills inks 25&#45;year on&#45;site heat and power agreement expected to save $30M – Facilities Dive</title>
<link>https://sdgtalks.ai/general-mills-inks-25-year-on-site-heat-and-power-agreement-expected-to-save-30m-facilities-dive</link>
<guid>https://sdgtalks.ai/general-mills-inks-25-year-on-site-heat-and-power-agreement-expected-to-save-30m-facilities-dive</guid>
<description><![CDATA[ General Mills inks 25-year on-site heat and power agreement expected to save $30M  Facilities Dive ]]></description>
<enclosure url="https://www.facilitiesdive.com/static/img/play.svg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 08 Mar 2026 01:00:12 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>General, Mills, inks, 25-year, on-site, heat, and, power, agreement, expected, save, 30M, –, Facilities, Dive</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>General Mills Implements On-Site Combined Heat and Power System to Advance Sustainable Development Goals</h2>
<h3>Overview of the Energy Services Agreement</h3>
<ol>
<li>General Mills has entered into a 25-year energy services agreement with Unison Energy to deploy an <a href="https://unisonenergy.com/resources/blog/general-mills-partners-with-unison-energy-and-hannibal-board-of-public-works-to-establish-onsite-combined-heat-and-power-chp-system-at-its-hannibal-plant/">on-site combined heat and power (CHP) system</a> at its manufacturing facility in Hannibal, Missouri.</li>
<li>The CHP system is designed to supply approximately 90% of the plant’s annual electricity demand and around 70% of its steam requirements.</li>
<li>Unison Energy is responsible for financing, designing, constructing, owning, operating, and maintaining the system.</li>
<li>The project is expected to generate over $30 million in savings throughout the agreement’s lifecycle.</li>
</ol>
<h3>Alignment with Sustainable Development Goals (SDGs)</h3>
<ul>
<li><strong>SDG 7 – Affordable and Clean Energy:</strong> The CHP system provides a reliable, low-carbon energy source that significantly reduces dependence on traditional utilities, promoting access to sustainable energy.</li>
<li><strong>SDG 9 – Industry, Innovation, and Infrastructure:</strong> The initiative exemplifies innovative infrastructure development through the integration of advanced energy technologies within industrial operations.</li>
<li><strong>SDG 12 – Responsible Consumption and Production:</strong> By optimizing energy efficiency and reducing emissions, the project supports sustainable industrial consumption patterns.</li>
<li><strong>SDG 13 – Climate Action:</strong> The CHP system is projected to reduce the facility’s Scope 1 greenhouse gas emissions by approximately 57% and total site emissions by 28% annually, contributing to climate change mitigation efforts.</li>
<li><strong>SDG 17 – Partnerships for the Goals:</strong> The collaboration between General Mills, Unison Energy, and the Hannibal Board of Public Works demonstrates a strong public-private partnership fostering sustainable development.</li>
</ul>
<h2>Project Impact and Benefits</h2>
<h3>Energy Efficiency and Cost Savings</h3>
<ul>
<li>The CHP system will deliver low-emission power and greenhouse gas-free steam, enhancing the plant’s energy efficiency.</li>
<li>General Mills benefits from a predictable long-term energy supply with a fixed annual rate escalation of 2.5%, which is substantially lower than anticipated utility cost increases.</li>
<li>Estimated energy savings exceed $300,000 in the first year of operation.</li>
</ul>
<h3>Environmental and Emission Reductions</h3>
<ul>
<li>The facility’s Scope 1 emissions are expected to decrease by about 57%, while total site emissions will reduce by approximately 28% annually.</li>
<li>This reduction represents an estimated 5% of General Mills’ global Scope 1 emissions footprint across its supply chain.</li>
</ul>
<h3>Collaborative Framework and Public-Private Partnership</h3>
<ul>
<li>The agreement includes a dedicated standby framework for on-site generation developed jointly by General Mills, Unison Energy, and the Hannibal Board of Public Works.</li>
<li>The deal compensates the local utility for maintaining capacity and incorporates performance and outage provisions to ensure reliability and financial sustainability.</li>
<li>This partnership serves as a model for securing long-term economic and environmental benefits while supporting local government and utility financial health.</li>
</ul>
<h2>Statements from Key Stakeholders</h2>
<h3>Unison Energy</h3>
<p>Mariko Meier, CEO of Unison Energy, stated: “By aligning our long-term Energy Services Agreement with General Mills’ utility needs and sustainability goals, and by partnering with Hannibal Board of Public Works to develop a mutually beneficial business solution, we have created a blueprint for reliable, cost-effective, and low-carbon energy solutions.”</p>
<h3>General Mills</h3>
<p>Daren Kaiser, Global Energy Strategy Leader at General Mills, commented: “This project exemplifies the strength of like-minded, public-private collaboration, to create a sustainable solution that will deliver reliable, efficient energy. These forward-thinking organizations developed a plan that will allow us to balance the challenge of reducing emissions and adding needed power to the grid.”</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses the implementation of an on-site combined heat and power (CHP) system designed to provide a significant portion of the facility’s electric and steam load with low-emissions power.</li>
<li>This aligns with SDG 7’s aim to ensure access to affordable, reliable, sustainable, and modern energy for all.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong>
<ul>
<li>The collaboration between General Mills, Unison Energy, and the Hannibal Board of Public Works to develop a dedicated standby framework and implement innovative energy solutions reflects SDG 9’s focus on building resilient infrastructure and fostering innovation.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The project’s goal to reduce emissions and improve energy efficiency supports sustainable consumption and production patterns.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>The reduction of Scope 1 emissions by about 57% and total site emissions by approximately 28% per year directly contributes to combating climate change and its impacts.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 7 Targets</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
<li>Target 7.3: Double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 9 Targets</strong>
<ul>
<li>Target 9.4: Upgrade infrastructure and retrofit industries to make them sustainable, with increased resource-use efficiency and greater adoption of clean and environmentally sound technologies.</li>
</ul>
</li>
<li><strong>SDG 12 Targets</strong>
<ul>
<li>Target 12.2: Achieve the sustainable management and efficient use of natural resources.</li>
</ul>
</li>
<li><strong>SDG 13 Targets</strong>
<ul>
<li>Target 13.2: Integrate climate change measures into policies, strategies, and planning.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Energy Supply and Efficiency Indicators</strong>
<ul>
<li>Percentage of the facility’s annual electric load supplied by the CHP system (~90%).</li>
<li>Percentage of the facility’s steam load supplied by the CHP system (~70%).</li>
<li>Annual energy savings in monetary terms (e.g., $300,000 in the first year).</li>
</ul>
</li>
<li><strong>Emission Reduction Indicators</strong>
<ul>
<li>Reduction in Scope 1 emissions by about 57% at the facility level.</li>
<li>Reduction in total site emissions by approximately 28% per year.</li>
<li>Contribution to General Mills’ global Scope 1 footprint reduction (~5%).</li>
</ul>
</li>
<li><strong>Financial and Operational Indicators</strong>
<ul>
<li>Fixed annual rate escalation of 2.5%, compared to projected utility increases.</li>
<li>Long-term cost savings over the 25-year agreement (over $30 million).</li>
<li>Performance and outage provisions ensuring reliability.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy</li>
<li>7.3: Double rate of energy efficiency improvement</li>
</ul>
</td>
<td>
<ul>
<li>~90% of facility’s electric load supplied by CHP</li>
<li>~70% of facility’s steam load supplied by CHP</li>
<li>Annual energy savings ($300,000 in first year)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation, and Infrastructure</td>
<td>
<ul>
<li>9.4: Upgrade infrastructure for sustainability and clean technologies</li>
</ul>
</td>
<td>
<ul>
<li>Implementation of on-site CHP system</li>
<li>Development of dedicated standby framework for on-site generation</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.2: Sustainable management and efficient use of natural resources</li>
</ul>
</td>
<td>
<ul>
<li>Reduction in energy consumption through efficient CHP system</li>
<li>Long-term cost savings and resource efficiency</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.2: Integrate climate change measures into policies and planning</li>
</ul>
</td>
<td>
<ul>
<li>57% reduction in Scope 1 emissions at facility</li>
<li>28% reduction in total site emissions annually</li>
<li>5% contribution to global Scope 1 footprint reduction</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.facilitiesdive.com/news/general-mills-inks-25-year-on-site-heat-and-power-agreement-expected-to-sav/813652/">facilitiesdive.com</a></strong></p>
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<title>WMW | Biowaste: Anaerobic digestion powers Minnesota’s circular economy ambitions – Waste Management World</title>
<link>https://sdgtalks.ai/wmw-biowaste-anaerobic-digestion-powers-minnesotas-circular-economy-ambitions-waste-management-world</link>
<guid>https://sdgtalks.ai/wmw-biowaste-anaerobic-digestion-powers-minnesotas-circular-economy-ambitions-waste-management-world</guid>
<description><![CDATA[ WMW | Biowaste: Anaerobic digestion powers Minnesota&#039;s circular economy ambitions  Waste Management World ]]></description>
<enclosure url="https://s3.eu-central-1.amazonaws.com/weka-alps-media/media/wasteManagementWorld/_1200x630_crop_center-center_82_none/groundbreaking_louisville_township.jpg" length="49398" type="image/jpeg"/>
<pubDate>Fri, 06 Mar 2026 13:00:13 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>WMW, Biowaste:, Anaerobic, digestion, powers, Minnesota’s, circular, economy, ambitions, –, Waste, Management, World</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Louisville Township Renewable Gas Project: Advancing Sustainable Development Goals through Anaerobic Digestion</h2>
<div><img decoding="async" src="https://s3.eu-central-1.amazonaws.com/weka-alps-media/media/wasteManagementWorld/_1200x630_crop_center-center_82_none/groundbreaking_louisville_township.jpg?mtime=1772706942" alt="Louisville Township Renewable Gas Project"></div>
<h3>Project Overview</h3>
<p>Kanadevia Inova, a global leader in green technology formerly known as Hitachi Zosen Inova, has initiated construction of the Louisville Township Renewable Gas Project in Minnesota. This large-scale anaerobic digestion facility, developed in partnership with Dem-Con Companies LLC under the joint venture DCHZI BioEnergy, represents a significant advancement in organic waste-to-renewable gas technology in the region.</p>
<h3>Key Project Details</h3>
<ol>
<li><strong>Operational Timeline:</strong> The facility is scheduled to begin processing organic materials in 2027.</li>
<li><strong>Capacity:</strong> It will process up to 75,000 tonnes of organic waste annually.</li>
<li><strong>Renewable Energy Output:</strong> The project will produce approximately 200,000 MMBtu of renewable natural gas (RNG) each year.</li>
<li><strong>By-product Generation:</strong> Approximately 8,000 tonnes of biochar will be generated annually, serving as a carbon-sequestering material with applications in agriculture, industry, and environmental remediation.</li>
</ol>
<h3>Contribution to Sustainable Development Goals (SDGs)</h3>
<ul>
<li><strong>SDG 7 – Affordable and Clean Energy:</strong> By converting organic waste into renewable natural gas, the project promotes clean and sustainable energy sources.</li>
<li><strong>SDG 11 – Sustainable Cities and Communities:</strong> The facility supports sustainable waste management practices by processing municipal organic waste from surrounding counties.</li>
<li><strong>SDG 12 – Responsible Consumption and Production:</strong> The project exemplifies circular economy principles by transforming waste into valuable energy and materials.</li>
<li><strong>SDG 13 – Climate Action:</strong> The production of biochar contributes to carbon sequestration, reducing the overall carbon footprint of the facility and mitigating climate change impacts.</li>
<li><strong>SDG 15 – Life on Land:</strong> Biochar applications in agriculture enhance soil health and promote sustainable land use.</li>
</ul>
<h3>Expert Commentary</h3>
<p>Heath Jones, Regional President North America at Kanadevia Inova, stated: “This cutting-edge facility will convert the organic fraction of municipal waste from surrounding counties into renewable energy through anaerobic digestion, biogas upgrading, and advanced gasification. In addition to biomethane, it will be the first facility of its kind to produce biochar, a carbon-sequestering byproduct that reduces the plant’s carbon intensity and creates valuable applications for agriculture and industry.”</p>
<h3>Conclusion</h3>
<p>The Louisville Township Renewable Gas Project exemplifies innovation in sustainable waste management and renewable energy production. By aligning with multiple Sustainable Development Goals, the project not only advances environmental stewardship but also fosters economic and social benefits within the community and beyond.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses the production of renewable natural gas (RNG), a clean energy source, contributing to affordable and sustainable energy.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>The project converts municipal organic waste into renewable energy, promoting sustainable waste management in local communities.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The anaerobic digestion facility processes organic waste, supporting sustainable consumption and waste reduction.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>The facility produces biochar, a carbon-sequestering by-product, which helps reduce carbon intensity and mitigate climate change.</li>
</ul>
</li>
<li><strong>SDG 15: Life on Land</strong>
<ul>
<li>Biochar applications in agriculture and environmental remediation support sustainable land use and ecosystem health.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Target 11.6: Reduce the adverse per capita environmental impact of cities, including by paying special attention to waste management.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.2: Integrate climate change measures into national policies, strategies, and planning.</li>
</ul>
</li>
<li><strong>SDG 15: Life on Land</strong>
<ul>
<li>Target 15.3: Combat desertification, restore degraded land and soil, including land affected by desertification, drought, and floods.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>SDG 7 Indicators</strong>
<ul>
<li>Indicator 7.2.1: Renewable energy share in the total final energy consumption — implied by the production of approximately 200,000 MMBtu of renewable natural gas annually.</li>
</ul>
</li>
<li><strong>SDG 11 Indicators</strong>
<ul>
<li>Indicator 11.6.1: Proportion of municipal solid waste collected and managed in controlled facilities — implied by the facility handling 75,000 tonnes of organic materials per year.</li>
</ul>
</li>
<li><strong>SDG 12 Indicators</strong>
<ul>
<li>Indicator 12.5.1: National recycling rate, tons of material recycled — implied through the conversion of organic waste into renewable energy and biochar.</li>
</ul>
</li>
<li><strong>SDG 13 Indicators</strong>
<ul>
<li>Indicator 13.2.2: Total greenhouse gas emissions per year — implied reduction through carbon sequestration by biochar and renewable energy production reducing fossil fuel use.</li>
</ul>
</li>
<li><strong>SDG 15 Indicators</strong>
<ul>
<li>Indicator 15.3.1: Proportion of land that is degraded over total land area — implied improvement through biochar applications in agriculture and environmental remediation.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>7.2: Increase substantially the share of renewable energy in the global energy mix.</td>
<td>7.2.1: Renewable energy share in the total final energy consumption (implied by 200,000 MMBtu RNG production annually)</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>11.6: Reduce the adverse per capita environmental impact of cities, including waste management.</td>
<td>11.6.1: Proportion of municipal solid waste collected and managed in controlled facilities (implied by 75,000 tonnes organic waste processing)</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</td>
<td>12.5.1: National recycling rate, tons of material recycled (implied by organic waste conversion to RNG and biochar)</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>13.2: Integrate climate change measures into national policies, strategies, and planning.</td>
<td>13.2.2: Total greenhouse gas emissions per year (implied reduction via biochar carbon sequestration and renewable energy)</td>
</tr>
<tr>
<td>SDG 15: Life on Land</td>
<td>15.3: Combat desertification, restore degraded land and soil.</td>
<td>15.3.1: Proportion of land that is degraded over total land area (implied improvement through biochar applications)</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://waste-management-world.com/materials/anaerobic-digestion-powers-minnesotas-circular-economy-ambitions/">waste-management-world.com</a></strong></p>
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<title>Anaerobic Digestion Market Size | Industry Report, 2033 – Grand View Research</title>
<link>https://sdgtalks.ai/anaerobic-digestion-market-size-industry-report-2033-grand-view-research</link>
<guid>https://sdgtalks.ai/anaerobic-digestion-market-size-industry-report-2033-grand-view-research</guid>
<description><![CDATA[ Anaerobic Digestion Market Size | Industry Report, 2033  Grand View Research ]]></description>
<enclosure url="https://www.grandviewresearch.com/static/img/research/anaerobic-digestion-market-size.webp" length="49398" type="image/jpeg"/>
<pubDate>Tue, 03 Mar 2026 07:00:12 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Anaerobic, Digestion, Market, Size, Industry, Report, 2033, –, Grand, View, Research</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Anaerobic Digestion Market Report with Emphasis on Sustainable Development Goals (SDGs)</h2>
<h3>Market Overview and Sustainable Development Context</h3>
<p>The global anaerobic digestion market was valued at <strong>USD 18.07 billion in 2025</strong> and is projected to grow to <strong>USD 39.42 billion by 2033</strong>, exhibiting a compound annual growth rate (CAGR) of <strong>10.3% from 2026 to 2033</strong>. This growth aligns with several Sustainable Development Goals (SDGs), including SDG 7 (Affordable and Clean Energy), SDG 11 (Sustainable Cities and Communities), SDG 12 (Responsible Consumption and Production), and SDG 13 (Climate Action).</p>
<p>Key drivers include the increasing demand for renewable energy, sustainable waste management practices, and stringent regulations targeting greenhouse gas emission reductions, directly contributing to global climate action efforts.</p>
<h3>Key Market Trends and Insights</h3>
<ul>
<li>North America held the largest revenue share (~35.1%) in 2025, reflecting strong policy support for renewable energy (SDG 7) and sustainable infrastructure (SDG 9).</li>
<li>The United States is a major contributor, with investments supporting clean energy transitions.</li>
<li>Wet anaerobic digestion technology dominated the market in 2025 due to its efficiency in processing high-moisture organic waste, supporting SDG 12.</li>
<li>Agricultural waste was the leading feedstock segment, promoting sustainable agriculture (SDG 2) and circular economy principles.</li>
<li>The agriculture sector accounted for over 30% of end-use market share, enhancing sustainable farming practices and nutrient recycling.</li>
</ul>
<h3>Market Size and Forecast</h3>
<ul>
<li><strong>2025 Market Size:</strong> USD 18.07 Billion</li>
<li><strong>2033 Projected Market Size:</strong> USD 39.42 Billion</li>
<li><strong>CAGR (2026-2033):</strong> 10.3%</li>
<li><strong>Regional Highlights:</strong> North America leads in market size; Asia Pacific is the fastest-growing region, advancing SDG 7 and SDG 11.</li>
</ul>
<h2>Role of Anaerobic Digestion in Achieving Sustainable Development Goals</h2>
<h3>Contribution to SDG 7: Affordable and Clean Energy</h3>
<p>Anaerobic digestion facilitates the conversion of organic waste into biogas and renewable natural gas (RNG), providing dispatchable and clean energy sources. This supports energy diversification and reduces reliance on fossil fuels, advancing SDG 7 targets.</p>
<h3>Advancement of SDG 12: Responsible Consumption and Production</h3>
<p>The technology promotes circular economy practices by converting food waste, manure, sewage sludge, and industrial residues into valuable energy and nutrient-rich digestate, reducing landfill dependency and waste generation.</p>
<h3>Support for SDG 13: Climate Action</h3>
<p>By mitigating methane emissions from organic waste and generating low-carbon energy, anaerobic digestion contributes to greenhouse gas reduction efforts and national decarbonization targets.</p>
<h3>Enhancement of SDG 2: Zero Hunger and Sustainable Agriculture</h3>
<p>The use of digestate as an organic fertilizer improves soil health and reduces chemical fertilizer use, supporting sustainable agriculture and food security.</p>
<h2>Drivers, Opportunities, and Challenges</h2>
<h3>Market Drivers</h3>
<ul>
<li>Increasing organic waste generation and demand for renewable energy.</li>
<li>Stringent environmental regulations targeting methane and greenhouse gas emissions.</li>
<li>Government incentives including feed-in tariffs, tax credits, and carbon credit programs aligned with SDG 13.</li>
<li>Growing adoption of circular economy and sustainable waste management practices.</li>
</ul>
<h3>Opportunities</h3>
<ul>
<li>Expansion of renewable natural gas markets supported by policy frameworks.</li>
<li>Technological advancements improving methane yields and operational efficiency.</li>
<li>Strategic partnerships enhancing feedstock security and integrated waste-to-energy infrastructure.</li>
<li>Scaling up decentralized energy solutions to support SDG 7 and SDG 11.</li>
</ul>
<h3>Challenges and Restraints</h3>
<ul>
<li>High initial capital investment for plant development and gas upgrading infrastructure.</li>
<li>Feedstock supply chain complexities including segregation and logistics.</li>
<li>Lengthy permitting processes and evolving regulatory frameworks.</li>
<li>Price volatility in renewable natural gas markets.</li>
</ul>
<h2>Technology Insights</h2>
<h3>Wet Anaerobic Digestion</h3>
<p>Dominating with a 52.2% market share in 2025, wet anaerobic digestion is favored for its maturity, stability, and efficiency in processing high-moisture feedstocks such as food waste and sewage sludge. This technology supports SDG 12 by enabling effective organic waste treatment.</p>
<h3>Two-Phase Anaerobic Digestion</h3>
<p>Projected to grow at a CAGR of 13.3%, two-phase systems optimize biological processes by separating acidogenesis and methanogenesis, enhancing methane yields and process control. This innovation supports SDG 9 (Industry, Innovation, and Infrastructure) and SDG 7.</p>
<h2>Feedstock Insights</h2>
<h3>Agricultural Waste</h3>
<p>Holding the largest market share (~26.6%) in 2025, agricultural waste utilization supports sustainable agriculture (SDG 2) and circular economy models by converting manure and crop residues into renewable energy and organic fertilizers.</p>
<h3>Food Waste</h3>
<p>Expected to register the fastest growth (CAGR 13.3%), driven by urbanization and regulations diverting organic waste from landfills. This supports SDG 11 by promoting sustainable urban waste management.</p>
<h2>End Use Insights</h2>
<h3>Agriculture Sector</h3>
<p>Leading with approximately 30.1% market share, the agriculture sector leverages anaerobic digestion to manage organic waste, generate renewable energy, and produce nutrient-rich digestate, advancing SDG 2 and SDG 12.</p>
<h3>Energy Sector</h3>
<p>Projected to grow at 11.2% CAGR, the energy sector’s investment in anaerobic digestion enhances renewable energy portfolios, grid reliability, and supports decarbonization mandates (SDG 7 and SDG 13).</p>
<h2>Regional Market Insights</h2>
<h3>North America</h3>
<p>Largest market share (~35.1%) due to robust policy frameworks supporting renewable natural gas, landfill diversion, and carbon credit programs. These efforts contribute to SDG 7, SDG 11, and SDG 13.</p>
<h3>United States</h3>
<p>Key contributor with expanding RNG production and incentives promoting methane reduction and climate goals.</p>
<h3>Asia Pacific</h3>
<p>Fastest-growing region (CAGR 13.7%) driven by urbanization, organic waste generation, and government focus on renewable energy adoption, supporting SDG 7 and SDG 11.</p>
<h3>Europe</h3>
<p>Significant market share supported by stringent environmental regulations, carbon neutrality targets, and mature biogas infrastructure, advancing SDG 13 and SDG 12.</p>
<h3>Latin America</h3>
<p>Steady growth fueled by agricultural expansion and sustainable waste management initiatives, contributing to SDG 2 and SDG 12.</p>
<h3>Middle East & Africa</h3>
<p>Developing market with increasing renewable energy awareness and waste management improvements, aligned with SDG 7 and SDG 13.</p>
<h2>Key Market Players and Innovation</h2>
<ul>
<li>EnviTec Biogas AG</li>
<li>PlanET Biogas Group GmbH</li>
<li>Hitachi Zosen Inova AG</li>
<li>WELTEC BIOPOWER GmbH</li>
<li>Anaergia Inc.</li>
<li>BioConstruct GmbH</li>
<li>BTS Biogas</li>
<li>Renergon International AG</li>
<li>DVO, Inc.</li>
<li>Organic Recycling Systems Ltd.</li>
</ul>
<p>These companies focus on advancing anaerobic digestion technologies that enhance methane yields, process stability, and plant efficiency, supporting SDG 9 and SDG 7. Strategic partnerships and modular system developments enable decentralized energy infrastructure and circular economy solutions, contributing to multiple SDGs.</p>
<h2>Recent Developments</h2>
<ol>
<li><strong>March 2025:</strong> EnviTec Biogas commissioned its largest U.S. anaerobic digestion facility in South Dakota, processing over 300,000 gallons of dairy manure daily to produce approximately 778 Nm³/h of biomethane, exemplifying scalable sustainable biogas solutions aligned with SDG 7 and SDG 13.</li>
<li><strong>April 2025:</strong> PlanET Biogas became the technology supplier for the Convertus York Biofuels Facility in Ontario, Canada, aiming to convert organic waste into renewable natural gas, supporting SDG 12 and SDG 7.</li>
</ol>
<h2>Market Scope and Segmentation</h2>
<table border="1" cellpadding="5" cellspacing="0" width="100%">
<tbody>
<tr>
<th>Report Attribute</th>
<th>Details</th>
</tr>
<tr>
<td>Market Definition</td>
<td>Global revenue from technologies converting organic waste into biogas and renewable energy supporting sustainable waste management and decarbonization (SDG 7, SDG 12, SDG 13).</td>
</tr>
<tr>
<td>Market Size (2026)</td>
<td>USD 19.86 billion</td>
</tr>
<tr>
<td>Revenue Forecast (2033)</td>
<td>USD 39.42 billion</td>
</tr>
<tr>
<td>Growth Rate</td>
<td>CAGR of 10.3% (2026-2033)</td>
</tr>
<tr>
<td>Base Year</td>
<td>2025</td>
</tr>
<tr>
<td>Historical Data</td>
<td>2021 – 2024</td>
</tr>
<tr>
<td>Forecast Period</td>
<td>2026 – 2033</td>
</tr>
<tr>
<td>Quantitative Units</td>
<td>Revenue in USD billion/million and CAGR</td>
</tr>
<tr>
<td>Report Coverage</td>
<td>Revenue forecast, competitive landscape, growth factors, and trends</td>
</tr>
<tr>
<td>Segments Covered</td>
<td>Technology, feedstock, end use, region</td>
</tr>
<tr>
<td>Regional Scope</td>
<td>North America; Europe; Asia Pacific; Latin America; Middle East & Africa</td>
</tr>
<tr>
<td>Country Scope</td>
<td>U.S., Canada, Mexico, Germany, UK, France, Italy, Spain, China, India, Japan, Brazil, Argentina, Saudi Arabia, UAE, South Africa</td>
</tr>
<tr>
<td>Key Companies Profiled</td>
<td>EnviTec Biogas AG, PlanET Biogas Group GmbH, Hitachi Zosen Inova AG, WELTEC BIOPOWER GmbH, Anaergia Inc., BioConstruct GmbH, Renergon International AG, BTS Biogas Srl/GmbH, DVO, Inc., Organic Recycling Systems Ltd.</td>
</tr>
</tbody>
</table>
<h2>Global Anaerobic Digestion Market Segmentation</h2>
<p>The market is segmented by technology, feedstock, end use, and region to analyze revenue growth and trends from 2021 to 2033.</p>
<h3>Technology Outlook</h3>
<ul>
<li>Wet Anaerobic Digestion</li>
<li>Dry Anaerobic Digestion</li>
<li>Two-Phase Anaerobic Digestion</li>
</ul>
<h3>Feedstock Outlook</h3>
<ul>
<li>Agricultural Waste</li>
<li>Animal Manure</li>
<li>Food Waste</li>
<li>Industrial Waste</li>
<li>Sewage Sludge</li>
</ul>
<h3>End Use Outlook</h3>
<ul>
<li>Agriculture</li>
<li>Energy Sector</li>
<li>Waste Management</li>
<li>Food and Beverage</li>
</ul>
<h3>Regional Outlook</h3>
<ul>
<li>North America (U.S., Canada, Mexico)</li>
<li>Europe (Germany, UK, France, Italy, Spain)</li>
<li>Asia Pacific (China, India, Japan)</li>
<li>Latin America (Brazil, Argentina)</li>
<li>Middle East & Africa (Saudi Arabia, UAE, South Africa)</li>
</ul>
<h2>Frequently Asked Questions</h2>
<ul>
<li>The global anaerobic digestion market size was estimated at USD 18.07 billion in 2025 and is expected to reach USD 19.86 billion in 2026.</li>
<li>The market is expected to grow at a CAGR of 10.3% from 2026 to 2033, reaching USD 39.42 billion by 2033.</li>
<li>Agricultural waste held the largest revenue share of over 26% in 2025.</li>
<li>Key vendors include EnviTec Biogas AG, PlanET Biogas Group GmbH, Hitachi Zosen Inova AG, and others.</li>
<li>Market drivers include rising organic waste generation, demand for renewable natural gas and biogas, environmental regulations, and investments in sustainable waste-to-energy infrastructure supporting global decarbonization.</li>
</ul>
<h2>1. Sustainable Development Goals (SDGs) Addressed in the Article</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses the growth of the anaerobic digestion market as a source of renewable energy, including biogas and renewable natural gas (RNG), contributing to clean and sustainable energy solutions.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Emphasis on sustainable waste management, circular economy practices, and converting organic waste into energy aligns with responsible consumption and production.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Stringent regulations aimed at reducing greenhouse gas emissions and methane emission reductions are highlighted, supporting climate action goals.</li>
</ul>
</li>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>The use of nutrient-rich digestate as organic fertilizer supports sustainable agriculture and soil health.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Municipal waste management and landfill diversion efforts contribute to sustainable urban development.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under the Identified SDGs</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
<li>Target 7.3: Double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
<li>Target 12.4: Achieve environmentally sound management of chemicals and all wastes throughout their life cycle.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.2: Integrate climate change measures into national policies, strategies, and planning.</li>
<li>Target 13.3: Improve education, awareness-raising and human and institutional capacity on climate change mitigation.</li>
</ul>
</li>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>Target 2.4: Ensure sustainable food production systems and implement resilient agricultural practices.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Target 11.6: Reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal waste management.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Renewable Energy Capacity and Production</strong>
<ul>
<li>Market size and revenue growth of anaerobic digestion technologies (e.g., USD 18.07 billion in 2025 to USD 39.42 billion by 2033) indicate increased renewable energy deployment.</li>
<li>Growth rates such as CAGR of 10.3% for the anaerobic digestion market reflect progress in renewable energy adoption.</li>
</ul>
</li>
<li><strong>Waste Management and Reduction</strong>
<ul>
<li>Volume of organic waste processed (food waste, agricultural waste, sewage sludge) through anaerobic digestion systems.</li>
<li>Reduction in landfill dependency and methane emissions implied through adoption of anaerobic digestion.</li>
</ul>
</li>
<li><strong>Greenhouse Gas Emissions</strong>
<ul>
<li>Indicators related to methane emission reductions supported by regulatory frameworks and carbon credit programs.</li>
</ul>
</li>
<li><strong>Use of Digestate as Fertilizer</strong>
<ul>
<li>Production and application rates of nutrient-rich digestate for agriculture, supporting soil health and reducing chemical fertilizer use.</li>
</ul>
</li>
<li><strong>Energy Access and Reliability</strong>
<ul>
<li>Deployment of anaerobic digestion systems providing dispatchable power and integration with combined heat and power (CHP) systems.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy in global energy mix</li>
<li>7.3: Double the rate of improvement in energy efficiency</li>
</ul>
</td>
<td>
<ul>
<li>Market size growth of anaerobic digestion (USD 18.07B in 2025 to USD 39.42B in 2033)</li>
<li>CAGR of 10.3% from 2026 to 2033</li>
<li>Capacity of biogas and RNG production</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.5: Reduce waste generation through prevention, recycling, reuse</li>
<li>12.4: Environmentally sound management of waste</li>
</ul>
</td>
<td>
<ul>
<li>Volume of organic waste processed (food waste, agricultural waste, sewage sludge)</li>
<li>Reduction in landfill dependency</li>
<li>Implementation of circular economy practices</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.2: Integrate climate measures into policies</li>
<li>13.3: Improve education and capacity on climate mitigation</li>
</ul>
</td>
<td>
<ul>
<li>Methane emission reductions supported by regulations and carbon credit programs</li>
<li>Adoption of renewable natural gas mandates</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 2: Zero Hunger</td>
<td>
<ul>
<li>2.4: Ensure sustainable food production and resilient agriculture</li>
</ul>
</td>
<td>
<ul>
<li>Use of nutrient-rich digestate as organic fertilizer</li>
<li>Reduction in chemical fertilizer dependency</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>
<ul>
<li>11.6: Reduce environmental impact of cities including waste management</li>
</ul>
</td>
<td>
<ul>
<li>Deployment of municipal anaerobic digestion systems</li>
<li>Landfill diversion rates</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.grandviewresearch.com/industry-analysis/anaerobic-digestion-market-report">grandviewresearch.com</a></strong></p>
<p> </p>]]> </content:encoded>
</item>

<item>
<title>Ministry for Development of Communities and Territories of Ukraine – Міністерство розвитку громад та територій України</title>
<link>https://sdgtalks.ai/ministry-for-development-of-communities-and-territories-of-ukraine-ministerstvo-rozvitku-gromad-ta-teritoriy-ukraini</link>
<guid>https://sdgtalks.ai/ministry-for-development-of-communities-and-territories-of-ukraine-ministerstvo-rozvitku-gromad-ta-teritoriy-ukraini</guid>
<description><![CDATA[ Ministry for Development of Communities and Territories of Ukraine  Міністерство розвитку громад та територій України ]]></description>
<enclosure url="https://mindev.gov.ua/storage/app/sites/1/uploaded-files/sait2.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 03 Mar 2026 07:00:12 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Ministry, for, Development, Communities, and, Territories, Ukraine, –, Міністерство, розвитку, громад, та, територій, України</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Emergency Recovery and Reconstruction Project Supported by JICA</h2>
<h3>Introduction</h3>
<p>Within the framework of the Emergency Recovery and Reconstruction Project, supported by the Japan International Cooperation Agency (JICA), technical equipment will be supplied to frontline regions of Ukraine. This initiative aligns with several Sustainable Development Goals (SDGs), including SDG 9 (Industry, Innovation, and Infrastructure), SDG 11 (Sustainable Cities and Communities), and SDG 17 (Partnerships for the Goals).</p>
<h3>Key Equipment Deliveries</h3>
<ol>
<li>
    <strong>20 Modular Ukrposhta Branches for Frontline Regions</strong>
<ul>
<li>Fully functional postal hubs installed in settlements where stationary branches were destroyed or damaged due to hostilities.</li>
<li>Ensure stable provision of postal and financial services even under limited infrastructure conditions.</li>
<li>Supports SDG 9 and SDG 11 by enhancing resilient infrastructure and sustainable community services.</li>
</ul>
</li>
<li>
    <strong>40 Units of Additional Heavy Machinery</strong>
<ul>
<li>Equipment for debris removal and municipal services in Sumy, Zaporizhzhia, and Chernihiv regions.</li>
<li>Contributes to SDG 11 by facilitating the restoration of sustainable cities and communities.</li>
</ul>
</li>
<li>
    <strong>Modern Training Simulator and Construction Equipment</strong>
<ul>
<li>A state-of-the-art training simulator for heavy construction machinery operators.</li>
<li>Five units of modern construction and cargo machinery for students at the Training Center in Bila Tserkva.</li>
<li>Supports SDG 4 (Quality Education) and SDG 8 (Decent Work and Economic Growth) through skills development and employment opportunities.</li>
</ul>
</li>
</ol>
<h3>Statements from Government Officials</h3>
<blockquote>
<p>“Japan remains one of our key strategic partners whose support is systematic and timely. It is critically important for us to ensure the livelihood of frontline regions, which face daily shelling. This assistance enables communities to recover quickly, provide basic services to people, and become more resilient despite the challenges of war,” emphasized Oleksii Kuleba, Vice Prime Minister for Ukraine’s Recovery and Minister for Communities and Territories Development.</p>
</blockquote>
<blockquote>
<p>“Cooperation with JICA delivers tangible results for our communities. The supply of modular Ukrposhta branches guarantees uninterrupted access to postal and other services where they are limited due to hostilities. Additionally, the heavy machinery for Sumy, Zaporizhzhia, and Chernihiv regions serves as an operational resource for debris removal and rapid restoration of municipal infrastructure,” stated Marina Denysiuk, Deputy Minister for Communities and Territories Development of Ukraine.</p>
</blockquote>
<h3>Project Implementation and Impact</h3>
<ul>
<li>The procurement will be conducted by the Japanese side, with equipment delivered to Ukrainian cities within the next six months.</li>
<li>The Emergency Recovery and Reconstruction Project is an international technical assistance initiative focused on infrastructure restoration through quick impact projects (QIP).</li>
<li>Since 2023, over USD 700 million in technical and grant assistance from the Government of Japan, coordinated by the Ministry of Development and implemented jointly with JICA, has been provided.</li>
<li>Funds have been allocated to sectors including energy, transport infrastructure, healthcare, education, water supply, humanitarian demining, agro-industrial complex, and municipal facilities.</li>
<li>This comprehensive support advances multiple SDGs such as SDG 3 (Good Health and Well-being), SDG 6 (Clean Water and Sanitation), SDG 7 (Affordable and Clean Energy), and SDG 2 (Zero Hunger).</li>
</ul>
<h3>Conclusion</h3>
<p>The project exemplifies effective international partnership (SDG 17) and contributes significantly to Ukraine’s sustainable recovery and development, enhancing resilience and quality of life in frontline communities.</p>
<h3>Follow the Ministry of Communities and Territories Development of Ukraine</h3>
<ul>
<li><a href="https://www.facebook.com/Ministry.for.development/">Facebook</a></li>
<li><a href="https://x.com/minforuadev?s=21&t=Aaxn7DoX40r2EAZNrgf09Q">Twitter</a></li>
<li><a href="https://t.me/MinDevUA">Telegram</a></li>
<li><a href="https://whatsapp.com/channel/0029VapjxCf4NViry5Apvy3v">WhatsApp</a></li>
</ul>
<h2>1. Sustainable Development Goals (SDGs) Addressed in the Article</h2>
<ol>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong>
<ul>
<li>Focus on rebuilding infrastructure in frontline regions through technical equipment and machinery.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Restoration of municipal services and infrastructure in conflict-affected areas.</li>
</ul>
</li>
<li><strong>SDG 3: Good Health and Well-being</strong>
<ul>
<li>Support to healthcare facilities through equipment provision.</li>
</ul>
</li>
<li><strong>SDG 4: Quality Education</strong>
<ul>
<li>Training and skill development for operators of heavy machinery and students.</li>
</ul>
</li>
<li><strong>SDG 6: Clean Water and Sanitation</strong>
<ul>
<li>Investment in water supply infrastructure.</li>
</ul>
</li>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Support to energy infrastructure.</li>
</ul>
</li>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>Support to the agro-industrial complex.</li>
</ul>
</li>
<li><strong>SDG 16: Peace, Justice and Strong Institutions</strong>
<ul>
<li>Humanitarian demining efforts.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under the Identified SDGs</h2>
<ol>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong>
<ul>
<li>Target 9.1: Develop quality, reliable, sustainable and resilient infrastructure.</li>
<li>Target 9.2: Promote inclusive and sustainable industrialization and, by 2030, significantly raise industry’s share of employment and gross domestic product.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Target 11.3: Enhance inclusive and sustainable urbanization and capacity for participatory, integrated and sustainable human settlement planning and management.</li>
<li>Target 11.5: Reduce the number of deaths and the number of people affected by disasters.</li>
</ul>
</li>
<li><strong>SDG 3: Good Health and Well-being</strong>
<ul>
<li>Target 3.8: Achieve universal health coverage, including financial risk protection and access to quality essential health-care services.</li>
</ul>
</li>
<li><strong>SDG 4: Quality Education</strong>
<ul>
<li>Target 4.4: Increase the number of youth and adults who have relevant skills, including technical and vocational skills, for employment.</li>
</ul>
</li>
<li><strong>SDG 6: Clean Water and Sanitation</strong>
<ul>
<li>Target 6.1: Achieve universal and equitable access to safe and affordable drinking water.</li>
</ul>
</li>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.1: Ensure universal access to affordable, reliable and modern energy services.</li>
</ul>
</li>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>Target 2.3: Double the agricultural productivity and incomes of small-scale food producers.</li>
</ul>
</li>
<li><strong>SDG 16: Peace, Justice and Strong Institutions</strong>
<ul>
<li>Target 16.1: Significantly reduce all forms of violence and related death rates everywhere.</li>
<li>Target 16.6: Develop effective, accountable and transparent institutions at all levels.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied in the Article</h2>
<ol>
<li><strong>Indicators for SDG 9</strong>
<ul>
<li>Number of modular postal hubs established in conflict-affected areas.</li>
<li>Quantity of heavy machinery supplied for infrastructure recovery.</li>
</ul>
</li>
<li><strong>Indicators for SDG 11</strong>
<ul>
<li>Number of municipalities with restored services and infrastructure.</li>
<li>Reduction in service disruptions in frontline regions.</li>
</ul>
</li>
<li><strong>Indicators for SDG 3</strong>
<ul>
<li>Provision and availability of medical equipment in healthcare facilities.</li>
</ul>
</li>
<li><strong>Indicators for SDG 4</strong>
<ul>
<li>Number of students trained with modern equipment and simulators.</li>
<li>Number of training sessions conducted for skill development.</li>
</ul>
</li>
<li><strong>Indicators for SDG 6</strong>
<ul>
<li>Improvements in water supply infrastructure coverage.</li>
</ul>
</li>
<li><strong>Indicators for SDG 7</strong>
<ul>
<li>Investment amounts and projects implemented in energy infrastructure.</li>
</ul>
</li>
<li><strong>Indicators for SDG 2</strong>
<ul>
<li>Support and development projects in the agro-industrial sector.</li>
</ul>
</li>
<li><strong>Indicators for SDG 16</strong>
<ul>
<li>Extent of humanitarian demining operations completed.</li>
<li>Speed and effectiveness of municipal infrastructure recovery.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 9: Industry, Innovation and Infrastructure</td>
<td>
<ul>
<li>9.1: Develop quality, reliable, sustainable and resilient infrastructure.</li>
<li>9.2: Promote inclusive and sustainable industrialization.</li>
</ul>
</td>
<td>
<ul>
<li>Number of modular postal hubs established.</li>
<li>Quantity of heavy machinery supplied.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>
<ul>
<li>11.3: Enhance inclusive and sustainable urbanization.</li>
<li>11.5: Reduce deaths and people affected by disasters.</li>
</ul>
</td>
<td>
<ul>
<li>Number of municipalities with restored services.</li>
<li>Reduction in service disruptions.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 3: Good Health and Well-being</td>
<td>
<ul>
<li>3.8: Achieve universal health coverage.</li>
</ul>
</td>
<td>
<ul>
<li>Provision of medical equipment to healthcare facilities.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 4: Quality Education</td>
<td>
<ul>
<li>4.4: Increase youth and adults with relevant skills.</li>
</ul>
</td>
<td>
<ul>
<li>Number of students trained with simulators and equipment.</li>
<li>Number of training sessions conducted.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 6: Clean Water and Sanitation</td>
<td>
<ul>
<li>6.1: Achieve universal access to safe drinking water.</li>
</ul>
</td>
<td>
<ul>
<li>Improvements in water supply infrastructure.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.1: Ensure universal access to affordable, reliable energy.</li>
</ul>
</td>
<td>
<ul>
<li>Investment and projects in energy infrastructure.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 2: Zero Hunger</td>
<td>
<ul>
<li>2.3: Double agricultural productivity and incomes.</li>
</ul>
</td>
<td>
<ul>
<li>Support projects in agro-industrial complex.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 16: Peace, Justice and Strong Institutions</td>
<td>
<ul>
<li>16.1: Reduce all forms of violence and related deaths.</li>
<li>16.6: Develop effective, accountable institutions.</li>
</ul>
</td>
<td>
<ul>
<li>Humanitarian demining operations completed.</li>
<li>Speed of municipal infrastructure recovery.</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://mindev.gov.ua/news/yaponiia-peredast-66-odynyts-tekhnichnoho-obladnannia-dlia-pryfrontovykh-rehioniv">mindev.gov.ua</a></strong></p>
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<title>Ammonia leak on commercial vessel in north Queen Anne prompts hazmat response – KOMO</title>
<link>https://sdgtalks.ai/ammonia-leak-on-commercial-vessel-in-north-queen-anne-prompts-hazmat-response-komo</link>
<guid>https://sdgtalks.ai/ammonia-leak-on-commercial-vessel-in-north-queen-anne-prompts-hazmat-response-komo</guid>
<description><![CDATA[ Ammonia leak on commercial vessel in north Queen Anne prompts hazmat response  KOMO ]]></description>
<enclosure url="https://komonews.com/resources/media2/16x9/4760/1320/0x535/90/5b6123f5-85c1-470a-b176-f32c97ba4776-Image.jpeg" length="49398" type="image/jpeg"/>
<pubDate>Sat, 28 Feb 2026 19:00:14 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Ammonia, leak, commercial, vessel, north, Queen, Anne, prompts, hazmat, response, –, KOMO</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on Ammonia Leak Incident on Commercial Fishing Vessel in Seattle</h2>
<h3>Incident Overview</h3>
<p>On Friday morning, an ammonia leak was detected on a commercial fishing vessel docked in Seattle, prompting an immediate hazardous materials response by the Seattle Fire Department (SFD). The vessel was located in the 600 block of West Ewing Street in north Queen Anne, near the Ballard Bridge, at the former Foss Maritime shipyard along the Lake Washington Ship Canal.</p>
<h3>Emergency Response Actions</h3>
<ol>
<li>At 8:44 a.m., the Seattle Fire Department evacuated the vessel as a safety precaution to protect personnel and the surrounding community.</li>
<li>Hazardous materials (Hazmat) crews boarded the ship to investigate the source of the ammonia leak.</li>
<li>Efforts were undertaken to shut off valves on the vessel to stop the ammonia leak and mitigate environmental and health risks.</li>
</ol>
<h3>Health and Safety Outcomes</h3>
<ul>
<li>No injuries were reported as a result of the incident.</li>
<li>The prompt evacuation and response minimized potential harm to individuals and the environment.</li>
</ul>
<h2>Alignment with Sustainable Development Goals (SDGs)</h2>
<h3>SDG 3: Good Health and Well-being</h3>
<ul>
<li>The rapid evacuation and intervention by emergency responders ensured the health and safety of the crew and nearby residents, directly supporting SDG 3 by reducing risks associated with hazardous chemical exposure.</li>
</ul>
<h3>SDG 11: Sustainable Cities and Communities</h3>
<ul>
<li>The incident management highlights the importance of resilient infrastructure and emergency preparedness in urban areas, contributing to safer and more sustainable communities.</li>
</ul>
<h3>SDG 12: Responsible Consumption and Production</h3>
<ul>
<li>Proper handling and containment of hazardous substances like ammonia prevent environmental contamination, aligning with responsible production and consumption practices.</li>
</ul>
<h3>SDG 13: Climate Action</h3>
<ul>
<li>Effective hazardous materials management reduces the risk of environmental pollution, supporting climate action efforts by protecting ecosystems and water resources.</li>
</ul>
<h3>SDG 14: Life Below Water</h3>
<ul>
<li>Preventing ammonia leakage into the Lake Washington Ship Canal safeguards aquatic life and water quality, promoting the conservation and sustainable use of marine resources.</li>
</ul>
<h2>Conclusion</h2>
<p>The Seattle Fire Department’s swift response to the ammonia leak on the commercial fishing vessel exemplifies effective emergency management that prioritizes human health, environmental protection, and sustainable urban living. This incident underscores the critical role of coordinated actions in advancing multiple Sustainable Development Goals, particularly those related to health, safety, environmental stewardship, and resilient communities.</p>
<div><img decoding="async" src="https://komonews.com/resources/media2/16x9/4760/1320/0x535/90/5b6123f5-85c1-470a-b176-f32c97ba4776-Image.jpeg" alt="Seattle Fire Department responding to ammonia leak on vessel"></div>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 3: Good Health and Well-being</strong>
<ul>
<li>The article discusses an ammonia leak on a commercial fishing vessel, which is a hazardous event with potential health risks. The response by the Seattle Fire Department to evacuate the vessel and manage the leak relates directly to protecting human health and safety.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>The incident occurred in a city setting (Seattle), involving emergency response to a hazardous material incident, which relates to making cities safe and resilient.</li>
</ul>
</li>
<li><strong>SDG 14: Life Below Water</strong>
<ul>
<li>The leak happened on a vessel docked near a ship canal, posing potential risks to aquatic ecosystems. Managing chemical leaks is important for protecting marine environments.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The handling of hazardous materials and prevention of leaks aligns with sustainable management and reduction of chemical hazards.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 3: Good Health and Well-being</strong>
<ul>
<li><strong>Target 3.9:</strong> “By 2030, substantially reduce the number of deaths and illnesses from hazardous chemicals and air, water and soil pollution and contamination.”</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li><strong>Target 11.5:</strong> “Significantly reduce the number of deaths and the number of people affected and decrease the direct economic losses caused by disasters, including water-related disasters, with a focus on protecting the poor and people in vulnerable situations.”</li>
<li><strong>Target 11.6:</strong> “Reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.”</li>
</ul>
</li>
<li><strong>SDG 14: Life Below Water</strong>
<ul>
<li><strong>Target 14.1:</strong> “By 2025, prevent and significantly reduce marine pollution of all kinds, in particular from land-based activities, including marine debris and nutrient pollution.”</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li><strong>Target 12.4:</strong> “By 2020, achieve the environmentally sound management of chemicals and all wastes throughout their life cycle, in accordance with agreed international frameworks, and significantly reduce their release to air, water and soil in order to minimize their adverse impacts on human health and the environment.”</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>SDG 3, Target 3.9 Indicator:</strong>
<ul>
<li>Mortality rate attributed to unintentional poisoning (Indicator 3.9.1) – The article implies monitoring incidents involving hazardous chemical exposure and injuries or deaths.</li>
</ul>
</li>
<li><strong>SDG 11, Target 11.5 Indicators:</strong>
<ul>
<li>Number of deaths, missing persons and directly affected persons attributed to disasters per 100,000 population (Indicator 11.5.1) – The article mentions no injuries reported, which is relevant to this indicator.</li>
<li>Direct economic loss in relation to global GDP caused by disasters (Indicator 11.5.2) – While not quantified in the article, economic losses from hazardous incidents are relevant.</li>
</ul>
</li>
<li><strong>SDG 14, Target 14.1 Indicator:</strong>
<ul>
<li>Index of coastal eutrophication and floating plastic debris density (Indicator 14.1.1) – The article implies concern for marine pollution from chemical leaks.</li>
</ul>
</li>
<li><strong>SDG 12, Target 12.4 Indicator:</strong>
<ul>
<li>Number of parties to international multilateral environmental agreements on hazardous waste and chemicals and other chemicals that meet their commitments (Indicator 12.4.1) – The article’s hazmat response reflects efforts to manage chemical hazards.</li>
</ul>
</li>
</ol>
<h2>4. Summary Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 3: Good Health and Well-being</td>
<td>Target 3.9: Reduce deaths and illnesses from hazardous chemicals and pollution</td>
<td>Indicator 3.9.1: Mortality rate attributed to unintentional poisoning</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>
        Target 11.5: Reduce deaths and economic losses from disasters<br>
        Target 11.6: Reduce adverse environmental impact of cities
      </td>
<td>
        Indicator 11.5.1: Number of deaths and affected persons from disasters<br>
        Indicator 11.5.2: Direct economic loss caused by disasters
      </td>
</tr>
<tr>
<td>SDG 14: Life Below Water</td>
<td>Target 14.1: Prevent and reduce marine pollution</td>
<td>Indicator 14.1.1: Index of coastal eutrophication and floating plastic debris density</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>Target 12.4: Environmentally sound management of chemicals and wastes</td>
<td>Indicator 12.4.1: Compliance with international agreements on hazardous waste and chemicals</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://komonews.com/news/local/hazmat-ammonia-leak-commercial-boat-vessel-docked-in-ballard-hazardous-materials-evacuation-precaution">komonews.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Enhanced resistance and resilience of anaerobic digestion microbiome after single and dual short&#45;term disturbances – Nature</title>
<link>https://sdgtalks.ai/enhanced-resistance-and-resilience-of-anaerobic-digestion-microbiome-after-single-and-dual-short-term-disturbances-nature</link>
<guid>https://sdgtalks.ai/enhanced-resistance-and-resilience-of-anaerobic-digestion-microbiome-after-single-and-dual-short-term-disturbances-nature</guid>
<description><![CDATA[ Enhanced resistance and resilience of anaerobic digestion microbiome after single and dual short-term disturbances  Nature ]]></description>
<enclosure url="https://media.springernature.com/lw685/springer-static/image/art:10.1038/s41598-025-33212-2/MediaObjects/41598_2025_33212_Fig1_HTML.png" length="49398" type="image/jpeg"/>
<pubDate>Thu, 26 Feb 2026 07:00:20 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Enhanced, resistance, and, resilience, anaerobic, digestion, microbiome, after, single, and, dual, short-term, disturbances, –, Nature</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on Enhancing Anaerobic Digestion Microbiome Resilience through Pulse Disturbances</h2>
<h3>Abstract</h3>
<p>Anaerobic digesters conventionally operate at solids retention times (SRTs) of 20 days or longer to prevent substrate overloading and biomass washout, ensuring the retention of slow-growing methanogens. This study evaluates the impact of short-term pulse disturbances, characterized by temporary SRT reductions and corresponding organic loading rate (OLR) spikes, on microbial resilience and process stabilization during subsequent press disturbances (prolonged SRT reduction). Four mesophilic anaerobic digesters treating wastewater sludge were subjected to one or two pulse disturbances (SRT reduced from 15 to 5 days), followed by sustained operation at 5-day SRT. Results demonstrated that dual pulse disturbances accelerated process recovery (60 days) compared to a single pulse disturbance (104 days), with stabilized volatile fatty acids (VFAs) and methane content. Microbial community dynamics revealed shifts between K-strategists (slow-growing, resource-efficient taxa) and r-strategists (fast-growing, stress-tolerant taxa), underpinning functional redundancy and resilience. This approach offers a practical strategy to enhance microbiome resilience, supporting stable anaerobic digestion under fluctuating substrate conditions, aligning with Sustainable Development Goals (SDGs) such as affordable and clean energy (SDG 7) and responsible consumption and production (SDG 12).</p>
<h2>Introduction</h2>
<p>Anaerobic digestion (AD) is a biological process for organic waste treatment that produces renewable energy through metabolic pathways including hydrolysis, acidogenesis, acetogenesis, and methanogenesis. AD contributes to sustainable waste management by reducing operational costs, sludge production, and nutrient requirements, supporting SDG 12 (Responsible Consumption and Production) and SDG 7 (Affordable and Clean Energy). However, AD is susceptible to process instability caused by sudden changes in operational parameters such as organic loading rate (OLR), solids retention time (SRT), and pH, which can lead to process failure.</p>
<p>Typically, digesters operate at stable SRTs to avoid overloading; however, inadvertent flow or substrate concentration changes can transiently shorten SRT, causing overloading events. Understanding microbial community responses to such disturbances is critical for improving AD robustness. Microbial communities exhibit resistance, resilience, and functional redundancy, concepts essential for ecosystem stability and relevant to SDG 15 (Life on Land).</p>
<p>This study investigates the effects of pulse disturbances (temporary SRT reductions) on AD microbial communities and process performance, hypothesizing that increased pulse disturbance frequency enhances recovery and resilience during subsequent press disturbances.</p>
<h2>Materials and Methods</h2>
<h3>Experimental Design</h3>
<ol>
<li>Four mesophilic anaerobic digesters (R1–R4) with 4.2 L working volume were operated at 35 ± 1 °C.</li>
<li>Seed sludge and substrate comprised a 1:1 volume ratio of thickened primary sludge and waste activated sludge from a municipal wastewater treatment plant.</li>
<li>Digesters R1, R2, and R3 were acclimated at 15-day SRT for 3 months; R4 had an 18-day acclimation due to prior starvation but showed comparable performance.</li>
<li>Pulse disturbances were applied by reducing SRT from 15 to 5 days for 6–7 days, increasing OLR from approximately 5 to 13 g COD/L·d.</li>
<li>Following pulse disturbances, digesters were operated at 15-day SRT, then divided into two groups: Group A (R2, R4) received a single press disturbance (sustained 5-day SRT), and Group B (R1, R3) received a second pulse disturbance followed by a press disturbance.</li>
<li>Process parameters and microbial community dynamics were monitored through physicochemical analyses and 16S rRNA gene sequencing.</li>
</ol>
<h3>Analytical Methods</h3>
<ul>
<li>Measurement of total solids, volatile solids, chemical oxygen demand (COD), volatile fatty acids (VFAs), pH, biogas volume, and composition.</li>
<li>Genomic DNA extraction and 16S rRNA amplicon sequencing for microbial community analysis.</li>
<li>Bioinformatics and statistical analyses including diversity indices, PERMANOVA, and correlation analyses.</li>
</ul>
<h2>Results and Discussion</h2>
<h3>Process Performance under Pulse and Press Disturbances</h3>
<p>Pulse disturbances caused significant increases in acetate and propionate concentrations and a drop in methane content, indicating temporary process instability. Recovery occurred rapidly after returning to 15-day SRT. Dual pulse disturbances resulted in faster recovery during subsequent press disturbances compared to a single pulse disturbance, with stabilized VFAs and methane content around 66%. These findings demonstrate that controlled pulse disturbances can prime microbial communities for enhanced resilience, contributing to stable biogas production and waste treatment efficiency, supporting SDG 7 and SDG 12.</p>
<h3>Microbial Community Dynamics</h3>
<ul>
<li>Bacterial communities were dominated by Firmicutes and Bacteroidetes, while archaeal communities included Methanosaeta, Methanosarcina, and Methanobacterium.</li>
<li>Pulse and press disturbances induced shifts from K-strategists (e.g., Methanosaeta spp.) to r-strategists (e.g., Methanosarcina spp.), reflecting adaptation to stress and high organic loads.</li>
<li>Functional redundancy and resilience within microbial communities minimized process disruptions, enabling stable AD performance despite disturbances.</li>
<li>Dual pulse disturbances accelerated the recovery of key syntrophic bacteria (Syntrophomonas spp., DMER64), facilitating faster VFA degradation and methane production.</li>
</ul>
<h3>Microbial Diversity and Community Structure</h3>
<p>Alpha diversity increased during disturbance periods due to proliferation of stress-tolerant taxa, enhancing functional redundancy and ecosystem stability. Beta diversity analyses revealed distinct microbial community assemblages corresponding to disturbance phases, indicating dynamic community succession. These microbial ecological insights align with SDG 15 by promoting sustainable ecosystem functions within engineered environments.</p>
<h3>Ecological Interpretation via r/K Selection Theory</h3>
<p>Microbial taxa were classified as K-strategists (slow-growing, stable environment specialists) or r-strategists (fast-growing, disturbance-adapted). Disturbances favored r-strategists, which degraded accumulated VFAs and restored favorable conditions for K-strategists, facilitating community resilience and process recovery. This ecological framework informs operational strategies to enhance AD stability and efficiency.</p>
<h3>Implications for Sustainable Development Goals (SDGs)</h3>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong> – Enhanced anaerobic digestion stability improves biogas production, contributing to renewable energy generation.</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong> – Efficient organic waste treatment reduces environmental pollution and resource consumption.</li>
<li><strong>SDG 15: Life on Land</strong> – Understanding microbial community resilience supports sustainable ecosystem management in engineered systems.</li>
</ol>
<h2>Conclusions</h2>
<p>This study demonstrates that implementing short-term pulse disturbances by temporarily reducing SRT can effectively prime anaerobic digestion microbial communities, enhancing their resistance and resilience to subsequent sustained disturbances at low SRTs. Dual pulse disturbances accelerated process recovery and maintained digestate quality with marginal impacts, despite operating at high OLRs. Microbial community shifts between K- and r-strategists underpin functional redundancy critical for stable AD performance. These findings provide a promising operational strategy to improve AD stability and efficiency, advancing sustainable waste management and renewable energy production aligned with the United Nations Sustainable Development Goals.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 6: Clean Water and Sanitation</strong>
<ul>
<li>The article discusses anaerobic digestion (AD) of wastewater sludge, a process related to sustainable wastewater treatment and sanitation.</li>
</ul>
</li>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>AD produces renewable energy in the form of biogas, mainly methane, contributing to clean energy generation.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>By treating organic wastes through AD, the study promotes sustainable waste management and resource recovery.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Enhanced methane production from AD can reduce greenhouse gas emissions by capturing biogas and reducing waste-related emissions.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under the Identified SDGs</h2>
<ol>
<li><strong>SDG 6: Clean Water and Sanitation</strong>
<ul>
<li><em>Target 6.3:</em> Improve water quality by reducing pollution, minimizing release of hazardous chemicals and materials, and substantially increasing recycling and safe reuse globally.</li>
<li>The article’s focus on stable anaerobic digestion of wastewater sludge supports improved wastewater treatment and pollution reduction.</li>
</ul>
</li>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li><em>Target 7.2:</em> Increase substantially the share of renewable energy in the global energy mix.</li>
<li>The study’s investigation into enhancing methane biogas production from AD contributes to renewable energy generation.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li><em>Target 12.5:</em> Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
<li>Use of AD to treat organic waste aligns with reducing waste and promoting recycling of organic matter.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li><em>Target 13.2:</em> Integrate climate change measures into national policies, strategies, and planning.</li>
<li>Improved AD processes that enhance methane capture and reduce emissions contribute to climate change mitigation.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Process Performance Indicators</strong>
<ul>
<li><strong>Methane Content and Yield:</strong> Percentage of methane in biogas and methane volume per gram of COD added, indicating renewable energy production efficiency.</li>
<li><strong>Volatile Fatty Acids (VFA) Concentrations:</strong> Levels of acetate and propionate (mg COD/L) used as indicators of process stability and imbalance.</li>
<li><strong>Volatile Solids (VS) Removal:</strong> Percentage removal of volatile solids, indicating organic matter degradation efficiency.</li>
<li><strong>Chemical Oxygen Demand (COD) Removal:</strong> Total and soluble COD removal percentages, reflecting wastewater treatment effectiveness.</li>
<li><strong>pH and Alkalinity:</strong> Parameters indicating process stability and buffering capacity.</li>
</ul>
</li>
<li><strong>Microbial Community Indicators</strong>
<ul>
<li><strong>Microbial Diversity Indices:</strong> Alpha diversity (second order Hill number, <sup>2</sup>D) and beta diversity (community composition changes) as indicators of microbial community resilience and functional redundancy.</li>
<li><strong>Relative Abundance of Key Taxa:</strong> Changes in abundance of K-strategists (e.g., <i>Cloacimonadaceae W5</i>, <i>Syntrophomonas</i>, <i>Methanosaeta</i>) and r-strategists (e.g., <i>Sedimentibacter</i>, <i>Methanosarcina</i>) to assess microbial community dynamics and stability.</li>
</ul>
</li>
<li><strong>Operational Parameters</strong>
<ul>
<li><strong>Organic Loading Rate (OLR):</strong> Measured in g COD/L·d, used to quantify substrate loading and disturbance intensity.</li>
<li><strong>Solids Retention Time (SRT):</strong> Duration (days) of sludge retention, manipulated to induce pulse and press disturbances.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 6: Clean Water and Sanitation</td>
<td>6.3: Improve water quality by reducing pollution and increasing recycling and safe reuse</td>
<td>
<ul>
<li>COD removal (total and soluble)</li>
<li>Volatile solids (VS) removal</li>
<li>pH and alkalinity levels</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>7.2: Increase substantially the share of renewable energy in the global energy mix</td>
<td>
<ul>
<li>Methane content (%) in biogas</li>
<li>Methane yield (L/g COD added)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse</td>
<td>
<ul>
<li>Organic loading rate (OLR, g COD/L·d)</li>
<li>Solids retention time (SRT, days)</li>
<li>Volatile fatty acids (VFA) concentrations (acetate, propionate in mg COD/L)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>13.2: Integrate climate change measures into national policies, strategies, and planning</td>
<td>
<ul>
<li>Methane production and capture (methane content and yield)</li>
<li>Reduction in volatile fatty acids accumulation indicating process stability</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.nature.com/articles/s41598-025-33212-2">nature.com</a></strong></p>
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<title>New Mexicans Can Get Up To $14,000 For Home Energy Upgrades – Los Alamos Reporter</title>
<link>https://sdgtalks.ai/new-mexicans-can-get-up-to-14000-for-home-energy-upgrades-los-alamos-reporter</link>
<guid>https://sdgtalks.ai/new-mexicans-can-get-up-to-14000-for-home-energy-upgrades-los-alamos-reporter</guid>
<description><![CDATA[ New Mexicans Can Get Up To $14,000 For Home Energy Upgrades  Los Alamos Reporter ]]></description>
<enclosure url="https://i0.wp.com/losalamosreporter.com/wp-content/uploads/2026/02/image-97.png" length="49398" type="image/jpeg"/>
<pubDate>Wed, 25 Feb 2026 19:00:15 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>New, Mexicans, Can, Get, 14, 000, For, Home, Energy, Upgrades, –, Los, Alamos, Reporter</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>New Mexico Launches Energy Efficiency Rebate Program to Support Low-Income Households</h2>
<h3>Introduction</h3>
<p>The New Mexico Energy, Minerals and Natural Resources Department (EMNRD) has initiated a rebate program offering up to $14,000 to assist low-income households in upgrading to energy-efficient appliances and heating and cooling systems. This initiative aligns with the Sustainable Development Goals (SDGs), particularly SDG 7 (Affordable and Clean Energy), SDG 11 (Sustainable Cities and Communities), and SDG 13 (Climate Action), by promoting energy efficiency and reducing carbon emissions.</p>
<h3>Program Overview</h3>
<ol>
<li><strong>Eligibility Criteria</strong>
<ul>
<li>Applicants must be New Mexico homeowners or renters.</li>
<li>Income must be less than 80% of the median income for their area or participants in certain federal benefit programs.</li>
</ul>
</li>
<li><strong>Application Process</strong>
<ul>
<li>EMNRD certifies eligibility.</li>
<li>Applicants receive coupons convertible into instant rebates on qualifying energy-saving products.</li>
</ul>
</li>
<li><strong>Program Goals</strong>
<ul>
<li>Reduce household energy costs.</li>
<li>Cut carbon emissions in line with SDG 13.</li>
<li>Enhance home comfort and energy efficiency.</li>
</ul>
</li>
</ol>
<h3>Benefits and Impact</h3>
<ul>
<li>Rebates make energy-efficient upgrades more affordable, supporting SDG 1 (No Poverty) by reducing utility expenses for low-income families.</li>
<li>Heat pumps provide dual heating and cooling functions, improving energy conservation (SDG 7).</li>
<li>Case Study: Billy Martin of Portales utilized the rebates to install new insulation, replace his HVAC system with a heat pump, and purchase energy-efficient appliances, resulting in significant energy cost savings and improved home comfort.</li>
<li>Mr. Martin emphasized the program’s role in enabling him to remain in his home independently, highlighting social sustainability aspects (SDG 11).</li>
</ul>
<h3>Partnerships and Support</h3>
<ul>
<li>EMNRD’s Energy Conservation and Management Division (ECAM) administers the program.</li>
<li>Licensed HVAC contractors partner with ECAM to assist homeowners in selecting appropriate systems and ensuring quality installation.</li>
<li>Funding is provided by the U.S. Department of Energy’s Home Efficiency Assistance Rebate (HEAR) program, supporting national clean energy objectives.</li>
</ul>
<h3>Additional Information</h3>
<ul>
<li>Full program details, including eligibility, qualifying products, and application instructions, are available at <a href="https://clean.energy.nm.gov/programs/hear" target="_blank" rel="noreferrer noopener">https://clean.energy.nm.gov/programs/hear</a>.</li>
<li>A video featuring Billy Martin’s experience can be viewed <a href="https://www.youtube.com/watch?v=5DI6f2LgoKQ" target="_blank" rel="noreferrer noopener">here</a>.</li>
</ul>
<h2>1. Sustainable Development Goals (SDGs) Addressed</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses providing rebates for energy-efficient appliances and heating/cooling systems, promoting access to affordable and clean energy solutions for low-income households.</li>
</ul>
</li>
<li><strong>SDG 1: No Poverty</strong>
<ul>
<li>By targeting low-income households and reducing their utility bills, the program helps alleviate energy poverty and supports economic stability.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>The program aims to cut carbon emissions by encouraging energy efficiency upgrades, contributing to climate change mitigation efforts.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Improving home energy efficiency enhances living conditions and sustainability in communities.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under the Identified SDGs</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.1: By 2030, ensure universal access to affordable, reliable, and modern energy services.</li>
<li>Target 7.3: By 2030, double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 1: No Poverty</strong>
<ul>
<li>Target 1.2: By 2030, reduce at least by half the proportion of men, women and children living in poverty in all its dimensions according to national definitions.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.2: Integrate climate change measures into national policies, strategies, and planning.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Target 11.1: By 2030, ensure access for all to adequate, safe and affordable housing and basic services.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Energy Efficiency Improvements</strong>
<ul>
<li>Number or proportion of households receiving rebates for energy-efficient appliances and heating/cooling systems.</li>
<li>Reduction in monthly utility bills for participating households, indicating improved energy affordability.</li>
</ul>
</li>
<li><strong>Carbon Emissions Reduction</strong>
<ul>
<li>Decrease in household carbon emissions due to adoption of energy-efficient technologies.</li>
</ul>
</li>
<li><strong>Access to Energy Services</strong>
<ul>
<li>Proportion of low-income households with access to energy-efficient appliances and improved heating/cooling systems.</li>
</ul>
</li>
<li><strong>Program Participation and Eligibility</strong>
<ul>
<li>Number of applicants certified eligible and receiving rebates under the program.</li>
</ul>
</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.1: Universal access to affordable, reliable, modern energy services</li>
<li>7.3: Double the rate of improvement in energy efficiency</li>
</ul>
</td>
<td>
<ul>
<li>Number/proportion of households receiving energy-efficiency rebates</li>
<li>Reduction in monthly utility bills</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 1: No Poverty</td>
<td>
<ul>
<li>1.2: Reduce by half the proportion of people living in poverty</li>
</ul>
</td>
<td>
<ul>
<li>Number of low-income households benefiting from energy cost reductions</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.2: Integrate climate change measures into policies and planning</li>
</ul>
</td>
<td>
<ul>
<li>Reduction in household carbon emissions due to energy-efficient upgrades</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>
<ul>
<li>11.1: Access to adequate, safe, and affordable housing and basic services</li>
</ul>
</td>
<td>
<ul>
<li>Improved home comfort and sustainability through energy-efficient installations</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://losalamosreporter.com/2026/02/25/new-mexicans-can-get-up-to-14000-for-home-energy-upgrades/">losalamosreporter.com</a></strong></p>
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<title>Amazon: The Future of Education for Sustainable Development – Inter&#45;American Development Bank</title>
<link>https://sdgtalks.ai/amazon-the-future-of-education-for-sustainable-development-inter-american-development-bank</link>
<guid>https://sdgtalks.ai/amazon-the-future-of-education-for-sustainable-development-inter-american-development-bank</guid>
<description><![CDATA[ Amazon: The Future of Education for Sustainable Development  Inter-American Development Bank ]]></description>
<enclosure url="https://www.iadb.org/sites/default/files/2026-01/educlimate.jpeg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 22 Feb 2026 04:00:16 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Amazon:, The, Future, Education, for, Sustainable, Development, –, Inter-American, Development, Bank</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Strengthening Sustainability Education at COP30</h2>
<p>The COP30 conference provided a strategic platform to enhance sustainability education by bringing together governments, international agencies, and civil society organizations. The central focus was on developing competencies that enable students to understand the reciprocal relationship between human actions and climate change, as well as the impact of climate on people’s lives and ecosystems. This initiative aligns closely with several Sustainable Development Goals (SDGs), particularly SDG 4 (Quality Education), SDG 13 (Climate Action), and SDG 15 (Life on Land).</p>
<h3>OECD’s Pilot Climate and Environmental Literacy Assessment</h3>
<p>In collaboration with the Pará State Education Department (SEDUC-PA), the Organization for Economic Cooperation and Development (OECD) implemented a pilot climate and environmental literacy assessment through its Programme for International Student Assessment (PISA). Key details include:</p>
<ol>
<li>Location: Pará State, Brazil, within the Amazon region</li>
<li>Participants: 90 public schools involving approximately 16,000 students</li>
<li>Objective: To evaluate students’ knowledge, skills, values, and behaviors related to climate and environmental issues</li>
</ol>
<p>This pilot represents the first of its kind in the Amazon and is expected to provide foundational data for future international PISA assessments. It supports the integration of green citizenship into educational curricula, contributing to SDG 4 by promoting inclusive and equitable quality education and lifelong learning opportunities.</p>
<h3>Assessment Goals and Impact on Sustainable Development</h3>
<ul>
<li><strong>Knowledge Development:</strong> Measuring students’ understanding of climate science and environmental challenges.</li>
<li><strong>Skill Enhancement:</strong> Assessing critical thinking and problem-solving abilities related to sustainability.</li>
<li><strong>Value Formation:</strong> Encouraging attitudes that support environmental stewardship and responsible citizenship.</li>
<li><strong>Behavioral Adaptation:</strong> Evaluating actions students take to address climate change and promote sustainability.</li>
</ul>
<p>According to the <a href="https://www.oecd.org/content/dam/oecd/en/publications/reports/2024/11/ClimateBrochure_Nov2024_FIN.pdf">OECD report</a>, these assessments aim to identify the level of environmental competencies among students, ensuring they are equipped to face current and future climate challenges. This initiative directly supports SDG 13 by fostering climate action through education and SDG 17 (Partnerships for the Goals) by exemplifying collaboration between international organizations and local governments.</p>
<h2>1. Which SDGs are addressed or connected to the issues highlighted in the article?</h2>
<ol>
<li><strong>SDG 4: Quality Education</strong> – The article focuses on strengthening sustainability education and developing competencies among students related to climate and environmental literacy.</li>
<li><strong>SDG 13: Climate Action</strong> – The emphasis on understanding human impact on climate and the effects on ecosystems aligns with climate action goals.</li>
<li><strong>SDG 15: Life on Land</strong> – The article’s context in the Amazon region and focus on ecosystems relates to the protection and sustainable use of terrestrial ecosystems.</li>
</ol>
<h2>2. What specific targets under those SDGs can be identified based on the article’s content?</h2>
<ol>
<li><strong>SDG 4 – Target 4.7:</strong> Ensure that all learners acquire knowledge and skills needed to promote sustainable development, including education for sustainable development and sustainable lifestyles, human rights, gender equality, promotion of a culture of peace and non-violence, global citizenship, and appreciation of cultural diversity.</li>
<li><strong>SDG 13 – Target 13.3:</strong> Improve education, awareness-raising and human and institutional capacity on climate change mitigation, adaptation, impact reduction, and early warning.</li>
<li><strong>SDG 15 – Target 15.1:</strong> Ensure the conservation, restoration and sustainable use of terrestrial and inland freshwater ecosystems and their services.</li>
</ol>
<h2>3. Are there any indicators mentioned or implied in the article that can be used to measure progress towards the identified targets?</h2>
<ol>
<li>The article mentions the <strong>OECD’s Programme for International Student Assessment (PISA)</strong> pilot climate and environmental literacy assessment, which serves as an indicator to measure students’ knowledge, skills, values, and behaviors related to climate challenges.</li>
<li>The assessment results from the <strong>90 public schools in Pará State</strong> provide data to measure progress in environmental competencies among students, which can be linked to Target 4.7 and 13.3.</li>
<li>Implied indicators include:
<ul>
<li>Level of development in environmental knowledge and skills among students.</li>
<li>Behavioral adaptation to climate challenges.</li>
<li>Incorporation of green citizenship into educational agendas.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 4: Quality Education</td>
<td>4.7: Ensure all learners acquire knowledge and skills for sustainable development including education for sustainable lifestyles and global citizenship.</td>
<td>OECD PISA climate and environmental literacy assessment results measuring students’ knowledge, skills, values, and behaviors.</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>13.3: Improve education, awareness-raising and human and institutional capacity on climate change mitigation, adaptation, impact reduction, and early warning.</td>
<td>Data from PISA pilot assessment on environmental competencies; indicators of awareness and behavioral adaptation to climate challenges.</td>
</tr>
<tr>
<td>SDG 15: Life on Land</td>
<td>15.1: Ensure conservation, restoration and sustainable use of terrestrial ecosystems and their services.</td>
<td>Implied measurement through educational focus on ecosystems in the Amazon region and incorporation of green citizenship concepts.</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.iadb.org/en/blog/education/amazon-future-education-sustainable-development">iadb.org</a></strong></p>
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<title>State penalizes Seattle Barrel Company after finding hazardous waste failures – KOMO</title>
<link>https://sdgtalks.ai/state-penalizes-seattle-barrel-company-after-finding-hazardous-waste-failures-komo</link>
<guid>https://sdgtalks.ai/state-penalizes-seattle-barrel-company-after-finding-hazardous-waste-failures-komo</guid>
<description><![CDATA[ State penalizes Seattle Barrel Company after finding hazardous waste failures  KOMO ]]></description>
<enclosure url="https://komonews.com/resources/media2/16x9/815/1320/194x221/90/80613193-3070-4b64-8ab3-64d5802484bd-AP19352804482955.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sat, 14 Feb 2026 22:00:13 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>State, penalizes, Seattle, Barrel, Company, after, finding, hazardous, waste, failures, –, KOMO</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on Environmental Violations and Penalties at Seattle Barrel Company</h2>
<h3>Introduction</h3>
<p>The Washington Department of Ecology has imposed a fine of $150,000 on Seattle Barrel Company for improper management of dangerous waste. This action highlights critical concerns related to environmental protection and aligns with several Sustainable Development Goals (SDGs), particularly SDG 6 (Clean Water and Sanitation), SDG 12 (Responsible Consumption and Production), and SDG 15 (Life on Land).</p>
<h3>Background and Violations</h3>
<ol>
<li><strong>Company Profile:</strong> Seattle Barrel Company refurbishes and recycles used steel and plastic drums that previously contained petroleum products, solvents, paints, inks, and food-grade fats and oils.</li>
<li><strong>Waste Generated:</strong> Waste products include wash water, wastewater evaporator sludge, absorbent pads, and filters.</li>
<li><strong>Inspection Findings (February 2025):</strong>
<ul>
<li>Failure to document proper identification of hazardous waste.</li>
<li>Inadequate tracking of waste through the disposal process.</li>
<li>Unsafe storage of hazardous materials.</li>
<li>Lack of required emergency plans and employee training.</li>
</ul>
</li>
<li><strong>Compliance Issues:</strong> Some violations were corrected; however, others remained unaddressed. The company did not comply with a legal order issued in August 2025 requiring full compliance within 30 days.</li>
</ol>
<h3>Previous Enforcement Actions</h3>
<ul>
<li>2014: Initial fine imposed by the Department of Ecology.</li>
<li>2017: Legal order issued for compliance.</li>
<li>2023: Federal court sentencing of the company (then Seattle Barrel and Cooperage Company) and its owner, Louie Sanft, for conspiracy, false statements, and 33 Clean Water Act violations related to dumping highly caustic wastewater into the sewer system.</li>
<li>Penalties included:
<ul>
<li>Owner Louie Sanft sentenced to 18 months in prison and fined $250,000.</li>
<li>Company placed on five years of probation.</li>
</ul>
</li>
</ul>
<h3>Implications for Sustainable Development Goals (SDGs)</h3>
<ol>
<li><strong>SDG 6: Clean Water and Sanitation</strong>
<ul>
<li>Improper disposal of hazardous wastewater threatens water quality and ecosystem health.</li>
<li>Enforcement actions aim to prevent water pollution and promote sustainable water management.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Proper hazardous waste management is essential for sustainable industrial practices.</li>
<li>Training employees and maintaining emergency plans support responsible production processes.</li>
</ul>
</li>
<li><strong>SDG 15: Life on Land</strong>
<ul>
<li>Preventing hazardous waste contamination protects terrestrial ecosystems and biodiversity.</li>
</ul>
</li>
<li><strong>SDG 16: Peace, Justice, and Strong Institutions</strong>
<ul>
<li>Legal enforcement and penalties reinforce accountability and environmental justice.</li>
</ul>
</li>
</ol>
<h3>Conclusion</h3>
<p>The $150,000 fine against Seattle Barrel Company underscores the importance of strict adherence to hazardous waste management regulations to safeguard environmental and public health. Continuous monitoring, compliance with legal orders, and alignment with Sustainable Development Goals are critical to achieving sustainable industrial operations and protecting natural resources.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 6: Clean Water and Sanitation</strong> – The article discusses violations related to dumping caustic wastewater and improper hazardous waste management, impacting water quality and sanitation.</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong> – The company refurbishes and recycles barrels, but fails in managing hazardous waste responsibly, highlighting issues in sustainable production and waste management.</li>
<li><strong>SDG 3: Good Health and Well-being</strong> – Improper handling of hazardous waste and lack of emergency training pose risks to workers’ health and community well-being.</li>
<li><strong>SDG 16: Peace, Justice, and Strong Institutions</strong> – Enforcement actions, legal orders, and penalties reflect governance and rule of law in environmental regulation.</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 6 – Target 6.3:</strong> Improve water quality by reducing pollution, minimizing release of hazardous chemicals and materials, and substantially increasing recycling and safe reuse globally.</li>
<li><strong>SDG 12 – Target 12.4:</strong> Achieve environmentally sound management of chemicals and all wastes throughout their life cycle to minimize adverse impacts on human health and the environment.</li>
<li><strong>SDG 3 – Target 3.9:</strong> Substantially reduce the number of deaths and illnesses from hazardous chemicals and air, water, and soil pollution and contamination.</li>
<li><strong>SDG 16 – Target 16.3:</strong> Promote the rule of law at the national and international levels and ensure equal access to justice for all.</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ul>
<li><strong>Indicator for SDG 6.3:</strong> Proportion of wastewater safely treated; reduction in hazardous waste discharge into water bodies.</li>
<li><strong>Indicator for SDG 12.4:</strong> Number of parties to international multilateral environmental agreements on hazardous waste and chemicals that meet their commitments; compliance rates with hazardous waste management regulations.</li>
<li><strong>Indicator for SDG 3.9:</strong> Mortality rate attributed to unsafe water, unsafe sanitation, and lack of hygiene; incidence of illnesses related to hazardous chemical exposure.</li>
<li><strong>Indicator for SDG 16.3:</strong> Proportion of victims of violence who report their victimization to competent authorities; number of enforcement actions and legal penalties issued for environmental violations.</li>
</ul>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 6: Clean Water and Sanitation</td>
<td>Target 6.3: Improve water quality by reducing pollution and hazardous materials release.</td>
<td>Proportion of wastewater safely treated; reduction in hazardous waste discharge into water bodies.</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>Target 12.4: Environmentally sound management of chemicals and wastes throughout their life cycle.</td>
<td>Compliance rates with hazardous waste management regulations; number of parties meeting hazardous waste agreements.</td>
</tr>
<tr>
<td>SDG 3: Good Health and Well-being</td>
<td>Target 3.9: Reduce deaths and illnesses from hazardous chemicals and pollution.</td>
<td>Mortality rate from unsafe water and chemical exposure; incidence of related illnesses.</td>
</tr>
<tr>
<td>SDG 16: Peace, Justice, and Strong Institutions</td>
<td>Target 16.3: Promote rule of law and ensure equal access to justice.</td>
<td>Number of enforcement actions and legal penalties for environmental violations; reporting rates of violations.</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://komonews.com/news/local/seattle-barrel-company-ecology-fine-seattle-barrel-company-waste-water-environmental-reporting-dangerous-waste-washington-state-puget-sound">komonews.com</a></strong></p>
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<title>Visitor Center Improvements Aim to Increase Energy Efficiency – Maine Audubon</title>
<link>https://sdgtalks.ai/visitor-center-improvements-aim-to-increase-energy-efficiency-maine-audubon</link>
<guid>https://sdgtalks.ai/visitor-center-improvements-aim-to-increase-energy-efficiency-maine-audubon</guid>
<description><![CDATA[ Visitor Center Improvements Aim to Increase Energy Efficiency  Maine Audubon ]]></description>
<enclosure url="https://i0.wp.com/maineaudubon.org/wp-content/uploads/20260130_GFAC_VisitorCenter.jpg" length="49398" type="image/jpeg"/>
<pubDate>Wed, 04 Feb 2026 04:00:17 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Visitor, Center, Improvements, Aim, Increase, Energy, Efficiency, –, Maine, Audubon</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Gilsland Farm Audubon Center Expansion and Renovation Report</h2>
<h3>Introduction</h3>
<p>The Gilsland Farm Audubon Center in Falmouth is undergoing significant development and renovation to enhance its conservation efforts and community engagement. These initiatives strongly align with the United Nations Sustainable Development Goals (SDGs), particularly SDG 11 (Sustainable Cities and Communities), SDG 13 (Climate Action), SDG 15 (Life on Land), and SDG 7 (Affordable and Clean Energy).</p>
<h3>New Facilities and Conservation Efforts</h3>
<p>In May 2026, the center will inaugurate the <strong>Ann and Jim Hancock Native Plants Education Center</strong>, which will:</p>
<ul>
<li>Expand capacity for conservation horticulture and native plant restoration (SDG 15)</li>
<li>Create additional programming space for education and community engagement (SDG 4 – Quality Education)</li>
<li>Serve as a community gathering place (SDG 11)</li>
</ul>
<p>Adjacent to this, the new <strong>Stewardship Annex</strong> will provide:</p>
<ul>
<li>Storage and workspace for seasonal teams protecting coastal birds and Common Loons (SDG 15)</li>
<li>Facilities for stewardship equipment used across state sanctuaries</li>
</ul>
<h3>Visitor Center Renovation and Energy Efficiency Upgrades</h3>
<p>Since October 2025, renovation work has been underway on the <strong>Visitor Center</strong>, focusing on enhancing building performance and sustainability. Key improvements include:</p>
<ol>
<li>Replacement of the HVAC system with energy-efficient air source heat pumps (SDG 7)</li>
<li>Upgraded building ventilation systems</li>
<li>Installation of significant insulation above the ceiling</li>
<li>Roof replacement</li>
<li>Planned replacement of cedar shingle siding with added exterior wood fiber board insulation sourced locally from Timber HP, reducing environmental footprint compared to conventional materials (SDG 12 – Responsible Consumption and Production)</li>
<li>Installation of high-efficiency triple-pane windows and bird-safe window treatments to protect local avian species (SDG 15)</li>
</ol>
<p>These renovations represent a deep energy retrofit aimed at increasing energy efficiency and incorporating sustainable building technologies, continuing the center’s legacy of green design since its original opening in 1996.</p>
<h3>Renewable Energy Expansion</h3>
<p>In addition to reducing energy consumption, Maine Audubon is increasing renewable energy production on campus by installing new solar arrays on the Native Plants Education Center and Stewardship Annex. These arrays are projected to generate an additional 60,000 kWh annually, further decreasing reliance on external energy sources and supporting SDG 7 (Affordable and Clean Energy) and SDG 13 (Climate Action).</p>
<h3>Project Timeline and Community Impact</h3>
<ul>
<li>Majority of construction and renovation work is scheduled for completion before summer 2026</li>
<li>Temporary closures and restricted access to the Visitor Center during renovation</li>
<li>Efforts to maintain winter and spring programming with minimal disruption to the Nature Store, which will remain largely open</li>
</ul>
<h3>Partnerships and Collaboration</h3>
<p>The project is supported by key partners including Kaplan Thompson Architects, Mathew Alcorn Builders, Bruss Project Management, Petersen Engineering, and Atlantic Comfort Systems, exemplifying collaborative efforts towards sustainable development.</p>
<h3>Conclusion</h3>
<p>These developments at Gilsland Farm Audubon Center demonstrate a strong commitment to advancing the Sustainable Development Goals by promoting environmental stewardship, sustainable infrastructure, renewable energy, and community education. The center is poised to continue serving as a vital hub for conservation and sustainability in Maine for decades to come.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong> – The article discusses upgrading the Visitor Center with energy-efficient systems such as air source heat pumps, improved insulation, and solar arrays to reduce energy consumption and increase renewable energy production.</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong> – Renovation of the Visitor Center and construction of new facilities aim to create more sustainable, energy-efficient, and bird-friendly community spaces.</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong> – Use of sustainable building materials like wood fiber board insulation and recycled steel reflects responsible consumption and production practices.</li>
<li><strong>SDG 13: Climate Action</strong> – The deep energy retrofit and renewable energy installations contribute to reducing greenhouse gas emissions and combating climate change.</li>
<li><strong>SDG 15: Life on Land</strong> – Conservation horticulture, native plant restoration, and protection of coastal birds and Common Loons highlight efforts to preserve terrestrial ecosystems and biodiversity.</li>
</ol>
<h2>2. Specific Targets Under Those SDGs</h2>
<ol>
<li><strong>SDG 7</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
<li>Target 7.3: Double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 11</strong>
<ul>
<li>Target 11.6: Reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.</li>
<li>Target 11.7: Provide universal access to safe, inclusive, and accessible green and public spaces.</li>
</ul>
</li>
<li><strong>SDG 12</strong>
<ul>
<li>Target 12.2: Achieve the sustainable management and efficient use of natural resources.</li>
<li>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
</ul>
</li>
<li><strong>SDG 13</strong>
<ul>
<li>Target 13.1: Strengthen resilience and adaptive capacity to climate-related hazards and natural disasters.</li>
<li>Target 13.2: Integrate climate change measures into policies and planning.</li>
</ul>
</li>
<li><strong>SDG 15</strong>
<ul>
<li>Target 15.1: Ensure the conservation, restoration, and sustainable use of terrestrial and inland freshwater ecosystems and their services.</li>
<li>Target 15.5: Take urgent and significant action to reduce the degradation of natural habitats and halt the loss of biodiversity.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Energy Efficiency and Renewable Energy Indicators</strong>
<ul>
<li>Amount of electricity produced by solar arrays (e.g., additional 60,000 kWh/year from new installations).</li>
<li>Energy consumption reduction through HVAC upgrades and insulation improvements (implied through system replacements and insulation “r value” increases).</li>
</ul>
</li>
<li><strong>Building Sustainability Indicators</strong>
<ul>
<li>Use of sustainable materials such as wood fiber board insulation and recycled steel.</li>
<li>Implementation of bird-friendly architectural features (implied as a measure of environmental impact mitigation).</li>
</ul>
</li>
<li><strong>Conservation and Biodiversity Indicators</strong>
<ul>
<li>Protection efforts for coastal birds and Common Loons (implied through stewardship activities).</li>
<li>Expansion of native plant restoration and conservation horticulture capacity.</li>
</ul>
</li>
<li><strong>Community Engagement Indicators</strong>
<ul>
<li>Increased programming space and community gathering areas (implied measure of social sustainability and inclusion).</li>
</ul>
</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy</li>
<li>7.3: Double rate of energy efficiency improvement</li>
</ul>
</td>
<td>
<ul>
<li>Electricity produced by solar arrays (e.g., 60,000 kWh/year)</li>
<li>Energy consumption reduction from HVAC and insulation upgrades</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>
<ul>
<li>11.6: Reduce environmental impact of cities</li>
<li>11.7: Provide access to green and public spaces</li>
</ul>
</td>
<td>
<ul>
<li>Implementation of bird-friendly architectural features</li>
<li>Increased community programming and gathering spaces</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.2: Sustainable management of natural resources</li>
<li>12.5: Reduce waste generation</li>
</ul>
</td>
<td>
<ul>
<li>Use of sustainable building materials (wood fiber board, recycled steel)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.1: Strengthen resilience to climate hazards</li>
<li>13.2: Integrate climate measures into planning</li>
</ul>
</td>
<td>
<ul>
<li>Energy retrofit reducing greenhouse gas emissions (implied)</li>
<li>Renewable energy installations</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 15: Life on Land</td>
<td>
<ul>
<li>15.1: Conservation and restoration of terrestrial ecosystems</li>
<li>15.5: Reduce degradation and biodiversity loss</li>
</ul>
</td>
<td>
<ul>
<li>Protection of coastal birds and Common Loons</li>
<li>Expansion of native plant restoration programs</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://maineaudubon.org/news/visitor-center-improvements-aim-to-increase-energy-efficiency/">maineaudubon.org</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Sandworm’s DynoWiper Attack Targeting Polish Combined Heat and Power and Renewable Energy Management Systems: Incident Analysis and Lessons Learned – Rescana</title>
<link>https://sdgtalks.ai/sandworms-dynowiper-attack-targeting-polish-combined-heat-and-power-and-renewable-energy-management-systems-incident-analysis-and-lessons-learned-rescana</link>
<guid>https://sdgtalks.ai/sandworms-dynowiper-attack-targeting-polish-combined-heat-and-power-and-renewable-energy-management-systems-incident-analysis-and-lessons-learned-rescana</guid>
<description><![CDATA[ Sandworm’s DynoWiper Attack Targeting Polish Combined Heat and Power and Renewable Energy Management Systems: Incident Analysis and Lessons Learned  Rescana ]]></description>
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<pubDate>Sun, 01 Feb 2026 16:00:18 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Sandworm’s, DynoWiper, Attack, Targeting, Polish, Combined, Heat, and, Power, and, Renewable, Energy, Management, Systems:, Incident, Analysis, and, Lessons, Learned, –, Rescana</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Executive Summary</h2>
<p>In December 2025, the Polish energy sector experienced a sophisticated cyberattack attributed to the Russian state-sponsored advanced persistent threat (APT) group <strong>Sandworm</strong>. The attack utilized a newly identified data-wiping malware named <strong>DynoWiper</strong> targeting critical energy infrastructure, including combined heat and power (CHP) plants and renewable energy management systems. Despite the advanced nature of the attack, Polish authorities and security teams successfully detected and mitigated the threat before any operational impact occurred. This report provides a detailed technical analysis of the incident, the threat actor’s profile, their tactics, techniques, and procedures (TTPs), and actionable mitigation strategies for organizations in critical infrastructure sectors. The incident highlights the importance of safeguarding sustainable energy systems, aligning with the United Nations Sustainable Development Goals (SDGs), particularly SDG 7 (Affordable and Clean Energy) and SDG 9 (Industry, Innovation, and Infrastructure).</p>
<h2>Threat Actor Profile</h2>
<p><strong>Sandworm</strong> is a notorious Russian APT group, also known as APT44, UAC-0113, Seashell Blizzard, and Voodoo Bear. Believed to operate under the Russian GRU (Main Intelligence Directorate), Sandworm has a history of targeting critical infrastructure in Ukraine and Europe. Their operations include the 2015 and 2016 Ukrainian power grid attacks using BlackEnergy and Industroyer malware, the 2017 NotPetya ransomware/wiper campaign, and multiple wiper attacks during the ongoing Russia-Ukraine conflict. The group’s focus on destructive malware and high-impact, politically motivated operations poses significant risks to critical infrastructure, threatening SDG 16 (Peace, Justice, and Strong Institutions) by undermining security and stability.</p>
<h2>Technical Analysis of Malware and Tactics, Techniques, and Procedures (TTPs)</h2>
<p>The primary malware used in the December 2025 attack was <strong>DynoWiper</strong>, detected by ESET as <strong>Win32/KillFiles.NMO</strong>. This data-wiping tool irreversibly destroys files and disables Windows-based systems by deleting files and corrupting system components, effectively bricking targeted hosts. This method is consistent with previous Sandworm wiper campaigns such as KillDisk, HermeticWiper, and CaddyWiper.</p>
<p>The initial access vector remains undisclosed; however, based on Sandworm’s historical TTPs, likely methods include spear-phishing, exploitation of public-facing applications, and use of stolen credentials. Once inside, DynoWiper was deployed across operational technology (OT) and information technology (IT) systems to maximize disruption.</p>
<p>The attack coincided with the 10th anniversary of Sandworm’s 2015 attack on Ukraine’s power grid, indicating symbolic intent and a demonstration of ongoing capability.</p>
<h3>Key MITRE ATT&CK Techniques Observed or Suspected</h3>
<ol>
<li>T1485 – Data Destruction</li>
<li>T1561 – Disk Wipe</li>
<li>T1204 – User Execution</li>
<li>T1190 – Exploit Public-Facing Application</li>
<li>T1078 – Valid Accounts</li>
</ol>
<h2>Exploitation in the Wild</h2>
<p>The December 2025 attack on Poland’s energy sector was unsuccessful but forms part of a broader pattern of Sandworm activity targeting European critical infrastructure. Throughout 2025, Sandworm conducted multiple wiper attacks in Ukraine using malware families such as PathWiper, HermeticWiper, ZEROLOT, and Sting against government, energy, logistics, and agricultural sectors. The attempted attack on Poland represents a significant escalation, extending destructive operations beyond Ukraine into the European Union.</p>
<p>The Polish incident specifically targeted two CHP plants and a management system for wind and photovoltaic farms. Thanks to robust monitoring and incident response capabilities, the attack was detected and contained before operational disruption occurred. This incident underscores the critical need to protect sustainable energy infrastructure, supporting SDG 7 (Affordable and Clean Energy) and SDG 13 (Climate Action) by ensuring resilience of renewable energy systems.</p>
<h2>Victimology and Targeting</h2>
<p>The primary victims were entities within Poland’s energy sector, particularly operators of combined heat and power plants and renewable energy management systems. This targeting aligns with Sandworm’s strategic objective to undermine critical infrastructure for geopolitical aims. The timing, coinciding with the anniversary of the 2015 Ukrainian blackout, suggests a message to Poland and the broader European community regarding Sandworm’s capabilities and willingness to escalate.</p>
<p>Historically focused on Ukraine, Sandworm’s recent campaigns indicate an expanded scope to other European countries, especially those supporting Ukraine or opposing Russian interests. Targeting both traditional and renewable energy assets demonstrates an understanding of the evolving energy landscape and a willingness to disrupt legacy and modern infrastructure alike. This poses challenges to achieving SDG 7 (Affordable and Clean Energy) and SDG 9 (Industry, Innovation, and Infrastructure).</p>
<h2>Mitigation and Countermeasures</h2>
<p>Organizations operating in critical infrastructure sectors should adopt a multi-layered defense strategy to mitigate risks posed by Sandworm and similar threat actors. Key recommendations include:</p>
<ul>
<li><strong>Network Segmentation:</strong> Isolate critical OT and IT systems from business networks and the public internet to reduce attack surfaces and limit lateral movement.</li>
<li><strong>Endpoint Protection:</strong> Deploy and regularly update endpoint protection solutions to detect and block wiper malware, including signatures for Win32/KillFiles.NMO and related threats.</li>
<li><strong>Incident Response Planning:</strong> Review and test incident response plans with specific scenarios for destructive malware and wiper attacks to ensure rapid containment and recovery.</li>
<li><strong>User Awareness Training:</strong> Conduct training to reduce risks from spear-phishing and social engineering, common initial access vectors for APT groups.</li>
<li><strong>Patch Management:</strong> Implement rigorous patch management with prompt application of security updates, especially for internet-exposed systems.</li>
<li><strong>Access Controls:</strong> Enforce least privilege principles and monitor for anomalous account activity indicating credential compromise.</li>
</ul>
<p>Additionally, organizations should monitor for indicators of compromise (IOCs) associated with DynoWiper and other Sandworm tools, including the SHA-1 hash <code>4EC3C90846AF6B79EE1A5188EEFA3FD21F6D4CF6</code> and the ESET detection name <strong>Win32/KillFiles.NMO</strong>. Collaboration with national cybersecurity authorities and participation in information sharing initiatives can enhance situational awareness and collective defense. These measures contribute to SDG 16 (Peace, Justice, and Strong Institutions) by strengthening institutional resilience and security.</p>
<h2>References</h2>
<p>Technical and threat intelligence sources related to this report are available upon request.</p>
<h2>About Rescana</h2>
<p>Rescana is a leader in third-party risk management (TPRM), providing organizations with a comprehensive platform to assess, monitor, and mitigate cyber risks across their supply chains and critical infrastructure. Our advanced threat intelligence and risk management solutions empower clients to proactively defend against emerging threats and ensure operational resilience. This commitment supports multiple Sustainable Development Goals by promoting secure, resilient, and sustainable infrastructure.</p>
<p>For more information about our platform or to discuss how Rescana can support your organization’s cybersecurity strategy, please contact us at <a href="mailto:ops@rescana.com">ops@rescana.com</a>.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses attacks on Poland’s combined heat and power (CHP) plants and renewable energy management systems, highlighting the importance of protecting clean energy infrastructure.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong>
<ul>
<li>The focus on critical infrastructure protection, cybersecurity, and resilience of energy systems aligns with SDG 9’s goal to build resilient infrastructure and foster innovation.</li>
</ul>
</li>
<li><strong>SDG 16: Peace, Justice, and Strong Institutions</strong>
<ul>
<li>The article addresses cyberattacks by a state-sponsored group, emphasizing the need for strong institutions, cybersecurity governance, and conflict prevention.</li>
</ul>
</li>
<li><strong>SDG 17: Partnerships for the Goals</strong>
<ul>
<li>Collaboration with national cybersecurity authorities and information sharing initiatives mentioned in the article reflect the importance of partnerships to strengthen cybersecurity and resilience.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
<li>Target 7.a: Enhance international cooperation to facilitate access to clean energy research and technology.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong>
<ul>
<li>Target 9.1: Develop quality, reliable, sustainable, and resilient infrastructure.</li>
<li>Target 9.c: Increase access to information and communications technology and strive to provide universal and affordable access to the Internet.</li>
</ul>
</li>
<li><strong>SDG 16: Peace, Justice, and Strong Institutions</strong>
<ul>
<li>Target 16.6: Develop effective, accountable, and transparent institutions at all levels.</li>
<li>Target 16.b: Promote and enforce non-discriminatory laws and policies for sustainable development.</li>
</ul>
</li>
<li><strong>SDG 17: Partnerships for the Goals</strong>
<ul>
<li>Target 17.16: Enhance the global partnership for sustainable development, complemented by multi-stakeholder partnerships.</li>
<li>Target 17.17: Encourage and promote effective public, public-private, and civil society partnerships.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Indicators related to SDG 7</strong>
<ul>
<li>Share of renewable energy in total final energy consumption (implied by focus on renewable energy management systems).</li>
<li>Number of energy infrastructure facilities protected against cyber threats (implied by mitigation and monitoring efforts).</li>
</ul>
</li>
<li><strong>Indicators related to SDG 9</strong>
<ul>
<li>Proportion of infrastructure that is resilient to cyberattacks and operational disruptions (implied by successful detection and mitigation of attacks).</li>
<li>Access to cybersecurity technologies and implementation of network segmentation and endpoint protection (implied by recommended countermeasures).</li>
</ul>
</li>
<li><strong>Indicators related to SDG 16</strong>
<ul>
<li>Number of institutions with established cybersecurity incident response plans and user awareness training programs (implied by mitigation strategies).</li>
<li>Frequency and effectiveness of collaboration between national cybersecurity authorities and organizations (implied by information sharing initiatives).</li>
</ul>
</li>
<li><strong>Indicators related to SDG 17</strong>
<ul>
<li>Number and quality of partnerships established for cybersecurity information sharing and collective defense (implied by collaboration efforts).</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy in the global energy mix</li>
<li>7.a: Enhance international cooperation on clean energy technology</li>
</ul>
</td>
<td>
<ul>
<li>Share of renewable energy in total final energy consumption</li>
<li>Number of energy infrastructure facilities protected against cyber threats</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation, and Infrastructure</td>
<td>
<ul>
<li>9.1: Develop resilient infrastructure</li>
<li>9.c: Increase access to ICT and affordable Internet</li>
</ul>
</td>
<td>
<ul>
<li>Proportion of infrastructure resilient to cyberattacks</li>
<li>Access to cybersecurity technologies and implementation of network segmentation</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 16: Peace, Justice, and Strong Institutions</td>
<td>
<ul>
<li>16.6: Develop effective, accountable institutions</li>
<li>16.b: Promote non-discriminatory laws and policies</li>
</ul>
</td>
<td>
<ul>
<li>Number of institutions with cybersecurity incident response plans</li>
<li>Frequency and effectiveness of collaboration between cybersecurity authorities and organizations</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 17: Partnerships for the Goals</td>
<td>
<ul>
<li>17.16: Enhance global partnership for sustainable development</li>
<li>17.17: Promote effective public, private, and civil society partnerships</li>
</ul>
</td>
<td>
<ul>
<li>Number and quality of cybersecurity information sharing partnerships</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.rescana.com/post/sandworm-s-dynowiper-attack-targeting-polish-combined-heat-and-power-and-renewable-energy-management">rescana.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Alpena Power Company and Efficiency United awards Thunder Bay Community Health Service for energy efficiency rebate – thealpenanews.com</title>
<link>https://sdgtalks.ai/alpena-power-company-and-efficiency-united-awards-thunder-bay-community-health-service-for-energy-efficiency-rebate-thealpenanewscom</link>
<guid>https://sdgtalks.ai/alpena-power-company-and-efficiency-united-awards-thunder-bay-community-health-service-for-energy-efficiency-rebate-thealpenanewscom</guid>
<description><![CDATA[ Alpena Power Company and Efficiency United awards Thunder Bay Community Health Service for energy efficiency rebate  thealpenanews.com ]]></description>
<enclosure url="https://ogden_images.s3.amazonaws.com/www.thealpenanews.com/images/2026/01/29142830/processed-952BBEE5-6877-4FD6-B2B9-6A4CAB2B1C40-1100x825.jpeg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 01 Feb 2026 16:00:18 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Alpena, Power, Company, and, Efficiency, United, awards, Thunder, Bay, Community, Health, Service, for, energy, efficiency, rebate, –, thealpenanews.com</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Energy Efficiency Recognition for Thunder Bay Community Health Service</h2>
<h3>Introduction</h3>
<p>Alpena Power Company and Efficiency United have awarded Thunder Bay Community Health Service (TBCHS) a rebate in recognition of their commitment to sustainable energy practices. This acknowledgment highlights the integration of energy-efficient installations in the recently renovated facility located at 200 W. Chisholm Street, which houses TBCHS administrative offices and the Bay Athletic Club.</p>
<h3>Energy-Conscious Renovation</h3>
<p>The 12-month renovation of the formerly vacant bank building incorporated multiple energy-efficient features, demonstrating TBCHS’s dedication to sustainable development in alignment with the United Nations Sustainable Development Goals (SDGs), particularly SDG 7 (Affordable and Clean Energy) and SDG 11 (Sustainable Cities and Communities).</p>
<ul>
<li>Installation of energy-efficient appliances</li>
<li>Use of advanced lighting systems</li>
<li>Implementation of motion-sensor control panels</li>
<li>Modernization to accommodate both fitness center and office space needs</li>
</ul>
<h3>Efficiency United Commercial and Industrial Energy Efficiency Program</h3>
<p>The rebate is part of the Efficiency United program, facilitated by CLEAResult and the Michigan Community Action Agency Association. This statewide initiative supports organizations that invest in energy-saving technologies, contributing to SDG 9 (Industry, Innovation, and Infrastructure) and SDG 13 (Climate Action) by reducing energy consumption and alleviating strain on the electric grid.</p>
<ol>
<li>Encourages adoption of sustainable energy solutions</li>
<li>Reduces customer energy costs</li>
<li>Supports grid reliability and environmental sustainability</li>
</ol>
<h3>Ceremonial Presentation and Community Engagement</h3>
<p>On Thursday, January 29th, representatives from Alpena Power Company and Efficiency United CLEAResult presented TBCHS with a ceremonial check to honor their energy-efficient efforts. A public open house is scheduled for spring at the renovated facility, promoting community awareness and engagement in sustainable development practices, aligning with SDG 17 (Partnerships for the Goals).</p>
<h3>Conclusion</h3>
<p>This recognition exemplifies how community organizations can contribute to the achievement of the Sustainable Development Goals through practical energy efficiency measures. TBCHS’s initiative serves as a model for sustainable renovation projects that support environmental stewardship, economic savings, and community well-being.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article highlights energy-efficient installations and energy-saving technology, directly relating to ensuring access to affordable, reliable, sustainable, and modern energy.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>The renovation of a long-vacant building into a modern, energy-efficient facility supports sustainable urban development and community infrastructure.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Use of energy-efficient appliances and lighting promotes sustainable consumption and production patterns.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 7 Targets</strong>
<ul>
<li><em>Target 7.3:</em> By 2030, double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 11 Targets</strong>
<ul>
<li><em>Target 11.6:</em> By 2030, reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.</li>
</ul>
</li>
<li><strong>SDG 12 Targets</strong>
<ul>
<li><em>Target 12.2:</em> By 2030, achieve the sustainable management and efficient use of natural resources.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied in the Article</h2>
<ol>
<li><strong>Energy Efficiency Improvements</strong>
<ul>
<li>Use of energy-efficient appliances, lighting, and motion-sensor control panels implies measurement of energy consumption reduction.</li>
</ul>
</li>
<li><strong>Reduction in Customer Energy Spending</strong>
<ul>
<li>The article mentions reducing customer spending on energy, which can be an indicator of cost savings due to energy efficiency.</li>
</ul>
</li>
<li><strong>Strain on Electric Grid</strong>
<ul>
<li>Reduction in strain on the electric grid is an implied indicator of improved energy management and sustainability.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>Target 7.3: Double the global rate of improvement in energy efficiency by 2030.</td>
<td>
<ul>
<li>Energy consumption reduction through energy-efficient appliances and lighting.</li>
<li>Reduction in customer energy spending.</li>
<li>Reduced strain on the electric grid.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>Target 11.6: Reduce the adverse per capita environmental impact of cities by 2030.</td>
<td>
<ul>
<li>Energy-conscious renovation of urban buildings.</li>
<li>Improvement in building sustainability and environmental impact.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>Target 12.2: Achieve sustainable management and efficient use of natural resources by 2030.</td>
<td>
<ul>
<li>Use of energy-efficient technologies indicating efficient resource use.</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.thealpenanews.com/news/2026/01/alpena-power-company-and-efficiency-united-awards-thunder-bay-community-health-service-for-energy-efficiency-rebate/">thealpenanews.com</a></strong></p>
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<title>Factory to be powered with own waste in Ireland first – BBC</title>
<link>https://sdgtalks.ai/factory-to-be-powered-with-own-waste-in-ireland-first-bbc</link>
<guid>https://sdgtalks.ai/factory-to-be-powered-with-own-waste-in-ireland-first-bbc</guid>
<description><![CDATA[ Factory to be powered with own waste in Ireland first  BBC ]]></description>
<enclosure url="https://ichef.bbci.co.uk/news/1024/branded_news/3197/live/a956e330-fdbf-11f0-9fd1-b16cd887f03f.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 01 Feb 2026 16:00:17 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Factory, powered, with, own, waste, Ireland, first, –, BBC</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on Employment Growth and Sustainability Initiatives</h2>
<h3>Introduction</h3>
<p>This report highlights the employment growth and sustainability efforts of a local business, emphasizing its alignment with the United Nations Sustainable Development Goals (SDGs).</p>
<h3>Employment and Workforce Development</h3>
<p>The company currently employs approximately 400 people in the area, maintaining a loyal and dedicated workforce.</p>
<h3>Commitment to Sustainable Growth</h3>
<p>The business is focused on growth that integrates sustainability principles, creating new job opportunities in the community.</p>
<h3>Alignment with Sustainable Development Goals</h3>
<ol>
<li><strong>SDG 8: Decent Work and Economic Growth</strong>
<ul>
<li>By expanding employment opportunities, the company promotes sustained, inclusive economic growth and productive employment.</li>
<li>Ongoing recruitment efforts ensure continuous workforce development.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong>
<ul>
<li>Growth initiatives are designed to enhance sustainable industrialization.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The company’s sustainability focus supports responsible business practices.</li>
</ul>
</li>
</ol>
<h3>Conclusion</h3>
<p>The company’s strategy to increase employment through sustainable growth demonstrates a strong commitment to the SDGs, particularly in fostering economic development and responsible business operations.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 8: Decent Work and Economic Growth</strong>
<ul>
<li>The article discusses employment and job opportunities, which are directly related to promoting sustained, inclusive, and sustainable economic growth, full and productive employment, and decent work for all.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong>
<ul>
<li>The mention of business growth and sustainability implies development in industry and infrastructure.</li>
</ul>
</li>
<li><strong>SDG 1: No Poverty</strong>
<ul>
<li>Creating more job opportunities can contribute to poverty reduction by increasing income and economic security for local populations.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs</h2>
<ol>
<li><strong>SDG 8 Targets</strong>
<ul>
<li>Target 8.5: Achieve full and productive employment and decent work for all women and men, including young people and persons with disabilities, and equal pay for work of equal value.</li>
<li>Target 8.3: Promote development-oriented policies that support productive activities, decent job creation, entrepreneurship, creativity, and innovation.</li>
</ul>
</li>
<li><strong>SDG 9 Targets</strong>
<ul>
<li>Target 9.2: Promote inclusive and sustainable industrialization and, by 2030, significantly raise industry’s share of employment and gross domestic product.</li>
</ul>
</li>
<li><strong>SDG 1 Targets</strong>
<ul>
<li>Target 1.2: By 2030, reduce at least by half the proportion of men, women, and children of all ages living in poverty in all its dimensions according to national definitions.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Employment Numbers</strong>
<ul>
<li>The article mentions employing around 400 people and the potential for more job opportunities, implying the indicator measuring the number of employed persons or employment rate.</li>
</ul>
</li>
<li><strong>Workforce Loyalty and Recruitment</strong>
<ul>
<li>While not a formal SDG indicator, the mention of a loyal workforce and ongoing recruitment suggests measuring workforce stability and job creation rates.</li>
</ul>
</li>
<li><strong>Business Growth and Sustainability</strong>
<ul>
<li>Implied indicators could include industrial growth rates, productivity metrics, or sustainability assessments related to business operations.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 8: Decent Work and Economic Growth</td>
<td>
<ul>
<li>8.5: Achieve full and productive employment and decent work for all</li>
<li>8.3: Promote policies supporting productive activities and decent job creation</li>
</ul>
</td>
<td>
<ul>
<li>Employment rate / Number of employed persons</li>
<li>Job creation rate</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation, and Infrastructure</td>
<td>
<ul>
<li>9.2: Promote inclusive and sustainable industrialization and raise industry’s share of employment and GDP</li>
</ul>
</td>
<td>
<ul>
<li>Industrial employment share</li>
<li>Business growth metrics</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 1: No Poverty</td>
<td>
<ul>
<li>1.2: Reduce by half the proportion of people living in poverty</li>
</ul>
</td>
<td>
<ul>
<li>Income levels of employed persons</li>
<li>Poverty rate reduction</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.bbc.com/news/articles/cql41le9drxo">bbc.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<item>
<title>Anaerobic Digestion Market Forecast to Reach USD 32.88 Billion by 2034 – openPR.com</title>
<link>https://sdgtalks.ai/anaerobic-digestion-market-forecast-to-reach-usd-3288-billion-by-2034-openprcom</link>
<guid>https://sdgtalks.ai/anaerobic-digestion-market-forecast-to-reach-usd-3288-billion-by-2034-openprcom</guid>
<description><![CDATA[ Anaerobic Digestion Market Forecast to Reach USD 32.88 Billion by 2034  openPR.com ]]></description>
<enclosure url="https://cdn.open-pr.com/L/1/L128227522_g.jpg" length="49398" type="image/jpeg"/>
<pubDate>Wed, 28 Jan 2026 16:00:13 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Anaerobic, Digestion, Market, Forecast, Reach, USD, 32.88, Billion, 2034, –, openPR.com</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Anaerobic Digestion Market Overview and Sustainable Development Goals Alignment</h2>
<h3>Market Forecast and Growth Potential</h3>
<p>The Anaerobic Digestion (AD) market is poised for significant expansion, driven by the increasing emphasis on sustainable waste management and renewable energy generation. Valued at USD 14.99 billion in 2023, the market is projected to reach USD 32.88 billion by 2034, growing at a robust Compound Annual Growth Rate (CAGR) of 10.96% from 2024 to 2034. This growth supports multiple Sustainable Development Goals (SDGs), including:</p>
<ul>
<li><strong>SDG 7:</strong> Affordable and Clean Energy</li>
<li><strong>SDG 11:</strong> Sustainable Cities and Communities</li>
<li><strong>SDG 12:</strong> Responsible Consumption and Production</li>
<li><strong>SDG 13:</strong> Climate Action</li>
</ul>
<h3>High Opportunity of Organic Waste Utilization</h3>
<p>Organic waste, abundant across various sectors, serves as a prime feedstock for anaerobic digestion. This process converts organic matter into biogas, a renewable energy source, and digestate, a nutrient-rich biofertilizer. The dual benefits of effective waste management and resource production contribute to:</p>
<ol>
<li>Reduction of landfill waste and associated greenhouse gas emissions (<strong>SDG 13</strong>).</li>
<li>Generation of renewable energy, reducing reliance on fossil fuels (<strong>SDG 7</strong>).</li>
<li>Promotion of sustainable agriculture through biofertilizer use (<strong>SDG 2: Zero Hunger</strong> and <strong>SDG 15: Life on Land</strong>).</li>
</ol>
<h2>Challenges in the Anaerobic Digestion Market</h2>
<h3>Key Barriers</h3>
<ul>
<li><strong>High Initial Capital Investment and Maintenance:</strong> The establishment of AD plants requires substantial upfront costs for construction, biogas upgrading systems, and grid integration. This financial barrier particularly affects small and medium-sized enterprises (SMEs) and agricultural producers.</li>
<li><strong>Skilled Labor Requirement:</strong> Operation and maintenance of AD facilities demand a skilled workforce proficient in digester operation, biogas upgrading, and feedstock management.</li>
<li><strong>Digestate Management:</strong> Efficient management and disposal of digestate pose challenges, especially in regions with limited agricultural demand for biofertilizers.</li>
</ul>
<h3>Proposed Solutions and Opportunities</h3>
<p>Addressing these challenges can unlock the full potential of the AD market and advance several SDGs:</p>
<ul>
<li><strong>Expansion of Renewable Energy and Biogas Markets:</strong> Technologies that upgrade biogas to Renewable Natural Gas (RNG) for grid injection or transportation fuel use align with <strong>SDG 7</strong> and support the global hydrogen economy through Power-to-Gas (P2G) systems producing green hydrogen.</li>
<li><strong>Agricultural and Industrial Waste Utilization:</strong> Large industries and agricultural operations (e.g., dairy farms, poultry farms, breweries, sugar mills, food processing plants) can convert organic waste into energy, enhancing energy security, reducing costs, and minimizing environmental footprints (<strong>SDG 12</strong> and <strong>SDG 13</strong>).</li>
<li><strong>Nutrient-Rich Digestate Use:</strong> Promoting digestate as a substitute for chemical fertilizers supports sustainable farming and fosters a circular economy model (<strong>SDG 2</strong> and <strong>SDG 15</strong>).</li>
</ul>
<h2>Impact of US Tariffs on the Anaerobic Digestion Market</h2>
<h3>Tariff Implications</h3>
<p>US tariffs significantly affect the AD market, particularly regarding gas separation membranes essential for biogas upgrading. Key impacts include:</p>
<ul>
<li><strong>Increased Production Costs:</strong> Tariffs on imported raw materials such as polysulfone, polyimide, PTFE, specialized housing materials, and valves raise production expenses for biogas plants.</li>
<li><strong>Reduced Profit Margins:</strong> Manufacturers face margin compression, especially under long-term OEM contracts limiting cost pass-through.</li>
<li><strong>Slowed Investment:</strong> Increased costs and uncertainty may delay investments in manufacturing, pilot plants, and R&D for advanced AD technologies, including CO2 capture solutions.</li>
<li><strong>Shift Towards Domestic Production:</strong> Tariffs encourage domestic membrane production to reduce import reliance, though challenges such as skilled labor shortages and higher compliance costs persist.</li>
<li><strong>Indirect Infrastructure Cost Increases:</strong> Tariffs on steel and aluminum raise infrastructure development costs, affecting large-scale AD project economics.</li>
</ul>
<h3>Strategic Adaptations</h3>
<p>To mitigate tariff impacts, the market must focus on:</p>
<ul>
<li>Investing in domestic production capabilities.</li>
<li>Diversifying supply chains.</li>
<li>Enhancing overall system efficiency to reduce upfront costs.</li>
</ul>
<h2>Conclusion and Further Opportunities</h2>
<p>The anaerobic digestion market presents a vital pathway to achieving multiple Sustainable Development Goals by promoting renewable energy, sustainable waste management, and circular economy practices. Overcoming financial, operational, and regulatory challenges through strategic solutions will be critical to unlocking its full potential.</p>
<p>For more detailed insights, market trends, and strategies, the full report is available at: <a href="https://evolvebi.com/report/anaerobic-digestion-market-analysis/" target="_blank" rel="nofollow">Anaerobic Digestion Market Analysis</a>.</p>
<h3>Contact Information</h3>
<ul>
<li><strong>Evolve Business Intelligence</strong></li>
<li>C-218, 2nd floor, M-Cube, Gujarat 396191, India</li>
<li>Email: <a href="mailto:sales@evolvebi.com">sales@evolvebi.com</a></li>
<li>Website: <a href="https://evolvebi.com/" target="_blank">https://evolvebi.com/</a></li>
</ul>
<p>For inquiries or to explore further opportunities in the anaerobic digestion market, please contact: <a href="mailto:info@evolvebi.com">info@evolvebi.com</a>.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses anaerobic digestion as a source of renewable energy (biogas and renewable natural gas), contributing to clean energy generation.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Focus on sustainable waste management by converting organic waste into energy and biofertilizers.</li>
<li>Promotion of circular economy through nutrient-rich digestate use as biofertilizer.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Reduction of environmental footprint by utilizing organic waste and producing renewable energy.</li>
<li>Potential for green hydrogen production aligning with global hydrogen economy goals.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong>
<ul>
<li>Development of advanced AD technologies, biogas upgrading systems, and infrastructure.</li>
<li>Challenges related to skilled labor and investment in R&D.</li>
</ul>
</li>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>Use of nutrient-rich digestate as biofertilizer supports sustainable agriculture.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
<li>Target 7.a: Enhance international cooperation to facilitate access to clean energy research and technology.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
<li>Target 12.4: Achieve environmentally sound management of chemicals and all wastes throughout their life cycle.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.2: Integrate climate change measures into national policies, strategies, and planning.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong>
<ul>
<li>Target 9.4: Upgrade infrastructure and retrofit industries to make them sustainable, with increased resource-use efficiency.</li>
<li>Target 9.5: Enhance scientific research and upgrade technological capabilities of industrial sectors.</li>
</ul>
</li>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>Target 2.4: Ensure sustainable food production systems and implement resilient agricultural practices.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>SDG 7 Indicators</strong>
<ul>
<li>Proportion of renewable energy in total final energy consumption (Indicator 7.2.1).</li>
<li>Investment in clean energy technologies (implied through market growth and R&D investments).</li>
</ul>
</li>
<li><strong>SDG 12 Indicators</strong>
<ul>
<li>Amount of organic waste diverted from landfill to anaerobic digestion (implied through waste management efficiency).</li>
<li>Quantity of nutrient-rich digestate used as biofertilizer (implied through circular economy practices).</li>
</ul>
</li>
<li><strong>SDG 13 Indicators</strong>
<ul>
<li>Reduction in greenhouse gas emissions from waste management and energy production (implied through adoption of AD technology).</li>
</ul>
</li>
<li><strong>SDG 9 Indicators</strong>
<ul>
<li>Number of AD plants established and operational (implied through market growth data).</li>
<li>Investment in R&D and technological innovation in AD sector (implied by discussion on advanced technologies and skilled labor).</li>
</ul>
</li>
<li><strong>SDG 2 Indicators</strong>
<ul>
<li>Use of biofertilizers in agriculture (implied through promotion of digestate as fertilizer).</li>
</ul>
</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy in global energy mix</li>
<li>7.a: Enhance cooperation for clean energy technology access</li>
</ul>
</td>
<td>
<ul>
<li>7.2.1: Proportion of renewable energy in total final energy consumption</li>
<li>Investment in clean energy technologies (implied)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.5: Reduce waste generation through prevention, recycling, reuse</li>
<li>12.4: Environmentally sound management of chemicals and wastes</li>
</ul>
</td>
<td>
<ul>
<li>Organic waste diverted to anaerobic digestion (implied)</li>
<li>Quantity of nutrient-rich digestate used as biofertilizer (implied)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.2: Integrate climate change measures into policies and planning</li>
</ul>
</td>
<td>
<ul>
<li>Reduction in greenhouse gas emissions from waste and energy sectors (implied)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation and Infrastructure</td>
<td>
<ul>
<li>9.4: Upgrade infrastructure and retrofit industries for sustainability</li>
<li>9.5: Enhance scientific research and technological capabilities</li>
</ul>
</td>
<td>
<ul>
<li>Number of AD plants operational (implied)</li>
<li>Investment in R&D and innovation in AD technologies (implied)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 2: Zero Hunger</td>
<td>
<ul>
<li>2.4: Ensure sustainable food production and resilient agriculture</li>
</ul>
</td>
<td>
<ul>
<li>Use of biofertilizers in agriculture (implied)</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.openpr.com/news/4365671/anaerobic-digestion-market-forecast-to-reach-usd-32-88-billion">openpr.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<item>
<title>Reducing Risk and Increasing Value Under Building Performance Standards – Facilitiesnet</title>
<link>https://sdgtalks.ai/reducing-risk-and-increasing-value-under-building-performance-standards-facilitiesnet</link>
<guid>https://sdgtalks.ai/reducing-risk-and-increasing-value-under-building-performance-standards-facilitiesnet</guid>
<description><![CDATA[ Reducing Risk and Increasing Value Under Building Performance Standards  Facilitiesnet ]]></description>
<enclosure url="https://www.facilitiesnet.com/resources/editorial/2026/20832_gauge_shutterstock_2169741941.jpg" length="49398" type="image/jpeg"/>
<pubDate>Mon, 26 Jan 2026 10:36:47 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Reducing, Risk, and, Increasing, Value, Under, Building, Performance, Standards, –, Facilitiesnet</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Building Performance Standards and Tenant Cooperation: Advancing Sustainable Development Goals</h2>
<h3>Introduction to Building Performance Standards (BPS)</h3>
<p>Building Performance Standards (BPS) are transforming commercial real estate by requiring ongoing operational performance metrics such as energy use intensity (EUI) and greenhouse gas (GHG) emissions over multi-year cycles. Unlike traditional building codes focused on construction, BPS emphasize sustainability aligned with the <strong>Sustainable Development Goals (SDGs)</strong>, particularly SDG 7 (Affordable and Clean Energy), SDG 11 (Sustainable Cities and Communities), and SDG 13 (Climate Action).</p>
<h3>Role of Tenants in BPS Compliance</h3>
<p>While building owners hold legal responsibility for BPS compliance, tenants significantly influence outcomes through their daily operations, including plug loads and HVAC usage. Tenant cooperation is critical to achieving energy efficiency and emissions reduction goals, contributing to SDG 12 (Responsible Consumption and Production) and SDG 13.</p>
<h3>Key Aspects of Tenant Cooperation and Lease Agreements</h3>
<ol>
<li><strong>Data Sharing and Access:</strong> Tenants are often requested to share utility data, allow submetering, and provide access for audits and retrofits. Such collaboration supports transparency and accountability, essential for SDG 16 (Peace, Justice, and Strong Institutions).</li>
<li><strong>Penalty Protections:</strong> Penalties for non-compliance generally remain the owner’s responsibility and cannot be passed to tenants, safeguarding tenant interests and promoting fair practices.</li>
<li><strong>Cost Recovery and Guardrails:</strong> Owners may recover capital costs for efficiency upgrades through leases, but best practices include amortization over the asset’s useful life, capping annual pass-throughs at verified savings, and applying rebates or tax credits first. This approach aligns with SDG 8 (Decent Work and Economic Growth) by fostering sustainable economic practices.</li>
</ol>
<h3>Lease Structures and Their Impact on BPS Obligations</h3>
<ul>
<li><strong>Gross, Full-Service Leases:</strong> Tenants pay fixed rent; owners manage utilities and compliance.</li>
<li><strong>Net Leases (Single, Double, Triple):</strong> Tenants bear more variable expenses, including utilities and maintenance.</li>
<li><strong>Modified Gross and Percentage Leases:</strong> Shared responsibilities require clear definitions to avoid disputes.</li>
<li><strong>Absolute Net (Bond) Leases:</strong> Tenants assume full compliance and penalty obligations, common in long-term single-tenant agreements.</li>
</ul>
<h3>Green Lease Language and Tenant Rights</h3>
<p>Incorporating green lease provisions supports SDG 17 (Partnerships for the Goals) by fostering collaboration between tenants and owners. Essential elements include:</p>
<ul>
<li>Monthly energy and water data sharing with confidentiality safeguards.</li>
<li>Reasonable operational standards balancing comfort and sustainability.</li>
<li>Cost recovery tied to measurement and verification (M&V) of savings.</li>
<li>Remedies for non-performance with cure periods and fair cost allocation.</li>
</ul>
<h3>Tenant Rights Under BPS</h3>
<ul>
<li><strong>Penalty Protection:</strong> Ensures penalties remain owner liabilities.</li>
<li><strong>Transparency and Disclosure:</strong> Access to building performance data and compliance plans.</li>
<li><strong>Data Privacy:</strong> Confidential handling of tenant operational data.</li>
<li><strong>Habitability and Business Continuity:</strong> Minimizing disruption during compliance activities.</li>
<li><strong>Affordability and Anti-Displacement:</strong> Protection against rent increases due to upgrades.</li>
<li><strong>CAM and Utilities Clarity:</strong> Transparent definitions and allocation rules.</li>
<li><strong>ESG and Marketing Rights:</strong> Use of building compliance in sustainability reporting.</li>
<li><strong>Performance-Based Alignment:</strong> Rent or incentives linked to actual energy or GHG performance.</li>
</ul>
<h3>Tenant Negotiation Checklist for BPS Compliance</h3>
<ol>
<li><strong>Scope and Exposure:</strong> Confirm BPS applicability, targets, deadlines, and current performance.</li>
<li><strong>Penalty Protections:</strong> Include “No penalty pass-through” clauses and define cooperation standards.</li>
<li><strong>Cost Recovery Guardrails:</strong> Link capital cost recovery to amortization and M&V-verified savings with annual reconciliations.</li>
<li><strong>Operational Standards and Tenant Equipment:</strong> Agree on reasonable standards and equipment responsibilities.</li>
<li><strong>Data, Privacy, and Reporting:</strong> Define data sharing cadence, confidentiality, and reporting requirements.</li>
<li><strong>Access and Habitability:</strong> Establish notice periods, disruption limits, and remedies for significant impacts.</li>
<li><strong>CAM and Utilities Transparency:</strong> Clarify CAM coverage, utility metering, allocation, and audit rights.</li>
<li><strong>ESG and Marketing Rights:</strong> Secure rights to reference certifications and obtain owner cooperation for ESG disclosures.</li>
<li><strong>Performance-Based Leasing Options:</strong> Consider rent adjustments or incentives tied to verified energy or GHG targets.</li>
</ol>
<h3>Conclusion: Creating Win-Win Outcomes for Sustainable Development</h3>
<p>BPS compliance centers on owners legally but depends heavily on tenant operations. Tenants who establish clear cooperation standards, codify penalty protections, and negotiate cost recovery with M&V guardrails contribute to achieving SDGs by promoting energy efficiency, reducing emissions, and enhancing workplace quality. This collaborative approach fosters sustainable urban development, supports climate action, and strengthens environmental, social, and governance (ESG) outcomes.</p>
<p>By treating BPS as an opportunity for value creation, tenants and owners can co-invest in high-return upgrades, ensure transparency, and share benefits such as lower utility costs and improved reputations. This partnership advances the global agenda for sustainable cities and communities (SDG 11) and climate resilience.</p>
<p><em>Craig Walter is Principal Energy Advisor at <a href="https://www.engieimpact.com/" target="_blank" rel="noopener">ENGIE Impact</a>.</em></p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses building performance standards (BPS) focused on energy use intensity (EUI) and greenhouse gas (GHG) emissions, emphasizing energy efficiency and clean energy use in commercial buildings.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>BPS aims to improve building operations and reduce emissions, contributing to sustainable urban environments and healthier workplaces.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Encourages efficient use of resources, such as energy and water, through operational standards and data sharing.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Focus on reducing greenhouse gas emissions from buildings aligns with climate mitigation efforts.</li>
</ul>
</li>
<li><strong>SDG 16: Peace, Justice and Strong Institutions</strong>
<ul>
<li>Legal frameworks and lease agreements codify responsibilities, penalties, and protections, promoting transparent and accountable governance in building management.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 7 – Target 7.3:</strong> By 2030, double the global rate of improvement in energy efficiency.
<ul>
<li>BPS requires ongoing operational performance improvements measured by energy use intensity and GHG emissions.</li>
</ul>
</li>
<li><strong>SDG 11 – Target 11.6:</strong> Reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.
<ul>
<li>Building emissions performance standards contribute to reducing environmental impacts of urban buildings.</li>
</ul>
</li>
<li><strong>SDG 12 – Target 12.2:</strong> Achieve sustainable management and efficient use of natural resources.
<ul>
<li>Operational standards and tenant cooperation promote efficient energy and water use.</li>
</ul>
</li>
<li><strong>SDG 13 – Target 13.2:</strong> Integrate climate change measures into policies and planning.
<ul>
<li>BPS and related lease clauses integrate climate action into building management policies.</li>
</ul>
</li>
<li><strong>SDG 16 – Target 16.6:</strong> Develop effective, accountable and transparent institutions at all levels.
<ul>
<li>Lease agreements codify penalty protections, cooperation standards, and data privacy, ensuring accountability and transparency.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Energy Use Intensity (EUI)</strong>
<ul>
<li>Used as a metric to measure building energy performance over time.</li>
</ul>
</li>
<li><strong>Greenhouse Gas (GHG) Emissions</strong>
<ul>
<li>Measured to assess compliance with emissions reduction targets.</li>
</ul>
</li>
<li><strong>Measurement and Verification (M&V)</strong>
<ul>
<li>Annual measurement and verification processes to reconcile energy savings and cost recovery, ensuring accuracy in performance reporting.</li>
</ul>
</li>
<li><strong>Utility Data Sharing and Submetering</strong>
<ul>
<li>Data cadence and access enable tracking of energy and water use at tenant and building levels.</li>
</ul>
</li>
<li><strong>Compliance Roadmaps and Performance Scores</strong>
<ul>
<li>Used to track progress toward meeting BPS targets and deadlines.</li>
</ul>
</li>
<li><strong>Rebates, Tax Credits, and Grants Applied</strong>
<ul>
<li>Indicators of financial incentives utilized to support energy efficiency upgrades.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>Target 7.3: Double the global rate of improvement in energy efficiency by 2030</td>
<td>
<ul>
<li>Energy Use Intensity (EUI)</li>
<li>Measurement and Verification (M&V) of energy savings</li>
<li>Utility data sharing and submetering</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>Target 11.6: Reduce adverse environmental impact of cities</td>
<td>
<ul>
<li>Greenhouse Gas (GHG) emissions monitoring</li>
<li>Compliance roadmaps and performance scores</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>Target 12.2: Achieve sustainable management and efficient use of natural resources</td>
<td>
<ul>
<li>Operational standards for energy and water use</li>
<li>Utility data sharing and submetering</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>Target 13.2: Integrate climate change measures into policies and planning</td>
<td>
<ul>
<li>Building emissions performance standards</li>
<li>Lease clauses codifying cooperation and penalty protections</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 16: Peace, Justice and Strong Institutions</td>
<td>Target 16.6: Develop effective, accountable and transparent institutions</td>
<td>
<ul>
<li>Lease agreement provisions for penalty protections and data privacy</li>
<li>Transparency in compliance and cost recovery processes</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.facilitiesnet.com/energyefficiency/article/Reducing-Risk-and-Increasing-Value-Under-Building-Performance-Standards--20832">facilitiesnet.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Austin Energy Green Building 2026 Single Family Rating Update – speakupaustin.org</title>
<link>https://sdgtalks.ai/austin-energy-green-building-2026-single-family-rating-update-speakupaustinorg</link>
<guid>https://sdgtalks.ai/austin-energy-green-building-2026-single-family-rating-update-speakupaustinorg</guid>
<description><![CDATA[ Austin Energy Green Building 2026 Single Family Rating Update  speakupaustin.org ]]></description>
<enclosure url="https://www.speakupaustin.org/img/mzikisufs3n7d8tsowgq_4000_1000.JPG" length="49398" type="image/jpeg"/>
<pubDate>Sun, 25 Jan 2026 17:00:12 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Austin, Energy, Green, Building, 2026, Single, Family, Rating, Update, –, speakupaustin.org</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>AEGB Single Family Rating Update Report</h2>
<h3>About the Update</h3>
<p>Austin Energy Green Building (AEGB) is revising its Single Family Rating system to align with new building codes and City policies, including the <a href="http://codes.iccsafe.org/content/IECC2024P1">2024 International Energy Conservation Code</a> and the <a href="http://www.austintexas.gov/page/austin-climate-equity-plan">City of Austin Climate Equity Plan</a>. This update emphasizes the importance of community feedback to develop a rating tool that supports sustainable, high-performing, and health-promoting buildings, directly contributing to the achievement of the United Nations Sustainable Development Goals (SDGs), particularly SDG 11 (Sustainable Cities and Communities) and SDG 13 (Climate Action).</p>
<h3>Program Background</h3>
<p>Since 1991, AEGB has driven innovation in green building to enhance environmental, economic, and human well-being within the Austin community. The program promotes sustainability through green building ratings, consulting, code advancement, education, and professional development. As Austin grows, AEGB continuously raises standards in key sustainability areas such as:</p>
<ul>
<li>Energy efficiency (SDG 7: Affordable and Clean Energy)</li>
<li>Water quality and conservation (SDG 6: Clean Water and Sanitation)</li>
<li>Indoor environmental quality (SDG 3: Good Health and Well-being)</li>
<li>Material resource management (SDG 12: Responsible Consumption and Production)</li>
<li>Site development (SDG 15: Life on Land)</li>
</ul>
<p>The 2023.1 Single Family Rating update reflects recent changes in local goals, codes, policies, and advances in building technology and practices. It addresses Central Texas’ environmental, community, health, and economic priorities, with a broader impact on the global ecosystem, supporting SDG 13 (Climate Action) and SDG 17 (Partnerships for the Goals).</p>
<h3>Our Process</h3>
<p>The AEGB residential team collaborates with City departments, local non-profits, building professionals, and the community to develop standards that encourage higher performance in design and development. The rating system:</p>
<ol>
<li>Rewards sustainable building practices</li>
<li>Leads to high-performing buildings</li>
<li>Creates market demand for sustainable buildings</li>
</ol>
<p>Projects are rated on a one to five-star scale based on a points system that includes required and voluntary sustainable measures. As sustainable practices gain market recognition through AEGB ratings, these measures are integrated into Austin’s building codes and regulations, advancing SDG 9 (Industry, Innovation, and Infrastructure) and SDG 11 (Sustainable Cities and Communities).</p>
<h3>Alignment with Austin Plans</h3>
<p>The AEGB Single Family Rating update aligns with several City of Austin plans, including:</p>
<ul>
<li>Austin Climate Equity Plan (SDG 10: Reduced Inequalities, SDG 13: Climate Action)</li>
<li>Austin Water Forward (SDG 6: Clean Water and Sanitation)</li>
<li>Austin Resource Recovery Zero Waste by 2040 (SDG 12: Responsible Consumption and Production)</li>
<li>Imagine Austin (SDG 11: Sustainable Cities and Communities)</li>
<li>Austin Energy Resource, Generation and Climate Protection Plan to 2035 (SDG 7: Affordable and Clean Energy, SDG 13: Climate Action)</li>
</ul>
<p>These plans collectively aim to foster a community that is healthy, affordable, accessible, and culturally reflective, supporting the achievement of multiple SDGs.</p>
<h3>Get Involved</h3>
<p>Community participation is essential to the success of this program update. Interested parties are encouraged to register for project updates via the <strong>Registration tab</strong> on the AEGB website. For questions or to provide feedback, contact AEGB directly via email.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 3: Good Health and Well-being</strong>
<ul>
<li>The article emphasizes health-promoting buildings and indoor environmental quality, which relate to ensuring healthy lives and promoting well-being.</li>
</ul>
</li>
<li><strong>SDG 6: Clean Water and Sanitation</strong>
<ul>
<li>References to water quality and conservation align with ensuring availability and sustainable management of water.</li>
</ul>
</li>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Focus on energy efficiency and the Austin Energy Resource, Generation and Climate Protection Plan to 2035 connect to ensuring access to affordable, reliable, sustainable energy.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>The article discusses sustainable building practices, affordable and accessible environments, and local culture, which relate to making cities inclusive, safe, resilient, and sustainable.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Material resources and zero waste goals align with sustainable consumption and production patterns.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>The Austin Climate Equity Plan and climate protection efforts relate directly to combating climate change and its impacts.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 3 – Target 3.9:</strong> Reduce illnesses from hazardous chemicals and pollution by improving indoor environmental quality.</li>
<li><strong>SDG 6 – Target 6.4:</strong> Increase water-use efficiency and ensure sustainable withdrawals.</li>
<li><strong>SDG 7 – Target 7.3:</strong> Double the global rate of improvement in energy efficiency.</li>
<li><strong>SDG 11 – Target 11.1:</strong> Ensure access to safe and affordable housing and basic services.</li>
<li><strong>SDG 12 – Target 12.5:</strong> Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
<li><strong>SDG 13 – Target 13.2:</strong> Integrate climate change measures into policies, strategies, and planning.</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Building Rating Scale (1 to 5 stars):</strong> Measures the level of sustainable building practices implemented, reflecting progress on energy efficiency, water conservation, and material resource use.</li>
<li><strong>Points System for Sustainable Measures:</strong> Quantifies required and voluntary sustainable building measures, serving as an indicator of adoption and performance.</li>
<li><strong>Incorporation into Local Codes and Regulations:</strong> The extent to which sustainable measures are adopted into city codes indicates progress towards climate action and sustainable urban development.</li>
<li><strong>Community Participation and Feedback:</strong> Engagement levels can be an indicator of inclusiveness and awareness in sustainable development efforts.</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 3: Good Health and Well-being</td>
<td>Target 3.9: Reduce illnesses from hazardous chemicals and pollution</td>
<td>Indoor environmental quality measures in building ratings</td>
</tr>
<tr>
<td>SDG 6: Clean Water and Sanitation</td>
<td>Target 6.4: Increase water-use efficiency</td>
<td>Water quality and conservation points in rating system</td>
</tr>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>Target 7.3: Double rate of improvement in energy efficiency</td>
<td>Energy efficiency scores in AEGB rating scale</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>Target 11.1: Access to safe, affordable housing</td>
<td>Star rating reflecting sustainable building practices and affordability</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>Target 12.5: Reduce waste generation</td>
<td>Material resource use and zero waste goals in rating criteria</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>Target 13.2: Integrate climate change measures into policies</td>
<td>Adoption of sustainable measures into city codes and policies</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.speakupaustin.org/y22254">speakupaustin.org</a></strong></p>
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<title>From voluntary to mandatory: new energy efficiency rules take shape across APAC – Lexology</title>
<link>https://sdgtalks.ai/from-voluntary-to-mandatory-new-energy-efficiency-rules-take-shape-across-apac-lexology</link>
<guid>https://sdgtalks.ai/from-voluntary-to-mandatory-new-energy-efficiency-rules-take-shape-across-apac-lexology</guid>
<description><![CDATA[ From voluntary to mandatory: new energy efficiency rules take shape across APAC  Lexology ]]></description>
<enclosure url="https://files.lexology.com/images/lexology/firm/adb540ff-dd2e-490b-ba24-e9a3437947c6/20230503105019.png" length="49398" type="image/jpeg"/>
<pubDate>Fri, 23 Jan 2026 15:30:13 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>From, voluntary, mandatory:, new, energy, efficiency, rules, take, shape, across, APAC, –, Lexology</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on New Energy Efficiency Regulations in the APAC Region</h2>
<h3>Introduction</h3>
<p>As of 23 January 2026, new regulations across the Asia-Pacific (APAC) region have made energy efficiency mandatory for companies. These regulatory changes are aligned with the global commitment to the Sustainable Development Goals (SDGs), particularly SDG 7 (Affordable and Clean Energy), SDG 9 (Industry, Innovation and Infrastructure), and SDG 13 (Climate Action).</p>
<h3>Regulatory Overview</h3>
<p>The tightened standards introduced in 2026 impose strict energy efficiency requirements on businesses operating within the APAC region. Non-compliance with these regulations will result in significant consequences, including:</p>
<ol>
<li>Fines imposed on offending companies</li>
<li>Market bans restricting the sale or operation of non-compliant products or services</li>
<li>Public naming-and-shaming to increase transparency and accountability</li>
</ol>
<h3>Implications for Sustainable Development Goals (SDGs)</h3>
<p>The enforcement of these energy efficiency regulations directly supports several SDGs:</p>
<ul>
<li><strong>SDG 7: Affordable and Clean Energy</strong> – By mandating energy efficiency, the regulations promote the use of cleaner energy and reduce overall energy consumption.</li>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong> – Encouraging companies to innovate and improve infrastructure to meet energy efficiency standards fosters sustainable industrialization.</li>
<li><strong>SDG 13: Climate Action</strong> – Reducing energy waste contributes to lowering greenhouse gas emissions, supporting global efforts to combat climate change.</li>
</ul>
<h3>Conclusion</h3>
<p>The new APAC energy efficiency regulations represent a significant step towards sustainable industrial practices in the region. Companies are urged to comply promptly to avoid penalties and contribute to the achievement of the Sustainable Development Goals, ensuring a more sustainable and environmentally responsible future.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses new regulations in APAC making energy efficiency mandatory, which aligns with SDG 7’s focus on ensuring access to affordable, reliable, sustainable, and modern energy for all.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The emphasis on energy efficiency and compliance with tightened standards relates to promoting sustainable consumption and production patterns.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Improving energy efficiency contributes to reducing greenhouse gas emissions, supporting climate action goals.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs</h2>
<ol>
<li><strong>SDG 7 Targets</strong>
<ul>
<li><em>Target 7.3:</em> By 2030, double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 12 Targets</strong>
<ul>
<li><em>Target 12.2:</em> By 2030, achieve the sustainable management and efficient use of natural resources.</li>
<li><em>Target 12.4:</em> By 2020, achieve the environmentally sound management of chemicals and all wastes throughout their life cycle.</li>
</ul>
</li>
<li><strong>SDG 13 Targets</strong>
<ul>
<li><em>Target 13.2:</em> Integrate climate change measures into national policies, strategies, and planning.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied in the Article</h2>
<ol>
<li><strong>Energy Efficiency Improvement Rate</strong>
<ul>
<li>Implied through the mandatory regulations and tightened standards aimed at improving energy efficiency in companies.</li>
</ul>
</li>
<li><strong>Compliance Rate with Energy Efficiency Regulations</strong>
<ul>
<li>Implied by the mention of fines, market bans, and public naming-and-shaming for non-compliance, indicating monitoring of compliance as an indicator.</li>
</ul>
</li>
<li><strong>Reduction in Energy Consumption or Emissions</strong>
<ul>
<li>While not explicitly stated, the focus on energy efficiency implies measuring reductions in energy use or associated emissions.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>Target 7.3: Double the global rate of improvement in energy efficiency by 2030</td>
<td>Energy Efficiency Improvement Rate; Compliance Rate with Energy Efficiency Regulations</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
                Target 12.2: Sustainable management and efficient use of natural resources by 2030<br>
                Target 12.4: Environmentally sound management of chemicals and wastes by 2020
            </td>
<td>Compliance Rate with Energy Efficiency Regulations; Reduction in Energy Consumption</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>Target 13.2: Integrate climate change measures into national policies, strategies, and planning</td>
<td>Reduction in Energy Consumption or Emissions</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.lexology.com/pro/content/voluntary-mandatory-new-energy-efficiency-rules-take-shape-across-apac">lexology.com</a></strong></p>
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<title>Environmental groups petition to end federal grants for on&#45;farm digesters – Waste Dive</title>
<link>https://sdgtalks.ai/environmental-groups-petition-to-end-federal-grants-for-on-farm-digesters-waste-dive</link>
<guid>https://sdgtalks.ai/environmental-groups-petition-to-end-federal-grants-for-on-farm-digesters-waste-dive</guid>
<description><![CDATA[ Environmental groups petition to end federal grants for on-farm digesters  Waste Dive ]]></description>
<enclosure url="https://www.wastedive.com/static/img/play.svg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 18 Jan 2026 03:30:16 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Environmental, groups, petition, end, federal, grants, for, on-farm, digesters, –, Waste, Dive</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on U.S. Department of Agriculture Funding for On-Farm Manure Digesters and Sustainable Development Goals</h2>
<h3>Introduction</h3>
<p>A coalition of 34 environmental and agricultural organizations has petitioned the U.S. Department of Agriculture (USDA) to exclude on-farm manure digesters from eligibility for funding under the Rural Energy for America Program (REAP). This petition highlights concerns regarding the environmental and economic impacts of digesters and emphasizes alignment with the United Nations Sustainable Development Goals (SDGs), particularly those related to responsible consumption and production, climate action, clean water, and sustainable communities.</p>
<h3>Background and Petition Details</h3>
<ul>
<li>The coalition includes prominent environmental groups such as Friends of the Earth, Waterkeeper Alliance, and Food & Water Watch, alongside agricultural advocacy organizations like Farm Aid and the Animal Legal Defense Fund.</li>
<li>According to the petition, approximately $257 million of the $3.2 billion disbursed by REAP from 2021 to 2025 was allocated to manure digester projects.</li>
<li>The average grant or loan guarantee for digesters was significantly higher than for solar or wind energy projects, which are also supported by REAP.</li>
<li>Earthjustice has filed a lawsuit requesting the USDA to disclose records detailing the methodology used to justify funding for digesters.</li>
<li>REAP funding has experienced delays due to a backlog of applicants.</li>
</ul>
<h3>Analysis of Environmental and Social Impacts in Relation to SDGs</h3>
<h4>Environmental Concerns</h4>
<ul>
<li>Opponents argue that manure digesters may cause more environmental harm than benefits, potentially undermining SDG 13 (Climate Action) and SDG 6 (Clean Water and Sanitation).</li>
<li>Studies cited in the petition indicate that digesters contribute to the consolidation of dairy herds, increasing risks of air and water pollution, which conflicts with SDG 3 (Good Health and Well-being) and SDG 15 (Life on Land).</li>
<li>The anaerobic digestion process increases production of ammonia and enhances solubility of nutrients like nitrogen and phosphorus, raising concerns about water quality and ecosystem health.</li>
<li>Documented cases of water pollution from digester projects funded by REAP highlight potential violations of environmental permits.</li>
</ul>
<h4>Economic and Social Considerations</h4>
<ul>
<li>The petitioners emphasize that REAP should prioritize projects that provide environmental benefits, support small farms in lower-income rural communities, and are cost-efficient, aligning with SDG 1 (No Poverty) and SDG 10 (Reduced Inequalities).</li>
<li>Analysis of EPA data revealed that 17% of on-farm digesters have ceased operations, often due to financial difficulties, raising concerns about the sustainability and economic viability of these projects.</li>
<li>Critics argue that funding digesters may inadvertently support factory farms rather than fostering resilient rural economies and communities.</li>
</ul>
<h3>Stakeholder Perspectives</h3>
<ol>
<li><strong>Petitioners’ Viewpoint:</strong>
<ul>
<li>REAP funding should not support digesters as they do not fulfill the program’s environmental and social criteria.</li>
<li>Resources should be redirected to projects that more effectively reduce energy costs and strengthen rural communities.</li>
<li>Quote: “REAP exists to help farmers and rural small businesses lower energy costs and foster stronger communities, not prop up factory farms.” – Molly Armus, Friends of the Earth.</li>
</ul>
</li>
<li><strong>Biogas Industry Response:</strong>
<ul>
<li>Biogas advocates argue digesters capture emissions more effectively than alternative methods, contributing to SDG 7 (Affordable and Clean Energy) and SDG 13 (Climate Action).</li>
<li>They highlight economic benefits for farmers, including additional revenue streams and reduced fertilizer costs.</li>
<li>Quote: “Biogas systems and digesters align directly with REAP’s statutory goal of providing environmental and public health benefits in rural America.” – Patrick Serfass, American Biogas Council.</li>
</ul>
</li>
</ol>
<h3>Broader Context and Policy Implications</h3>
<ul>
<li>The debate over digester subsidies is influencing other incentive programs nationwide, including California’s Low Carbon Fuel Standard and New Mexico’s clean fuels program.</li>
<li>Environmental justice advisors have advocated for removing digester incentives to better align with SDG 10 (Reduced Inequalities) and SDG 12 (Responsible Consumption and Production).</li>
<li>The USDA has previously excluded projects involving fossil fuel co-burning from REAP funding, indicating potential for policy adjustments regarding digesters.</li>
</ul>
<h3>Conclusion and Recommendations</h3>
<ol>
<li><strong>Policy Review:</strong> The USDA should thoroughly evaluate the environmental, economic, and social impacts of manure digesters in relation to the Sustainable Development Goals before continuing funding.</li>
<li><strong>Transparency:</strong> Release of detailed methodologies and data supporting funding decisions is essential for accountability and informed policymaking.</li>
<li><strong>Focus on Sustainable Alternatives:</strong> Prioritize renewable energy projects such as solar and wind that demonstrate clear environmental benefits and support small-scale rural development.</li>
<li><strong>Address Environmental Risks:</strong> Implement stricter monitoring and regulation to mitigate pollution risks associated with digestate management.</li>
<li><strong>Support Rural Communities:</strong> Ensure funding programs promote equitable economic opportunities and environmental health in rural areas, advancing SDGs 1, 8 (Decent Work and Economic Growth), and 11 (Sustainable Cities and Communities).</li>
</ol>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected to the Issues Highlighted in the Article</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article discusses funding for renewable energy projects such as anaerobic digesters, solar, and wind projects through the Rural Energy for America Program (REAP).</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The debate over the environmental impact of manure digesters, including concerns about pollution and waste management, relates to sustainable production practices.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Discussions about emissions reduction from manure digesters and biogas systems relate to efforts to combat climate change.</li>
</ul>
</li>
<li><strong>SDG 14: Life Below Water</strong>
<ul>
<li>Concerns about water pollution from digester waste affecting surface and groundwater quality connect to the protection of aquatic ecosystems.</li>
</ul>
</li>
<li><strong>SDG 15: Life on Land</strong>
<ul>
<li>Issues related to land pollution and the environmental impact of farm consolidation affect terrestrial ecosystems.</li>
</ul>
</li>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>The article touches on agriculture practices and the economic viability of farms, which relate to sustainable agriculture and food security.</li>
</ul>
</li>
<li><strong>SDG 10: Reduced Inequalities</strong>
<ul>
<li>The petition emphasizes favoring small farms in lower-income rural communities, addressing inequalities in access to funding and resources.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified Based on the Article’s Content</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
<li>Target 7.a: Enhance international cooperation to facilitate access to clean energy research and technology.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Target 12.4: Achieve environmentally sound management of chemicals and all wastes throughout their life cycle.</li>
<li>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.2: Integrate climate change measures into national policies, strategies, and planning.</li>
</ul>
</li>
<li><strong>SDG 14: Life Below Water</strong>
<ul>
<li>Target 14.1: Prevent and significantly reduce marine pollution of all kinds.</li>
</ul>
</li>
<li><strong>SDG 15: Life on Land</strong>
<ul>
<li>Target 15.1: Ensure the conservation, restoration, and sustainable use of terrestrial and inland freshwater ecosystems.</li>
</ul>
</li>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>Target 2.4: Ensure sustainable food production systems and implement resilient agricultural practices.</li>
</ul>
</li>
<li><strong>SDG 10: Reduced Inequalities</strong>
<ul>
<li>Target 10.2: Empower and promote the social, economic, and political inclusion of all, irrespective of age, sex, disability, race, ethnicity, origin, or economic status.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied in the Article to Measure Progress Towards the Identified Targets</h2>
<ol>
<li><strong>Funding Allocation and Distribution</strong>
<ul>
<li>Amount of funding disbursed to different renewable energy projects (e.g., $257 million to digesters vs. solar/wind projects).</li>
<li>Average grant or loan guarantee size for digesters compared to other projects.</li>
</ul>
</li>
<li><strong>Environmental Impact Indicators</strong>
<ul>
<li>Incidence of water pollution events or permit violations related to digester projects (e.g., documented discharges, runoff, leachate).</li>
<li>Levels of pollutants such as ammonia, nitrogen, and phosphorus in ground and surface water.</li>
<li>Changes in herd sizes and their correlation with environmental pollution.</li>
</ul>
</li>
<li><strong>Operational and Financial Sustainability</strong>
<ul>
<li>Percentage of digesters that have shut down due to financial challenges (17% as per EPA data analysis).</li>
<li>Economic returns and cost-effectiveness of digesters in rural communities.</li>
</ul>
</li>
<li><strong>Social and Economic Inclusion</strong>
<ul>
<li>Extent to which funding benefits small farms and lower-income rural communities versus large factory farms.</li>
</ul>
</li>
<li><strong>Emission Reduction</strong>
<ul>
<li>Effectiveness of digesters in capturing methane and reducing greenhouse gas emissions compared to other methods.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy</li>
<li>7.a: Enhance access to clean energy technology</li>
</ul>
</td>
<td>
<ul>
<li>Funding amounts allocated to renewable energy projects (digesters, solar, wind)</li>
<li>Average grant/loan size per project type</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.4: Environmentally sound management of chemicals and waste</li>
<li>12.5: Reduce waste generation</li>
</ul>
</td>
<td>
<ul>
<li>Incidence of water pollution and permit violations from digesters</li>
<li>Levels of ammonia, nitrogen, phosphorus in water</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.2: Integrate climate change measures into policies</li>
</ul>
</td>
<td>
<ul>
<li>Methane emissions captured by digesters</li>
<li>Reduction in greenhouse gas emissions from manure management</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 14: Life Below Water</td>
<td>
<ul>
<li>14.1: Reduce marine pollution</li>
</ul>
</td>
<td>
<ul>
<li>Water quality measurements in surface and groundwater near farms</li>
<li>Reported pollution incidents linked to digesters</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 15: Life on Land</td>
<td>
<ul>
<li>15.1: Conservation and sustainable use of terrestrial ecosystems</li>
</ul>
</td>
<td>
<ul>
<li>Extent of land pollution from digester waste</li>
<li>Changes in farm consolidation and herd sizes</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 2: Zero Hunger</td>
<td>
<ul>
<li>2.4: Sustainable food production systems</li>
</ul>
</td>
<td>
<ul>
<li>Economic viability of farms using digesters</li>
<li>Reduction in fertilizer costs due to digesters</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 10: Reduced Inequalities</td>
<td>
<ul>
<li>10.2: Promote social and economic inclusion</li>
</ul>
</td>
<td>
<ul>
<li>Proportion of funding benefiting small farms and lower-income communities</li>
<li>Access to REAP funding by farm size and community income level</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.wastedive.com/news/reap-digester-funding-petition-environmental-groups/809743/">wastedive.com</a></strong></p>
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<item>
<title>Maximize Efficiency with Professional Building Energy Modeling Services in 2026 – Programming Insider</title>
<link>https://sdgtalks.ai/maximize-efficiency-with-professional-building-energy-modeling-services-in-2026-programming-insider</link>
<guid>https://sdgtalks.ai/maximize-efficiency-with-professional-building-energy-modeling-services-in-2026-programming-insider</guid>
<description><![CDATA[ Maximize Efficiency with Professional Building Energy Modeling Services in 2026  Programming Insider ]]></description>
<enclosure url="https://programminginsider.com/wp-content/uploads/2026/01/allison-saeng-l9hWybV2H-w-unsplash-scaled.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 18 Jan 2026 03:30:16 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Maximize, Efficiency, with, Professional, Building, Energy, Modeling, Services, 2026, –, Programming, Insider</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on Building Energy Modeling Services and Sustainable Development Goals in 2026</h2>
<h3>Introduction</h3>
<p>In 2026, sustainability has become a paramount concern for developers, architects, and building owners. Building energy modeling services emerge as a critical tool to predict, optimize, and enhance energy performance in buildings. These services utilize advanced simulation software to create virtual models of buildings, enabling the forecasting of energy consumption, identification of savings opportunities, and ensuring compliance with evolving energy codes and green standards. This report emphasizes the alignment of building energy modeling services with the United Nations Sustainable Development Goals (SDGs), particularly SDG 7 (Affordable and Clean Energy), SDG 11 (Sustainable Cities and Communities), and SDG 13 (Climate Action).</p>
<h2>Understanding Building Energy Modeling Services</h2>
<p>Building Energy Modeling (BEM) involves physics-based computer simulations that replicate a building’s energy use under various conditions. Using platforms such as EnergyPlus, experts input data including building geometry, envelope materials, HVAC systems, lighting, occupancy patterns, and local climate to predict annual energy consumption and peak loads.</p>
<p>Professional building energy modeling services provide the following key functions:</p>
<ul>
<li>Early-stage design analysis to compare options such as envelope upgrades, HVAC alternatives, and renewable energy integrations</li>
<li>Code compliance modeling (e.g., ASHRAE 90.1 Appendix G) to ensure adherence to energy codes</li>
<li>Performance rating for green certifications including LEED, ENERGY STAR, and net-zero targets</li>
<li>Lifecycle cost analysis, payback period estimation, and qualification for incentives and tax credits (e.g., 179D deductions)</li>
<li>Development of decarbonization roadmaps and carbon footprint reduction strategies</li>
</ul>
<p>These services support SDG 7 by promoting energy efficiency and clean energy use, SDG 11 by fostering sustainable urban development, and SDG 13 by contributing to climate change mitigation.</p>
<h2>Key Benefits of Investing in Building Energy Modeling Services</h2>
<p>Engaging expert building energy modeling services delivers significant advantages throughout project phases, including:</p>
<ul>
<li><strong>Significant Energy and Cost Reductions:</strong> Early modeling can identify 20-40% savings in annual energy consumption through optimized design strategies, supporting SDG 7.</li>
<li><strong>Faster Return on Investment and Financial Incentives:</strong> Enables identification of measures with quick paybacks and qualification for tax credits, utility rebates, and performance-based incentives.</li>
<li><strong>Enhanced Sustainability Credentials:</strong> Facilitates achievement of LEED Platinum, net-zero certification, and other green building ratings, advancing SDG 11.</li>
<li><strong>Risk Mitigation:</strong> Virtual scenario testing reduces costly redesigns and construction delays.</li>
<li><strong>Improved Occupant Comfort and Resilience:</strong> Enhances indoor air quality, thermal comfort, and adaptability to climate challenges, aligning with SDG 3 (Good Health and Well-being) and SDG 13.</li>
<li><strong>Regulatory Compliance:</strong> Ensures buildings meet or exceed energy codes, performance standards, and electrification mandates.</li>
</ul>
<h2>Operational Process of Building Energy Modeling Services</h2>
<p>Top providers follow a structured methodology to deliver comprehensive modeling services:</p>
<ol>
<li><strong>Data Collection:</strong> Compilation of architectural drawings, material specifications, occupancy schedules, and utility data.</li>
<li><strong>Model Creation:</strong> Development of a calibrated virtual model that reflects real-world building conditions.</li>
<li><strong>Baseline and Proposed Simulations:</strong> Comparison of code-compliant baseline models against design alternatives.</li>
<li><strong>Iterative Optimization:</strong> Evaluation of envelope improvements, efficient HVAC systems, daylighting strategies, renewable energy integration, and control systems.</li>
<li><strong>Reporting and Recommendations:</strong> Delivery of detailed reports including energy savings projections and documentation for certifications and incentives.</li>
</ol>
<p>Integration with Mechanical, Electrical, and Plumbing (MEP) design, commissioning, and computational fluid dynamics further enhances holistic building performance.</p>
<h2>2026 Trends Influencing Building Energy Modeling Services</h2>
<p>The advancement of building energy modeling services is driven by technological innovation and policy developments, including:</p>
<ul>
<li><strong>Artificial Intelligence and Machine Learning Integration:</strong> Accelerates model calibration, predictive analytics, and automated optimization processes.</li>
<li><strong>Electrification Focus:</strong> Modeling of heat pumps, electric vehicle charging infrastructure, and all-electric building systems to enhance grid resilience.</li>
<li><strong>Digital Twins and Real-Time Simulation:</strong> Linking models with building sensor data for continuous performance monitoring and optimization.</li>
<li><strong>Decarbonization Emphasis:</strong> Incorporation of carbon footprint analysis alongside energy consumption metrics to support SDG 13.</li>
<li><strong>Grid-Interactive Efficient Buildings:</strong> Designing buildings capable of demand response and flexible load management to support sustainable energy systems.</li>
</ul>
<h2>Rationale for Selecting Experienced Building Energy Modeling Providers</h2>
<p>Choosing a provider with demonstrated expertise in high-performance buildings and in-house modeling capabilities is critical. Providers with experience across sectors such as commercial, healthcare, science and technology, and education are preferred. The integration of technical precision with sustainability consulting ensures alignment of energy strategies with overall project goals, advancing multiple SDGs.</p>
<p>In 2026, building energy modeling services represent a strategic investment that transcends regulatory compliance. They enable the creation of efficient, resilient, and future-ready buildings, delivering actionable insights and measurable performance improvements.</p>
<h5><em>Source: ENGR NEWS WIRE</em></h5>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ul>
<li><b>SDG 7: Affordable and Clean Energy</b> – The article focuses on building energy modeling services that optimize energy consumption, promote energy efficiency, and support renewable energy integration.</li>
<li><b>SDG 9: Industry, Innovation, and Infrastructure</b> – The use of advanced simulation software, AI, machine learning, and digital twins reflects innovation in infrastructure and industrial processes.</li>
<li><b>SDG 11: Sustainable Cities and Communities</b> – The article discusses sustainable building practices, improved occupant comfort, and resilience, contributing to sustainable urban development.</li>
<li><b>SDG 12: Responsible Consumption and Production</b> – Lifecycle cost analysis, payback periods, and incentives promote responsible resource use and sustainable consumption.</li>
<li><b>SDG 13: Climate Action</b> – Decarbonization roadmaps, carbon footprint reduction strategies, and compliance with energy codes support climate change mitigation efforts.</li>
</ul>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ul>
<li><b>SDG 7 Targets:</b>
<ul>
<li>7.3 – By 2030, double the global rate of improvement in energy efficiency.</li>
<li>7.2 – Increase substantially the share of renewable energy in the global energy mix.</li>
</ul>
</li>
<li><b>SDG 9 Targets:</b>
<ul>
<li>9.4 – Upgrade infrastructure and retrofit industries to make them sustainable, with increased resource-use efficiency and greater adoption of clean and environmentally sound technologies.</li>
</ul>
</li>
<li><b>SDG 11 Targets:</b>
<ul>
<li>11.6 – Reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.</li>
</ul>
</li>
<li><b>SDG 12 Targets:</b>
<ul>
<li>12.2 – Achieve sustainable management and efficient use of natural resources.</li>
<li>12.7 – Promote public procurement practices that are sustainable.</li>
</ul>
</li>
<li><b>SDG 13 Targets:</b>
<ul>
<li>13.2 – Integrate climate change measures into national policies, strategies, and planning.</li>
</ul>
</li>
</ul>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ul>
<li>Energy consumption reduction percentages (e.g., 20-40% savings in annual energy use) as a measure of energy efficiency improvements.</li>
<li>Compliance with energy codes and standards such as ASHRAE 90.1 Appendix G.</li>
<li>Achievement of green certifications like LEED Platinum, ENERGY STAR, and net-zero certification.</li>
<li>Carbon footprint reduction metrics and decarbonization progress.</li>
<li>Financial indicators such as payback periods, qualification for tax credits (e.g., 179D deductions), and utility rebates.</li>
<li>Use of digital twins and real-time simulation data for ongoing performance tracking.</li>
</ul>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.3 – Double the global rate of improvement in energy efficiency.</li>
<li>7.2 – Increase renewable energy share.</li>
</ul>
</td>
<td>
<ul>
<li>Percentage reduction in annual energy consumption (20-40% savings).</li>
<li>Integration of renewable energy systems in buildings.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation, and Infrastructure</td>
<td>
<ul>
<li>9.4 – Upgrade infrastructure for sustainability and clean technologies.</li>
</ul>
</td>
<td>
<ul>
<li>Use of advanced simulation tools (EnergyPlus, AI, machine learning).</li>
<li>Implementation of electrification and grid-interactive efficient buildings.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>
<ul>
<li>11.6 – Reduce environmental impact of cities.</li>
</ul>
</td>
<td>
<ul>
<li>Improved indoor air quality and thermal comfort metrics.</li>
<li>Green building certification achievements (LEED, net-zero).</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.2 – Sustainable management and efficient use of natural resources.</li>
<li>12.7 – Promote sustainable public procurement.</li>
</ul>
</td>
<td>
<ul>
<li>Lifecycle cost analysis and payback period evaluations.</li>
<li>Qualification for tax credits and incentives.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.2 – Integrate climate change measures into policies and planning.</li>
</ul>
</td>
<td>
<ul>
<li>Carbon footprint reduction metrics.</li>
<li>Decarbonization roadmaps and strategies.</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://programminginsider.com/maximize-efficiency-with-professional-building-energy-modeling-services-in-2026/">programminginsider.com</a></strong></p>
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<item>
<title>Office of Energy – Mississippi Development Authority</title>
<link>https://sdgtalks.ai/office-of-energy-mississippi-development-authority</link>
<guid>https://sdgtalks.ai/office-of-energy-mississippi-development-authority</guid>
<description><![CDATA[ Office of Energy  Mississippi Development Authority ]]></description>
<enclosure url="https://mississippi.org/wp-content/uploads/Campaign-Leader-Badge-300x300.png" length="49398" type="image/jpeg"/>
<pubDate>Fri, 16 Jan 2026 01:00:13 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Office, Energy, –, Mississippi, Development, Authority</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Mississippi Energy Services and Sustainable Development Initiatives Report</h2>
<h3>Legal Framework for Energy Services Contracts</h3>
<p>Section 31-7-14 of the Mississippi Code authorizes public entities to enter into energy services contracts, energy performance contracts, or shared-savings contracts aimed at financing cost-saving energy efficiency projects. These contracts enable building improvements with minimal or no upfront capital costs, leveraging future energy and operational savings from the improvements. Typical projects include:</p>
<ol>
<li>Energy-efficient technologies</li>
<li>Lighting upgrades</li>
<li>Energy management controls</li>
<li>Heating, ventilation, and air conditioning (HVAC) systems</li>
<li>Renewable energy technologies</li>
<li>Other energy-saving measures</li>
</ol>
<h3>Energy Service Providers and Procurement Process</h3>
<p>The Energy and Natural Resources Division (MDA-ENRD) maintains a list of energy service providers qualified under the U.S. Department of Energy’s (DOE) Qualified Energy Service Companies (ESCOs) program and certified by the Mississippi State Board of Contractors. Public entities may procure services from any provider on this list.</p>
<p>Contact information for interested companies:</p>
<ul>
<li><strong>Phone:</strong> 601-359-3449</li>
<li><a href="https://mississippi.org/wp-content/uploads/24-0325-Prequalified-Energy-Services-Providers_MS_October2024.pdf"><em>List of Mississippi’s Pre-Qualified Energy Service Providers</em></a></li>
</ul>
<p>Entities planning to issue a Request for Proposal (RFP) or Request for Qualifications (RFQ) must notify MDA-ENRD in writing at:</p>
<address>
Joe Hagerman, Director<br>
MDA-Energy & Natural Resources Division<br>
Post Office Box 849<br>
Jackson, MS 39205-0849<br>
</address>
<h2>Resources and Tools for Energy Savings Performance Contracting (ESPC)</h2>
<p>The MDA-ENRD provides comprehensive resources to support the procurement and implementation of energy savings performance contracts, contributing directly to Sustainable Development Goals (SDGs) such as Affordable and Clean Energy (SDG 7), Sustainable Cities and Communities (SDG 11), and Climate Action (SDG 13).</p>
<ul>
<li><a href="https://betterbuildingssolutioncenter.energy.gov/energy-savings-performance-contracting-espc-toolkit">ESPC Toolkit</a> – Best practices for building owners to successfully complete projects.</li>
<li><a href="https://www.energy.gov/eere/slsc/energy-savings-performance-contracting">DOE State and Local Solutions Center</a> – Reports and resources for effective ESPC programs.</li>
<li><a href="https://www.energy.gov/sites/prod/files/2019/02/f59/understanding-espc-savings-guarantee.pdf">Understanding Your ESPC Savings Guarantee</a> – Guide explaining savings guarantees in ESPCs.</li>
<li><a href="https://www.energy.gov/eere/slsc/eproject-express">eProjecteXpress</a> – Online database for tracking project data and verifying savings.</li>
<li><a href="https://www.energy.gov/sites/prod/files/2019/02/f59/business-case-mv-espc_0.pdf">The Business Case for Measurement and Verification</a> – Importance of tracking guaranteed savings in ESPC projects.</li>
<li><a href="https://www.youtube.com/watch?v=F1QIBisHWn0">Foundations of Energy Savings Performance Contracting in Mississippi Training Video</a> – Educational resource from September 2023 event.</li>
</ul>
<h2>ESPC Campaign Participation and Impact</h2>
<p>Mississippi has joined the U.S. Department of Energy’s Energy Savings Performance Contracting (ESPC) Campaign, a voluntary initiative supporting states, local governments, schools, and public-sector organizations in modernizing buildings and achieving energy and water savings. This campaign aligns with multiple SDGs, including:</p>
<ul>
<li><strong>SDG 7:</strong> Affordable and Clean Energy</li>
<li><strong>SDG 8:</strong> Decent Work and Economic Growth</li>
<li><strong>SDG 11:</strong> Sustainable Cities and Communities</li>
<li><strong>SDG 13:</strong> Climate Action</li>
</ul>
<p>The campaign promotes budget-neutral facility upgrades paid over time through guaranteed savings, supports local economic development, and addresses deferred maintenance. Mississippi collaborates with DOE and campaign partners to achieve $1 billion in measured and verified savings.</p>
<p>For more information, visit the <a href="https://www.energy.gov/scep/espc-campaign/home">ESPC Campaign website</a> or contact <a href="mailto:ESPCcampaign@hq.doe.gov">ESPCcampaign@hq.doe.gov</a>.</p>
<p><img fetchpriority="high" decoding="async" src="https://mississippi.org/wp-content/uploads/Campaign-Leader-Badge-300x300.png" alt="ESPC Campaign Leader Badge" width="300" height="300"></p>
<h2>State Energy Management Program</h2>
<p>The Energy and Natural Resources Division offers technical assistance and training to state-owned facilities to reduce energy consumption and costs. This program supports SDG 7 (Affordable and Clean Energy) and SDG 13 (Climate Action) by promoting energy efficiency through:</p>
<ul>
<li>Building energy codes</li>
<li>Data gathering and energy audits</li>
<li>Employee education</li>
<li>Energy consumption reduction techniques</li>
</ul>
<p>State agencies are required to report energy metrics, granting access to online databases, video tutorials, and training opportunities.</p>
<p>Contact: <a href="mailto:semp@mississippi.org">semp@mississippi.org</a></p>
<h2>SolSmart Program: Advancing Solar Energy Leadership</h2>
<h3>Program Overview</h3>
<p>SolSmart is a national designation and technical assistance program that helps local governments and regional organizations promote solar market growth. As a SolSmart State Partner, Mississippi supports communities in achieving SolSmart designation levels—Platinum, Gold, Silver, or Bronze—signaling readiness for solar energy development.</p>
<p>By 2023, over 500 U.S. cities, towns, counties, and regional organizations have earned SolSmart designation, contributing to SDGs such as Affordable and Clean Energy (SDG 7), Sustainable Cities and Communities (SDG 11), and Decent Work and Economic Growth (SDG 8).</p>
<h3>Benefits of Joining SolSmart</h3>
<p>Communities participating in SolSmart receive free technical assistance to adopt best practices, enabling them to:</p>
<ul>
<li>Support energy resilience and local power generation</li>
<li>Achieve local energy and sustainability goals</li>
<li>Increase clean energy sector jobs and spur business development</li>
<li>Improve permitting and inspection processes</li>
<li>Reduce and stabilize energy costs for residents and businesses</li>
<li>Offer community education and engagement activities</li>
<li>Create equitable and inclusive clean energy access programs</li>
</ul>
<h3>Program Leadership and Funding</h3>
<p>SolSmart is led by The Solar Foundation and the International City/County Management Association (ICMA), funded by the U.S. Department of Energy Solar Energy Technologies</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article focuses on energy efficiency projects, renewable technologies, and solar energy leadership, directly supporting the goal of ensuring access to affordable, reliable, sustainable, and modern energy for all.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Through programs like SolSmart, local governments are encouraged to adopt clean energy solutions, improve energy resilience, and promote sustainable urban development.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Energy savings performance contracts and energy management practices promote efficient use of resources and reduction of energy consumption.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>By implementing energy efficiency and renewable energy projects, the initiatives contribute to reducing greenhouse gas emissions and addressing climate change.</li>
</ul>
</li>
<li><strong>SDG 8: Decent Work and Economic Growth</strong>
<ul>
<li>The promotion of clean energy jobs and local economic development through energy efficiency projects and SolSmart program supports sustainable economic growth and employment.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
<li>Target 7.3: Double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Target 11.3: Enhance inclusive and sustainable urbanization and capacity for participatory, integrated and sustainable human settlement planning and management.</li>
<li>Target 11.b: Increase the number of cities adopting and implementing integrated policies and plans towards inclusion, resource efficiency, mitigation and adaptation to climate change.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Target 12.2: Achieve the sustainable management and efficient use of natural resources.</li>
<li>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling and reuse.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.2: Integrate climate change measures into national policies, strategies and planning.</li>
</ul>
</li>
<li><strong>SDG 8: Decent Work and Economic Growth</strong>
<ul>
<li>Target 8.3: Promote development-oriented policies that support productive activities, decent job creation, entrepreneurship, creativity and innovation.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Energy Savings and Efficiency Indicators</strong>
<ul>
<li>Measurement and Verification (M&V) processes to track guaranteed energy savings from energy performance contracts.</li>
<li>Use of the eProjecteXpress database to document and track project data, including energy and operational savings.</li>
<li>Reporting of energy metrics by state agencies as required by the State Energy Management Program.</li>
</ul>
</li>
<li><strong>Renewable Energy Adoption Indicators</strong>
<ul>
<li>Number of local governments and regional organizations achieving SolSmart designation levels (Platinum, Gold, Silver, Bronze) indicating solar market growth.</li>
</ul>
</li>
<li><strong>Economic and Employment Indicators</strong>
<ul>
<li>Increase in jobs in the clean energy sector and local economic development as a result of energy efficiency and renewable energy projects.</li>
</ul>
</li>
<li><strong>Environmental Impact Indicators</strong>
<ul>
<li>Reduction in energy and water bills as a proxy for decreased resource consumption and environmental footprint.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy</li>
<li>7.3: Double rate of improvement in energy efficiency</li>
</ul>
</td>
<td>
<ul>
<li>Measurement and Verification (M&V) of energy savings</li>
<li>Energy metrics reporting by state agencies</li>
<li>Energy savings documented in eProjecteXpress</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>
<ul>
<li>11.3: Enhance sustainable urbanization and planning</li>
<li>11.b: Increase cities adopting integrated climate policies</li>
</ul>
</td>
<td>
<ul>
<li>Number of local governments with SolSmart designation</li>
<li>Implementation of best practices in permitting and inspection</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.2: Efficient use of natural resources</li>
<li>12.5: Reduce waste generation</li>
</ul>
</td>
<td>
<ul>
<li>Reduction in energy and water consumption</li>
<li>Energy savings from performance contracts</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.2: Integrate climate change measures into policies</li>
</ul>
</td>
<td>
<ul>
<li>Energy and water savings contributing to emission reductions</li>
<li>Adoption of renewable energy and efficiency projects</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 8: Decent Work and Economic Growth</td>
<td>
<ul>
<li>8.3: Promote policies supporting decent job creation</li>
</ul>
</td>
<td>
<ul>
<li>Increase in clean energy sector jobs</li>
<li>Local economic development linked to energy projects</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://mississippi.org/community-resources/office-of-energy/">mississippi.org</a></strong></p>
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<title>Postdoctoral researcher Kirkland Sheriff targets faster, smarter detection of explosive and other hazardous materials – Clemson News</title>
<link>https://sdgtalks.ai/postdoctoral-researcher-kirkland-sheriff-targets-faster-smarter-detection-of-explosive-and-other-hazardous-materials-clemson-news</link>
<guid>https://sdgtalks.ai/postdoctoral-researcher-kirkland-sheriff-targets-faster-smarter-detection-of-explosive-and-other-hazardous-materials-clemson-news</guid>
<description><![CDATA[ Postdoctoral researcher Kirkland Sheriff targets faster, smarter detection of explosive and other hazardous materials  Clemson News ]]></description>
<enclosure url="https://news.clemson.edu/wp-content/uploads/2025/12/111125_Kirkland-Sheriff_PM_066-scaled.jpg" length="49398" type="image/jpeg"/>
<pubDate>Mon, 12 Jan 2026 13:00:14 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Postdoctoral, researcher, Kirkland, Sheriff, targets, faster, smarter, detection, explosive, and, other, hazardous, materials, –, Clemson, News</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Postdoctoral Researcher Kirkland Sheriff Advances Detection of Explosive and Hazardous Materials</h2>
<h3>Introduction</h3>
<p>Kirkland Sheriff, a postdoctoral researcher at Clemson University, has been awarded the prestigious Intelligence Community Postdoctoral Research Fellowship by the Office of the Director of National Intelligence. This fellowship supports his research aimed at developing faster and smarter detection methods for explosives and other hazardous materials.</p>
<h3>Research Objectives and Impact on Sustainable Development Goals (SDGs)</h3>
<p>The research led by Sheriff aligns with multiple United Nations Sustainable Development Goals, particularly:</p>
<ul>
<li><strong>SDG 3: Good Health and Well-being</strong> – by improving detection of hazardous materials, the research contributes to reducing health risks associated with exposure to explosives and toxic substances.</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong> – the development of advanced detection technologies fosters innovation in safety and security infrastructure.</li>
<li><strong>SDG 16: Peace, Justice, and Strong Institutions</strong> – enhancing the ability to detect explosives supports efforts to maintain peace and security by preventing acts of terrorism and violence.</li>
</ul>
<h3>Research Focus and Methodology</h3>
<ol>
<li><strong>Development of Detection Technologies:</strong> Sheriff’s work focuses on creating novel chemical sensors and analytical methods that can rapidly identify explosive compounds and hazardous materials with high accuracy.</li>
<li><strong>Integration of Smart Systems:</strong> The research incorporates smart detection systems capable of real-time monitoring and data analysis to improve response times in critical situations.</li>
<li><strong>Collaboration and Application:</strong> The project involves collaboration with intelligence and security agencies to ensure practical applicability and deployment of the detection technologies.</li>
</ol>
<h3>Expected Outcomes and Contributions</h3>
<ul>
<li>Enhanced safety protocols through quicker identification of threats.</li>
<li>Reduction in environmental and human health hazards by preventing exposure to dangerous substances.</li>
<li>Support for national and global security efforts, contributing to safer communities.</li>
<li>Promotion of scientific innovation consistent with sustainable and responsible development.</li>
</ul>
<h3>Conclusion</h3>
<p>Kirkland Sheriff’s fellowship-supported research exemplifies the integration of scientific innovation with sustainable development priorities. By targeting faster and smarter detection of explosives and hazardous materials, this work contributes significantly to advancing health, safety, innovation, and security, thereby supporting the achievement of key Sustainable Development Goals.</p>
<div><img decoding="async" src="https://news.clemson.edu/wp-content/uploads/2025/12/111125_Kirkland-Sheriff_PM_066-scaled.jpg" alt="Kirkland Sheriff"></div>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 3: Good Health and Well-being</strong> – The article discusses faster and smarter detection of explosive and hazardous materials, which relates to protecting health and safety by preventing exposure to harmful substances.</li>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong> – The research focuses on innovative detection technologies, aligning with fostering innovation and building resilient infrastructure.</li>
<li><strong>SDG 16: Peace, Justice and Strong Institutions</strong> – Detection of explosives and hazardous materials contributes to promoting peace and security by preventing violence and terrorism.</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 3 – Target 3.9:</strong> Reduce the number of deaths and illnesses from hazardous chemicals and air, water and soil pollution and contamination.</li>
<li><strong>SDG 9 – Target 9.5:</strong> Enhance scientific research, upgrade the technological capabilities of industrial sectors, including encouraging innovation and research.</li>
<li><strong>SDG 16 – Target 16.1:</strong> Significantly reduce all forms of violence and related death rates everywhere.</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ul>
<li><strong>Indicator for SDG 3.9:</strong> Mortality rate attributed to unintentional poisoning (including exposure to hazardous materials).</li>
<li><strong>Indicator for SDG 9.5:</strong> Research and development expenditure as a proportion of GDP and number of researchers per million inhabitants.</li>
<li><strong>Indicator for SDG 16.1:</strong> Number of victims of intentional homicide per 100,000 population, by sex and age.</li>
<li><em>Implied indicators:</em> Speed and accuracy of detection technologies for hazardous materials; number of incidents prevented due to improved detection methods.</li>
</ul>
<h2>4. Table of SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 3: Good Health and Well-being</td>
<td>Target 3.9: Reduce deaths and illnesses from hazardous chemicals and pollution</td>
<td>Mortality rate attributed to unintentional poisoning; exposure to hazardous materials</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation and Infrastructure</td>
<td>Target 9.5: Enhance scientific research and technological capabilities</td>
<td>R&D expenditure as % of GDP; number of researchers per million inhabitants; speed and accuracy of detection technologies</td>
</tr>
<tr>
<td>SDG 16: Peace, Justice and Strong Institutions</td>
<td>Target 16.1: Reduce all forms of violence and related death rates</td>
<td>Number of victims of intentional homicide per 100,000 population; incidents prevented by improved detection</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://news.clemson.edu/postdoctoral-researcher-kirkland-sheriff-targets-faster-smarter-detection-of-explosive-and-other-hazardous-materials/">news.clemson.edu</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Trump’s blatant oil grab lays bare the violence of a fossil fuel economy – TBIJ</title>
<link>https://sdgtalks.ai/trumps-blatant-oil-grab-lays-bare-the-violence-of-a-fossil-fuel-economy-tbij</link>
<guid>https://sdgtalks.ai/trumps-blatant-oil-grab-lays-bare-the-violence-of-a-fossil-fuel-economy-tbij</guid>
<description><![CDATA[ Trump’s blatant oil grab lays bare the violence of a fossil fuel economy  TBIJ ]]></description>
<enclosure url="https://www.thebureauinvestigates.com/cdn-cgi/image/width=1200,height=630,quality=82,format=auto,fit=cover/filestore/images/trump-oil.png" length="49398" type="image/jpeg"/>
<pubDate>Fri, 09 Jan 2026 03:23:58 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Trump’s, blatant, oil, grab, lays, bare, the, violence, fossil, fuel, economy, –, TBIJ</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on the Venezuelan Crisis and Its Implications for Sustainable Development Goals (SDGs)</h2>
<div><img decoding="async" src="https://www.thebureauinvestigates.com/cdn-cgi/image/width=1200,height=630,quality=82,format=auto,fit=cover/filestore/images/trump-oil.png?mtime=1767778500" alt="Venezuelan Oil Interests"></div>
<h3>Overview of the Situation</h3>
<p>The recent events in Venezuela do not constitute a conventional invasion or political coup. There has been minimal rhetoric about spreading liberty and democracy, no deployment of US troops, and senior government officials remain in place, indicating limited interest in regime change. The plight of Venezuelan citizens, both within the country and among the millions of migrants, who have suffered political oppression and severe economic hardship, has received little attention.</p>
<h3>Underlying Motives: Oil and Economic Interests</h3>
<p>The primary motive behind international interest in Venezuela is its oil resources. This is underscored by local sentiment, as illustrated by a viral comment highlighting foreign powers’ focus on Venezuela’s oil rather than its culture. For the United States, particularly under the Trump administration, this interest aligns with settling disputes related to the nationalization of oil assets by former president Hugo Chávez.</p>
<h3>Trump Administration’s National Security Strategy</h3>
<p>The Trump administration’s 2025 National Security Strategy emphasizes a strong stance against drug trafficking and a robust support for fossil fuel industries. This approach has manifested in aggressive policies that may include military action, signaling a potential shift in global security dynamics, sovereignty issues, and environmental concerns.</p>
<h2>Implications for Sustainable Development Goals (SDGs)</h2>
<h3>SDG 7: Affordable and Clean Energy</h3>
<ul>
<li>The focus on fossil fuels contradicts the global agenda to transition towards renewable energy sources.</li>
<li>Continued exploitation of oil resources in Venezuela may delay progress in clean energy adoption.</li>
</ul>
<h3>SDG 13: Climate Action</h3>
<ul>
<li>Military aggression and fossil fuel promotion risk exacerbating climate change impacts.</li>
<li>Environmental degradation in Venezuela could increase due to intensified oil extraction activities.</li>
</ul>
<h3>SDG 16: Peace, Justice, and Strong Institutions</h3>
<ul>
<li>The abduction of President Maduro has been described by legal experts as a kidnapping, raising concerns about respect for international law.</li>
<li>Regional condemnation by Brazil, Chile, Spain, Uruguay, Mexico, and Colombia highlights the threat to peace and security in the Americas.</li>
<li>Such actions undermine sovereignty and the rule of law, essential components of SDG 16.</li>
</ul>
<h3>SDG 1: No Poverty and SDG 10: Reduced Inequalities</h3>
<ul>
<li>The ongoing political and economic instability exacerbates poverty and inequality within Venezuela.</li>
<li>Millions of Venezuelan migrants face hardships that hinder progress towards these goals.</li>
</ul>
<h2>Regional and International Reactions</h2>
<ol>
<li>Following the controversial abduction of President Maduro, warnings have been issued to neighboring countries, including Colombia and Mexico, indicating potential threats to their security.</li>
<li>A coalition of countries—Brazil, Chile, Spain, Uruguay, Mexico, and Colombia—issued a joint statement condemning the raid on Venezuela as a violation of international law and a dangerous precedent for peace and security in the region.</li>
</ol>
<h2>Conclusion</h2>
<p>The unfolding crisis in Venezuela, driven by strategic interests in fossil fuels and geopolitical maneuvers, poses significant challenges to multiple Sustainable Development Goals. The emphasis on military aggression and fossil fuel exploitation threatens climate action, peace, and social equity. Regional and international responses underscore the need for adherence to international law and the protection of human rights to ensure sustainable development and stability in the Americas.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 16: Peace, Justice and Strong Institutions</strong>
<ul>
<li>The article discusses political oppression, regime change, and violations of international law, which relate to promoting peaceful and inclusive societies, access to justice, and accountable institutions.</li>
</ul>
</li>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The focus on oil interests and fossil fuels connects to energy production and consumption patterns.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>The article highlights concerns about fossil fuel promotion and its impact on climate, indicating relevance to combating climate change and its impacts.</li>
</ul>
</li>
<li><strong>SDG 10: Reduced Inequalities</strong>
<ul>
<li>The mention of Venezuelan migrants and economic hardship relates to reducing inequalities within and among countries.</li>
</ul>
</li>
<li><strong>SDG 3: Good Health and Well-being</strong>
<ul>
<li>Drug production and trafficking issues mentioned relate indirectly to health and well-being challenges.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 16</strong>
<ul>
<li>Target 16.1: Significantly reduce all forms of violence and related death rates everywhere.</li>
<li>Target 16.3: Promote the rule of law at the national and international levels and ensure equal access to justice for all.</li>
<li>Target 16.7: Ensure responsive, inclusive, participatory and representative decision-making at all levels.</li>
</ul>
</li>
<li><strong>SDG 7</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
<li>Target 7.a: Enhance international cooperation to facilitate access to clean energy research and technology.</li>
</ul>
</li>
<li><strong>SDG 13</strong>
<ul>
<li>Target 13.2: Integrate climate change measures into national policies, strategies and planning.</li>
</ul>
</li>
<li><strong>SDG 10</strong>
<ul>
<li>Target 10.7: Facilitate orderly, safe, regular and responsible migration and mobility of people.</li>
</ul>
</li>
<li><strong>SDG 3</strong>
<ul>
<li>Target 3.5: Strengthen the prevention and treatment of substance abuse, including narcotic drug abuse and harmful use of alcohol.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>For SDG 16</strong>
<ul>
<li>Indicator 16.1.3: Proportion of population subjected to physical, psychological or sexual violence in the previous 12 months.</li>
<li>Indicator 16.3.1: Proportion of victims of violence in the previous 12 months who reported their victimization to competent authorities.</li>
<li>Indicator 16.7.2: Proportion of population who believe decision-making is inclusive and responsive.</li>
</ul>
</li>
<li><strong>For SDG 7</strong>
<ul>
<li>Indicator 7.2.1: Renewable energy share in the total final energy consumption.</li>
<li>Indicator 7.a.1: International financial flows to developing countries in support of clean energy research and development.</li>
</ul>
</li>
<li><strong>For SDG 13</strong>
<ul>
<li>Indicator 13.2.1: Number of countries that have communicated the establishment or operationalization of an integrated policy/strategy/plan which increases their ability to adapt to the adverse impacts of climate change.</li>
</ul>
</li>
<li><strong>For SDG 10</strong>
<ul>
<li>Indicator 10.7.2: Number of countries that have implemented well-managed migration policies.</li>
</ul>
</li>
<li><strong>For SDG 3</strong>
<ul>
<li>Indicator 3.5.1: Coverage of treatment interventions (pharmacological, psychosocial and rehabilitation and aftercare services) for substance use disorders.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 16: Peace, Justice and Strong Institutions</td>
<td>
<ul>
<li>16.1: Reduce violence and related deaths</li>
<li>16.3: Promote rule of law and access to justice</li>
<li>16.7: Inclusive decision-making</li>
</ul>
</td>
<td>
<ul>
<li>16.1.3: Population subjected to violence</li>
<li>16.3.1: Victims reporting violence</li>
<li>16.7.2: Perception of inclusive decision-making</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase renewable energy share</li>
<li>7.a: Support clean energy research and technology</li>
</ul>
</td>
<td>
<ul>
<li>7.2.1: Renewable energy share in consumption</li>
<li>7.a.1: Financial flows for clean energy R&D</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.2: Integrate climate change measures into policies</li>
</ul>
</td>
<td>
<ul>
<li>13.2.1: Countries with integrated climate policies</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 10: Reduced Inequalities</td>
<td>
<ul>
<li>10.7: Facilitate safe and responsible migration</li>
</ul>
</td>
<td>
<ul>
<li>10.7.2: Countries implementing migration policies</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 3: Good Health and Well-being</td>
<td>
<ul>
<li>3.5: Prevention and treatment of substance abuse</li>
</ul>
</td>
<td>
<ul>
<li>3.5.1: Coverage of treatment interventions for substance use disorders</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.thebureauinvestigates.com/stories/2026-01-07/trumps-blatant-oil-grab-lays-bare-the-violence-of-the-fossil-fuel-economy">thebureauinvestigates.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Beyond Energy Use: Strategies for Sustainable Data Center Operations – Data Center Knowledge</title>
<link>https://sdgtalks.ai/beyond-energy-use-strategies-for-sustainable-data-center-operations-data-center-knowledge</link>
<guid>https://sdgtalks.ai/beyond-energy-use-strategies-for-sustainable-data-center-operations-data-center-knowledge</guid>
<description><![CDATA[ Beyond Energy Use: Strategies for Sustainable Data Center Operations  Data Center Knowledge ]]></description>
<enclosure url="https://eu-images.contentstack.com/v3/assets/blt8eb3cdfc1fce5194/blt451c9fee473a6e21/695c089a4f81f946c211c360/Data-Center-at-Night-Alamy.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 06 Jan 2026 22:00:12 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Beyond, Energy, Use:, Strategies, for, Sustainable, Data, Center, Operations, –, Data, Center, Knowledge</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Sustainable Development in the Expansion of Data Centers</h2>
<h3>Overview of Data Center Growth and Energy Consumption</h3>
<p>The rapid expansion of data centers, driven by the increasing adoption of artificial intelligence (AI), presents significant sustainability challenges. By the end of 2024, 1,240 data centers in the United States were either built or approved for construction, intensifying concerns about their energy and natural resource consumption.</p>
<p>According to the International Energy Agency (IEA), a typical hyperscale data center consumes as much electricity as 100,000 households, with larger facilities under construction expected to use up to 20 times more energy. In 2023, data centers accounted for approximately 26% of Virginia’s total electricity consumption, with notable shares in North Dakota (15%) and Nebraska (12%), as reported by the Electric Power Research Institute.</p>
<h3>Legislative Measures and Energy Efficiency Initiatives</h3>
<p>To align with Sustainable Development Goal (SDG) 7: Affordable and Clean Energy, several states have introduced legislation to mitigate grid strain caused by data centers. These measures include incentives or requirements for data centers to provide energy storage or generation to enhance grid reliability.</p>
<ol>
<li>Illinois has enacted H.B. 3758 and S.B. 2497, targeting 15 GW of state energy storage and establishing a virtual power plant program aimed at job creation and energy price reduction.</li>
<li>California’s Public Utilities Commission enforces energy efficiency and carbon footprint standards under the California Energy Code (Title 24), indirectly promoting renewable energy use.</li>
</ol>
<h2>Strategic E-Waste Reduction and Circular Economy Practices</h2>
<h3>Challenges of E-Waste from Data Centers</h3>
<p>Data centers contribute significantly to electronic waste (e-waste), with server and GPU refresh cycles occurring every two to five years. Over 80% of outdated equipment is discarded, contributing to millions of tons of e-waste globally. In 2022, an estimated 62 million tons of e-waste were generated worldwide, ranking it among the fastest-growing solid waste streams, per the World Health Organization.</p>
<p>A recent study highlights that generative AI alone could add 1.2 to 5 million tons of annual e-waste, exacerbating environmental and health risks. Addressing this issue supports SDG 12: Responsible Consumption and Production.</p>
<h3>Implementing Sustainable Lifecycle Practices</h3>
<ul>
<li><strong>Modular and Upgradeable Systems:</strong> Data centers can reduce e-waste by adopting modular, repairable, and upgradeable hardware systems. Replacing individual components such as power supplies, memory, or processors extends equipment life and reduces full hardware replacements.</li>
<li><strong>AI-Powered Asset Tracking and Secure Sanitization:</strong> Utilizing AI-driven asset tracking and standards-based data sanitization software (e.g., NIST 800-88, ISO 27040) enables secure refurbishment, resale, or donation of hardware components. This approach ensures compliance with data privacy laws and Environmental, Social, and Governance (ESG) requirements, furthering SDG 9: Industry, Innovation, and Infrastructure.</li>
</ul>
<h2>Partner Engagement for Sustainable End-of-Life Hardware Management</h2>
<h3>Role of Third-Party IT Asset Disposition (ITAD) Companies</h3>
<p>Collaboration with certified ITAD providers (R2v3 or e-Stewards certified) is essential for responsible hardware disposal. These partners specialize in circular economy processes, extracting usable materials, managing resale channels, and extending component lifecycles, thereby reducing landfill waste and supporting SDG 11: Sustainable Cities and Communities.</p>
<p>ITAD partnerships help data center operators meet sustainability targets, monetize used assets, and enhance their reputation among eco-conscious stakeholders.</p>
<h2>Building a Sustainable Future for Data Centers</h2>
<h3>Holistic Sustainability Approach</h3>
<p>The ongoing expansion of data centers requires operators to adopt comprehensive sustainability strategies that address energy consumption and e-waste management. Integrating AI-enabled lifecycle visibility, secure sanitization, circular design principles, and certified reuse/resale programs enables data centers to:</p>
<ul>
<li>Minimize environmental impact on regional energy grids (supporting SDG 7 and SDG 13: Climate Action)</li>
<li>Reduce landfill waste and preserve critical materials (advancing SDG 12)</li>
<li>Enhance cyber-resilience and infrastructure sustainability (aligning with SDG 9)</li>
</ul>
<p>By balancing data security with environmental responsibility, data center operators can contribute significantly to the achievement of the United Nations Sustainable Development Goals.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Article discusses the high energy consumption of data centers and efforts to improve energy efficiency and use renewable energy sources.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong>
<ul>
<li>Focus on sustainable infrastructure development for data centers and adoption of innovative technologies like AI-powered asset tracking.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Emphasis on reducing e-waste through circular economy models, reuse, refurbishment, and sustainable lifecycle practices.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Addressing carbon footprint management and reducing environmental impact of data centers.</li>
</ul>
</li>
<li><strong>SDG 17: Partnerships for the Goals</strong>
<ul>
<li>Collaboration with third-party IT asset disposition companies to achieve sustainability goals.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Identified SDGs</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix (implied by California Energy Code promoting renewable energy use).</li>
<li>Target 7.3: Double the global rate of improvement in energy efficiency (energy efficiency standards for data centers).</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong>
<ul>
<li>Target 9.4: Upgrade infrastructure and retrofit industries to make them sustainable, with increased resource-use efficiency and greater adoption of clean and environmentally sound technologies.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse (circular data center models, reuse and refurbishment of hardware).</li>
<li>Target 12.6: Encourage companies to adopt sustainable practices and sustainability reporting.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.1: Strengthen resilience and adaptive capacity to climate-related hazards and natural disasters (carbon footprint management and energy storage to reduce grid strain).</li>
</ul>
</li>
<li><strong>SDG 17: Partnerships for the Goals</strong>
<ul>
<li>Target 17.16: Enhance the global partnership for sustainable development, complemented by multi-stakeholder partnerships (collaboration with certified ITAD companies).</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Energy Consumption Metrics</strong>
<ul>
<li>Percentage of total electricity supply consumed by data centers in states (e.g., 26% in Virginia, 15% in North Dakota, 12% in Nebraska).</li>
<li>Energy efficiency standards compliance (e.g., California Energy Code Title 24).</li>
<li>Capacity targets for energy storage (e.g., Illinois targeting 15 GW of state energy storage).</li>
</ul>
</li>
<li><strong>E-Waste Generation and Reduction</strong>
<ul>
<li>Amount of e-waste generated globally and by data centers (e.g., 62 million tons globally in 2022, additional 1.2–5 million tons from generative AI).</li>
<li>Percentage of e-waste discarded vs. reused or refurbished (more than 80% discarded currently).</li>
</ul>
</li>
<li><strong>Certification and Compliance Indicators</strong>
<ul>
<li>Use of standards-based data sanitization software compliant with NIST 800-88 and ISO 27040.</li>
<li>Certification of IT asset disposition partners (R2v3 or e-Stewards certified).</li>
<li>Audit logs generated for compliance with data privacy laws and ESG requirements.</li>
</ul>
</li>
<li><strong>Job Creation and Economic Impact</strong>
<ul>
<li>Creation of jobs through programs like virtual power plants (e.g., Illinois legislation).</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy</li>
<li>7.3: Improve energy efficiency</li>
</ul>
</td>
<td>
<ul>
<li>Energy consumption as % of state electricity supply (e.g., 26% in Virginia)</li>
<li>Compliance with California Energy Code (Title 24)</li>
<li>State energy storage capacity targets (e.g., 15 GW in Illinois)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation and Infrastructure</td>
<td>
<ul>
<li>9.4: Upgrade infrastructure for sustainability and resource efficiency</li>
</ul>
</td>
<td>
<ul>
<li>Adoption of AI-powered asset tracking and sustainable lifecycle practices</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.5: Reduce waste generation through reuse and recycling</li>
<li>12.6: Encourage sustainable corporate practices</li>
</ul>
</td>
<td>
<ul>
<li>Volume of e-waste generated and recycled/refurbished</li>
<li>Percentage of e-waste discarded (currently >80%)</li>
<li>Use of circular economy models in data centers</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.1: Strengthen resilience and adaptive capacity to climate hazards</li>
</ul>
</td>
<td>
<ul>
<li>Carbon footprint management standards</li>
<li>Energy storage and generation to reduce grid strain</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 17: Partnerships for the Goals</td>
<td>
<ul>
<li>17.16: Enhance multi-stakeholder partnerships for sustainable development</li>
</ul>
</td>
<td>
<ul>
<li>Engagement with certified IT asset disposition partners (R2v3, e-Stewards)</li>
<li>Audit logs ensuring compliance with data privacy and ESG requirements</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.datacenterknowledge.com/sustainability/beyond-energy-use-strategies-for-more-sustainable-data-center-operations">datacenterknowledge.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Top Waste Management Stocks To Consider – January 4th – MarketBeat</title>
<link>https://sdgtalks.ai/top-waste-management-stocks-to-consider-january-4th-marketbeat</link>
<guid>https://sdgtalks.ai/top-waste-management-stocks-to-consider-january-4th-marketbeat</guid>
<description><![CDATA[ Top Waste Management Stocks To Consider - January 4th  MarketBeat ]]></description>
<enclosure url="https://www.marketbeat.com/logos/premium-reports/small_20250423161124_reportpreview2025-04-elon-musks-next-move---cover.png" length="49398" type="image/jpeg"/>
<pubDate>Mon, 05 Jan 2026 00:00:12 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Top, Waste, Management, Stocks, Consider, –, January, 4th, –, MarketBeat</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Report on Leading Waste Management Stocks and Their Alignment with Sustainable Development Goals (SDGs)</h2>
<p>This report highlights three prominent waste management stocks identified by MarketBeat’s stock screener tool: Waste Management (WM), GFL Environmental (GFL), and Custom Truck One Source (CTOS). These companies play a critical role in environmental sustainability by managing municipal, commercial, and industrial waste through collection, transportation, processing, recycling, and disposal services. Their operations contribute directly to several United Nations Sustainable Development Goals (SDGs), including SDG 11 (Sustainable Cities and Communities), SDG 12 (Responsible Consumption and Production), and SDG 13 (Climate Action).</p>
<h2>1. Waste Management (WM)</h2>
<h3>Company Overview</h3>
<p>Waste Management, Inc. provides comprehensive environmental solutions across the United States and Canada. The company’s services include:</p>
<ul>
<li>Collection and transportation of waste and recyclable materials</li>
<li>Operation of transfer stations and material recovery facilities (MRFs)</li>
<li>Development and management of landfill sites that generate renewable natural gas from landfill gas for electricity production</li>
</ul>
<p>These activities support SDG 7 (Affordable and Clean Energy) through renewable natural gas generation and SDG 13 by reducing greenhouse gas emissions.</p>
<p><a href="https://www.marketbeat.com/arnreports/ReportTickerOptin.aspx?RegistrationCode=TickerHyperlink&Prefix=NYSE&Symbol=WM">Read Our Latest Research Report on WM</a></p>
<h2>2. GFL Environmental (GFL)</h2>
<h3>Company Overview</h3>
<p>GFL Environmental Inc. specializes in non-hazardous solid waste management and environmental services in Canada and the United States. Its service portfolio includes:</p>
<ul>
<li>Solid waste management</li>
<li>Liquid waste management</li>
<li>Soil remediation</li>
<li>Collection, transportation, transfer, recycling, and disposal services for municipal, residential, commercial, and industrial customers</li>
</ul>
<p>GFL’s operations contribute to SDG 6 (Clean Water and Sanitation) by managing liquid waste and SDG 15 (Life on Land) through soil remediation initiatives.</p>
<p><a href="https://www.marketbeat.com/arnreports/ReportTickerOptin.aspx?RegistrationCode=TickerHyperlink&Prefix=NYSE&Symbol=GFL">Read Our Latest Research Report on GFL</a></p>
<h2>3. Custom Truck One Source (CTOS)</h2>
<h3>Company Overview</h3>
<p>Custom Truck One Source, Inc. provides specialty equipment rental and sales services supporting infrastructure industries such as electric utility transmission, telecommunications, rail, forestry, and waste management in the United States and Canada. The company operates through three segments:</p>
<ol>
<li>Equipment Rental Solutions (ERS)</li>
<li>Truck and Equipment Sales (TES)</li>
<li>Aftermarket Parts and Services (APS)</li>
</ol>
<p>By enabling efficient infrastructure maintenance and development, CTOS supports SDG 9 (Industry, Innovation, and Infrastructure) and SDG 11 (Sustainable Cities and Communities).</p>
<p><a href="https://www.marketbeat.com/arnreports/ReportTickerOptin.aspx?RegistrationCode=TickerHyperlink&Prefix=NYSE&Symbol=CTOS">Read Our Latest Research Report on CTOS</a></p>
<h2>Market Insights and Analyst Recommendations</h2>
<p>MarketBeat monitors top-rated Wall Street analysts and their stock recommendations daily. Although Waste Management currently holds a Moderate Buy rating, analysts have identified five alternative stocks with stronger buy potential. This insight encourages investors to consider diversified opportunities within the waste management and environmental services sectors to support sustainable investment aligned with SDGs.</p>
<p><a class="btn btn-featured" href="https://www.marketbeat.com/newsletter/PDFoffer.aspx?offer=top5&RegistrationCode=ArticlePage-ShouldYouInvest">View The Five Stocks Here <span class="mr-3 fa-regular fa-angle-right" aria-hidden="true"></span></a></p>
<h2>Conclusion</h2>
<p>The highlighted waste management companies demonstrate significant contributions to sustainable development through their environmental services and infrastructure support. Their operations align with multiple SDGs, emphasizing the importance of sustainable waste management practices in achieving global environmental and social objectives.</p>
<h2>Sharing and Further Information</h2>
<p>For further dissemination of this report and to promote awareness of sustainable investment opportunities in waste management, please share this information through the following platforms:</p>
<ul>
<li><a href="https://www.facebook.com/sharer/sharer.php?u=https://www.marketbeat.com/instant-alerts/top-waste-management-stocks-to-consider-january-4th-2026-01-04/" target="_blank" rel="nofollow noopener">Facebook</a></li>
<li><a href="https://twitter.com/intent/tweet?text=Top+Waste+Management+Stocks+To+Consider+-+January+4th%20%24WM%20%23WM%20https://www.marketbeat.com/instant-alerts/top-waste-management-stocks-to-consider-january-4th-2026-01-04/" target="_blank" rel="nofollow noopener">Twitter</a></li>
<li><a href="https://www.linkedin.com/cws/share?mini=true&url=https://www.marketbeat.com/instant-alerts/top-waste-management-stocks-to-consider-january-4th-2026-01-04/" target="popup" rel="nofollow noopener">LinkedIn</a></li>
<li><a href="https://api.stocktwits.com/widgets/share?via=MarketBeat&body=Top+Waste+Management+Stocks+To+Consider+-+January+4th%20https://www.marketbeat.com/instant-alerts/top-waste-management-stocks-to-consider-january-4th-2026-01-04/" target="_blank" rel="nofollow noopener">StockTwits</a></li>
</ul>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>The article discusses waste management services that contribute to sustainable urban living through proper waste collection, recycling, and disposal.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The focus on recycling, waste processing, and environmental services aligns with promoting sustainable consumption and production patterns.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Waste Management’s operation of landfill facilities producing landfill gas used as renewable natural gas for electricity generation supports climate action by reducing greenhouse gas emissions.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation and Infrastructure</strong>
<ul>
<li>Custom Truck One Source provides specialty equipment rental and sales to infrastructure-related industries, supporting resilient infrastructure and innovation.</li>
</ul>
</li>
<li><strong>SDG 6: Clean Water and Sanitation</strong>
<ul>
<li>GFL Environmental’s liquid waste management and soil remediation services contribute to clean water and sanitation by managing waste that could affect water quality.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 11: Target 11.6</strong>
<ul>
<li>Reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.</li>
</ul>
</li>
<li><strong>SDG 12: Target 12.5</strong>
<ul>
<li>Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
</ul>
</li>
<li><strong>SDG 13: Target 13.2</strong>
<ul>
<li>Integrate climate change measures into policies and strategies, such as using renewable energy sources like landfill gas for electricity generation.</li>
</ul>
</li>
<li><strong>SDG 9: Target 9.1</strong>
<ul>
<li>Develop quality, reliable, sustainable, and resilient infrastructure, including regional and transborder infrastructure, to support economic development and human well-being.</li>
</ul>
</li>
<li><strong>SDG 6: Target 6.3</strong>
<ul>
<li>Improve water quality by reducing pollution, eliminating dumping, and minimizing release of hazardous chemicals and materials.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Indicator for SDG 11.6</strong>
<ul>
<li>Municipal waste collected and managed in controlled facilities.</li>
<li>Reduction in per capita waste generation.</li>
</ul>
</li>
<li><strong>Indicator for SDG 12.5</strong>
<ul>
<li>Amount of waste recycled and reused as a percentage of total waste generated.</li>
</ul>
</li>
<li><strong>Indicator for SDG 13.2</strong>
<ul>
<li>Amount of renewable energy generated from landfill gas (e.g., landfill gas used as renewable natural gas for electricity).</li>
</ul>
</li>
<li><strong>Indicator for SDG 9.1</strong>
<ul>
<li>Availability and use of specialty equipment supporting infrastructure sectors.</li>
</ul>
</li>
<li><strong>Indicator for SDG 6.3</strong>
<ul>
<li>Volume of liquid waste treated and soil remediated to reduce pollution.</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>Target 11.6: Reduce the adverse per capita environmental impact of cities, including municipal waste management.</td>
<td>Municipal waste collected and managed in controlled facilities; Reduction in per capita waste generation.</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</td>
<td>Amount of waste recycled and reused as a percentage of total waste generated.</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>Target 13.2: Integrate climate change measures into policies and strategies.</td>
<td>Amount of renewable energy generated from landfill gas used for electricity.</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation and Infrastructure</td>
<td>Target 9.1: Develop sustainable and resilient infrastructure to support economic development.</td>
<td>Availability and use of specialty equipment supporting infrastructure sectors.</td>
</tr>
<tr>
<td>SDG 6: Clean Water and Sanitation</td>
<td>Target 6.3: Improve water quality by reducing pollution and minimizing hazardous waste release.</td>
<td>Volume of liquid waste treated and soil remediated to reduce pollution.</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.marketbeat.com/instant-alerts/top-waste-management-stocks-to-consider-january-4th-2026-01-04/">marketbeat.com</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>Clean Buildings Performance Standard (CBPS) – Washington State Department of Commerce (.gov)</title>
<link>https://sdgtalks.ai/clean-buildings-performance-standard-cbps-washington-state-department-of-commerce-gov</link>
<guid>https://sdgtalks.ai/clean-buildings-performance-standard-cbps-washington-state-department-of-commerce-gov</guid>
<description><![CDATA[ Clean Buildings Performance Standard (CBPS)  Washington State Department of Commerce (.gov) ]]></description>
<enclosure url="https://www.commerce.wa.gov/wp-content/uploads/2024/07/AdobeStock_620542466-scaled-1-1024x574.jpeg" length="49398" type="image/jpeg"/>
<pubDate>Thu, 01 Jan 2026 06:00:15 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Clean, Buildings, Performance, Standard, CBPS, –, Washington, State, Department, Commerce, .gov</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Clean Buildings Initiative and Sustainable Development Goals</h2>
<p>Clean buildings play a critical role in advancing the Sustainable Development Goals (SDGs), particularly SDG 7 (Affordable and Clean Energy), SDG 11 (Sustainable Cities and Communities), and SDG 13 (Climate Action). In 2019, the Clean Buildings bill was enacted and subsequently expanded in 2022 and 2023 to reduce energy costs and pollution associated with fossil fuel consumption in existing covered buildings, multifamily residences, and campus district energy systems within the state.</p>
<p>The legislation incentivizes early energy efficiency improvements through Tier 1 and Tier 2 programs, supporting the transition towards sustainable energy use and contributing to climate resilience and sustainable urban development.</p>
<h2>Compliance Deadlines Aligned with SDGs</h2>
<h3>Tier 1 Covered Buildings Reporting Schedule</h3>
<ol>
<li><strong>June 1, 2026:</strong> Buildings larger than 220,000 sq. ft.</li>
<li><strong>June 1, 2027:</strong> Buildings between 90,001 and 220,000 sq. ft.</li>
<li><strong>June 1, 2028:</strong> Buildings between 50,001 and 90,000 sq. ft.</li>
</ol>
<h3>Tier 2 Covered Buildings Reporting Schedule</h3>
<ul>
<li><strong>July 1, 2027:</strong> Buildings between 20,001 and 50,000 sq. ft. and all multifamily residential buildings over 20,000 sq. ft.</li>
</ul>
<p>These deadlines ensure systematic progress toward energy efficiency, supporting SDG 7 by promoting clean energy consumption and SDG 13 by mitigating climate change impacts.</p>
<h2>HB1543 Rulemaking Process Supporting SDG Implementation</h2>
<ul>
<li><a href="https://app.smartsheet.com/b/publish?EQBCT=eac76bad3436427ca460a17469ac1ae5">HB1543 Rulemaking Comment Dashboard</a></li>
<li>Informational Session: Overview of HB1543 and the rulemaking process</li>
<li>Workshop 1: Extensions and exemptions</li>
<li>Workshop 2: Alternative compliance pathways</li>
<li>Workshop 3: Clarifying language</li>
<li>Workshop 4: Comprehensive review</li>
</ul>
<p>The rulemaking workshops facilitate stakeholder engagement and transparency, fostering inclusive decision-making aligned with SDG 17 (Partnerships for the Goals).</p>
<h2>Qualified Energy Manager (QEM) Training</h2>
<p>The program offers specialized training for Qualified Energy Managers, equipping professionals with skills to implement energy efficiency measures effectively. This initiative supports SDG 4 (Quality Education) by providing targeted capacity-building opportunities and SDG 7 by enhancing energy management expertise.</p>
<h2>News and Updates</h2>
<h3>Funding Opportunity for CBPS Compliance</h3>
<p><strong>Date:</strong> December 31, 2025</p>
<p>An upcoming proposal conference is scheduled for January 28, 2026, from 12:00 to 1:00 p.m. to discuss a new Request for Applications (RFA) aimed at assisting stakeholders in meeting Clean Buildings Performance Standard (CBPS) compliance. This funding opportunity promotes SDG 9 (Industry, Innovation, and Infrastructure) by supporting innovative energy solutions.</p>
<h2>Resources to Support Sustainable Development</h2>
<h3>Office Hours</h3>
<p>Monthly office hours are held on the fourth Tuesday from 10:00 to 11:00 a.m. PT, providing stakeholders with direct access to Clean Buildings staff for guidance, questions, and scenario discussions. This resource enhances community engagement and knowledge sharing, contributing to SDG 11 and SDG 17.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article focuses on reducing fossil fuel consumption and improving energy efficiency in buildings, directly relating to SDG 7’s aim to ensure access to affordable, reliable, sustainable, and modern energy.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>By targeting energy efficiency in existing buildings and multifamily residential buildings, the article addresses making cities and human settlements inclusive, safe, resilient, and sustainable.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>The reduction of pollution from fossil fuel consumption in buildings contributes to combating climate change and its impacts.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under the Identified SDGs</h2>
<ol>
<li><strong>SDG 7 Targets</strong>
<ul>
<li><strong>Target 7.3:</strong> By 2030, double the global rate of improvement in energy efficiency.</li>
<li>The Clean Buildings bill’s focus on energy efficiency improvements and incentives aligns with this target.</li>
</ul>
</li>
<li><strong>SDG 11 Targets</strong>
<ul>
<li><strong>Target 11.6:</strong> Reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.</li>
<li>Reducing pollution from fossil fuel consumption in buildings supports this target.</li>
</ul>
</li>
<li><strong>SDG 13 Targets</strong>
<ul>
<li><strong>Target 13.2:</strong> Integrate climate change measures into national policies, strategies, and planning.</li>
<li>The Clean Buildings law and its rulemaking workshops indicate integration of climate action into state policy.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Energy Consumption Metrics</strong>
<ul>
<li>Reporting schedules based on building size (square footage) imply measurement of energy use and efficiency improvements in covered buildings.</li>
</ul>
</li>
<li><strong>Compliance Reporting Deadlines</strong>
<ul>
<li>Deadlines for Tier 1 and Tier 2 covered buildings to report compliance indicate tracking of adherence to energy efficiency standards.</li>
</ul>
</li>
<li><strong>Incentive Uptake</strong>
<ul>
<li>The availability of Tier 1 and Tier 2 incentives to encourage early improvements suggests monitoring the number of building owners utilizing these incentives.</li>
</ul>
</li>
<li><strong>Rulemaking and Policy Implementation</strong>
<ul>
<li>Workshops and rulemaking processes (HB1543) imply indicators related to policy development and implementation progress.</li>
</ul>
</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>Target 7.3: Double the global rate of improvement in energy efficiency by 2030.</td>
<td>
<ul>
<li>Energy consumption data from covered buildings.</li>
<li>Number of buildings reporting compliance by deadlines.</li>
<li>Uptake of Tier 1 and Tier 2 incentives.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>Target 11.6: Reduce adverse environmental impact of cities, including air quality improvements.</td>
<td>
<ul>
<li>Reduction in pollution from fossil fuel consumption in buildings.</li>
<li>Compliance with Clean Buildings Performance Standards.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>Target 13.2: Integrate climate change measures into policies and planning.</td>
<td>
<ul>
<li>Progress in HB1543 rulemaking workshops and policy adoption.</li>
<li>Implementation of Clean Buildings law provisions.</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.commerce.wa.gov/cbps/">commerce.wa.gov</a></strong></p>
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<title>Vanguard Renewables Opens Second Anaerobic Digestion Facility in Wisconsin – FoodEngineeringMag.com</title>
<link>https://sdgtalks.ai/vanguard-renewables-opens-second-anaerobic-digestion-facility-in-wisconsin-foodengineeringmagcom</link>
<guid>https://sdgtalks.ai/vanguard-renewables-opens-second-anaerobic-digestion-facility-in-wisconsin-foodengineeringmagcom</guid>
<description><![CDATA[ Vanguard Renewables Opens Second Anaerobic Digestion Facility in Wisconsin  FoodEngineeringMag.com ]]></description>
<enclosure url="https://www.foodengineeringmag.com/ext/resources/2025/12/23/Vanguard-Renewables-River-Falls-Facility_1170x658.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sat, 27 Dec 2025 01:30:17 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Vanguard, Renewables, Opens, Second, Anaerobic, Digestion, Facility, Wisconsin, –, FoodEngineeringMag.com</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Vanguard Renewables Opens Anaerobic Digestion and Depackaging Facility in River Falls, Wisconsin</h2>
<h3>Introduction</h3>
<p>Vanguard Renewables has inaugurated a new anaerobic digestion and depackaging facility located in River Falls, Wisconsin. This facility aims to support food and beverage manufacturers, retailers, and processors in the Minneapolis-St. Paul region by providing an efficient and sustainable method for recycling food waste.</p>
<h3>Addressing Regulatory and Sustainability Challenges</h3>
<p>Food and beverage companies in Wisconsin and Minnesota are increasingly facing regulatory pressures to manage organic waste responsibly and recover packaging materials. Both states are implementing policies such as Extended Producer Responsibility (EPR) for packaging and commercial organics diversion requirements. These policies drive demand for solutions that ensure compliance while advancing sustainability goals aligned with the United Nations Sustainable Development Goals (SDGs), particularly:</p>
<ul>
<li><strong>SDG 12:</strong> Responsible Consumption and Production</li>
<li><strong>SDG 13:</strong> Climate Action</li>
<li><strong>SDG 7:</strong> Affordable and Clean Energy</li>
</ul>
<h3>Turnkey Solutions for Organics Recycling</h3>
<p>Kent Bartley, President of Organic Solutions at Vanguard Renewables, highlights the company’s comprehensive approach:</p>
<blockquote>
<p>“Vanguard Renewables gives food and beverage companies a turnkey solution to simplify organics recycling and reduce risk. We combine deep industry expertise with full-service capabilities, from managing logistics with our own fleet to providing real-time data for compliance and reporting. Our approach makes organics recycling simple and reliable.”</p>
</blockquote>
<h3>Facility Capabilities and Impact</h3>
<ol>
<li><strong>Location and Capacity:</strong> Situated at Peterson Family Dairy, a fourth-generation farm in Pierce County, the River Falls facility can process up to 275 tons of food and beverage waste daily.</li>
<li><strong>Renewable Energy Production:</strong> The facility will generate approximately 289,000 MMBtu of renewable natural gas (RNG) annually, sufficient to power 53,000 homes and businesses each year, contributing to SDG 7 (Affordable and Clean Energy) and SDG 13 (Climate Action).</li>
<li><strong>Client and Waste Stream Diversity:</strong> It processes over 50 different waste streams from more than 30 customers in the region, supporting SDG 12 (Responsible Consumption and Production).</li>
<li><strong>Advanced Technology:</strong> The facility employs advanced depackaging technology capable of handling both bulk and packaged food and beverage products, enhancing waste recovery and recycling efficiency.</li>
</ol>
<h3>Partnerships and Regional Expansion</h3>
<ul>
<li>The renewable natural gas produced will be utilized to power AstraZeneca’s U.S. research and manufacturing facilities, demonstrating a commitment to sustainable industrial practices.</li>
<li>This facility represents Vanguard Renewables’ second operational site in Wisconsin, complementing its existing location in Eden, which serves the Milwaukee area.</li>
</ul>
<h3>Conclusion</h3>
<p>The River Falls facility exemplifies a strategic investment in sustainable waste management and renewable energy production, directly contributing to multiple Sustainable Development Goals. By enabling food and beverage companies to meet regulatory requirements and sustainability targets, Vanguard Renewables supports a circular economy and advances environmental stewardship in the region.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected</h2>
<ol>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The article discusses food waste recycling and packaging material recovery, which aligns with sustainable consumption and production patterns.</li>
</ul>
</li>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The production of renewable natural gas (RNG) from food waste contributes to clean energy generation.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>By reducing food waste and generating renewable energy, the facility helps mitigate climate change impacts.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong>
<ul>
<li>The deployment of advanced depackaging technology and logistics solutions reflects innovation in infrastructure and industry.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified</h2>
<ol>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Target 12.5: Substantially reduce waste generation through prevention, reduction, recycling, and reuse.</li>
<li>Target 12.4: Achieve environmentally sound management of chemicals and all wastes throughout their life cycle.</li>
</ul>
</li>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>Target 7.2: Increase substantially the share of renewable energy in the global energy mix.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.1: Strengthen resilience and adaptive capacity to climate-related hazards and natural disasters.</li>
</ul>
</li>
<li><strong>SDG 9: Industry, Innovation, and Infrastructure</strong>
<ul>
<li>Target 9.4: Upgrade infrastructure and retrofit industries to make them sustainable, with increased resource-use efficiency and greater adoption of clean and environmentally sound technologies.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied to Measure Progress</h2>
<ol>
<li><strong>Indicator for Target 12.5:</strong> Tons of food and beverage waste processed (275 tons per day capacity).</li>
<li><strong>Indicator for Target 7.2:</strong> Amount of renewable natural gas generated annually (289,000 MMBtu).</li>
<li><strong>Indicator for Target 12.4:</strong> Number of waste streams processed (more than 50 waste streams from over 30 customers).</li>
<li><strong>Indicator for Target 9.4:</strong> Deployment of advanced depackaging technology and logistics capabilities.</li>
<li><strong>Additional Indicator:</strong> Number of homes and businesses powered by RNG annually (53,000).</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>12.5: Reduce waste generation through prevention, reduction, recycling, and reuse.</li>
<li>12.4: Environmentally sound management of chemicals and wastes.</li>
</ul>
</td>
<td>
<ul>
<li>275 tons/day of food and beverage waste processed.</li>
<li>Processing of more than 50 waste streams from 30+ customers.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>
<ul>
<li>7.2: Increase share of renewable energy in the global energy mix.</li>
</ul>
</td>
<td>
<ul>
<li>289,000 MMBtu of renewable natural gas generated annually.</li>
<li>RNG powering 53,000 homes and businesses annually.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>13.1: Strengthen resilience and adaptive capacity to climate-related hazards.</li>
</ul>
</td>
<td>
<ul>
<li>Reduction of food waste contributing to climate mitigation.</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 9: Industry, Innovation, and Infrastructure</td>
<td>
<ul>
<li>9.4: Upgrade infrastructure and retrofit industries for sustainability.</li>
</ul>
</td>
<td>
<ul>
<li>Use of advanced depackaging technology and logistics management.</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://www.foodengineeringmag.com/articles/103442-vanguard-renewables-opens-second-anaerobic-digestion-facility-in-wisconsin">foodengineeringmag.com</a></strong></p>
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<title>New Scorecard Warns: U.S. Food Retailers Lag on Reducing Harmful Pesticides – Perishable News</title>
<link>https://sdgtalks.ai/new-scorecard-warns-us-food-retailers-lag-on-reducing-harmful-pesticides-perishable-news</link>
<guid>https://sdgtalks.ai/new-scorecard-warns-us-food-retailers-lag-on-reducing-harmful-pesticides-perishable-news</guid>
<description><![CDATA[ New Scorecard Warns: U.S. Food Retailers Lag on Reducing Harmful Pesticides  Perishable News ]]></description>
<enclosure url="https://perishablenews.com/wp-content/uploads/2025/12/a-r1-2.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 23 Dec 2025 07:30:16 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>New, Scorecard, Warns:, U.S., Food, Retailers, Lag, Reducing, Harmful, Pesticides, –, Perishable, News</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>2025 Bee-Friendly Retailer Scorecard Highlights Sustainable Development Challenges</h2>
<h3>Introduction</h3>
<p>Friends of the Earth has released its 2025 <a href="https://foe.org/retailer-report-card/"><strong>Bee-Friendly Retailer Scorecard</strong></a>, a national assessment evaluating how the largest U.S. grocery retailers address toxic pesticides in their supply chains. This report emphasizes the critical role of Sustainable Development Goals (SDGs), particularly those related to responsible consumption and production (SDG 12), life on land (SDG 15), and good health and well-being (SDG 3).</p>
<h3>Retailer Performance and Sustainable Practices</h3>
<p>The Scorecard assesses 25 top grocery retailers on their commitments and progress in reducing pesticides linked to declines in pollinators, biodiversity, soil health, and human health. Key findings include:</p>
<ol>
<li><strong>Sprouts Farmers Market, Inc (NASDAQ: SFM)</strong> achieved an “A-” grade, becoming the second company after Whole Foods to reach the “A” range. Sprouts introduced a new <a href="https://foe.org/nursery-retailer-commitments/">commitment to pollinator health</a>, aiming to reduce toxic pesticide use and enhance organic sales, supporting SDG 12 and SDG 15.</li>
<li><strong>Costco (NASDAQ: COST)</strong> improved from a “C” to a “B+” due to strong organic sales and progress in implementing its pollinator health policy.</li>
<li><strong>Amazon (NASDAQ: AMZN)</strong> advanced from an “F” to a “D-” based on organic product offerings and third-party certifications.</li>
</ol>
<h3>Organic Sales as a Sustainable Benchmark</h3>
<ul>
<li>The USDA Organic seal remains the most trusted standard for reduced pesticide use, prohibiting over 900 synthetic pesticides harmful to pollinators, soil, and human health.</li>
<li>Organic sales are a key differentiator for retailers, aligning with SDG 12 by promoting sustainable consumption and production patterns.</li>
</ul>
<h2>Challenges and Risks in Pesticide Management</h2>
<h3>Retailers Lagging Behind</h3>
<p>Despite increasing consumer demand for safer food, several major retailers show insufficient progress:</p>
<ul>
<li>Six companies including Albertsons, Aldi, CVS, Kroger, Southeastern Grocers, and Target lost points for inadequate communication on pollinator health commitments.</li>
<li>Target’s rating dropped from “D-” to “F,” joining other low-scoring retailers such as Wegmans, BJ’s Wholesale Club, H-E-B, Walgreens, Hy-Vee, Dollar General, Publix, and Wakefern.</li>
</ul>
<h3>Consumer Concerns and Pesticide Exposure</h3>
<ul>
<li>National polls indicate rising consumer demand for organic and pesticide-free products, with expectations for retailer transparency.</li>
<li>Investigative studies revealed toxic pesticides, including neurotoxins, hormone disruptors, and PFAS “forever chemicals,” in Target’s baby food products, raising serious health concerns (SDG 3).</li>
</ul>
<h3>Financial and Supply Chain Risks</h3>
<p>A <a href="https://foe.org/wp-content/uploads/2024/12/Pesticides-Food-Retailers-Econ-Risks-Profundo-Final.pdf">recent analysis</a> estimates that pesticide-dependent agriculture exposes the U.S. food retail sector to $219 billion in climate, financial, and biodiversity risks, impacting SDG 13 (Climate Action) and SDG 15 (Life on Land).</p>
<ul>
<li>Pollinator decline threatens crop yields for apples, cherries, and other produce, risking supply constraints and price volatility.</li>
<li>Retailers have significant influence to drive systemic change toward sustainable agriculture.</li>
</ul>
<h2>Retailer Rankings and Scores</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>Retailer</th>
<th>Grade</th>
<th>Score</th>
</tr>
</thead>
<tbody>
<tr>
<td>Whole Foods Market</td>
<td>A</td>
<td>133</td>
</tr>
<tr>
<td>Sprouts Farmers Market</td>
<td>A-</td>
<td>121</td>
</tr>
<tr>
<td>Giant Eagle</td>
<td>B+</td>
<td>115</td>
</tr>
<tr>
<td>Costco</td>
<td>B+</td>
<td>110</td>
</tr>
<tr>
<td>Walmart</td>
<td>B-</td>
<td>94</td>
</tr>
<tr>
<td>Meijer</td>
<td>B-</td>
<td>86.5</td>
</tr>
<tr>
<td>Kroger</td>
<td>C-</td>
<td>65</td>
</tr>
<tr>
<td>CVS</td>
<td>D+</td>
<td>46.5</td>
</tr>
<tr>
<td>Dollar Tree</td>
<td>D</td>
<td>43</td>
</tr>
<tr>
<td>Trader Joe’s</td>
<td>D</td>
<td>42</td>
</tr>
<tr>
<td>Aldi (US)</td>
<td>D</td>
<td>40</td>
</tr>
<tr>
<td>Southeastern Grocers</td>
<td>D-</td>
<td>33</td>
</tr>
<tr>
<td>Amazon.com</td>
<td>D-</td>
<td>32</td>
</tr>
<tr>
<td>Albertsons</td>
<td>D-</td>
<td>26</td>
</tr>
<tr>
<td>Ahold Delhaize</td>
<td>D-</td>
<td>30</td>
</tr>
<tr>
<td>Target</td>
<td>F</td>
<td>23</td>
</tr>
<tr>
<td>Wegmans</td>
<td>F</td>
<td>17</td>
</tr>
<tr>
<td>BJ’s Wholesale Club</td>
<td>F</td>
<td>14</td>
</tr>
<tr>
<td>H-E-B</td>
<td>F</td>
<td>9</td>
</tr>
<tr>
<td>Walgreens</td>
<td>F</td>
<td>5</td>
</tr>
<tr>
<td>Hy-Vee</td>
<td>F</td>
<td>5</td>
</tr>
<tr>
<td>Dollar General</td>
<td>F</td>
<td>0</td>
</tr>
<tr>
<td>Publix</td>
<td>F</td>
<td>0</td>
</tr>
<tr>
<td>Wakefern Food</td>
<td>F</td>
<td>0</td>
</tr>
</tbody>
</table>
<h2>Broader Impacts of Pesticides</h2>
<h3>Environmental and Human Health Threats</h3>
<ul>
<li>Common pesticides threaten soil organisms essential for carbon sequestration, water conservation, and climate resilience, directly impacting SDG 13 and SDG 15.</li>
<li>Human health is compromised from farmworkers’ daily exposure to consumers ingesting pesticide residues, with infants and children particularly vulnerable (SDG 3).</li>
<li>Current federal standards inadequately protect these vulnerable populations.</li>
</ul>
<h2>Retailers’ Role in Driving Sustainable Change</h2>
<p>The largest grocery retailers, including Walmart, Kroger, Costco, Amazon, Albertsons, and Target, control approximately <strong>$754 billion in annual grocery sales</strong>. This market power positions them to lead pesticide reduction efforts and promote sustainable agricultural practices aligned with SDG 12 and SDG 15.</p>
<h3>Collaborative Efforts</h3>
<ul>
<li>The Bee-Friendly Retailer campaign is supported by over 100 organizations spanning beekeeping, farming, farmworker, consumer, and environmental sectors.</li>
<li>Initiatives such as the Campaign for Healthier Solutions work to eliminate hazardous chemicals from retail environments, fostering safer communities and ecosystems.</li>
</ul>
<h3>Conclusion</h3>
<p>Friends of the Earth continues to advocate for environmental protection and social justice by holding corporations accountable and promoting sustainable food and agriculture systems. The 2025 Bee-Friendly Retailer Scorecard underscores the urgent need for retailers to align their operations with the Sustainable Development Goals to ensure a healthy planet and population.</p>
<h2>1. Sustainable Development Goals (SDGs) Addressed or Connected to the Issues Highlighted in the Article</h2>
<ol>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>The article discusses the impact of pesticides on food production, pollinators, and soil health, which are critical to sustainable agriculture and food security.</li>
</ul>
</li>
<li><strong>SDG 3: Good Health and Well-being</strong>
<ul>
<li>Concerns about toxic pesticides affecting human health, including neurotoxins and hormone disruptors, highlight the relevance to health and well-being.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>The article emphasizes consumer demand for organic and pesticide-free products and retailer commitments to reducing hazardous pesticides in supply chains.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Pesticides threaten soil organisms essential for carbon sequestration and climate resilience, linking to climate action goals.</li>
</ul>
</li>
<li><strong>SDG 15: Life on Land</strong>
<ul>
<li>The decline of pollinators and biodiversity due to pesticide use directly relates to protecting terrestrial ecosystems.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs Identified Based on the Article’s Content</h2>
<ol>
<li><strong>SDG 2: Zero Hunger</strong>
<ul>
<li>Target 2.4: By 2030, ensure sustainable food production systems and implement resilient agricultural practices that increase productivity and production, help maintain ecosystems, and strengthen capacity for adaptation to climate change.</li>
</ul>
</li>
<li><strong>SDG 3: Good Health and Well-being</strong>
<ul>
<li>Target 3.9: By 2030, substantially reduce the number of deaths and illnesses from hazardous chemicals and air, water, and soil pollution and contamination.</li>
</ul>
</li>
<li><strong>SDG 12: Responsible Consumption and Production</strong>
<ul>
<li>Target 12.4: By 2020, achieve the environmentally sound management of chemicals and all wastes throughout their life cycle, in accordance with agreed international frameworks.</li>
<li>Target 12.8: By 2030, ensure that people everywhere have the relevant information and awareness for sustainable development and lifestyles in harmony with nature.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Target 13.1: Strengthen resilience and adaptive capacity to climate-related hazards and natural disasters in all countries.</li>
</ul>
</li>
<li><strong>SDG 15: Life on Land</strong>
<ul>
<li>Target 15.1: By 2020, ensure the conservation, restoration, and sustainable use of terrestrial and inland freshwater ecosystems and their services.</li>
<li>Target 15.5: Take urgent and significant action to reduce the degradation of natural habitats, halt the loss of biodiversity, and protect and prevent the extinction of threatened species.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied in the Article to Measure Progress Towards the Identified Targets</h2>
<ol>
<li><strong>Percentage of retailers with policies to reduce hazardous pesticide use</strong>
<ul>
<li>Implied by the Bee-Friendly Retailer Scorecard ratings and commitments to pollinator health policies.</li>
</ul>
</li>
<li><strong>Organic sales as a proportion of total sales</strong>
<ul>
<li>Used as a key differentiator and indicator of reduced pesticide use (e.g., USDA Organic seal).</li>
</ul>
</li>
<li><strong>Presence of toxic pesticides in food products</strong>
<ul>
<li>Measured by investigative testing detecting pesticides in baby food and other products.</li>
</ul>
</li>
<li><strong>Pollinator population trends and biodiversity indicators</strong>
<ul>
<li>Implied by references to pollinator declines linked to pesticide use and impacts on crop yields.</li>
</ul>
</li>
<li><strong>Financial risk estimates related to pesticide-dependent agriculture</strong>
<ul>
<li>Estimated $219 billion in climate, financial, and biodiversity risks for the food retail sector.</li>
</ul>
</li>
<li><strong>Consumer awareness and demand for organic/pesticide-free products</strong>
<ul>
<li>Indicated by national polling data showing rising consumer concern.</li>
</ul>
</li>
</ol>
<h2>4. Table: SDGs, Targets and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 2: Zero Hunger</td>
<td>Target 2.4: Sustainable food production systems and resilient agricultural practices</td>
<td>
<ul>
<li>Retailer commitments to reducing hazardous pesticides</li>
<li>Pollinator population trends</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 3: Good Health and Well-being</td>
<td>Target 3.9: Reduce deaths and illnesses from hazardous chemicals and pollution</td>
<td>
<ul>
<li>Testing for toxic pesticides in food products (e.g., baby food)</li>
<li>Incidence of pesticide-related health issues</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 12: Responsible Consumption and Production</td>
<td>
<ul>
<li>Target 12.4: Environmentally sound management of chemicals</li>
<li>Target 12.8: Information and awareness for sustainable development</li>
</ul>
</td>
<td>
<ul>
<li>Percentage of retailers with pollinator health policies</li>
<li>Organic sales proportion</li>
<li>Consumer demand and awareness surveys</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>Target 13.1: Strengthen resilience and adaptive capacity to climate hazards</td>
<td>
<ul>
<li>Soil health indicators related to pesticide impact</li>
<li>Financial risk assessments linked to pesticide use</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 15: Life on Land</td>
<td>
<ul>
<li>Target 15.1: Conservation and sustainable use of terrestrial ecosystems</li>
<li>Target 15.5: Reduce biodiversity loss and protect threatened species</li>
</ul>
</td>
<td>
<ul>
<li>Pollinator population and biodiversity monitoring</li>
<li>Extent of pesticide reduction in agriculture</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://perishablenews.com/retailfoodservice/new-scorecard-warns-u-s-food-retailers-lag-on-reducing-harmful-pesticides/">perishablenews.com</a></strong></p>
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<title>Science for the Planet: Engineering a Cooler Future Through Smarter Buildings – Columbia University</title>
<link>https://sdgtalks.ai/science-for-the-planet-engineering-a-cooler-future-through-smarter-buildings-columbia-university</link>
<guid>https://sdgtalks.ai/science-for-the-planet-engineering-a-cooler-future-through-smarter-buildings-columbia-university</guid>
<description><![CDATA[ Science for the Planet: Engineering a Cooler Future Through Smarter Buildings  Columbia University ]]></description>
<enclosure url="https://media.news.climate.columbia.edu/wp-content/uploads/2025/12/Screenshot-2025-12-17-at-5.42.02-PM-1-1300x736.jpg" length="49398" type="image/jpeg"/>
<pubDate>Mon, 22 Dec 2025 19:30:11 -0500</pubDate>
<dc:creator>sdgtalks</dc:creator>
<media:keywords>Science, for, the, Planet:, Engineering, Cooler, Future, Through, Smarter, Buildings, –, Columbia, University</media:keywords>
<content:encoded><![CDATA[<p> </p>
<h2>Engineering a Cooler Future: Enhancing Building Efficiency to Combat Climate Change</h2>
<div><img decoding="async" src="https://media.news.climate.columbia.edu/wp-content/uploads/2025/12/Screenshot-2025-12-17-at-5.42.02-PM-1-1300x736.jpg" alt="Energy Efficient Buildings"></div>
<h3>Introduction</h3>
<p>Buildings represent one of the largest sources of greenhouse gas emissions globally. Addressing energy consumption in buildings offers a rapid and cost-effective strategy to mitigate climate change, aligning closely with the United Nations Sustainable Development Goals (SDGs), particularly SDG 7 (Affordable and Clean Energy), SDG 11 (Sustainable Cities and Communities), and SDG 13 (Climate Action).</p>
<h3>Research and Innovation in Building Efficiency</h3>
<p><a href="https://people.climate.columbia.edu/users/profile/alexis-abramson">Alexis Abramson</a>, professor and dean at the Columbia Climate School, leads research focused on improving building efficiency through advanced data analytics, machine learning, and intelligent design. Her work involves analyzing electricity usage across thousands of buildings to identify opportunities for substantial reductions in energy consumption and emissions.</p>
<h3>Key Findings and Strategies</h3>
<ol>
<li><strong>Modernizing Building Operations:</strong> Many buildings continue to operate using outdated systems. Modernizing these systems presents a significant opportunity to reduce emissions.</li>
<li><strong>Simple Upgrades:</strong> Replacing traditional lighting with LED technology can lead to immediate energy savings.</li>
<li><strong>System Overhauls:</strong> Upgrading heating and cooling systems can reduce energy use by up to 50%, contributing to lower greenhouse gas emissions.</li>
</ol>
<h3>Impact on Sustainable Development Goals</h3>
<ul>
<li><strong>SDG 7 – Affordable and Clean Energy:</strong> Energy-efficient buildings reduce overall energy demand, facilitating the transition to renewable energy sources.</li>
<li><strong>SDG 11 – Sustainable Cities and Communities:</strong> Enhancing building efficiency contributes to creating sustainable urban environments with reduced carbon footprints.</li>
<li><strong>SDG 13 – Climate Action:</strong> Lowering emissions from buildings directly supports global efforts to combat climate change.</li>
<li><strong>SDG 9 – Industry, Innovation, and Infrastructure:</strong> The integration of machine learning and smart design exemplifies innovation in infrastructure development.</li>
</ul>
<h3>Additional Resources</h3>
<p>For further insights into Alexis Abramson’s research and the role of energy efficiency in climate solutions, refer to the detailed conversation available here: <a href="https://news.climate.columbia.edu/2025/05/19/energy-efficiency-begins-at-home-a-conversation-with-alexis-abramson/">Energy Efficiency Begins at Home: A Conversation with Alexis Abramson</a>.</p>
<h3>Multimedia Engagement</h3>
<figure class="wp-block-embed is-type-video is-provider-youtube wp-block-embed-youtube wp-embed-aspect-16-9 wp-has-aspect-ratio">
  <br>
</figure>
<p><em>This video is part of the ongoing <a href="https://youtube.com/playlist?list=PLPmPmV9ZCh-itR4FSkMt2Gc7wRTtUyjee&si=y8R8mQ3S5XI5SoWK">Science for the Planet</a> explainer series, showcasing how Columbia Climate School scientists are advancing understanding and solutions to climate change.</em></p>
<h2>1. Sustainable Development Goals (SDGs) Addressed</h2>
<ol>
<li><strong>SDG 7: Affordable and Clean Energy</strong>
<ul>
<li>The article focuses on improving energy efficiency in buildings, which aligns with ensuring access to affordable, reliable, sustainable, and modern energy.</li>
</ul>
</li>
<li><strong>SDG 11: Sustainable Cities and Communities</strong>
<ul>
<li>Making buildings more energy-efficient contributes to sustainable urban development and reducing environmental impact.</li>
</ul>
</li>
<li><strong>SDG 13: Climate Action</strong>
<ul>
<li>Reducing greenhouse gas emissions from buildings directly supports combating climate change and its impacts.</li>
</ul>
</li>
</ol>
<h2>2. Specific Targets Under Those SDGs</h2>
<ol>
<li><strong>SDG 7 Targets</strong>
<ul>
<li><strong>Target 7.3:</strong> By 2030, double the global rate of improvement in energy efficiency.</li>
</ul>
</li>
<li><strong>SDG 11 Targets</strong>
<ul>
<li><strong>Target 11.6:</strong> By 2030, reduce the adverse per capita environmental impact of cities, including by paying special attention to air quality and municipal and other waste management.</li>
</ul>
</li>
<li><strong>SDG 13 Targets</strong>
<ul>
<li><strong>Target 13.1:</strong> Strengthen resilience and adaptive capacity to climate-related hazards and natural disasters in all countries.</li>
<li><strong>Target 13.2:</strong> Integrate climate change measures into national policies, strategies, and planning.</li>
</ul>
</li>
</ol>
<h2>3. Indicators Mentioned or Implied in the Article</h2>
<ol>
<li><strong>Energy Consumption Metrics</strong>
<ul>
<li>Electricity use data from thousands of buildings analyzed to measure energy efficiency improvements.</li>
</ul>
</li>
<li><strong>Greenhouse Gas Emissions</strong>
<ul>
<li>Reduction in emissions from buildings as a result of energy efficiency measures such as LED lighting and upgraded heating/cooling systems.</li>
</ul>
</li>
<li><strong>Energy Efficiency Improvement Rate</strong>
<ul>
<li>Percentage reduction in energy use (e.g., up to 50% reduction in heating and cooling energy consumption).</li>
</ul>
</li>
</ol>
<h2>4. Table of SDGs, Targets, and Indicators</h2>
<table border="1" cellpadding="5" cellspacing="0">
<thead>
<tr>
<th>SDGs</th>
<th>Targets</th>
<th>Indicators</th>
</tr>
</thead>
<tbody>
<tr>
<td>SDG 7: Affordable and Clean Energy</td>
<td>Target 7.3: Double the global rate of improvement in energy efficiency by 2030.</td>
<td>
<ul>
<li>Electricity consumption data from buildings</li>
<li>Rate of energy efficiency improvement (%)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 11: Sustainable Cities and Communities</td>
<td>Target 11.6: Reduce adverse environmental impact of cities by 2030.</td>
<td>
<ul>
<li>Greenhouse gas emissions from buildings</li>
<li>Air quality indicators (implied)</li>
</ul>
</td>
</tr>
<tr>
<td>SDG 13: Climate Action</td>
<td>
<ul>
<li>Target 13.1: Strengthen resilience and adaptive capacity to climate-related hazards.</li>
<li>Target 13.2: Integrate climate change measures into policies and planning.</li>
</ul>
</td>
<td>
<ul>
<li>Reduction in greenhouse gas emissions</li>
<li>Implementation of energy efficiency measures in buildings</li>
</ul>
</td>
</tr>
</tbody>
</table>
<p></p>
<p><strong>Source: <a href="https://news.climate.columbia.edu/2025/12/22/science-for-the-planet-abramson/">news.climate.columbia.edu</a></strong></p>
<p> </p>]]> </content:encoded>
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<title>The Future of Builders: Embracing Sustainable Building Practices!</title>
<link>https://sdgtalks.ai/the-future-of-builders-embracing-sustainable-building-practices</link>
<guid>https://sdgtalks.ai/the-future-of-builders-embracing-sustainable-building-practices</guid>
<description><![CDATA[ This blog from the Master Builders Association of Pierce County argues that the construction sector’s future hinges on mainstreaming sustainable building. It sketches eight focus areas—greener materials (e.g., engineered wood, recycled steel), energy efficiency, prefabrication/modular methods, green certifications (like LEED), net-zero design, smart-building controls, climate-savvy design principles, and circular-economy practices—and frames them as both environmental necessity and sound business. The takeaway: integrating these tools can cut carbon, reduce waste, and improve project performance while positioning builders competitively as codes and client expectations rise. ]]></description>
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<pubDate>Mon, 08 Dec 2025 15:31:13 -0500</pubDate>
<dc:creator>clolli</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p>The construction industry is at a crossroads. As we face the challenges of climate change and resource depletion, the need for sustainable building practices has never been greater. The future of builders is in embracing sustainable building practices, and in this blog post, we will explore the key trends and innovations shaping the industry.</p>
<h5 class="wp-block-heading" id="green-building-materials-for-sustainable-building-practices"><strong>Green Building Materials for Sustainable Building Practices</strong></h5>
<p>One of the most significant shifts in<span> </span><a href="https://masterbuilderspierce.com/pwb-professional-women-in-building-1/">construction</a><span> </span>practices is the adoption of green building materials. Traditional construction materials such as concrete and steel are resource-intensive and contribute to high carbon emissions. In response, builders are turning to sustainable alternatives like bamboo, recycled steel, and engineered wood. These materials are not only eco-friendly but often cost-effective as well.</p>
<h5 class="wp-block-heading" id="energy-efficiency"> Energy Efficiency</h5>
<p>Energy-efficient buildings are becoming the norm rather than the exception. From energy-efficient insulation to solar panels and smart building management systems, the<span> </span><a href="https://masterbuilderspierce.com/tacoma-youthbuild-is-seeking-construction-industry-partners/">construction industry</a><span> </span>is rapidly integrating technologies and practices that reduce energy consumption and decrease a building’s carbon footprint.</p>
<p></p>
<h5 class="wp-block-heading" id="prefabrication-and-modular-construction">Prefabrication and Modular Construction</h5>
<p>Prefabrication and modular construction methods are revolutionizing the way buildings are put together. These techniques reduce waste, save time, and promote sustainability. With components manufactured in controlled environments, there is less material waste and greater precision in construction.</p>
<h5 class="wp-block-heading" id="green-certifications-for-sustainable-building-practices">Green Certifications for Sustainable Building Practices</h5>
<p>Sustainability certifications such as LEED (<a href="https://www.usgbc.org/leed" target="_blank" rel="noreferrer noopener">Leadership in Energy and Environmental Design</a>) have gained prominence in the construction industry. These certifications set standards for environmentally responsible construction and provide a framework for architects and builders to follow.</p>
<h5 class="wp-block-heading" id="net-zero-buildings">Net-Zero Buildings</h5>
<p>The concept of net-zero buildings, which produce as much energy as they consume, is gaining traction for sustainable building practices. These buildings are designed with a holistic approach, incorporating energy-efficient design, renewable energy sources, and water conservation practices. Achieving a net-zero building can significantly reduce a structure’s impact on the environment.</p>
<h5 class="wp-block-heading" id="smart-buildings">Smart Buildings</h5>
<p>Smart technology is making buildings more sustainable and efficient. From automated lighting and HVAC systems to sensors that optimize energy use, smart buildings are reducing resource waste and enhancing occupant comfort.</p>
<h5 class="wp-block-heading" id="sustainable-design-principles">Sustainable Design Principles</h5>
<p>Architects and designers are embracing sustainable design principles that focus on integrating<span> </span><a href="https://masterbuilderspierce.com/natural-gas-on-the-line/">buildings</a><span> </span>with their natural surroundings. This includes optimizing natural lighting, passive heating and cooling, and using landscaping to reduce energy needs.</p>
<figure class="wp-block-image aligncenter size-large"><img decoding="async" width="1024" height="307" src="https://masterbuilderspierce.com/wp-content/uploads/2023/11/MBA-sustainable-building-practices1-1024x307.png" data-src="https://masterbuilderspierce.com/wp-content/uploads/2023/11/MBA-sustainable-building-practices1-1024x307.png" alt="sustainable building practices" class="wp-image-8008 lazyloaded" title="The Future of Builders: Embracing Sustainable Building Practices! 3" data-srcset="https://masterbuilderspierce.com/wp-content/uploads/2023/11/MBA-sustainable-building-practices1-980x294.png 980w, https://masterbuilderspierce.com/wp-content/uploads/2023/11/MBA-sustainable-building-practices1-480x144.png 480w" sizes="(min-width: 0px) and (max-width: 480px) 480px, (min-width: 481px) and (max-width: 980px) 980px, (min-width: 981px) 1024px, 100vw" srcset="https://masterbuilderspierce.com/wp-content/uploads/2023/11/MBA-sustainable-building-practices1-980x294.png 980w, https://masterbuilderspierce.com/wp-content/uploads/2023/11/MBA-sustainable-building-practices1-480x144.png 480w"></figure>
<h5 class="wp-block-heading" id="circular-economy-practices">Circular Economy Practices</h5>
<p>The construction industry is increasingly adopting circular economy practices, which involve recycling and reusing materials to reduce waste and minimize the extraction of new resources. By repurposing materials and minimizing waste, the industry is moving toward a more sustainable future.</p>
<h5 class="wp-block-heading" id="conclusion">Conclusion</h5>
<p>The future of construction is undoubtedly tied to sustainability. From green building materials and<span> </span><a href="https://masterbuilderspierce.com/puget-sound-energy-open-letter-to-building-community-partners/">energy efficiency</a><span> </span>to innovative construction methods and smart technology, the industry is evolving to meet the demands of a changing world. Embracing sustainable building practices is not just an environmental necessity; it’s also a smart business decision. As the construction industry continues to adapt to the challenges of the 21st century, it is clear that the path forward is a sustainable one. By adopting these practices and staying informed about emerging technologies, construction professionals can lead the way towards a greener, more sustainable future.</p>]]> </content:encoded>
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<title>This engineered fungus cuts emissions and tastes like meat</title>
<link>https://sdgtalks.ai/this-engineered-fungus-cuts-emissions-and-tastes-like-meat</link>
<guid>https://sdgtalks.ai/this-engineered-fungus-cuts-emissions-and-tastes-like-meat</guid>
<description><![CDATA[ Researchers used CRISPR to tweak a common mycoprotein fungus so it grows protein faster, needs less sugar, and is easier to digest—cutting the modeled environmental footprint of production compared to the standard strain and even outperforming chicken on land and water impacts. The study positions gene-edited fungal proteins as a promising, lower-impact way to meet rising demand for meat-like foods. ]]></description>
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<pubDate>Tue, 02 Dec 2025 16:27:58 -0500</pubDate>
<dc:creator>clolli</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p id="first" class="lead">A recent study published November 19 in<span> </span><em>Trends in Biotechnology</em><span> </span>reports that scientists used the gene-editing tool CRISPR to improve how efficiently a fungus produces protein while also lowering the environmental footprint of that production by as much as 61% -- all without introducing foreign DNA. The modified fungus has a meatlike flavor and is easier for people to digest than the natural strain it originated from.</p>
<div id="text" data-content-ads-inserted="true">
<p data-slot-rendered-content="true">"There is a popular demand for better and more sustainable protein for food," says corresponding author Xiao Liu of Jiangnan University in Wuxi, China. "We successfully made a fungus not only more nutritious but also more environmentally friendly by tweaking its genes."</p>
<p><strong>Sustainable Protein and the Need for Alternatives</strong></p>
<p>Animal agriculture accounts for about 14% of global greenhouse gas emissions. It also requires large amounts of land and fresh water, both of which are increasingly strained by climate change and human activity. Because of these challenges, microbial proteins found in yeast and fungi have gained attention as promising alternatives to meat.</p>
<p>Among the many mycoprotein sources studied so far, the fungus Fusarium venenatum has become a prominent choice because its natural flavor and texture closely mimic meat. It has already been approved for consumption in several regions, including the United Kingdom, China, and the United States.</p>
<p><strong>Why<span> </span><em>Fusarium venenatum</em><span> </span>Needed Improvement</strong></p>
<p>Even with its advantages, Fusarium venenatum has thick cell walls that limit how well humans can digest it. Producing it is also resource intensive. Growing even modest quantities of mycoprotein requires significant inputs, and the spores must be cultivated in large metal tanks filled with sugar-rich feedstock and added nutrients such as ammonium sulfate.</p>
<p>Liu and his colleagues wanted to determine whether CRISPR could make this fungus easier to digest and more efficient to grow while still avoiding the introduction of foreign DNA into the organism.</p>
<p><strong>Key Gene Edits That Boost Efficiency</strong></p>
<p data-slot-rendered-content="true">To explore this approach, the researchers removed two genes linked to the enzymes chitin synthase and pyruvate decarboxylase. Removing the chitin synthase gene resulted in a thinner cell wall, which made the internal protein more accessible for digestion. The deletion of the pyruvate decarboxylase gene fine-tuned the fungus's metabolism, reducing the amount of nutrients needed for protein production.</p>
<p>Their analyses revealed that the modified strain, named FCPD, used 44% less sugar to create the same amount of protein as the original strain and did so 88% more quickly.</p>
<p>"A lot of people thought growing mycoprotein was more sustainable, but no one had really considered how to reduce the environmental impact of the entire production process, especially when compared to other alternative protein products" says first author, Xiaohui Wu of Jiangnan University.</p>
<p><strong>Life Cycle Footprint and Global Comparisons</strong></p>
<p>The team then assessed the environmental footprint of FCPD across its entire life cycle, from laboratory spores to inactivated meat-like products, at an industrial scale. They modeled production in six countries with different energy systems, including Finland, which depends largely on renewable energy, and China, which relies more heavily on coal. In every scenario, FCPD produced lower environmental impacts than conventional<span> </span><em>Fusarium venenatum</em>. Across its full life cycle, FCPD production reduced greenhouse gas emissions by up to 60%.</p>
<div id="insertion_bottom"></div>
<p><strong>How FCPD Compares to Animal Protein</strong></p>
<p>The researchers also compared the impacts of FCPD production to those associated with raising animals for food. Against chicken production in China, FCPD required 70% less land and lowered the potential for freshwater pollution by 78%.</p>
<p data-slot-rendered-content="true">"Gene-edited foods like this can meet growing food demands without the environmental costs of conventional farming," says Liu.</p>
<p data-slot-rendered-content="true"><span>This work was supported by the Key Research and Development Program of China, the Jiangsu Basic Research Center for Synthetic Biology, the Natural Science Foundation of Jiangsu Province, and the Postgraduate Research &amp; Practice Innovation Program of Jiangsu Province.</span></p>
<p><strong>Journal Reference</strong>:</p>
<ol class="journal">
<li>Xiaohui Wu, Mengru Wang, Shijun Luo, Zhitong Zhou, Yanan Wang, Guocheng Du, Jian Chen, Xiao Liu.<span> </span><strong>Dual enhancement of mycoprotein nutrition and sustainability via CRISPR-mediated metabolic engineering of Fusarium venenatum</strong>.<span> </span><em>Trends in Biotechnology</em>, 2025; DOI:<span> </span><a href="http://dx.doi.org/10.1016/j.tibtech.2025.09.016" rel="noopener noreferrer" target="_blank">10.1016/j.tibtech.2025.09.016</a></li>
</ol>
<p><span>Cell Press. "This engineered fungus cuts emissions and tastes like meat." ScienceDaily. ScienceDaily, 21 November 2025. &lt;www.sciencedaily.com</span><wbr><span>/</span><wbr><span>releases</span><wbr><span>/</span><wbr><span>2025</span><wbr><span>/</span><wbr><span>11</span><wbr><span>/</span><wbr><span>251121082049.htm&gt;.</span></p>
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<title>Farmland loans for regenerative agriculture: FBN and Walton family launch ‘first&#45;of&#45;its&#45;kind’ lending program</title>
<link>https://sdgtalks.ai/farmland-loans-for-regenerative-agriculture-fbn-and-walton-family-launch-first-of-its-kind-lending-program</link>
<guid>https://sdgtalks.ai/farmland-loans-for-regenerative-agriculture-fbn-and-walton-family-launch-first-of-its-kind-lending-program</guid>
<description><![CDATA[ The article reports that Farmers Business Network (FBN) and the Walton Family Foundation launched a pilot “Regenerative Agriculture Financing (RAF) Land Loan” program that reduces interest rates for farmers who adopt verified soil- and water-health practices. Backed by a $750,000 Walton Family Foundation investment, the pilot aims to serve about 20 farmers as a proof of concept, offering 0.25–0.5 percentage point rate discounts for seven years on newly financed or refinanced farmland, with eligibility determined using Environmental Defense Fund and Gradable criteria. Framed against a softening farm economy and uncertain federal funding, the initiative is positioned as a private-sector tool to cut borrowing costs while incentivizing long-term regenerative practices. ]]></description>
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<pubDate>Fri, 14 Nov 2025 13:56:38 -0500</pubDate>
<dc:creator>clolli</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p>As rising costs and regulatory uncertainty challenge farmers’ efforts to adopt regenerative agriculture practices, an<span> </span><a href="https://www.fbn.com/community/blog/fbn-launches-regenerative-agriculture-financing-land-loan?srsltid=AfmBOoq9FyC1An0j4F3Xmf6eE-9-O7uogL8b0-dPLjAghyKqxfkQlVW1">innovative new pilot</a><span> </span>with support from the Walton family looks to help finance the transition through discounts in private conservation loans.</p>
<p>Led by agriculture e-commerce marketplace Farmers Business Network, the Regenerative Agriculture Financing Land Loan pilot program offers discounted interest rates on land loans for farms who successfully adopt conservation practices benefiting soil health, water quality and overall climate resilience.</p>
<p>The loans are made possible through a $750,000 investment from the Walton Family Foundation, the philanthropic arm of Walmart founders Sam and Helen Walton.</p>
<div class="hybrid-ad-wrapper hide-small show-large">
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<p>“Helping farmers to grow crops while also protecting water and soil is key to protecting people and nature together,” Moira Mcdonald, environmental program director of the Walton Family Foundation, said in a statement, adding that the program will “provide farmers with access to affordable capital in order to incentivize the adoption of sustainable agricultural practices.”</p>
<p>The pilot program is expected to serve about 20 farmers as a “proof of concept” with hopes of expansion down the line, Dan English, general manager of FBN Financial, said in an interview with Agriculture Dive.</p>
<p>To access the discounts, farmers must implement sustainable soil and water health practices and meet environmental criteria developed by Environmental Defense Fund and Gradable,<span> </span><a href="https://www.agriculturedive.com/news/farmers-business-network-spins-off-gradable-for-adm-joint-venture/724562/">a sustainable grain platform co-owned by FBN and ADM</a>.</p>
<p>Eligible farmers will receive discounted interest rates — ranging from 0.25% to 0.5% — on newly financed land for seven years. The loans can be used to acquire or refinance land, English said, providing savings of around $5,000 to $6,000 a year.</p>
<p>The regenerative land loans build on the overwhelming demand for FBN’s sustainable financing program that provides operating loans to farms that implement regenerative practices. The operating loan program, launched as a pilot with the Environmental Defense Fund in 2021, has grown to support 140 farmers in 2024.</p>
<p>Private companies and partnerships could play more of a role in spurring adoption of regenerative agriculture, particularly amid a downturn in the farm economy and ongoing uncertainty around federal climate funding. There is demand among farmers to transition to regenerative practices, English said, but the sector needs “long term” investment.</p>
<div class="hide-small show-large" id="desktop-inline-signup" data-gtm-vis-recent-on-screen113061586_58="17508" data-gtm-vis-first-on-screen113061586_58="17508" data-gtm-vis-total-visible-time113061586_58="100" data-gtm-vis-has-fired113061586_58="1" data-gtm-vis-recent-on-screen132562684_151="17523" data-gtm-vis-first-on-screen132562684_151="17523" data-gtm-vis-total-visible-time132562684_151="100" data-gtm-vis-has-fired132562684_151="1">
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<title>For manufacturers, the circular economy strengthens supply chains. Here&amp;apos;s how</title>
<link>https://sdgtalks.ai/for-manufacturers-the-circular-economy-strengthens-supply-chains-heres-how</link>
<guid>https://sdgtalks.ai/for-manufacturers-the-circular-economy-strengthens-supply-chains-heres-how</guid>
<description><![CDATA[ To build resilient supply chains, integrating circular economy principles like recycling, remanufacturing, and repair is key. This approach reduces reliance on scarce resources, cuts emissions, and supports local production. Despite challenges, adopting circular practices offers long-term sustainability, efficiency, and competitive advantage. ]]></description>
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<pubDate>Sun, 08 Dec 2024 18:13:11 -0500</pubDate>
<dc:creator>Aneurin Toomey 1</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<div class="wef-zw4tnc">
<p>In an era defined by globalization and the pursuit of efficiency, supply chains have become essential yet<span> </span><a href="https://www.mckinsey.com/~/media/mckinsey/industries/semiconductors/our%20insights/semiconductor%20shortage%20how%20the%20automotive%20industry%20can%20succeed/semiconductor-shortage-how-the-automotive-industry-can-succeed.pdf">vulnerable networks</a><span> </span>within the global economy.</p>
</div>
<div class="wef-zw4tnc">
<p>This vulnerability, exacerbated by geopolitical tensions, environmental challenges and trade conflicts, underscores the critical need for resilience — not just for risk mitigation but as a strategic imperative that can serve as a competitive advantage in an uncertain world.</p>
</div>
<div class="wef-zw4tnc">
<p>Integrating circular economy principles offers a solution. Circular economy principles bolster sustainability and transform these vulnerabilities into strengths. Circular economy principles help supply chains adapt to and maintain operations amidst unforeseen disruptions, fostering sustainable growth and resilience in an interconnected world.</p>
</div>
<div class="wef-1qmtbdn">
<h2 class="chakra-heading wef-jbq6c6">The circular economy can strengthen supply chains</h2>
</div>
<div class="wef-zw4tnc">
<p><a href="https://www.weforum.org/agenda/circular-economy/">The circular economy</a><span> </span>represents a paradigm shift from the traditional linear model of "take-make-dispose" to a regenerative approach that emphasizes the restoration and regeneration of products, materials and energy. It<span> </span><a href="https://www.weforum.org/agenda/2024/02/why-businesses-must-embrace-the-circular-economy-for-a-more-sustainable-future/">challenges conventional metrics of value creation</a><span> </span>and encourages manufacturers to design products and business models with durability, repairability and recyclability in mind.</p>
</div>
<div class="wef-zw4tnc">
<p>Through recycling, part harvesting and remanufacturing, repair, refurbishment and<span> </span><a href="https://www.weforum.org/impact/strengthening-trust-in-second-hand-markets/">recommerce</a><span> </span>circular economy principles can reduce dependency on scarce resources and component suppliers, building adaptable and resilient supply chains.</p>
</div>
<div class="wef-zw4tnc">
<p>For manufacturers, this means ensuring parts and materials within their control<span> </span><i>never unintentionally exit their sphere of influence</i>. By retaining control over the lifecycle of products, materials and components, manufacturers can prevent resource loss, ensure efficient reuse, enable capitalization of circular practices and reduce their environmental impact.</p>
</div>
<div class="wef-ha4kjk">
<div class="wef-1qbpo0l">
<div class="wef-0"><img alt="The 5 Rs of the circular economy — recycling, remanufacturing, repair, refurbishment and recommerce — bolster supply chain resilience." src="https://assets.weforum.org/editor/v0TydkUtzt9c7n6s3XiIsnTUD-TKvT6wMVQ8h8E7A2o.png" loading="lazy" class="chakra-image wef-gbfd2a" sizes="100vw" pinger-seen="true"></div>
</div>
<span class="wef-0">The 5 Rs of the circular economy: recycling, remanufacturing, repair, refurbishment and recommerce.</span><span class="wef-0">Image:<span> </span>DXC Technology</span></div>
<div class="wef-zw4tnc">
<p>By prioritizing the management and recovery of materials and components, manufacturers can maintain a degree of control over their resources, ensuring that materials remain in use and within their control for as long as possible. This approach not only helps to decouple economic growth from resource consumption but also fosters a more sustainable and resilient supply chain.</p>
</div>
<div class="wef-zw4tnc">
<p>The circular approach compels manufacturers to consider the end-of-life stage of their products, facilitating a smoother transition of materials back into the supply chain, thereby conserving value and reducing environmental impact.</p>
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<div class="gtm-snippet wef-g0ovqs" data-gtm-section="What is a circular economy?">
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<p class="chakra-text wef-1tx9got"><span class="chakra-text wef-514cn4">What is a circular economy?</span></p>
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<p>Incorporating circular economy principles aligns with<span> </span><a href="https://www.whitehouse.gov/briefing-room/statements-releases/2022/08/09/fact-sheet-chips-and-science-act-will-lower-costs-create-jobs-strengthen-supply-chains-and-counter-china/">growing political pressures to develop local production capabilities</a>. This movement towards localization is driven by the desire for economic resilience, job creation and reduced dependencies on global supply chains.</p>
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<p>The circular economy fosters the development of local circular service provider markets by encouraging the design of products for longevity, repairability and recyclability. This approach supports local businesses and encourages the growth of repair services, remanufacturing facilities and recycling centers. By investing in local ecosystems that support the circular economy, regions can reduce their reliance on imported goods and materials, leading to more resilient local economies.</p>
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<p>Governments around the world are<span> </span><a href="https://www.linkedin.com/pulse/digitizing-compliance-unpacking-circular-economy-digital-jensen-3x7ae/">beginning to implement measures</a><span> </span>to encourage businesses to adopt these practices. This includes incentives for sustainable product design, support for local recycling and remanufacturing industries and regulations that favour the use of recycled materials in new products.</p>
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<p>This focus on creating local circular product and service markets provides a strategic response to supply chain vulnerabilities, fostering economic resilience, reducing environmental impacts and supporting the transition to more sustainable and self-sufficient local economies.</p>
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<h2 class="chakra-heading wef-jbq6c6">Overcoming circular economy barriers</h2>
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<p>Companies looking to integrate circular economy principles into their operations must navigate a complex landscape of regulatory, market and financial hurdles.</p>
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<h3 class="chakra-heading wef-16ykzuh">Navigating regulatory hurdles</h3>
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<p>Regulations regarding waste, product standards and cross-border movement of materials can inadvertently hinder recycling and remanufacturing efforts. For instance, certain materials classified as “waste” under current legislation<span> </span><a href="https://www.epa.gov/hw/regulatory-exclusions-and-alternative-standards-recycling-materials-solid-wastes-and-hazardous">may face strict controls or prohibitions</a><span> </span>on their reuse or transport, even for recycling or remanufacturing purposes.</p>
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<h3 class="chakra-heading wef-16ykzuh">Building market acceptance</h3>
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<p>Consumers and business customers alike may have<span> </span><a href="https://www.popsci.com/environment/recycled-product-concerns-sustainability/">reservations about products</a><span> </span>made from recycled materials or remanufactured products, perceiving them as inferior to new ones. Overcoming this perception requires substantial efforts in education and communication to demonstrate the benefits of circular products.</p>
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<h3 class="chakra-heading wef-16ykzuh">Addressing cost implications</h3>
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<p>The initial costs associated with transitioning to circular economy models can be prohibitive. Investing in the necessary infrastructure for recycling, remanufacturing or setting up product-as-a-service models requires upfront capital. Additionally, the operational costs of collecting, sorting and processing used products and materials can be higher than sourcing new materials, at least in the short term.</p>
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<h3 class="chakra-heading wef-16ykzuh">Fostering mindset shifts</h3>
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<p>Transitioning to a circular economy requires overcoming entrenched resistance at multiple levels. Internally, organizations may face inertia from established linear processes, with the prevailing “<i>this is how we've always done it</i>” mentality posing a significant barrier to change.</p>
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<p>Upstream in the supply chain, the shift can disrupt the value propositions of some players, leading to resistance from those who stand to lose from the transition away from linear models. While downstream, altering customer habits and preferences to align with circular practices requires concerted effort and engagement, as it challenges traditional behaviour patterns.</p>
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<h3 class="chakra-heading wef-16ykzuh">Building a market for services</h3>
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<p>Building a market for circular service providers requires creating demand for such services and ensuring a supply chain that supports the repair, refurbishment and recycling of products. Establishing this market requires overcoming consumer skepticism, adapting existing business models and fostering partnerships across industries.</p>
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<h3 class="chakra-heading wef-16ykzuh">Navigating the parts and recycling market</h3>
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<p>Establishing a competitive market for part harvesting and material recycling is crucial. Relying on single entities for these phases can undermine resilience. It is essential to cultivate a diverse ecosystem of partners to ensure flexibility and reliability in supply chain recovery processes.</p>
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<p><a href="https://www.linkedin.com/pulse/sustainable-manufacturing-intelligence-framework-synthesis-jensen-z3pwe/">Digitizing the circular economy</a><span> </span>presents challenges such as integrating technology into traditional systems, ensuring data security and managing the complexity of tracking products and materials across their lifecycle. Effective digitization requires substantial investment in technology and skills development.</p>
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<h2 class="chakra-heading wef-jbq6c6">Manufacturers and the circular economy: the path forward</h2>
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<p>Manufacturers, in embracing circular economy principles, have the opportunity to lead this transformation, building supply chains that are resilient to the shocks and stresses of the global market and sustainable and beneficial for society and the environment.</p>
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<p>The adoption of digital technologies such as Internet of Things, Digital Product Passports and Artificial Intelligence offers potential innovative solutions for manufcaturers, enabling transparent, efficient and adaptable supply chains that can support circular practices.</p>
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<p>The path forward calls for a fundamental reimagining of how products are designed, produced and consumed. To do this, manufacturers should start with a thorough audit of current practices, developing a strategic vision for circularity and implementing pilot projects to test and refine circular initiatives. This is a journey that requires a shift in mindset, from viewing waste and end-of-life products as problems to seeing them as opportunities for value creation and innovation.</p>
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<p>Overcoming this resistance requires persistence, leadership and a clear vision for the future — a future where circular economy principles are a central pillar of supply chain strategy. For manufacturers willing to lead the way, it offers the promise of a future where business success is aligned with environmental stewardship and societal well-being. The time to start is now.</p>
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<title>WSU Scientists Transform Agricultural Waste into Sustainable Jet Fuel</title>
<link>https://sdgtalks.ai/wsu-scientists-transform-agricultural-waste-into-sustainable-jet-fuel</link>
<guid>https://sdgtalks.ai/wsu-scientists-transform-agricultural-waste-into-sustainable-jet-fuel</guid>
<description><![CDATA[ Washington State University researchers have developed a continuous process to convert lignin, an agricultural waste product, into sustainable aviation fuel. This innovation could reduce the aviation industry&#039;s carbon footprint, provide cleaner fuel alternatives, and help meet global sustainability goals by utilizing abundant agricultural byproducts. ]]></description>
<enclosure url="https://alpha.creativecirclecdn.com/environment/original/20241002-094459-1d2-doctoral%20student%20and%20scientist%20at%20Pacific%20Northwest%20National%20Laboratory%2C%20tests%20a%20WSU-developed%20continuous%20process%20that%20turns%20lignin%2C%20a%20polymer%20found%20in%20plants%2C%20into%20jet%20fuel..png.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 08 Dec 2024 18:03:06 -0500</pubDate>
<dc:creator>Aneurin Toomey 1</dc:creator>
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<content:encoded><![CDATA[<h2>Lignin: An Untapped Resource for Sustainable Aviation Fuel</h2>
<p>Lignin is a class of complex structural molecules that give plants their woody characteristics, making them rigid and resistant to degradation. It is derived from agricultural byproducts such as<span> </span><a href="https://www.environmentenergyleader.com/stories/southwest-airlines-advances-sustainability-goals-with-saffire-renewables-acquisition,1081">corn stover</a>—the stalks, cobs, and leaves left after harvest—and is considered a waste product in many agricultural processes.</p>
<p>According to Professor Bin Yang, the lead researcher and a professor in WSU’s Department of Biological Systems Engineering, this development represents a critical step forward in utilizing agricultural waste to create renewable aviation fuel.</p>
<p>The<span> </span><a href="https://www.environmentenergyleader.com/stories/heres-how-jetblue-will-achieve-net-zero-emissions-by-2040,3356">aviation industry</a><span> </span>has significantly contributed to greenhouse gas emissions, consuming nearly 100 billion gallons of fuel in 2019. As global fuel demand is expected to increase by 32% by 2030 and potentially more than double by 2050, the need for alternative fuels is more pressing than ever.</p>
<p>In response, the aviation sector has focused on<a href="https://www.environmentenergyleader.com/stories/aviation-climate-taskforce-and-national-renewable-energy-laboratory-partner-on-sustainable-aviation,957"> sustainable aviation fuels (SAFs)</a><span> </span>derived from renewable resources like<span> </span><a href="https://www.environmentenergyleader.com/stories/two-companies-join-together-to-produce-commercial-quantities-of-saf-from-hemp-biomass,3017">plant-based biomass</a>. However, despite the progress made in biofuels, current technologies still face challenges in meeting the aviation industry’s strict performance and volume requirements.</p>
<p>Lignin, often discarded or underutilized in biorefining processes, presents a promising new pathway for sustainable fuel production. It is produced in large quantities—about 300 million tons annually—and its aromatic structure makes it a viable candidate for jet fuel. However, converting lignin into fuel continuously has been a challenge until now. The WSU team’s research builds on this potential by demonstrating a novel process that could overcome many technical hurdles.</p>
<h2>Innovative Technology: Simultaneous Depolymerization and Hydrodeoxygenation</h2>
<p>The WSU researchers developed "simultaneous depolymerization and hydrodeoxygenation" (SDHDO), which breaks down the lignin polymer into smaller molecules while simultaneously removing oxygen. This process converts lignin into hydrocarbons, which can be used to produce lignin-based jet fuel.</p>
<p>The key innovation in this research is the ability to perform this conversion continuously, making it more feasible for commercial-scale production. The industry prefers Continuous processes because they can operate without interruptions, increasing efficiency and reducing costs.</p>
<p>The research was conducted at WSU’s facility in Richland, Washington, where the scientists introduced dissolved lignin polymers into a hydrotreating reactor to produce jet fuel. This continuous process contrasts with previous research that used batch processing, which is less efficient for large-scale production. The WSU team’s success in creating a continuous process marks a significant milestone toward commercializing lignin-based aviation fuel.</p>
<p>“This achievement takes this technology one step closer to real-world use by providing data that lets us better gauge its feasibility for commercial aviation,” said Professor Yang. “We now have a clearer understanding of how this process can be scaled up, making it a strong candidate for sustainable aviation fuel production.”</p>
<h2>The Potential of Lignin-Based Jet Fuel in Aviation</h2>
<p>Aviation is a notoriously difficult sector to decarbonize due to its heavy reliance on energy-dense liquid fuels and the challenges of electrifying aircraft. Sustainable aviation fuels are a key solution to reducing the industry’s environmental impact, and lignin-based fuels offer several advantages.</p>
<p>One of the primary benefits is that lignin-derived hydrocarbons can replace aromatics. These fossil fuel-derived compounds enhance fuel density and contribute to contrail formation and other environmental impacts. Aromatics are still widely used in jet fuel because they help swell O-rings in metal-to-metal joints, making them critical to fuel system performance. However, they are also a significant soot source, which has environmental and health consequences.</p>
<p>Lignin-based fuels could offer a cleaner alternative to fossil fuel-derived aromatics, helping to reduce the formation of contrails and improve fuel performance. In addition, the hydrocarbons produced from lignin are dense, efficient, and compatible with existing aviation infrastructure. These characteristics make lignin-based jet fuel a strong contender for use in commercial aviation, as it can be blended with conventional jet fuels to increase the renewable content while maintaining the performance characteristics required by airlines.</p>
<h2>Overcoming Challenges for Commercialization</h2>
<p>One of the most significant challenges facing the aviation industry is the need for “drop-in” fuels—fuels that can be used without modifying existing aircraft engines or fueling infrastructure.<span> </span><a href="https://www.pnnl.gov/publications/lignin-based-jet-fuel-and-its-blending-effect-conventional-jet-fuel#:~:text=A%20lignin-based%20jet%20fuel%20(LJF)%20blend" target="_blank" rel="noopener">Lignin-based jet fuels</a><span> </span>have the potential to meet this requirement, as they offer sealing properties, energy density, and emissions profiles similar to conventional jet fuel. The WSU team’s research demonstrated that lignin-based jet fuel could be blended with conventional fuels to create a drop-in solution, moving the industry closer to producing 100% renewable aviation fuels.</p>
<p>The research also addressed another critical challenge: the<span> </span><a href="https://www.environmentenergyleader.com/stories/decarbonizing-aviation-technology-for-feedstock-production-will-be-key-to-the-takeoff-of-saf,48184">cost and complexity of producing sustainable fuels</a>. Using a less processed form of lignin, known as “technical lignin,” the team could reduce the cost and energy input required to produce the fuel. This contrasts with other studies that used highly processed lignin bio-oils, which are more expensive and energy-intensive.</p>
<p>The continuous process developed by WSU also used engineered catalysts, including a ruthenium-based catalyst (Ru-HY-60-MI), which proved effective in converting lignin into jet fuel range hydrocarbons. The researchers were able to achieve a carbon yield of 17.9%, producing a fuel rich in mono cycloalkanes and poly cycloalkanes, which are critical components for aviation fuel performance.</p>
<h2>A Sustainable Path Forward for Aviation</h2>
<p>The WSU team’s research represents a critical step toward making sustainable aviation fuels commercially viable. The successful demonstration of a continuous process for producing lignin-based jet fuel shows that<span> </span><a href="https://www.environmentenergyleader.com/stories/united-airlines-expands-sustainable-aviation-efforts-with-saf-at-ohare,44950">agricultural waste</a><span> </span>can be transformed into a valuable resource for the aviation industry. By utilizing lignin, which is often discarded or burned, this technology not only provides a renewable alternative to fossil fuels but also contributes to waste reduction and more efficient resource use.</p>
<p>In the broader context of global sustainability goals, the aviation industry has set ambitious targets to reduce its carbon footprint. The<span> </span><a href="https://www.environmentenergyleader.com/stories/green-skies-ahead-the-rise-of-sustainable-aviation,3602">International Air Transport Association (IATA)</a><span> </span>has committed to achieving net-zero carbon emissions by 2050, and sustainable aviation fuels will play a crucial role in meeting this goal. Lignin-based jet fuel offers a promising pathway to achieving these targets by reducing emissions, improving fuel efficiency, and providing a renewable alternative to fossil fuels.</p>
<p>The research was supported by several prominent organizations, including the<span> </span><a href="https://www.environmentenergyleader.com/stories/doe-allocates-118-million-to-increase-production-of-sustainable-biofuels,3568">U.S. Department of Energy’s Bioenergy Technologies Office</a>, the<span> </span><a href="https://www.environmentenergyleader.com/stories/exploiting-waste-to-propel-the-future-of-aviation,1189">Pacific Northwest National Laboratory (PNNL)</a>, the<span> </span><a href="https://www.environmentenergyleader.com/stories/aviation-climate-taskforce-and-national-renewable-energy-laboratory-partner-on-sustainable-aviation,957">National Renewable Energy Laboratory (NREL)</a>, and Advanced Refining Technologies LLC.</p>
<p>With continued support and further refinement of the technology, lignin-based jet fuel could become a vital component of the aviation industry’s efforts to reduce its environmental impact and transition to a more sustainable future.</p>]]> </content:encoded>
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<title>A Circuit Board Grown From Leaves Could Set a New Standard in Electronics</title>
<link>https://sdgtalks.ai/a-circuit-board-grown-from-leaves-could-set-a-new-standard-in-electronics</link>
<guid>https://sdgtalks.ai/a-circuit-board-grown-from-leaves-could-set-a-new-standard-in-electronics</guid>
<description><![CDATA[ Scientists at TU Dresden have developed &quot;leaftronics&quot;—biodegradable circuit boards crafted from natural tree leaves. These polymer films, built on the leaf&#039;s lignocellulose scaffolding, can withstand high temperatures and support technologies like OLEDs while remaining environmentally friendly. With 62 billion kilograms of e-waste produced in 2022 alone, this innovation signals a potential shift toward sustainable electronics. ]]></description>
<enclosure url="https://hips.hearstapps.com/hmg-prod/images/abstract-circuit-technology-background-royalty-free-illustration-1733260751.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sat, 07 Dec 2024 18:09:07 -0500</pubDate>
<dc:creator>Rose Ganshert</dc:creator>
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<content:encoded><![CDATA[<ul data-node-id="0" class="css-1r2vahp emevuu60">
<li>As e-waste continues piling in landfills, toxic sludge from rare earth metals leaches into the ground, propelling a growing environmental disaster.</li>
<li>To combat this, scientists at the Dresden University of Technology have created a biodegradable circuit board using a tree leaf.</li>
<li>Although not currently as robust as typical printed circuit boards, this research shows that the electronics industry isn’t somehow exempt from finding ways to make their products more sustainable.</li>
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<p data-journey-content="true" data-node-id="2" class="css-1nd4gv7 emevuu60">According<span> </span><a href="https://explodingtopics.com/blog/smartphone-stats" target="_blank" data-vars-ga-outbound-link="https://explodingtopics.com/blog/smartphone-stats" data-vars-ga-ux-element="Hyperlink" data-vars-ga-call-to-action="to recent estimates" class="body-link css-1kk1geb emevuu60" rel="noopener">to recent estimates</a>, there are nearly 7<span> </span><em>billion</em><span> </span>smartphones in the world. With many tech companies avidly hoping you’ll upgrade your pocket computer annually<span> </span><em>ad nauseum</em>, that means a lot of electronic waste (<a href="https://www.popularmechanics.com/technology/a20878/investigators-used-gps-to-track-us-toxic-electronic-waste-exports/" target="_blank" data-vars-ga-outbound-link="https://www.popularmechanics.com/technology/a20878/investigators-used-gps-to-track-us-toxic-electronic-waste-exports/" data-vars-ga-ux-element="Hyperlink" data-vars-ga-call-to-action="e-waste" class="body-link css-1kk1geb emevuu60" rel="noopener">e-waste</a>) in landfills leaking toxic chemicals detrimental to human and environmental health. And that’s<span> </span><em>only</em><span> </span>smartphones. The<span> </span><a href="https://earth.org/e-waste-recycling-rates-remain-dangerously-low-as-demand-for-electronic-devices-booms-un-report-reveals/" target="_blank" data-vars-ga-outbound-link="https://earth.org/e-waste-recycling-rates-remain-dangerously-low-as-demand-for-electronic-devices-booms-un-report-reveals/" data-vars-ga-ux-element="Hyperlink" data-vars-ga-call-to-action="U.N. estimates that in 2022" class="body-link css-1kk1geb emevuu60" rel="noopener"><u>U.N. estimates that in 2022</u></a>, the world produced 62 billion kilograms of e-waste—an 82 percent increase from just a decade earlier.</p>
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<p data-journey-content="true" data-node-id="4" class="css-1nd4gv7 emevuu60">While other industries have started transitioning toward biodegradable products, electronics is more complicated, as it often relies on rare earth metals that produce toxic waste But now, the industry may be turning over a new<span> </span><a href="https://www.popularmechanics.com/technology/news/a21218/bionic-leaf-turns-co2-back-into-fuel/" target="_blank" data-vars-ga-outbound-link="https://www.popularmechanics.com/technology/news/a21218/bionic-leaf-turns-co2-back-into-fuel/" data-vars-ga-ux-element="Hyperlink" data-vars-ga-call-to-action="leaf" class="body-link css-1kk1geb emevuu60" rel="noopener">leaf</a>… literally. An international team of scientists, led by researchers at the Dresden University of Technology (TU Dresden) in Germany, have leveraged the quasi-fractal lignocellulose structures—essentially the veiny scaffolding of a leaf—in leaves to create biodegradable polymer films. In other words, they’ve made leaf-based electronics, or “leaftronics,” as the researchers called it. The details of this process were published in the journal<span> </span><a href="https://www.science.org/doi/10.1126/sciadv.adq3276" target="_blank" data-vars-ga-outbound-link="https://www.science.org/doi/10.1126/sciadv.adq3276" data-vars-ga-ux-element="Hyperlink" data-vars-ga-call-to-action="Science Advances" class="body-link css-1kk1geb emevuu60" rel="noopener"><em><u>Science Advances</u></em></a><span> </span>in November.</p>
<p data-journey-content="true" data-node-id="5" class="css-1nd4gv7 emevuu60">“We were surprised to find that these natural quasi-fractal lignocellulose skeletons not only support living cells in nature, but can also hold solution-processable<span> </span><a href="https://www.popularmechanics.com/military/research/a28819719/self-destructing-polymer/" target="_blank" data-vars-ga-outbound-link="https://www.popularmechanics.com/military/research/a28819719/self-destructing-polymer/" data-vars-ga-ux-element="Hyperlink" data-vars-ga-call-to-action="polymers" class="body-link css-1kk1geb emevuu60" rel="noopener">polymers</a><span> </span>together, even at relatively high temperatures where these polymers should begin flowing,” TU Dresden’s Hans Kleemann, a co-author of the study,<span> </span><a href="https://tu-dresden.de/tu-dresden/newsportal/news/von-der-natur-inspiriert-leaftronics-ebnet-den-weg-fuer-biologisch-abbaubare-elektronik?set_language=en" target="_blank" data-vars-ga-outbound-link="https://tu-dresden.de/tu-dresden/newsportal/news/von-der-natur-inspiriert-leaftronics-ebnet-den-weg-fuer-biologisch-abbaubare-elektronik?set_language=en" data-vars-ga-ux-element="Hyperlink" data-vars-ga-call-to-action="said in a press statement" class="body-link css-1kk1geb emevuu60" rel="noopener">said in a press statement</a>.</p>
<p data-journey-content="true" data-node-id="7" class="css-1nd4gv7 emevuu60">These natural quasi-fractal structures thermomechanically stabilized polymers films, but crucially<span> </span><em>did not</em><span> </span>impact their biodegradability along the way. Furthermore, the researchers demonstrated that these polymer films can withstand soldered circuitry and support<span> </span><a href="https://www.popularmechanics.com/space/solar-system/news/a25235/ceres-organics/" target="_blank" data-vars-ga-outbound-link="https://www.popularmechanics.com/space/solar-system/news/a25235/ceres-organics/" data-vars-ga-ux-element="Hyperlink" data-vars-ga-call-to-action="organic" class="body-link css-1kk1geb emevuu60" rel="noopener">organic</a><span> </span>light-emitting diodes, or OLEDS.</p>]]> </content:encoded>
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<title>An organism used as fire starter for centuries could replace some plastics, study finds</title>
<link>https://sdgtalks.ai/an-organism-used-as-fire-starter-for-centuries-could-replace-some-plastics-study-finds</link>
<guid>https://sdgtalks.ai/an-organism-used-as-fire-starter-for-centuries-could-replace-some-plastics-study-finds</guid>
<description><![CDATA[ The resilient Fomes fomentarius fungus, known as “tinder fungus,” could revolutionize sustainable materials. With a structure rivaling plastics, leather, and plywood, it shows potential for industrial use in sports gear, insulation, and consumer goods. Researchers aim to grow it in labs, avoiding ecological harm while advancing an eco-friendly alternative to traditional materials. ]]></description>
<enclosure url="https://media.cnn.com/api/v1/images/stellar/prod/230222095519-fungus-replace-plastics-study-restricted.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sat, 07 Dec 2024 16:58:31 -0500</pubDate>
<dc:creator>Rose Ganshert</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<div data-uri="cms.cnn.com/_components/source/instances/source-h_85b24e34d2f69ce5a9722f841987ff38@published" data-component-name="source" class="source inline-placeholder" data-article-gutter="true"><cite class="source__cite"><span class="source__text" data-editable="source">(CNN)</span> — </cite>A tough, bell-shaped fungus that grows on the rotting bark of trees has been used as a fire starter for centuries, earning it the nickname “tinder fungus.”</div>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_AF8CA02D-A80F-B0A4-DF86-79F008C92ADC@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">Now, researchers are taking a closer look at the molecular structure of this oddly powerful organism<strong><span> </span></strong>— and they’ve found that it could hold the secrets to replacing some types of plastics.</p>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_52D2C7D1-1649-BCEA-7736-753A268F779A@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">Parts of the fungus, formally called Fomes fomentarius, were found to have similar structural strength to plywood or leather but at a lower weight, according to a<span> </span><a href="http://www.science.org/doi/10.1126/sciadv.ade5417?adobe_mc=MCMID%3D36256585715653386600174392311486120705%7CMCORGID%3D242B6472541199F70A4C98A6%2540AdobeOrg%7CTS%3D1677001072" target="_blank" rel="noopener">study</a><span> </span>published Wednesday in the journal Science Advances.</p>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_487A7768-F469-0F62-689B-7574748EBFEF@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">“F. fomentarius fruiting bodies are ingeniously lightweight biological designs, simple in composition but efficient in performance,” the study noted. “Growing the material using simple ingredients is an alternative solution to overcome the cost, time, mass production, and sustainability of how we make and consume materials in the future.”</p>
<h2 class="subheader inline-placeholder" data-editable="text" data-uri="cms.cnn.com/_components/subheader/instances/paragraph_9EB2EE49-FC96-94E0-B5E2-7A6A7F92865B@published" data-component-name="subheader" id="what-makes-f-fomentarius-so-strong" data-article-gutter="true">What makes F. fomentarius so strong</h2>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_4C25D82F-288D-AEC3-83C1-79BD629FA32C@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">Humans have long used F. fomentarius — also sometimes called “hoof fungus” because of its visual resemblance to a horse’s hoof — harvested in the wild to feed fires. It’s also been used to create some clothing items, including hats. But the fungus has only recently piqued the interest of the scientific community, according to the study.</p>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_DB3BAD19-6503-4A7F-993A-79BFCABF593D@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">Researchers at the VTT Technical Research Centre of Finland sought to analyze the internal structure of F. fomentarius more in depth, getting a glimpse of the microstructures that give the fungus its uniquely strong yet lightweight consistency. What they found was extremely promising, said study coauthor Dr. Pezhman Mohammadi, a senior scientist at VTT.</p>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_4AE29F86-DCCC-AC03-6D95-79D0E43DEEDD@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">The fungus has structural integrity similar to certain grades of plastic and could be used to replace shock-absorbing materials used in things like football helmets and other sporting equipment; heat and sound insulators; and even consumer product parts, such as headset parts, Mohammadi said via email.<strong></strong></p>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_E91B84DF-6816-6C25-4B7C-79D09428DA17@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">F. fomentarius “has a very stiff and hard protective outer layer, has softer spongy mid-layer, and a strong and tough inner layer each (of which) could outperform a different class of man-made and natural materials,” Mohammadi added.</p>
<h2 class="subheader inline-placeholder" data-editable="text" data-uri="cms.cnn.com/_components/subheader/instances/paragraph_9F482C94-F3B5-1806-2F00-7A6BD17D795F@published" data-component-name="subheader" id="potential-use-of-f-fomentarius" data-article-gutter="true">Potential use of F. fomentarius</h2>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_54ABCD5F-006F-A957-469C-7A6B69ADB566@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">The researchers are not suggesting<strong><span> </span></strong>that tinder fungus should be harvested from the wild and funneled into the industrial process. That wouldn’t be economically viable, Mohammadi noted, and F. fomentarius takes seven to 10 years to grow to a significant size. The fungus, which is very common across the Northern Hemisphere, also plays a crucial role in its ecosystem, blooming on the bark of rotting beech and birch trees to aid the decomposition process.</p>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_C46C7BC7-3C49-A9DC-1909-79DFE38EA5E4@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">But researchers have made promising steps toward growing the fungus or a similar species in a lab environment, Mohammadi said.</p>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_11CD86D4-A725-18C7-6B37-7563E7624EE5@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">“With the advances in industrial biotechnology, we forecast the production of Metric Tons in a matter of weeks in contrast to wild-type mushrooms that take years to grow,” Mohammadi wrote in an email. “For example in our research institute, we have 1000-liter pilot scale bioreactors where this could be carried out.</p>
<p class="paragraph inline-placeholder vossi-paragraph" data-uri="cms.cnn.com/_components/paragraph/instances/paragraph_1AA8C1A9-45D5-EE86-7FC0-79E6C53F96A0@published" data-editable="text" data-component-name="paragraph" data-article-gutter="true">“However, like any starting technology, it would take some years of R&amp;D to be realized fully.”</p>]]> </content:encoded>
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<title>California’s first plastic bag ban made things worse. Now it’s trying again</title>
<link>https://sdgtalks.ai/californias-first-plastic-bag-ban-made-things-worse-now-its-trying-again</link>
<guid>https://sdgtalks.ai/californias-first-plastic-bag-ban-made-things-worse-now-its-trying-again</guid>
<description><![CDATA[ California&#039;s initial plastic bag ban in 2014 backfired due to a loophole allowing thicker plastic bags, leading to increased landfill waste. The state has now passed a stricter law banning single-use plastic bags entirely by 2026 and requiring paper bags to contain 50% recycled materials by 2028. This shift aims to reduce environmental harm, hold manufacturers accountable, and encourage reusable alternatives, with California also suing ExxonMobil for misleading the public about plastic recycling&#039;s feasibility. ]]></description>
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<pubDate>Tue, 03 Dec 2024 14:55:14 -0500</pubDate>
<dc:creator>Jeremy Utt</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p>Ten years after California approved a plastic bag ban that’s been blamed for making its plastic bag problem worse, the state is banning single-use plastic grocery bags entirely.</p>
<p>In 2014, California became the first state to pass a plastic bag ban. It’s one of at least 12 states that now have some form of ban on single-use plastic bags.</p>
<p>But because of a loophole in its initial ban that allowed grocers to charge for thicker plastic bags, California still dumped 231,072 tons of plastic grocery and merchandise bags in landfills in 2021, according to the state’s recycling agency, CalRecycle. That was a sharp increase from the year the ban took effect — and nearly 100,000 more tons than in 2018.</p>
<p>California officials are saying that there's a perception that plastics — especially plastic bags — can be easily recycled. But they say that this is not the reality and that consumers have been deceived for decades.</p>
<p>“CalRecycle has not identified facilities that recycle plastic bags in the state of California,” the agency told NPR this week.</p>
<p>The state <a href="https://www.npr.org/2024/09/23/nx-s1-5123619/california-sues-exxonmobil-for-misleading-public-on-plastic-recycling">filed a suit </a>on Sunday alleging that ExxonMobil promoted recycling while knowing that it was technically and economically challenging and wouldn't make much of a dent in the plastic waste problem.</p>
<p>Here’s a rundown of California’s new ban and similar measures:</p>
<h3 class="edTag">Why did California’s initial bag ban backfire?</h3>
<p>The state’s ban on thin single-use bags had a loophole that let grocers sell shoppers thicker plastic bags for a small fee: just 10 cents. In theory, the heavier bags were reusable. But in practice, they became a more substantial form of waste.</p>
<p>“A plastic bag has an average lifespan of 12 minutes and then it is discarded, afflicting our environment with toxic microplastics that fester in our oceans and landfills for up to 1,000 years,” Sen. Catherine Blakespear, an author of the new ban, said in <a href="https://sd38.senate.ca.gov/news/governor-signs-legislation-ban-plastic-bags-grocery-store-checkouts">a news release</a> issued after Gov. Gavin Newsom signed the ban into law on Sunday.</p>
<p>The initial ban was also undermined by the COVID-19 pandemic. When it was still unknown how the coronavirus spread, shoppers were barred from bringing reusable bags into grocery stores out of fear that their bags might be contaminated.<em> </em> </p>
<p>“California kind of took one for the team as the first to pass a statewide ban on plastic bags,” Melissa Valliant, communications director for the advocacy group Beyond Plastics, told NPR. “It ended up providing a lesson for other state and even local governments to learn from and to not allow loopholes like thicker plastic bags.”</p>
<h3 class="edTag">What does the new California law do?</h3>
<p>Starting on Jan. 1, 2026, customers at most grocery stores, convenience stores, and other retailers will have three main options: Pay at least 10 cents for a paper bag; use a reusable bag; or hand-carry their purchase.</p>
<p>“Stores may offer paper bags at the point-of-sale, and they can also sell the canvas-style reusable bags in other areas of the store,” Nate Rose of the California Grocers Association, which supports the new ban, told NPR.</p>
<p>“These are the bags many shoppers are already accustomed to bringing with them to carry their groceries,” Rose added.</p>
<p>And starting in 2028, stores’ paper bags will be required to be composed of at least 50% postconsumer recycled materials.</p>
<p>More than 70 organizations supported the legislation, <a href="https://laist.com/news/politics/these-are-the-2024-california-bills-gavin-newsom-has-signed-into-law-and-the-ones-he-has-vetoed">member station LAist reports</a>, saying it “would prevent plastic waste, which releases toxic chemicals into the air, water and soil.”</p>
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<p>California's attorney general, Rob Bonta, has filed a lawsuit against ExxonMobil, alleging that the oil and gas corporation misled consumers by telling them that recycling was a viable solution for plastic waste. In 2021, some 231,072 tons of plastic grocery and merchandise bags went to landfills, according to the state’s recycling agency, CalRecycle.</p>
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<span class="credit" aria-label="Image credit"> Muhammad Owais Khan/Getty Images </span></div>
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<h3 class="edTag">What’s so bad about plastic bags?</h3>
<p>Despite industry claims about their recyclability, the thin bags are notoriously difficult and expensive to process and recycle. Instead, they often wind up in landfills, where they will persist for centuries, or in incinerators.</p>
<p>For a sense of the scale of the problem, consider Philadelphia. An evaluation commissioned by the city <a href="https://www.phila.gov/media/20230428110156/PlasticBagBanReportApril2023.pdf">said last year</a> that in Philadelphia, “an estimated 1 billion single-use disposable plastic bags are used annually,” adding to waste, litter and emissions challenges.</p>
<p>Municipal systems, the evaluation stated, “are unable to recycle plastic bags and the soft material causes equipment jamming at recycling centers, leading to dangerous and costly repairs that account for 150 hours of lost staff time and $300,000 in city costs.”</p>
<p>In contrast, restrictions like bag bans “can be expected to eliminate almost 300 single-use plastic bags per person per year, on average,” according to an analysis by Environment America and the U.S. PIRG Education Fund that was <a href="https://publicinterestnetwork.org/wp-content/uploads/2024/01/Plastic-Bag-Bans-Work-January-2024.pdf">published in January</a>.</p>
<h3 class="edTag">What does the plastic industry say?</h3>
<p>Bag manufacturers are against bans on their products and they insist that the thin plastic film bag, made of polyethylene, makes more sense than the alternatives.</p>
<p>“A polyethylene bag is 100% recyclable and can be recycled into itself, is produced with low carbon emissions, and the PE is made domestically from natural gas,” a general manager of bag supplier Crown Poly <a href="https://bagalliance.org/wp-content/uploads/2024/02/FCR-NJ-Plastic-Retail-Bag-Demand-1.pdf">said in a 2023 report</a> prepared by Freedonia Custom Research on behalf of an industry group, the American Recyclable Plastic Bag Alliance.</p>
<p>“Conversely, PP [polypropylene] bags are produced overseas and imported, produce higher emissions than film bags, and are not recyclable. In fact, 99% of PP is virgin and does not contain post-consumer recycled material,” the report states.</p>
<p>Note: While single-use bags can technically be recycled, it’s not an easy or cost-effective process.</p>
<p>“To the extent they get recycled, a lot of polyethylene plastics get turned into low-grade materials. You can’t take a plastic bag and then make another plastic bag with the same properties out of it,” chemistry researcher John Hartwig of the University of California, Berkeley <a href="https://www.npr.org/2024/09/25/nx-s1-5123535/as%20John%20Hartwig,%20UC%20Berkeley’s%20Henry%20Rapoport%20Chair%20in%20Organic%20Chemistry.">said in 2022</a>, as he worked on ways to reuse the ubiquitous material. </p>
<p>The American Recyclable Plastic Bag Alliance and another industry group, the Plastics Industry Association, did not respond to NPR’s request for comment on the new California ban before this story was published.</p>
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<p>California will require shoppers to use paper bags or a reusable bag. In this photo from 2007, a woman loads plastic bags of groceries into her car at a Safeway store in San Francisco, before the city — and later, the state — adopted a ban on plastic checkout bags.</p>
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<span class="credit" aria-label="Image credit"> David Paul Morris/Getty Images/Getty Images North America </span></div>
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<h3 class="edTag">Should people just use paper bags?</h3>
<p>When bans on single-use plastic bags haven’t also included a fee on paper bags, their use has soared. In Portland, Ore., for instance, paper bag use <a href="https://www.oregonlive.com/opinion/2012/10/portland_needs_to_expand_the_p.html">shot up by nearly 500%</a> after the city enacted a ban (and before the state imposed its own ban with a fee for paper alternatives).</p>
<p>A similar dynamic has played out in Philadelphia, where the proportion of supermarket shoppers using at least one paper bag tripled after a plastic-bag ban took effect without a fee for paper. A recent bid to <a href="https://www.inquirer.com/news/philadelphia/philadelphia-plastic-bag-ban-paper-bag-fee-2024.html#:~:text=A%20month%20ago%2C%20Philadelphia%20City,imposed%20citywide%20plastic%20bag%20ban.">tack on a 15-cent fee for paper bags</a> was axed by a pocket veto.</p>
<p>Paper bags are easier to recycle than plastic, and more degradable. But environmental advocates want retailers and shoppers to move away from single-use bags of any type. They argue that a few minutes of convenience isn’t enough to justify cumbersome networks of bag collection, processing and production needed to recycle single-use bags.</p>
<p>“The whole goal is to get people to switch from disposable options — especially plastic, but disposable options altogether — to reusable and refillable options,” Valliant said. “Because ultimately that is going to be the most sustainable and the best for both environment and human health.”</p>
<h3 class="edTag">Which 12 states have banned plastic bags? </h3>
<p>In 2024, Colorado and Rhode Island enacted statewide bans on single-use plastic bags, joining 10 states that already had restrictions in place: California, Connecticut, Delaware, Hawaii, Maine, New Jersey, New York, Oregon, Vermont and Washington.</p>
<p>At their core, such bans are attempts to shift responsibility for plastic waste from consumers upstream — to retailers and, by extension, plastic producers.</p>
<p>The same week California’s new ban became law, the state opened another front in its battle with plastic waste by <a href="https://www.npr.org/2024/09/23/nx-s1-5123619/california-sues-exxonmobil-for-misleading-public-on-plastic-recycling">filing a lawsuit against oil and gas giant ExxonMobil,</a> a leading producer of the polymers used to make single-use plastics.</p>
<p>“For decades, ExxonMobil has been deceiving the public to convince us that plastic recycling could solve the plastic waste and pollution crisis when they clearly knew this wasn’t possible,” California Attorney General Rob Bonta <a href="https://www.npr.org/2024/09/23/nx-s1-5123619/california-sues-exxonmobil-for-misleading-public-on-plastic-recycling">said</a>.</p>
<p>Bonta accused ExxonMobil of profiting from “convincing consumers that they were responsible for the proliferation of plastic waste through their own personal habits, rather than through Mobil’s and Exxon’s efforts to produce an increasing number of plastic products designed for single-use.”</p>]]> </content:encoded>
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<title>Plastic waste is everywhere. Countries have one more chance to agree on a solution</title>
<link>https://sdgtalks.ai/plastic-waste-is-everywhere-countries-have-one-more-chance-to-agree-on-a-solution</link>
<guid>https://sdgtalks.ai/plastic-waste-is-everywhere-countries-have-one-more-chance-to-agree-on-a-solution</guid>
<description><![CDATA[ Countries are in South Korea negotiating a global treaty to address plastic pollution, aiming to finalize a plan by the year&#039;s end amidst mounting environmental and health concerns. While scientists agree on actions like capping plastic production and regulating harmful chemicals, talks have stalled due to resistance from the oil, gas, and plastics industries, which prefer recycling-focused solutions. Observers believe a credible agreement is possible, but political will and timely action are critical, especially for developing nations advocating for stronger measures. ]]></description>
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<pubDate>Tue, 03 Dec 2024 14:27:01 -0500</pubDate>
<dc:creator>Jeremy Utt</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p>Negotiators from dozens of countries are in Busan, South Korea, trying to hammer out a global treaty to cut down on plastic pollution. It's their last chance before an end-of-year deadline to agree on a plan to stem a crisis that threatens the environment and human health.</p>
<p>The world produces <a href="https://www.unep.org/interactives/beat-plastic-pollution/">about 400 million metric tons of plastic waste</a> every year, according to the United Nations Environment Programme. That's about the sum total of <a href="https://e360.yale.edu/digest/mass-of-humans-livestock-wild-mammals">how much every human on the planet</a> weighs. Most plastic ends up in places like oceans, shorelines and landfills, where it breaks down into tiny pieces called microplastics that have been found in every corner of the environment and <a href="https://e360.yale.edu/digest/microplastics-human-brains#:~:text=Scientists%20have%20found%20microplastics%20in,part%20of%20the%20human%20body.">inside human bodies</a>. The problem is getting worse, with plastic pollution <a href="https://www.oecd.org/en/about/news/press-releases/2022/06/global-plastic-waste-set-to-almost-triple-by-2060.html">expected to soar in the coming decades</a>. So in 2022, <a href="https://www.unep.org/news-and-stories/press-release/historic-day-campaign-beat-plastic-pollution-nations-commit-develop">U.N. member states said</a> they'd write a legally binding agreement to keep plastic waste out of the environment.</p>
<p>But for months, the <a href="https://www.npr.org/2023/11/20/1214141053/un-plastic-waste-pollution-negotiations-treaty-kenya-fossil-fuel-climate-change">talks have been deadlocked</a>. Plastic is made from fossil fuels. Environmental groups, scientists and human rights activists say the oil and gas industry, along with major producers like Russia and Saudi Arabia, have delayed progress and blocked measures that could hurt demand for their products.</p>
<p>However, some observers of the negotiations now see a path for countries to broker a deal. That's due in part to signals from the Biden administration in recent months that the U.S. might support more aggressive actions to reduce plastic pollution.</p>
<p>"We have all the right conditions at play," says Erin Simon, head of plastic waste and business at the World Wildlife Fund. "Can the chair [of the U.N. negotiating committee] finish the job? And will these countries stand up and speak for what they have been saying they are committed to doing when the time is right? Will they drown out the few and speak for the majority?"</p>
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<p>A volunteer collects plastic waste that washed up on the shores and mangroves in the Philippines.</p>
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<span class="credit" aria-label="Image credit"> Ezra Acayan/Getty Images </span></div>
</div>
<h3 class="edTag">Talks open in the shadow of a U.S. election</h3>
<p>The final round of talks is getting underway weeks after <a href="https://www.npr.org/2024/11/06/nx-s1-5181891/trump-win-climate-change-fossil-fuels-clean-energy">U.S. voters reelected Donald Trump</a> as president. For years, Trump has cast doubt on the scientific consensus that the Earth is getting hotter mainly because of human-caused greenhouse gas emissions, which come primarily from burning fossil fuels. And Trump has promised to pursue policies in his second term that support the United States' oil and gas industry.</p>
<p>Trump's transition team did not respond to messages seeking comment about the incoming administration's stance on plastic pollution.</p>
<p>Simon says U.S. politics could have some impact on the plastic negotiations, but she says the goal isn't to set U.S. policy or design a treaty that can be ratified immediately by the United States.</p>
<p>"The target is, how do we mobilize globally," Simon says. "And how do we make sure that no matter what [happens] in the U.S., we're taking action?"</p>
<p>Even before Trump's reelection, observers of the negotiations were reluctant to count on U.S. leadership. The Biden administration <a href="https://www.npr.org/2024/04/23/1246293403/plastic-pollution-un-treaty-negotiations-waste-fossil-fuels-climate-change">faced sharp criticism</a> for backing policies that aligned with the interests of the plastics industry. And the U.S. historically has been a laggard in global environmental initiatives, says Carroll Muffett, executive director of the Foundation for International Law for the Environment.</p>
<p>There's a pattern of the U.S. "advocating for very weak agreements that it then ends up not participating in anyway," Muffett said ahead of a prior round of plastic negotiations in Canada this spring.</p>
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https://npr.brightspotcdn.com/dims3/default/strip/false/crop/5760x3840+0+0/resize/1800/quality/85/format/jpeg/?url=http%3A%2F%2Fnpr-brightspot.s3.amazonaws.com%2F61%2F35%2F950d97474a41877a18864edaca82%2Fgettyimages-2149282664.jpg 1800w" data-template="https://npr.brightspotcdn.com/dims3/default/strip/false/crop/5760x3840+0+0/resize/{width}/quality/{quality}/format/{format}/?url=http%3A%2F%2Fnpr-brightspot.s3.amazonaws.com%2F61%2F35%2F950d97474a41877a18864edaca82%2Fgettyimages-2149282664.jpg" sizes="(min-width: 1300px) 763px, (min-width: 1025px) calc(100vw - 496px), (min-width: 768px) calc(100vw - 171px), calc(100vw - 30px)" class="img" type="image/jpeg"> <img src="https://npr.brightspotcdn.com/dims3/default/strip/false/crop/5760x3840+0+0/resize/1100/quality/50/format/jpeg/?url=http%3A%2F%2Fnpr-brightspot.s3.amazonaws.com%2F61%2F35%2F950d97474a41877a18864edaca82%2Fgettyimages-2149282664.jpg" data-template="https://npr.brightspotcdn.com/dims3/default/strip/false/crop/5760x3840+0+0/resize/{width}/quality/{quality}/format/{format}/?url=http%3A%2F%2Fnpr-brightspot.s3.amazonaws.com%2F61%2F35%2F950d97474a41877a18864edaca82%2Fgettyimages-2149282664.jpg" class="img" alt="A sculpture titled " giant="" plastic="" tap"="" by="" canadian="" artist="" benjamin="" von="" wong="" is="" displayed="" outside="" the="" fourth="" session="" of="" u.n.="" intergovernmental="" negotiating="" committee="" on="" pollution="" in="" ottawa,="" canada,="" april."="" loading="lazy" width="600"> </picture></div>
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<div class="caption" aria-label="Image caption">
<p>A sculpture titled <em>Giant Plastic Tap</em> by Canadian artist Benjamin Von Wong is displayed outside the fourth session of the U.N. Intergovernmental Negotiating Committee on Plastic Pollution in Ottawa, Canada, in April.</p>
</div>
</div>
<span class="credit" aria-label="Image credit"> Dave Chan/AFP via Getty Images </span></div>
</div>
<h3 class="edTag">Scientists say the solutions to plastic waste are clear</h3>
<p>A major sticking point in these negotiations has been a measure to limit the production of new plastic. Scientists and environmental advocates, along with <a href="https://ag.ny.gov/press-release/2024/attorney-general-james-calls-us-state-department-take-action-curb-plastic#:~:text=NEW%20YORK%20%E2%80%93%20New%20York%20Attorney,to%20mitigate%20global%20plastic%20pollution.">attorneys general from New York, California and eight other states</a>, say that the world manufactures too much plastic to manage effectively and that countries need to cap production to have any hope of making a dent in pollution.</p>
<p>Plastic-makers see that sort of regulation as a threat to their business. The industry wants negotiators to focus on creating what's called a circular economy, where plastic is recycled and reused to prevent waste.</p>
<p>But investigations, including by NPR, have found that the plastics industry promoted recycling for decades even though <a href="https://www.npr.org/2020/09/11/897692090/how-big-oil-misled-the-public-into-believing-plastic-would-be-recycled">officials long knew</a> that it <a href="https://www.npr.org/2024/02/15/1231690415/plastic-recycling-waste-oil-fossil-fuels-climate-change">probably wouldn't work</a> on a large scale. Former industry officials have said the goal was to avoid regulation and ensure demand for plastics kept growing.</p>
<p>Current officials have said those investigations don't accurately portray today's industry.</p>
<p>Matt Seaholm, chief executive of the Plastics Industry Association, a trade group, said in a statement that his organization supports an "ambitious" treaty but warned against policies like production caps that he said would hurt plastic manufacturers "without reaching our shared sustainability goals."</p>
<p>Countries are also debating whether to regulate the chemicals that go into plastics. A study this year found that <a href="https://plastchem-project.org/">plastics contain more than 4,200 hazardous chemicals</a>, the vast majority of which aren't regulated globally, according to the researchers. The plastics industry argues that chemicals should be regulated by national governments, not by a global treaty on plastic pollution. But scientists and environmentalists calling for global chemical regulations note that plastic waste — as well as the chemicals the plastic is made from — doesn't stay in the country where it's produced. It travels around the world in rivers and oceans.</p>
<p>Other issues under consideration include setting design standards to ensure plastic is safe to reuse and recycle, requiring companies to use some recycled material in their plastic products and raising money to help pay for waste management infrastructure, especially in developing countries.</p>
<p>"From the vantage point of science, it's very clear what actions we need. So, there's no ambiguity there. It's just a matter of political will," says Douglas McCauley, a professor of environmental science at the University of California, Santa Barbara, who has <a href="https://msi.ucsb.edu/news/treaty-end-plastic-pollution">studied ways to cut plastic pollution</a>.</p>
<p>And McCauley says world leaders have plenty of reasons to act. "If you care about fighting cancer, well, there's a win here. If you care about environmental justice, there's a win here. If you care about the environment — oceans, rivers, all the rest — there's a win. If you care about climate change, there's a win," McCauley says.</p>
<p>A spokesperson for the White House Council on Environmental Quality said in a statement that the U.S. supports measures that address plastic supplies and the chemicals the industry uses. "Global plastic production is projected to triple by 2060, overwhelming solid waste management systems and contributing to pollution," the statement said. "An outsized proportion of that increase will be in the growth of single-use plastic products that will ultimately lead to more plastic pollution."</p>
<div id="resg-s1-35550" class="bucketwrap image large">
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https://npr.brightspotcdn.com/dims3/default/strip/false/crop/3379x2252+0+0/resize/1800/quality/85/format/jpeg/?url=http%3A%2F%2Fnpr-brightspot.s3.amazonaws.com%2Fcb%2Fc0%2F701f4f784140b80546b616ca4b30%2Fap24327284696392.jpg 1800w" data-template="https://npr.brightspotcdn.com/dims3/default/strip/false/crop/3379x2252+0+0/resize/{width}/quality/{quality}/format/{format}/?url=http%3A%2F%2Fnpr-brightspot.s3.amazonaws.com%2Fcb%2Fc0%2F701f4f784140b80546b616ca4b30%2Fap24327284696392.jpg" sizes="(min-width: 1300px) 763px, (min-width: 1025px) calc(100vw - 496px), (min-width: 768px) calc(100vw - 171px), calc(100vw - 30px)" class="img" type="image/jpeg"> <img src="https://npr.brightspotcdn.com/dims3/default/strip/false/crop/3379x2252+0+0/resize/1100/quality/50/format/jpeg/?url=http%3A%2F%2Fnpr-brightspot.s3.amazonaws.com%2Fcb%2Fc0%2F701f4f784140b80546b616ca4b30%2Fap24327284696392.jpg" data-template="https://npr.brightspotcdn.com/dims3/default/strip/false/crop/3379x2252+0+0/resize/{width}/quality/{quality}/format/{format}/?url=http%3A%2F%2Fnpr-brightspot.s3.amazonaws.com%2Fcb%2Fc0%2F701f4f784140b80546b616ca4b30%2Fap24327284696392.jpg" class="img" alt="People look for reusable material at a garbage dump filled with plastic and other waste on the outskirts of Jammu, India." loading="lazy" width="600"> </picture></div>
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<p>People look for reusable material at a garbage dump filled with plastic and other waste on the outskirts of Jammu, India.</p>
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</div>
<span class="credit" aria-label="Image credit"> Channi Anand/AP </span></div>
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<h3 class="edTag">Time is of the essence</h3>
<p>Observers of the negotiations say countries could produce a strong treaty in South Korea even if they leave some details to be worked out later.</p>
<p>"You can't get everything concluded in Busan," says Magnus Løvold, a project manager at the Norwegian Academy of International Law. "But you can set a starting point that is credible for [the] governance of plastics internationally" in the coming years.</p>
<p>But time appears to be running short to lay that groundwork. When countries agreed to write a treaty to end plastic pollution, they set a goal to finish this year. Negotiators often extend talks when they run into gridlock. However, McCauley says participants in these deliberations seem committed to sticking to the original timeline.</p>
<p>For developing nations especially, letting the talks drag out could sink their efforts to get a strong treaty, Simon says. The negotiations are scheduled to conclude Dec. 1.</p>
<p>"Those countries will run out of resources to be a major player in negotiations," Simon says. "The political pressure, the public pressure will wane as other things come into the picture."</p>]]> </content:encoded>
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<title>Barry Biomass: Incinerator future in doubt as investors pull out</title>
<link>https://sdgtalks.ai/barry-biomass-incinerator-future-in-doubt-as-investors-pull-out</link>
<guid>https://sdgtalks.ai/barry-biomass-incinerator-future-in-doubt-as-investors-pull-out</guid>
<description><![CDATA[ The Barry Biomass incinerator, located near Cardiff in the UK, may shut down soon, as investors pull out following significant local protests and opposition. These protests, led by local environmental groups, are centered around fears of regional pollution. ]]></description>
<enclosure url="https://www.eia.gov/energyexplained/biomass/images/wastetoenergy.png" length="49398" type="image/jpeg"/>
<pubDate>Sat, 30 Nov 2024 22:54:49 -0500</pubDate>
<dc:creator>Eadyn Thompson</dc:creator>
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<content:encoded><![CDATA[<div data-component="text-block" class="sc-18fde0d6-0 dlWCEZ">
<div data-component="caption-block" class="sc-18fde0d6-0 bdPeAJ"><img sizes="(min-width: 1280px) 50vw, (min-width: 1008px) 66vw, 96vw" srcset="https://ichef.bbci.co.uk/news/240/cpsprodpb/6355/live/ad0fb840-ae50-11ef-935d-6bccd7847ba3.jpg.webp 240w,https://ichef.bbci.co.uk/news/320/cpsprodpb/6355/live/ad0fb840-ae50-11ef-935d-6bccd7847ba3.jpg.webp 320w,https://ichef.bbci.co.uk/news/480/cpsprodpb/6355/live/ad0fb840-ae50-11ef-935d-6bccd7847ba3.jpg.webp 480w,https://ichef.bbci.co.uk/news/640/cpsprodpb/6355/live/ad0fb840-ae50-11ef-935d-6bccd7847ba3.jpg.webp 640w,https://ichef.bbci.co.uk/news/800/cpsprodpb/6355/live/ad0fb840-ae50-11ef-935d-6bccd7847ba3.jpg.webp 800w,https://ichef.bbci.co.uk/news/1024/cpsprodpb/6355/live/ad0fb840-ae50-11ef-935d-6bccd7847ba3.jpg.webp 1024w,https://ichef.bbci.co.uk/news/1536/cpsprodpb/6355/live/ad0fb840-ae50-11ef-935d-6bccd7847ba3.jpg.webp 1536w" src="https://ichef.bbci.co.uk/news/480/cpsprodpb/6355/live/ad0fb840-ae50-11ef-935d-6bccd7847ba3.jpg.webp" alt="Ade Pitman An aerial shot of Barry Docks: in the foreground is a body of water, behind that waste wood incinerator in and amongst industrial equipment. In the background, rows of houses in Barry" class="sc-a34861b-0 efFcac" loading="eager"></div>
<div data-component="caption-block" class="sc-18fde0d6-0 bdPeAJ">Aviva Investors say they have pulled out of the site because of significant cost and technology-related challenges</div>
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<p class="sc-eb7bd5f6-0 fYAfXe">The future of a controversial waste wood incinerator looks in doubt after an investment company pulled out of the site.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">Aviva Investors said the decision had been made because of significant cost and technology-related challenges at the Barry Biomass plant in the Vale of Glamorgan.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">Campaigners have fought for years for the wood incinerator in Barry Docks to be shut due to pollution fears.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">The plant's developers, Barry Biomass, and the Welsh government have been asked for comment.</p>
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<h2 data-testid="card-headline" class="sc-8ea7699c-3 dhclWg">Pollution fears over incinerator plan</h2>
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<h2 data-testid="card-headline" class="sc-8ea7699c-3 dhclWg">Q&amp;A: What is biomass?</h2>
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<p class="sc-eb7bd5f6-0 fYAfXe">Vale of Glamorgan council said it was seeking urgent clarification from Aviva for its plans for the site.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">The privately-run venture, which was backed by Aviva Investors, was given the go-ahead in 2018, <a target="_self" href="https://www.bbc.co.uk/news/uk-wales-south-east-wales-42981252" class="sc-c9299ecf-0 bZUiKB">despite protests and petitions</a> over pollution fears.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">But since then, it has been at the centre of a long-running planning row, remaining idle while waiting for the go-ahead to start operating.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">In 2021, it <a target="_self" href="https://www.bbc.co.uk/news/uk-wales-58413660" class="sc-c9299ecf-0 bZUiKB">faced an order to shut down</a>.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">In a statement, Aviva Investors said it had "made the decision to divest from the assets" in Barry, plus English sites at Hull and Boston.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">A spokesperson for Aviva Investors said: "Since the original investment, it has become apparent that the gasification technologies at these plants have significant challenges in their current form.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">"The assets have therefore not performed as we expected."</p>
<p class="sc-eb7bd5f6-0 fYAfXe">Following an independent review earlier this year, and informing investors of the situation, the decision was taken to move away from the sites.</p>
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<div data-testid="image" class="sc-a34861b-1 jxzoZC"><img sizes="(min-width: 1280px) 50vw, (min-width: 1008px) 66vw, 96vw" srcset="https://ichef.bbci.co.uk/news/240/cpsprodpb/b7f8/live/070f2260-ae4a-11ef-93a6-9fd2d3586a96.jpg.webp 240w,https://ichef.bbci.co.uk/news/320/cpsprodpb/b7f8/live/070f2260-ae4a-11ef-93a6-9fd2d3586a96.jpg.webp 320w,https://ichef.bbci.co.uk/news/480/cpsprodpb/b7f8/live/070f2260-ae4a-11ef-93a6-9fd2d3586a96.jpg.webp 480w,https://ichef.bbci.co.uk/news/640/cpsprodpb/b7f8/live/070f2260-ae4a-11ef-93a6-9fd2d3586a96.jpg.webp 640w,https://ichef.bbci.co.uk/news/800/cpsprodpb/b7f8/live/070f2260-ae4a-11ef-93a6-9fd2d3586a96.jpg.webp 800w,https://ichef.bbci.co.uk/news/1024/cpsprodpb/b7f8/live/070f2260-ae4a-11ef-93a6-9fd2d3586a96.jpg.webp 1024w,https://ichef.bbci.co.uk/news/1536/cpsprodpb/b7f8/live/070f2260-ae4a-11ef-93a6-9fd2d3586a96.jpg.webp 1536w" src="https://ichef.bbci.co.uk/news/480/cpsprodpb/b7f8/live/070f2260-ae4a-11ef-93a6-9fd2d3586a96.jpg.webp" alt="Protestors stand outside the incinerator in a line in Barry Docks. They are holding signs in protest, with the most visible being a sign saying 'No incinerator, no toxic ash'." class="sc-a34861b-0 efFcac" loading="lazy"></div>
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<figcaption class="sc-8353772e-0 cvNhQw">Campaigners have fought for years for the wood incinerator to be shut</figcaption>
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<div data-component="text-block" class="sc-18fde0d6-0 dlWCEZ">
<p class="sc-eb7bd5f6-0 fYAfXe">The Docks Incinerator Action Group (DIAG) which has opposed the plant, said it was happy with the decision. It said it hoped no other company would take on the project.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">Council leader Lis Burnett said the plant had "failed to conform" with its original planning permission.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">“Two retrospective planning application were refused in March, decisions that are currently being appealed," she said.</p>
<p class="sc-eb7bd5f6-0 fYAfXe">“We will now seek urgent clarification from Aviva regarding those appeals and its plans for the site.”</p>
<p class="sc-eb7bd5f6-0 fYAfXe">Barry Biomass has previously described the Barry site as environmentally responsible, safe and with a positive long-term impact on the local community.</p>
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<title>How Smart Packaging Reduces Food Waste and Preserves Resources</title>
<link>https://sdgtalks.ai/how-smart-packaging-reduces-food-waste-and-preserves-resources</link>
<guid>https://sdgtalks.ai/how-smart-packaging-reduces-food-waste-and-preserves-resources</guid>
<description><![CDATA[  ]]></description>
<enclosure url="https://images.pexels.com/photos/4480984/pexels-photo-4480984.jpeg" length="49398" type="image/jpeg"/>
<pubDate>Fri, 29 Nov 2024 05:21:05 -0500</pubDate>
<dc:creator>Kat Sarmiento</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p dir="ltr"><span>When we think of food waste and resource management, we often assume the solution lies in using fewer materials. However, simply reducing resources doesn’t automatically lead to less waste. Mismanagement can increase waste rather than reduce it.  In the food industry,  it’s even more crucial for people to take waste reduction seriously.</span></p>
<p dir="ltr"><span>With billions facing hunger annually, every industry must strive to reduce food waste. After all, </span><a href="https://socialimpactmovement.org/no-matter-where-we-work-every-job-is-a-climate-job-now/"><span>every job is a climate job now,</span></a><span> especially as corporations refuse to take responsibility for their wasteful processes. One such industry that needs a change is food shipment, and smart packaging is a step in the right direction.</span></p>
<h2 dir="ltr"><span>What Is Smart Packaging?</span></h2>
<p dir="ltr"><span>Unlike traditional packaging, which typically exists solely to keep the stuff inside for just long enough without falling out, smart packaging actively improves food preservation. That could mean advanced materials, electronic sensors, or clever packaging design. Either way, the end goal is preventing food from spoiling needlessly.</span></p>
<h3 dir="ltr"><span>Active Packaging</span></h3>
<p dir="ltr"><span>Active packaging deals directly with food to extend freshness and slow spoilage. It engages with the food’s environment by releasing or absorbing specific substances, particularly those that encourage food spoilage. Good examples include oxygen scavengers, </span><a href="https://www.fastcompany.com/91038247/cruz-foam-most-innovative-companies-2024"><span>eco-friendly foam alternatives</span></a><span>, and antimicrobial agents. These innovations create an ideal atmosphere inside the package, helping preserve food quality.</span></p>
<h3 dir="ltr"><span>Intelligent Packaging</span></h3>
<p dir="ltr"><span>Intelligent packaging lets people see food quality in real time, allowing consumers and suppliers to make informed decisions about freshness, safety, and usability. It integrates advanced sensors, indicators, or labels to monitor various conditions within the package. This technology goes beyond "use-by" or "sell-by" dates, offering valuable data on temperature, freshness, and ripeness. Naturally, it may cost a bit, so it’s best to use it for large-scale undertakings.</span></p>
<h2 dir="ltr"><span>How Smart Packaging Reduces Waste</span></h2>
<p dir="ltr"><span>As for how smart packaging actually impacts food waste, there’s a whole host of benefits, ranging from food freshness to adaptability:</span></p>
<h3 dir="ltr"><span>Maintaining Food Freshness</span></h3>
<p dir="ltr"><span>Keeping food fresh is one of the most difficult aspects of getting foodstuff from point A to point B. After all, the food has a built-in time limit, and bad packaging speeds up the clock surprisingly quickly. Keeping food in airtight containers built for preservation, with easy ways to monitor its quality, ensures food arrives at peak quality.</span></p>
<h3 dir="ltr"><span>Adapting to Environmental Conditions</span></h3>
<p dir="ltr"><span>Shipping can experience some surprisingly sudden climate and environmental changes. Sure, those cardboard might be okay for dry summers. However, the moment it’s exposed to any humid climate, it starts to rot faster than the food. Smart packaging is typically built to last in a variety of environments, with some advanced packaging even allowing for temperature control.</span></p>
<h3 dir="ltr"><span>Enhancing Supply Chain Management</span></h3>
<p dir="ltr"><span>Smart packaging enables real-time tracking, helping suppliers detect delays or issues in the supply chain. Maintaining a consistent environment during food transport is challenging, but intelligent packaging can record storage conditions and alert suppliers to potential problems. By improving supply chain efficiency, smart packaging reduces the risk of spoiled food reaching consumers.</span></p>
<h3 dir="ltr"><span>Minimizing Environmental Impact</span></h3>
<p dir="ltr"><span>Reducing food waste also means reducing the resources—such as water, energy, and labor—used in food production. A longer shelf life, thanks to packaging, helps reduce demand for food production, conserving resources and lowering the overall environmental footprint of food production.</span></p>
<h3 dir="ltr"><span>Reducing Packaging Waste</span></h3>
<p dir="ltr"><span>Many smart packaging solutions are now designed to be recyclable or biodegradable. Companies increasingly experiment with sustainable materials, which minimize the environmental impact of packaging waste. Combining these materials with the waste reduction achieved by preventing spoilage makes smart packaging an eco-friendly choice.</span></p>
<h3 dir="ltr"><span>Integrating Smart Packaging into Existing Workflows</span></h3>
<p dir="ltr"><span>Integrating smart packaging into a current workflow offers benefits like extended shelf life, enhanced supply chain visibility, and improved food safety. However, the transition requires careful planning to prevent workflow disruptions. Here’s how to integrate smart packaging effectively.</span></p>
<h3 dir="ltr"><span>Choosing the Right Smart Packaging Technology</span></h3>
<p dir="ltr"><span>Selecting the appropriate smart packaging technology is essential. Different products have unique requirements: temperature-sensitive goods benefit from temperature-monitoring capabilities, while fresh produce may need ripeness indicators. </span></p>
<p dir="ltr"><span>Compatibility with existing packaging designs is also crucial. Size, shape, and material must align with the chosen technology to avoid disruptions Some packages may need slight modifications to accommodate sensors or indicators, making these details important during the design phase.</span></p>
<h3 dir="ltr"><span>Updating Supply Chain Processes and Training</span></h3>
<p dir="ltr"><span>Smart packaging can enhance inventory management by providing real-time product condition data, though this may require inventory process adjustments. Integrating smart packaging data with inventory systems improves overall inventory control and product quality by tracking freshness, temperature, and other key factors.</span></p>
<p dir="ltr"><span>Training employees on the new technologies is essential. Warehouse staff need to interpret and respond to indicators, while store employees should understand freshness or ripeness indicators to assist customers effectively. Even if the packaging is bulletproof, if an employee leaves it open, then it’s all for naught.</span></p>
<h3 dir="ltr"><span>Building Partnerships with Suppliers and Distributors</span></h3>
<p dir="ltr"><span>Collaboration with packaging suppliers ensures that chosen smart packaging solutions meet specific product needs. Packaging suppliers offer valuable guidance on customizing technology and implementing best practices, easing the transition.</span></p>
<p dir="ltr"><span>Coordination with distributors and retailers is equally important. Smart packaging data benefits all partners in the supply chain. Open communication ensures everyone understands how to handle packaging.</span></p>
<h2 dir="ltr"><span>Final Thoughts</span></h2>
<p dir="ltr"><span>Smart packaging for the food chain won’t stop evolving anytime soon, but thankfully, it’s already tenable for many suppliers. That said, it can cost a lot if not properly understood. Make sure your business is ready for any major changes to its workflow by focusing on the right technology and training people correctly. By doing so, you help the industry take one more step towards sustainability.</span></p>
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<title>The blue&#45;green sustainable proteins of seaweed may soon be on your plate</title>
<link>https://sdgtalks.ai/the-blue-green-sustainable-proteins-of-seaweed-may-soon-be-on-your-plate</link>
<guid>https://sdgtalks.ai/the-blue-green-sustainable-proteins-of-seaweed-may-soon-be-on-your-plate</guid>
<description><![CDATA[ The protein in sea lettuce, a type of seaweed, is a promising complement to both meat and other current alternative protein sources. Seaweed also contains many other important nutrients, and is grown without needing to be watered, fertilized or sprayed with insecticides. ]]></description>
<enclosure url="https://ecomagazine.com/wp-content/uploads/2024/11/Image1_Ulva_a8ec9bb7fb0e8c70_org.jpg" length="49398" type="image/jpeg"/>
<pubDate>Mon, 25 Nov 2024 00:46:06 -0500</pubDate>
<dc:creator>Micaiah Will</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p id="first" class="lead">The protein in sea lettuce, a type of seaweed, is a promising complement to both meat and other current alternative protein sources. Seaweed also contains many other important nutrients, and is grown without needing to be watered, fertilised or sprayed with insecticides. However, the proteins are often tightly bound, and their full potential has not yet been realised on our plates. But now researchers at Chalmers University of Technology, in Sweden, have found a new way to extract these proteins three times more efficiently than before -- and this progress paves the way for seaweed burgers and protein smoothies from the sea.</p>
<p data-slot-rendered-content="true">"It tastes like umami with a certain salty flavour, despite not containing such high levels of salt. I would say it's a great flavour enhancer for seafood dishes and products, but the possibilities to explore are endless. Why not protein smoothies or 'blue burgers' from the sea?" says João Trigo, PhD in Food Science at Chalmers, about the dark green powder, which is a concentrate of proteins from sea lettuce, scientifically known as<span> </span><em>Ulva fenestrata.</em><span> </span>Sea lettuce is a type of macroalgae, commonly called seaweed, which grows on rocks in calm waters, or free-floating on the surface, and resembles ordinary lettuce leaves in appearance.</p>
<p>The so-called protein shift -- switching from red meat to more sustainable and healthy protein sources -- is a way to reduce the climate impact of food production while providing everyone with a nutritious diet. Many alternative protein sources, mainly based on pea, soy and mushroom, are common in our grocery stores. But all the vegetarian protein that is found under the sea is still an untapped source.</p>
<p>The CirkAlg-project, led by Chalmers University of Technology, has explored the possibilities of developing processes that can create a new, "blue-green" food industry in Sweden, and make use of seaweed as a promising source of protein. Within the framework of the project, a newly published scientific studyshows a unique way of extracting proteins from sea lettuce, so that it is now possible to extract three times more protein from the seaweed than was possible with previous methods.</p>
<p>"Our method is an important breakthrough, as it brings us closer to making it more affordable to extract these proteins, something that is done with pea and soy proteins today," says João Trigo.</p>
<p><strong>Contains several essential nutrients</strong></p>
<p data-slot-rendered-content="true">In addition to essential proteins, sea lettuce contains several other substances of great nutritional value for humans, such as vitamin B12 and the same kind of omega-3 fatty acids found in oily fish, like salmon. People who do not eat animal products are at risk of developing a deficiency of vitamin B12, which is necessary for the body to form red blood cells, among other things. And the cultivation of sea lettuce has several advantages compared to land-growing proteins -- such as the fact that the seaweed does not need to be watered, fertilised or sprayed with insecticides. Sea lettuce is also hardy and grows well under many different conditions, such as different salinity and access to nitrogen.</p>
<p>"Humanity will need to find and combine the intake of many more diversified protein sources than we have available in our diet today, to meet sustainability and nutritional requirements. Algae is a good addition to many of the products already on the market. We need all these solutions and so far, the sea-based possibilities, the so-called blue proteins, have been overlooked," says Ingrid Undeland, Professor of Food Science at Chalmers and coordinator of CirkAlg.</p>
<p>In addition to the newly published extraction method, the Chalmers researchers are working together with the University of Gothenburg to increase the actual protein content in the seaweed. By cultivating sea lettuce in process water from the seafood industry, the protein content can be increased significantly, while nutrients that would otherwise be lost are circulated back into the food chain. At Tjärnö Marine Laboratory (part of the University of Gothenburg) in northern Bohuslän in Sweden, a large number of successful cultivation experiments have been carried out within the CirkAlg-project, based on industrial water side currents.</p>
<p>"In the future, we also want to be able to make use of the parts of the algae that are not proteins, and that could be used in food, materials or for medical applications. The goal is that no molecules should go to waste, to achieve both sustainability and commercial opportunities," says Ingrid Undeland.</p>
<p><strong>More about the extraction method</strong></p>
<p>In addition to proteins that are water-soluble, sea lettuce also contains plenty of fat-soluble so-called membrane proteins. This means that the seaweed proteins are more complex to extract than, for example, soy and pea protein. In a first-step of the new process, the cell membranes of the sea lettuce are opened up in order to access the fat-soluble proteins. The different types of proteins are then extracted with water adjusted to a high pH, and in the next step, by making the solution acidic, the proteins are precipitated into aggregates that could then be separated from the water and utilised as a protein-rich ingredient. It was also seen that the marine omega-3 fatty acids were enriched in the protein ingredient, and a follow-up study confirmed that the same was true for vitamin B12. The new algae protein ingredient can thus help meet a wider range of nutritional needs compared to soy protein.</p>
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<title>Shop Locally: The Sustainable Practices of Farmers Markets</title>
<link>https://sdgtalks.ai/shop-locally-the-sustainable-practices-of-farmers-markets</link>
<guid>https://sdgtalks.ai/shop-locally-the-sustainable-practices-of-farmers-markets</guid>
<description><![CDATA[ Learn how shopping locally and supporting farmers markets can contribute to a more sustainable life and community. ]]></description>
<enclosure url="https://cookingenie.com/content/wp-content/uploads/2023/02/Local-farmer-markets-Sustainable-grocery-shopping.png" length="49398" type="image/jpeg"/>
<pubDate>Mon, 01 Jul 2024 13:40:48 -0500</pubDate>
<dc:creator>saffron@socialimpactmovement.org</dc:creator>
<media:keywords>Farmers Markets, Miami, Sustainability</media:keywords>
<content:encoded><![CDATA[<p dir="ltr"><span>Farmers Markets are some of the best small businesses to support as they are not only premiere destinations to find fresh produce and handmade products, but they also apply dozens of sustainable practices to their businesses. </span></p>
<p><b> </b></p>
<p dir="ltr"><span>Shopping locally at farmers markets is a great way to practice sustainable living due to the many benefits it offers not only to ourselves, but to the environment as well. <a href="https://news.climate.columbia.edu/2019/08/09/farmers-market-week-2019/">Supporting farmers markets and other small businesses helps to reduce carbon footprint and unnecessary waste as two prime examples.</a> With decreased transportation energy, less resources are utilized to get products from the site of production to buyers themselves. This greatly reduces any additional exhaust fumes and air pollution associated with mass means of product transportation, as well as the reduction of food waste. Additionally, farmers markets help to decrease the amount of packaging material used to store products, such as cardboard boxes or even the plastic bags given to customers after purchases–customers are instead encouraged to bring reusable shopping bags with them to store their purchases. </span></p>
<p><b> </b></p>
<p dir="ltr"><span>In terms of health benefits, farmers markets offer a variety of fresh produce and products that are homemade and rely on more traditional and sustainable production methods, making them healthier and more valuable than other mass methods you’d find in chain markets. With crops in particular, small vendors are less reliant on chemical agents and/or pesticides in their farming process, and instead employ more traditional methods. As a result, the fruits and vegetables grown have much higher nutritional values as they do not require preservatives or any added chemicals to stay fresh. These methods make locally grown crops much more nutritious to the average buyer than the products one would normally find in stores. </span></p>
<p><b> </b></p>
<p dir="ltr"><span>Here in Miami, we have many great farmers markets, two of the most notable being the <a href="https://www.miamiandbeaches.com/event/coconut-grove-organic-farmers-market/27613">Coconut Grove</a> and <a href="https://www.pinecrestgardens.org/Arts-Events/Events-Calendar/24-25-Farmers-Market">Pinecrest</a> farmers markets which are open every Saturday from midday to late afternoon. Both offer dozens of vendors with a variety of edible or handmade products anyone can enjoy with their friends and family. Practice sustainable living and stimulate your health by supporting a local farmers market!</span></p>]]> </content:encoded>
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<title>Contrasting Shifts in Vegetation &amp;quot;Greenness&amp;quot;</title>
<link>https://sdgtalks.ai/contrasting-shifts-in-vegetation-greenness</link>
<guid>https://sdgtalks.ai/contrasting-shifts-in-vegetation-greenness</guid>
<description><![CDATA[ This study delves into the interannual variability (IAV) of vegetation greenness and carbon sequestration, vital for assessing ecosystem stability and climate responses. Analyzing various satellite data and models, it reveals conflicting trends in IAV, particularly in tropical regions. Uncertainty persists due to differing methodologies among remote sensing products, challenging climate change impact assessments. ]]></description>
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<pubDate>Sun, 05 May 2024 23:32:29 -0500</pubDate>
<dc:creator>Cole Baggett</dc:creator>
<media:keywords>vegetation, greenness</media:keywords>
<content:encoded><![CDATA[<blockquote>
<p><span>Vegetation greenness changes year to year in response to climate variability and reflects the stability of ecosystems. How the interannual variability (IAV) of vegetation greenness has changed in the past decades, however, remained uncertain with recent studies reporting conflicting IAV trends using different satellite remote sensing products. Here, we investigated the greenness IAV trends of global vegetation using multiple mainstream satellite remote sensing products. We found that the changes in greenness IAV are conflicting on half of the global vegetated surface, while the differences in background climate, greening trends and nitrogen deposition rates account for either positive or negative trends in greenness IAV on the remaining half of the vegetated surface.</span></p>
</blockquote>
<div class="abstract-group  metis-abstract">
<section class="article-section article-section__abstract" lang="en" data-lang="en" id="section-1-en">
<h2 id="d20964033" class="article-section__header section__title main abstractlang_en main">Abstract</h2>
<div class="article-section__content en main">
<p>Changes in the interannual variability (IAV) of vegetation greenness and carbon sequestration are key indicators of the stability and climate sensitivities of terrestrial ecosystems. Recent studies have examined the changes in the vegetation IAV using atmospheric CO<sub>2</sub><span> </span>observations and dynamic global vegetation models (DGVMs), however, reported different and even contradictory IAV trends. Here, we investigate the changes in the IAV of vegetation greenness, quantified as coefficient of variability (CV), over the past few decades based on multiple satellite remote sensing products and DGVMs. Our results suggested that, on half of the global vegetated surface (mostly in the tropics), the CV trends detected by different satellite remote sensing products are conflicting. We found that 22.20% and 28.20% of the global vegetated surface (mostly in the non-tropical land surface) show significant positive and negative CV trends (<i>p</i> ≤ 0.1), respectively. Regions with higher air temperature and greater aridity tend to have increasing CV trends, whereas greater vegetation greening trend and higher nitrogen deposition lead to smaller CV trends. DGVMs generally cannot capture the CV trends obtained from satellite remote sensing products, while the inconsistency among satellite remote sensing products is likely caused by their process algorithms rather than the sensors utilized. Our study closely examines the changes in the IAV of global vegetation greenness, and highlights substantial uncertainty when using satellite remote sensing to study the response of terrestrial ecosystems to climate change.</p>
</div>
</section>
<section class="article-section article-section__abstract" lang="en" data-lang="en" id="section-3-en">
<h2 id="d20964035" class="article-section__header section__title short abstractlang_en short">Key Points</h2>
<div class="article-section__content en short">
<p></p>
<ul class="unordered-list">
<li>
<p>On half of the global vegetated surface, the changes in the vegetation greenness interannual variability (IAV) are conflicting</p>
</li>
<li>
<p>22.20% and 28.20% of the global vegetated surface show significant positive and negative trends of vegetation greenness IAV, respectively</p>
</li>
<li>
<p>Warmer and drier places lead to greater greenness IAV whereas greater greening trend and higher nitrogen deposition make IAV smaller</p>
</li>
</ul>
<p></p>
</div>
</section>
<section class="article-section article-section__abstract" lang="en" data-lang="en" id="section-2-en">
<h2 id="d20964038" class="article-section__header section__title synopsis abstractlang_en synopsis">Plain Language Summary</h2>
<div class="article-section__content en synopsis">
<p>Vegetation greenness changes year to year in response to climate variability and reflects the stability of ecosystems. How the interannual variability (IAV) of vegetation greenness has changed in the past decades, however, remained uncertain with recent studies reporting conflicting IAV trends using different satellite remote sensing products. Here, we investigated the greenness IAV trends of global vegetation using multiple mainstream satellite remote sensing products. We found that the changes in greenness IAV are conflicting on half of the global vegetated surface, while the differences in background climate, greening trends and nitrogen deposition rates account for either positive or negative trends in greenness IAV on the remaining half of the vegetated surface.</p>
</div>
</section>
</div>
<div class="pb-dropzone" data-pb-dropzone="below-abstract-group"></div>
<section class="article-section article-section__full">
<section class="article-section__content" id="eft21593-sec-0010">
<h2 class="article-section__title section__title section1" id="eft21593-sec-0010-title">1 Introduction</h2>
<p>Changes in the interannual variability (IAV) of vegetation greenness indicate the stability of terrestrial ecosystems (Berdugo et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0004" id="#eft21593-bib-0004_R_d20964025e434" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; De Keersmaecker et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0008" id="#eft21593-bib-0008_R_d20964025e437" class="bibLink tab-link" data-tab="pane-pcw-references">2014</a></span>; Huang &amp; Xia, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0019" id="#eft21593-bib-0019_R_d20964025e440" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>) and is critical for tracking the progression of vegetation-climate feedback under climate change (Alkama &amp; Cescatti, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0002" id="#eft21593-bib-0002_R_d20964025e443" class="bibLink tab-link" data-tab="pane-pcw-references">2016</a></span>; Zeng et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0050" id="#eft21593-bib-0050_R_d20964025e446" class="bibLink tab-link" data-tab="pane-pcw-references">2017</a></span>). When climate variability remains unchanged, a larger IAV suggests that the vegetation is more sensitive to climate change, while a smaller IAV suggests that vegetation is less sensitive. Several recent studies have examined the IAV changes of carbon sequestration using atmospheric observations and dynamic global vegetation models (DGVMs) (Fernández-Martínez et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0011" id="#eft21593-bib-0011_R_d20964025e450" class="bibLink tab-link" data-tab="pane-pcw-references">2023</a></span>; Luo &amp; Keenan, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0030" id="#eft21593-bib-0030_R_d20964025e453" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>) and reported an increase in the IAV from the 1950–1980s, however, they disagreed on the direction of the IAV trends from the 1980s onwards. Additionally, the conflicting evidence on the changes in climate sensitivities of vegetation greenness in recent decades (Zeng, Hu, et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0048" id="#eft21593-bib-0048_R_d20964025e456" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; Zhang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0053" id="#eft21593-bib-0053_R_d20964025e459" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; Zhang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0052" id="#eft21593-bib-0052_R_d20964025e462" class="bibLink tab-link" data-tab="pane-pcw-references">2023</a></span>) adds further debates to the unresolved understanding of the changes in the IAV of vegetation over the past 40 years.</p>
<p>Multiple factors in the global change can be linked to the changes in the IAV of vegetation activities. The greening of the earth indicates that terrestrial ecosystems hold more green leaves for carbon fluxes, which is more likely to demonstrate larger IAV in greenness and carbon fluxes. If the climate sensitivity of individual leaves remains unchanged, then climate variation would lead to a larger variation in greenness, simply because there are more leaves that can respond to climate variation. Therefore, the reasons for the greening, for example, CO<sub>2</sub><span> </span>fertilization effect and nitrogen deposition (N deposition) (Piao et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0036" id="#eft21593-bib-0036_R_d20964025e470" class="bibLink tab-link" data-tab="pane-pcw-references">2015</a></span>; Zhu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0057" id="#eft21593-bib-0057_R_d20964025e473" class="bibLink tab-link" data-tab="pane-pcw-references">2016</a></span>) are potential factors for the changes in IAV. Aridity is another potential factor, as the droughts have been reported to either induce the changes in the trend of vegetation greenness (and therefore, a change in the IAV assuming a constant trend) (Berdugo et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0004" id="#eft21593-bib-0004_R_d20964025e476" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>), or directly enhance the variability of carbon cycle by increasing tropical extreme droughts (Luo &amp; Keenan, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0030" id="#eft21593-bib-0030_R_d20964025e479" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>). Land cover and land use changes (e.g., expansion of croplands), temperature or CO<sub>2</sub><span> </span>induced the changes of respirations (Forkel et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0014" id="#eft21593-bib-0014_R_d20964025e485" class="bibLink tab-link" data-tab="pane-pcw-references">2016</a></span>; Piao et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0034" id="#eft21593-bib-0034_R_d20964025e488" class="bibLink tab-link" data-tab="pane-pcw-references">2018</a></span>), have been linked to the increase in seasonal amplitude of atmospheric CO<sub>2</sub><span> </span>(i.e., an indicator of intra-annual variability of the carbon cycle) (Gray et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0016" id="#eft21593-bib-0016_R_d20964025e493" class="bibLink tab-link" data-tab="pane-pcw-references">2014</a></span>), and may thus further imply the changes in the IAV of vegetation activities.</p>
<p>Although the changes in the vegetation IAV have been investigated and examined using atmospheric CO<sub>2</sub><span> </span>and DGVMs (Fernández-Martínez et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0011" id="#eft21593-bib-0011_R_d20964025e501" class="bibLink tab-link" data-tab="pane-pcw-references">2023</a></span>; Luo &amp; Keenan, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0030" id="#eft21593-bib-0030_R_d20964025e504" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>), they have rarely been investigated using satellite-based observations. Two previous studies examined the changes in the temporal variability of vegetation greenness using a single satellite remote sensing product but reported different IAV trends (Chen, Chen, et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0005" id="#eft21593-bib-0005_R_d20964025e507" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>; Luo &amp; Keenan, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0030" id="#eft21593-bib-0030_R_d20964025e510" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>). In this study, we used an ensemble of multiple satellite remote sensing products, covering different types of vegetation indicators, to investigate the changes in the IAV (i.e., CV; coefficient of variability) of global vegetation activities over the past 40 years. We primarily focus on the IAV of vegetation greenness including leaf area index (LAI) and normalized difference vegetation index (NDVI), but also examine other indicators, such as, solar-induced fluorescence (SIF) and vegetation optical depth (VOD). The use of CV aims to standardize the indicators, removing the differences in magnitude to ensure comparability among the results from different indicators. Beyond conducting a data intercomparison, we further collected LAI estimates from 12 DGVMs for a model-observation comparison, explored the potential factors driving the CV trends and quantified their respective contributions to the CV trends. Our study aims to improve our understanding of the IAV changes of the global vegetation greenness and identify the potential factors driving the changes in the IAV.</p>
</section>
<section class="article-section__content" id="eft21593-sec-0020">
<h2 class="article-section__title section__title section1" id="eft21593-sec-0020-title">2 Materials and Methods</h2>
<section class="article-section__sub-content" id="eft21593-sec-0030">
<h3 class="article-section__sub-title section2" id="eft21593-sec-0030-title">2.1 Satellite Remote Sensing Data</h3>
<p>We used six long-term and three short-term satellite remote sensing datasets in this study, covering four types of vegetation indicators - NDVI, LAI, SIF and VOD (Table <a class="tableLink scrollableLink" title="Link to table" href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-tbl-0001">1</a>). These remote sensing products include: (a) VIP15 NDVI product (1981–2014), which has 0.05° and 15-day resolutions and is developed by harmonizing the observations of Advanced Very High Resolution Radiometer (AVHRR) from 1981 to 1999 and Moderate Resolution Imaging Spectroradiometer (MODIS) C5 from 2000 to 2014 (Didan et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0010" id="#eft21593-bib-0010_R_d20964025e530" class="bibLink tab-link" data-tab="pane-pcw-references">2015</a></span>); (b) GIMMS NDVI3g (1981–2015), which has 15-day and 1/12° resolutions, and was produced by aggregating daily AVHRR surface reflectance (Pinzon &amp; Tucker, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0037" id="#eft21593-bib-0037_R_d20964025e533" class="bibLink tab-link" data-tab="pane-pcw-references">2014</a></span>); (c) GIMMS LAI3g product (1981–2015), which was further produced by GIMMS NDVI3g product using a neural network algorithm (Zhu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0056" id="#eft21593-bib-0056_R_d20964025e536" class="bibLink tab-link" data-tab="pane-pcw-references">2013</a></span>); (d) PKU GIMMS NDVI (1982–2020), which is a new version of GIMMS NDVI product produced by a machine learning model incorporating Landsat images (Li et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0027" id="#eft21593-bib-0027_R_d20964025e539" class="bibLink tab-link" data-tab="pane-pcw-references">2023</a></span>); (e) GLASS LAI product (1981–2018), which has 8-day temporal resolution and 0.05° spatial resolution, and was reconstructed by combing AVHRR LAI from 1981 to 1999 and MODIS LAI from 2000 to 2018 using a bidirectional long short-term memory (Bi-LSTM) model (Ma &amp; Liang, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0031" id="#eft21593-bib-0031_R_d20964025e543" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>); (f) GLOBMAP LAI (1982–2019) dataset at a spatial resolution of ∼0.07°, covering the period from 1982 to 2019, has half-month (1982–2000) and 8-day (2001–2019) temporal resolutions, and was produced by establishing a pixel-level AVHRR Simple Ratio (SR)-MODIS LAI relationship (Liu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0029" id="#eft21593-bib-0029_R_d20964025e546" class="bibLink tab-link" data-tab="pane-pcw-references">2012</a></span>); (g) MOD13C1 NDVI (2000–2020) product (C61), which has a 0.05° spatial resolution and a 16-day temporal resolution (Didan &amp; Munoz, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0009" id="#eft21593-bib-0009_R_d20964025e549" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>); (h) OCO2 SIF product (2000–2020) at resolutions of 0.05° and 4 days, which was generated from MODIS surface reflectance and OCO2 SIF data using a neural network approach (Zhang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0054" id="#eft21593-bib-0054_R_d20964025e552" class="bibLink tab-link" data-tab="pane-pcw-references">2018</a></span>); and (i) VOD (1987–2017) dataset, which was produced by merging observations from multiple microwave sensors at daily temporal resolution and 0.25° spatial resolution (Moesinger et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0033" id="#eft21593-bib-0033_R_d20964025e555" class="bibLink tab-link" data-tab="pane-pcw-references">2020</a></span>). We standardized these satellite remote sensing products to a 0.5° spatial resolution by using pixel aggregation (PA) method and to a monthly temporal interval by using maximum value composite (MVC) method (Ma et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0032" id="#eft21593-bib-0032_R_d20964025e558" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; Tian et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0041" id="#eft21593-bib-0041_R_d20964025e562" class="bibLink tab-link" data-tab="pane-pcw-references">2021</a></span>). Considering the high similarity among GIMMS-version datasets (Figure S1 in Supporting Information <a class="suppLink scrollableLink" href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#support-information-section">S1</a>), we only used GIMMS NDVI3g, along with other three independent long-term satellite remote sensing products (i.e., VIP15 NDVI, GLASS LAI and GLOBMAP LAI) for the main analysis.</p>
<div class="article-table-content" id="eft21593-tbl-0001"><header class="article-table-caption"><span class="table-caption__label">Table 1.<span> </span></span>Satellite Remote Sensing Datasets Used in This Study</header>
<div class="article-table-content-wrapper" tabindex="0">
<table class="table article-section__table">
<thead>
<tr>
<th class="bottom-bordered-cell right-bordered-cell left-aligned">Dataset</th>
<th class="bottom-bordered-cell center-aligned">Spatial resolution</th>
<th class="bottom-bordered-cell center-aligned">Temporal resolution</th>
<th class="bottom-bordered-cell center-aligned">Available period</th>
<th class="bottom-bordered-cell center-aligned">Ref</th>
</tr>
</thead>
<tbody>
<tr>
<td class="right-bordered-cell left-aligned">VIP15 NDVI</td>
<td class="center-aligned">0.05°</td>
<td class="center-aligned">15-day</td>
<td class="center-aligned">1981–2014</td>
<td class="center-aligned">(Didan et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0010" id="#eft21593-bib-0010_R_d20964025e636" class="bibLink tab-link" data-tab="pane-pcw-references">2015</a></span>)</td>
</tr>
<tr>
<td class="right-bordered-cell left-aligned">GIMMS NDVI3g</td>
<td class="center-aligned">1/12°</td>
<td class="center-aligned">15-day</td>
<td class="center-aligned">1981–2015</td>
<td class="center-aligned">(Pinzon &amp; Tucker, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0037" id="#eft21593-bib-0037_R_d20964025e657" class="bibLink tab-link" data-tab="pane-pcw-references">2014</a></span>)</td>
</tr>
<tr>
<td class="right-bordered-cell left-aligned">GIMMS LAI3g</td>
<td class="center-aligned">1/12°</td>
<td class="center-aligned">15-day</td>
<td class="center-aligned">1981–2015</td>
<td class="center-aligned">(Zhu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0056" id="#eft21593-bib-0056_R_d20964025e678" class="bibLink tab-link" data-tab="pane-pcw-references">2013</a></span>)</td>
</tr>
<tr>
<td class="right-bordered-cell left-aligned">PKU GIMMS NDVI</td>
<td class="center-aligned">1/12°</td>
<td class="center-aligned">15-day</td>
<td class="center-aligned">1982–2020</td>
<td class="center-aligned">(Li et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0027" id="#eft21593-bib-0027_R_d20964025e699" class="bibLink tab-link" data-tab="pane-pcw-references">2023</a></span>)</td>
</tr>
<tr>
<td class="right-bordered-cell left-aligned">GLASS LAI</td>
<td class="center-aligned">0.05°</td>
<td class="center-aligned">8-day</td>
<td class="center-aligned">1981–2018</td>
<td class="center-aligned">(Ma &amp; Liang, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0031" id="#eft21593-bib-0031_R_d20964025e720" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>)</td>
</tr>
<tr>
<td class="right-bordered-cell left-aligned">GLOBMAP LAI</td>
<td class="center-aligned">∼0.07°</td>
<td class="center-aligned">half-month (1982–2000) and 8-day (2001–2019)</td>
<td class="center-aligned">1982–2019</td>
<td class="center-aligned">(Liu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0029" id="#eft21593-bib-0029_R_d20964025e742" class="bibLink tab-link" data-tab="pane-pcw-references">2012</a></span>)</td>
</tr>
<tr>
<td class="right-bordered-cell left-aligned">MOD13C1 NDVI</td>
<td class="center-aligned">0.05°</td>
<td class="center-aligned">16-day</td>
<td class="center-aligned">2000–2020</td>
<td class="center-aligned">(Didan &amp; Munoz, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0009" id="#eft21593-bib-0009_R_d20964025e763" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>)</td>
</tr>
<tr>
<td class="right-bordered-cell left-aligned">OCO2 SIF</td>
<td class="center-aligned">0.05°</td>
<td class="center-aligned">4-day</td>
<td class="center-aligned">2000–2020</td>
<td class="center-aligned">(Zhang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0054" id="#eft21593-bib-0054_R_d20964025e784" class="bibLink tab-link" data-tab="pane-pcw-references">2018</a></span>)</td>
</tr>
<tr>
<td class="right-bordered-cell left-aligned">VOD</td>
<td class="center-aligned">0.25°</td>
<td class="center-aligned">Daily</td>
<td class="center-aligned">1987–2017</td>
<td class="center-aligned">(Moesinger et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0033" id="#eft21593-bib-0033_R_d20964025e805" class="bibLink tab-link" data-tab="pane-pcw-references">2020</a></span>)</td>
</tr>
</tbody>
</table>
</div>
<div class="article-section__table-source"></div>
</div>
</section>
<section class="article-section__sub-content" id="eft21593-sec-0040">
<h3 class="article-section__sub-title section2" id="eft21593-sec-0040-title">2.2 LAI Estimates</h3>
<p>We used monthly LAI estimates of 12 DGVMs from TRENDY v9 (Friedlingstein et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0015" id="#eft21593-bib-0015_R_d20964025e822" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; Sitch et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0038" id="#eft21593-bib-0038_R_d20964025e825" class="bibLink tab-link" data-tab="pane-pcw-references">2015</a></span>) to check the consistency of the changes in the vegetation IAV derived from satellite remote sensing products and model measurements. The 12 DGVMs include CABLE, CLASSIC, CLM5, ISAM, ISBA, JULES, LPJ, LPX, ORCHIDEE, SDGVM, VISIT and YIBs (Table S1 in Supporting Information <a class="suppLink scrollableLink" href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#support-information-section">S1</a>), which were driven by monthly CRU or 6-hourly CRU-JRA gridded climate datasets, as well as dynamic atmospheric CO<sub>2</sub><span> </span>concentrations. These models provide LAI estimates under four different scenarios, namely no change (S0), varying CO<sub>2</sub><span> </span>only (S1), varying CO<sub>2</sub><span> </span>and climate (S2), and varying CO<sub>2</sub>, climate and land cover change (S3). We analyzed CV trends from LAI estimates of S3 scenario in this study. To match the period of data availability with satellite remote sensing observations, we used LAI estimates from 1982 to 2014.</p>
</section>
<section class="article-section__sub-content" id="eft21593-sec-0050">
<h3 class="article-section__sub-title section2" id="eft21593-sec-0050-title">2.3 Quantifying the Vegetation IAV Changes</h3>
<p>We used the coefficient of variation (i.e., CV), the ratio of the standard deviation to the mean, to indicate vegetation IAV for each dataset. The use of CV is meant to remove the differences in magnitude between datasets (i.e., NDVI, LAI, SIF and VOD) to ensure the comparability among the results. To further quantify the CV changes, we first defined the growing season as the period when the mean daily air temperature is above zero (Jiang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0021" id="#eft21593-bib-0021_R_d20964025e849" class="bibLink tab-link" data-tab="pane-pcw-references">2017</a></span>; Smith et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0039" id="#eft21593-bib-0039_R_d20964025e852" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>) for each vegetated pixel (Figure S2 in Supporting Information <a class="suppLink scrollableLink" href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#support-information-section">S1</a>). We adopted a “methodological growing season” (Körner et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0025" id="#eft21593-bib-0025_R_d20964025e858" class="bibLink tab-link" data-tab="pane-pcw-references">2023</a></span>) as it allows for easy extraction and reproducibility without incurring uncertainties from more complex definitions of phenology. Meanwhile, this definition effectively eliminates the frozen period when there is no vegetation growth, and aligns well with the phenological dates extracted by MODIS NDVI (Leeper et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0026" id="#eft21593-bib-0026_R_d20964025e861" class="bibLink tab-link" data-tab="pane-pcw-references">2021</a></span>). We obtained yearly composites by summing all values within the growing season (Piao et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0035" id="#eft21593-bib-0035_R_d20964025e865" class="bibLink tab-link" data-tab="pane-pcw-references">2020</a></span>; Zhu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0057" id="#eft21593-bib-0057_R_d20964025e868" class="bibLink tab-link" data-tab="pane-pcw-references">2016</a></span>). Subsequently, we calculated the CV for every 10-year moving window and assigned the CV value to the middle year of the window. The Theil-Sen method was used to estimate the CV trend (i.e., slope) (Wang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0044" id="#eft21593-bib-0044_R_d20964025e871" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>), and its significance (i.e.,<span> </span><i>p</i><span> </span>value) was determined using a two-tailed Student’s<span> </span><i>t</i>-test (Jiang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0022" id="#eft21593-bib-0022_R_d20964025e878" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>; Xu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0047" id="#eft21593-bib-0047_R_d20964025e882" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>). Lastly, the non-parametric Mann-Kendall test was used to detect whether a significant monotonic increasing or decreasing trend exists (Jiang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0022" id="#eft21593-bib-0022_R_d20964025e885" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>).</p>
</section>
<section class="article-section__sub-content" id="eft21593-sec-0060">
<h3 class="article-section__sub-title section2" id="eft21593-sec-0060-title">2.4 Classifying the Levels of Consistency of Remote Sensing-Based CV Trends</h3>
<p>Considering potential inconsistency of CV trends across four long-term satellite remote sensing products (i.e., VIP15 NDVI, GIMMS NDVI3g, GLASS LAI and GLOBMAP LAI), we classified the levels of consistency of CV trends for each vegetated pixel using the following criterion (Kause et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0023" id="#eft21593-bib-0023_R_d20964025e897" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; Xu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0047" id="#eft21593-bib-0047_R_d20964025e900" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>): (a) “virtually certain” (CER) means the signs of CV trends derived from all four long-term satellite products are the same and significant (Mann-Kendall test,<span> </span><i>p</i> ≤ 0.1); (b) “likely” (LIK) if the signs of the CV trends are the same and significant in any three satellite products; (c) “about likely as not” (ALN) if the signs of the CV trends are the same and significant in any two satellite products; (d) “possibly” (POS) if only one satellite product yields significant CV trend, and others are insignificant; (e) “no change” (NOC) if no significant CV changes were detected in all four satellite products; and (f) “conflicting” (CON) if the observed CV trends are conflicting with each other (i.e., significant positive and negative CV trends were detected simultaneously across the four products). We further assigned “+” and “−” signs to the consistency levels that refer to the direction of CV trends (i.e., positive and negative trends, respectively). Overall, the levels of consistency were classified into four types, positive, that is, CER (+), LIK (+), ALN (+) and POS (+), negative, that is, CER (−), LIK (−), ALN (−) and POS (−), no change (NOC), and conflicting (CON), respectively. Based on previous studies, NDVI and LAI are both indicators of canopy structure and greenness, and they are strongly related (Wang et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0045" id="#eft21593-bib-0045_R_d20964025e905" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; Zeng, Hao, et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0049" id="#eft21593-bib-0049_R_d20964025e908" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>). Therefore, we deem that there is a clear physiological and statistical basis to treat them equally. In addition, we used both indicators to augment the number of available long-term datasets for our analysis, as some datasets (e.g., VIP15) only contain NDVI, while others (e.g., GLOBMAP) only include LAI.</p>
</section>
<section class="article-section__sub-content" id="eft21593-sec-0070">
<h3 class="article-section__sub-title section2" id="eft21593-sec-0070-title">2.5 Identifying Factors Driving the IAV Changes</h3>
<p>Based on the findings from previous studies (Baldocchi et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0003" id="#eft21593-bib-0003_R_d20964025e921" class="bibLink tab-link" data-tab="pane-pcw-references">2016</a></span>; Berdugo et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0004" id="#eft21593-bib-0004_R_d20964025e924" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; Forkel et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0014" id="#eft21593-bib-0014_R_d20964025e927" class="bibLink tab-link" data-tab="pane-pcw-references">2016</a></span>; Gray et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0016" id="#eft21593-bib-0016_R_d20964025e930" class="bibLink tab-link" data-tab="pane-pcw-references">2014</a></span>; Luo &amp; Keenan, <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0030" id="#eft21593-bib-0030_R_d20964025e933" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>; Piao et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0036" id="#eft21593-bib-0036_R_d20964025e937" class="bibLink tab-link" data-tab="pane-pcw-references">2015</a></span>; Zhu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0057" id="#eft21593-bib-0057_R_d20964025e940" class="bibLink tab-link" data-tab="pane-pcw-references">2016</a></span>), we investigated several factors that may serve as potential drivers for the IAV changes. These factors are aridity index (AI), mean annual air temperature (MAT), mean annual precipitation (MAP), land use and land cover change (LUCC), mean monthly LAI, the trend of LAI (LAI<sub>trend</sub>) and nitrogen deposition (N deposition). AI was obtained from the Global Aridity Index dataset at a 30 arc-second resolution from 1970 to 2000 (Zomer et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0058" id="#eft21593-bib-0058_R_d20964025e945" class="bibLink tab-link" data-tab="pane-pcw-references">2022</a></span>), in which lower AI values mean drier conditions. MAT and MAP data were extracted from the gridded CRU-JRA V2.1 dataset (6-hr and 0.5° resolutions) (Harris et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0018" id="#eft21593-bib-0018_R_d20964025e948" class="bibLink tab-link" data-tab="pane-pcw-references">2020</a></span>). LUCC intensity was obtained using a 300-m ESA CCI land cover type product with 22 land cover classes from 1992 to 2019. We first determined whether land cover change occurred in each 300-m pixel from 1992 to 2019, and then quantified the LUCC intensity as the proportions of land cover change in each 0.5° spatial grid. The mean annual LAI was the average of GLASS LAI and GLOBMAP LAI from 1982 to 2014, and the LAI<sub>trend</sub><span> </span>(i.e., slope) was estimated using Mann-Kendall and Theil-Sen method for each vegetated pixel. Most global vegetated regions show significant greening trends (i.e., LAI<sub>trend</sub> &gt; 0) over the past decades (Chen, Chi, et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0006" id="#eft21593-bib-0006_R_d20964025e956" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>; Zhu et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0057" id="#eft21593-bib-0057_R_d20964025e959" class="bibLink tab-link" data-tab="pane-pcw-references">2016</a></span>). This implies that terrestrial ecosystems have accumulated more green leaves for carbon fluxes and in response to climate change, which may induce IAV changes. The N deposition was the average of the nitrogen deposition dataset (2° × 2.5° grid resolution) from 1984 to 2016 (Ackerman et al., <span><a href="https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2023EF004119#eft21593-bib-0001" id="#eft21593-bib-0001_R_d20964025e962" class="bibLink tab-link" data-tab="pane-pcw-references">2019</a></span>). All the above datasets were resampled into a 0.5° spatial grid.</p>
<p>We first assessed the significance of each factor in driving the vegetation IAV by using a two-sample<span> </span><i>t</i>-test method, in which we examined whether the high and low values of each factor caused statistically different CV trends. For each factor, we used different criteria for the binary classification of high and low values, that is, the 50% for LUCC, the zero for LAI<sub>trend</sub>, and the global average for other drivers. After that, we selected the four factors (i.e., AI, MAT, LAI<sub>trend</sub><span> </span>and N deposition; see Results) that have significant impacts on the CV trend and quantified their respective impacts using a multiple regression method:<span> </span><span class="fallback__mathEquation" data-altimg="/cms/asset/c8780be6-f32b-4009-8ec7-6182a8012836/eft21593-math-0001.png"></span><mjx-container class="MathJax CtxtMenu_Attached_0" jax="CHTML" sre-explorer-id="5" role="application" ctxtmenu_oldtabindex="1" ctxtmenu_counter="5" tabindex="0"><mjx-math location="graphic/eft21593-math-0001.png" class="MJX-TEX" aria-hidden="true"><mjx-semantics><mjx-mrow data-semantic-type="relseq" data-semantic-role="equality" data-semantic-id="59" data-semantic-children="0,54" data-semantic-content="1" data-semantic-speech="y equals a upper X Subscript upper A upper I Baseline plus b upper X Subscript upper M upper A upper T Baseline plus c upper X Subscript upper L upper A upper I Sub Subscript t r e n d 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Baseline plus c upper X Subscript upper L upper A upper I Sub Subscript t r e n d Baseline plus d upper X Subscript upper N upper D Baseline plus epsilon"><mi data-semantic-type="identifier" data-semantic-role="latinletter" data-semantic-font="italic" data-semantic-annotation="clearspeak:simple" data-semantic-="" data-semantic-parent="59">]]> </content:encoded>
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<title>American Beverage</title>
<link>https://sdgtalks.ai/american-beverage</link>
<guid>https://sdgtalks.ai/american-beverage</guid>
<description><![CDATA[ American Beverage and their mission to recycle plastics. ]]></description>
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<pubDate>Thu, 02 May 2024 16:44:28 -0500</pubDate>
<dc:creator>Jillian Buck</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p>The American Beverage company is actively taking steps for a better use of plastic. They are working with companies like Pepsi and Coke to use 100% recyclable bottles. They are also supplying communites with more recycling bins as well as educational materials. Their commitments have resulted in the collection of 914 million pounds of PET over the next 10 years. They will be able to reuse the plastic from these bottles again, and again, and again!</p>
<p><iframe width="640" height="360" src="https://player.vimeo.com/video/937812967?h=f72562739e" frameborder="0" allow="autoplay; fullscreen; picture-in-picture" allowfullscreen="allowfullscreen"></iframe></p>
<p><a href="https://vimeo.com/937812967">Made To Be Remade</a> from <a href="https://vimeo.com/user2405205">American Beverage Association</a> on <a href="https://vimeo.com">Vimeo</a>.</p>
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<title>To eliminate waste we need to rediscover thrift</title>
<link>https://sdgtalks.ai/to-eliminate-waste-we-need-to-rediscover-thrift</link>
<guid>https://sdgtalks.ai/to-eliminate-waste-we-need-to-rediscover-thrift</guid>
<description><![CDATA[ Process need to be redesigned to consider disassembly to reuse materials. ]]></description>
<enclosure url="https://i.ytimg.com/vi/kZP8Kqr_bcw/sddefault.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 30 Apr 2024 17:22:37 -0500</pubDate>
<dc:creator>Jillian Buck</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p><span style="font-size: 12.0pt; line-height: 115%; font-family: 'Aptos',sans-serif; mso-ascii-theme-font: minor-latin; mso-fareast-font-family: Aptos; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: minor-latin; mso-bidi-font-family: 'Times New Roman'; mso-bidi-theme-font: minor-bidi; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;">He described the many ways we can reuse materials. He talked about how wasteful our processes of building are. We build to construct and demolish, rather than take apart and reuse. Things like this already happen in the automotive industry, we must model after them, 90% of vehicles can be reused again and again. His final point was about plastic. Plastic cannot be reused over and over again on its own, instead we need to introduce microbes to ‘refresh’ the plastic.</span></p>
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<title>Water&#45;Stressed Arizona Says State Will End Leases to Saudi&#45;Owned Farm</title>
<link>https://sdgtalks.ai/water-stressed-arizona-says-state-will-end-leases-to-saudi-owned-farm</link>
<guid>https://sdgtalks.ai/water-stressed-arizona-says-state-will-end-leases-to-saudi-owned-farm</guid>
<description><![CDATA[ A Saudi owned farm in Arizona has been pumping out tons of groundwater from the state&#039;s dwindling aquifers in order to feed its thirsty alfalfa crop. This crop is then shipped to Saudi Arabia to feed cattle, where ironically, it is illegal to grow  due to Saudi Arabia&#039;s own water crisis. This practice will, fortunately, no longer be allowed to continue after Arizona ends their lease with the farm. ]]></description>
<enclosure url="https://static01.nyt.com/images/2023/10/03/multimedia/03cli-arizona-tlpb/03cli-arizona-tlpb-superJumbo.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 23 Apr 2024 12:25:49 -0500</pubDate>
<dc:creator>Elias Shiffman</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<div class="css-s99gbd StoryBodyCompanionColumn">
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<p class="css-at9mc1 evys1bk0">An Arizona farm owned by a Saudi Arabian company that grows alfalfa for export is set to lose its access to state land in a move Gov. Katie Hobbs said would “protect Arizona’s water future.”</p>
<p class="css-at9mc1 evys1bk0">The farm, in Butler Valley in western Arizona, has been mired in controversy over its pumping of unlimited amounts of groundwater, free of charge, to irrigate its water-thirsty alfalfa crop. The company then ships the alfalfa to Saudi Arabia, where the crop is fed to dairy cows.</p>
<p class="css-at9mc1 evys1bk0">Arizona is moving to immediately terminate one lease held by Saudi-owned Fondomonte Arizona, which operates the farm, and will not renew three other leases that are set to expire in February, Governor Hobbs said in a statement this week.</p>
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<div class="css-8atqhb">The action by Arizona is the latest sign of a worsening groundwater crisis affecting farmers and communities nationwide. A recent <a class="css-yywogo" href="https://www.nytimes.com/interactive/2023/08/28/climate/groundwater-drying-climate-change.html" title="">New York Times investigation</a> found that America is depleting its reserves of groundwater at a dangerous rate. The majority of the nation’s drinking-water systems rely on groundwater, as do many farms, particularly in the West.</div>
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<p class="css-at9mc1 evys1bk0">Arizona, in particular, has seen an explosion of wells, which are getting deeper as users chase falling water levels downward. The state, home to some of the country’s fastest growing communities, said in June that it would<span> </span><a class="css-yywogo" href="https://www.nytimes.com/2023/06/01/climate/arizona-phoenix-permits-housing-water.html" title="">stop granting permission</a><span> </span>to housing projects in the Phoenix area that rely on groundwater.</p>
<p class="css-at9mc1 evys1bk0">Alfalfa, grown year-round in Arizona, is a particularly thirsty crop that relies on irrigation. It is mainly used to feed dairy cows and other livestock, which has increasingly made milk and meat products a burden on the nation’s water supply.</p>
<p class="css-at9mc1 evys1bk0">Saudi Arabia banned growing alfalfa and other green fodder crops within its own borders in 2018 in a bid to relieve pressure on the kingdom’s water resources.</p>
<p class="css-at9mc1 evys1bk0">Arizona’s decision to cancel the Fondomonte leases was triggered by violations by the company, including longstanding equipment problems confirmed during a state inspection earlier this year, the governor said. But the underlying concerns have gone beyond technical violations in a state contending with worsening drought and water scarcity, driven by decades of over-pumping, as well as climate change.</p>
<p class="css-at9mc1 evys1bk0">Fondomonte did not immediately return a request for comment.</p>
<p class="css-at9mc1 evys1bk0">Fondomonte’s leases, which covered more than 3,000 acres west of Phoenix, had given the Saudi firm license to pump the region’s dwindling groundwater for free. Governor Hobbs had been under pressure to curtail that access.</p>
<p class="css-at9mc1 evys1bk0">“It’s unacceptable that Fondomonte has continued to pump unchecked amounts of groundwater out of our state while in clear default on their lease,” Governor Hobbs said. She said she was determined to do “everything in my power to protect Arizona’s water so we can continue to sustainably grow for generations to come.”</p>
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<p><span class="css-97bxx6"><a class="authorPageLinkClass overrideLinkStyles" href="https://www.nytimes.com/by/hiroko-tabuchi">Hiroko Tabuchi</a></span><span> </span>is an investigative reporter on the Climate desk, reporting widely on money, influence and misinformation in climate policy.<span class="css-kzd6pg"><span> </span><a class="authorPageLinkClass overrideLinkStyles" href="https://www.nytimes.com/by/hiroko-tabuchi">More about Hiroko Tabuchi</a></span></p>
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<title>Japan&amp;apos;s thirst for biomass is having a harmful impact on Canada&amp;apos;s forests</title>
<link>https://sdgtalks.ai/japans-thirst-for-biomass-is-having-a-harmful-impact-on-canadas-forests</link>
<guid>https://sdgtalks.ai/japans-thirst-for-biomass-is-having-a-harmful-impact-on-canadas-forests</guid>
<description><![CDATA[ The logging industry in British Columbia has been on a tear for the past century, but a recent demand for wood pellets in Japan is leading to even more harmful practices. Japan&#039;s use of these wood pellets as &quot;biofuel&quot; is supposed to be a carbon neutral solution to coal. However, cutting down hundred year old trees to burn is not exactly a sustainable practice when done on such a large scale. ]]></description>
<enclosure url="https://cdn4.premiumread.com/" length="49398" type="image/jpeg"/>
<pubDate>Tue, 23 Apr 2024 12:17:49 -0500</pubDate>
<dc:creator>Elias Shiffman</dc:creator>
<media:keywords>BIOMASS, FORESTS, BRITISH COLUMBIA, CANADA, ENERGY, EMISSIONS, CLIMATE CHANGE</media:keywords>
<content:encoded><![CDATA[<p>When you walk through a fresh clearcut in British Columbia, you are surrounded by a “one-dimensional, dead landscape,” says Michelle Connolly of Conservation North, a volunteer conservation group based in the Canadian province.</p>
<p>The forest’s soft, mossy ground, the birdcalls and the cool moisture in the air are gone. In their place, twigs and debris lay everywhere, occasionally interspersed with pieces of garbage. Sound and movement from plants or animals have almost ceased, except for the buzzing of insects. The smell of burned piles of slash — wood debris not profitable enough to bring to a mill — hangs in the air.</p>
<div class="jt_content_ad DisplayAd no-print" id="div-gpt-ad-1499653692894-0"></div>
<p></p>
<p>“That’s the story of conventional forestry in BC,” Connolly says.</p>
<p>Last month, Connolly visited Japan to share how such scenes are linked to the nation’s “green” energy: A portion of BC’s razed forests are being used to make wood pellets, a type of biofuel that Japan is importing and burning in increasing quantities as an alternative to fossil fuels.</p>
<p>The Japanese government claims wood pellets are “carbon neutral” because trees absorb carbon dioxide throughout their lives and, therefore, do not result in a net increase of atmospheric carbon dioxide when burned. The Agency for Natural Resources and Energy, which is in charge of Japan’s biomass policy, did not respond to a request for comment.</p>
<p>Experts in the field, however, warn that this kind of carbon accounting is dangerously misguided.</p>
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<div class="imgCaption">Drax’s Meadowbank pellet mill in British Columbia in 2022. Piles of logs and, in the background, what appears to be woodchips await processing into wood pellets. |<span> </span><span class="image-credit">MIGHTY EARTH</span></div>
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<p>Research by British think tank Chatham House details how woody biomass fuels like wood pellets release a large amount of carbon dioxide during combustion — even more than coal — due to having lower energy density. Burning trees for electricity increases atmospheric carbon dioxide in the near term, precisely when the world most needs to reduce greenhouse gas emissions. And when forests are cut, their ability to absorb and sequester carbon is halted for decades.</p>
<p>The Japanese government plans to have biomass contribute 5% of Japan’s power needs by 2030, putting it on par with wind. Hydrogen and ammonia, the government and industry’s<span> </span><a href="https://www.japantimes.co.jp/environment/2023/10/22/resources/ammonia-cofiring-issues/">controversial long-term bet to decarbonize the power sector</a>, are expected to only contribute 1% by that year.</p>
<p>Japan began seriously investing in woody biomass after the 2011 Fukushima nuclear disaster triggered a sudden shortage of zero-emission energy, as the nation took all of its reactors offline. Beginning in 2012, generous government support for renewable energy projects led to 434 approvals for power plants designed to run either partially or fully on woody biomass, although only 191 had come online as of June 2022 and many don’t use imported pellets.</p>
<p>Still, the country’s wood pellet imports from Canada shot up accordingly, from 76,000 metric tons in 2013 to 1.4 million in 2022, representing 31% of Japan’s total pellet imports that year (other top sources of pellets include Vietnam, the U.S. and Malaysia).</p>
<p>Japan received 40% of all Canadian wood pellet exports in 2022, according to Canadian government statistics. Over the first 10 months of 2023, that figure rose to 55%, with practically all of that coming from BC.</p>
<p>However, Connolly and other experts warn that BC’s overstretched and declining forestry sector may not be able to provide Japan with a steady supply of wood pellets for long — and, for the present, it is leaving a trail of environmental destruction in its wake.</p>
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<div class="imgCaption">Conservation North’s Michelle Connolly stands in front of an under-construction storage tank at Sumitomo Corp.’s Sendai biomass power plant. |<span> </span><span class="image-credit">MIGHTY EARTH</span></div>
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<h3>Unknown exploitation</h3>
<p>Wood pellets are enmeshed in BC’s forestry industry, and proponents claim that pellets help utilize waste generated from producing other products, such as lumber. The catch, according to Connolly, is that “BC’s forestry system is fundamentally unsustainable.”</p>
<p>The province has experienced roughly a century “of forest exploitation, and the last 60 years of that has been ultra-aggressive,” she adds.</p>
<p>Forest land accounts for roughly two-thirds of BC’s total area, and that’s a large area — the province is three times the size of all of Japan. It’s unknown exactly how much of the province’s 600,000 square kilometers of forest remain untouched by logging, but experts and activists warn that such “primary forests” are dwindling. Although BC does release figures for “old growth” logging, primary forests represent a wider category of ecosystems that don’t contain signs of human disturbance but whose trees might not fit the definition of “old growth.”</p>
<p>The results of a government-initiated strategic review of old-growth forests in BC noted in 2020 that the province’s “economy is heavily dependent on trees harvested from primary forests of old trees.” This is especially true of logging in the province’s interior, where “large-scale commercial cutting of primary forests” began 50 or fewer years ago and where it can take “several decades” for replanted trees to be ready for a second harvest.</p>
<p>BC’s pellet industry is located in the interior. As a result, wood pellet feedstock likely comes from clearcut primary forest, whether a pellet mill uses byproducts such as sawmill waste or whole trees sourced directly from a logging site.</p>
<p>Connolly’s home city, Prince George, lies in an area of the BC interior where forests are currently being harvested — in part, for pellets.</p>
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<div class="imgCaption">Primary forest near Revelstoke, British Columbia. Forest land accounts for roughly two-thirds of the province's total area. |<span> </span><span class="image-credit">MIGHTY EARTH</span></div>
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<p>From 2017, 9% of the output of the 80,000-square-kilometer Prince George timber supply area has been set aside for “bioenergy stands” — trees fit for logging for pellets — defined as “mature, damaged pine-leading stands” with relatively low marketability as saw logs.</p>
<p>However, Andrew Weaver, a professor at the University of Victoria’s School of Earth &amp; Ocean Sciences and a former member of the province’s Legislative Assembly, told The Japan Times that even harvesting such “damaged” stands could set a dangerous precedent. After being cut, replanted trees will take decades to grow, during which time the wood pellet industry will need more raw materials. The impacts of climate change also make a future second harvest less predictable, Weaver added.</p>
<p>Connolly argues that BC’s remaining primary forest would be better left as-is.</p>
<p>Primary forests are the best habitat for much of BC’s wildlife, especially large-bodied mammals, including critically endangered caribou, as well as bears that make dens in large tree trunks. They also keep watersheds clean, an essential ecosystem service that benefits both animals and people (Vancouver, the province’s economic capital, has banned logging in its watersheds since the 1990s).</p>
<p>In addition, primary forests contribute significant carbon sinks, with much carbon dioxide stored in large, old trees and undisturbed soil and peat. Scientists note that primary forests are more effective at storing carbon than single-species plantation forests; it can take centuries for a replanted forest to store as much carbon as the primary forest it replaced.</p>
<p>Currently, U.K.-headquartered Drax — a utility at home and a pellet producer in Canada and the U.S. — controls eight of 12 BC pellet mills, roughly 80% of the province’s total wood pellet production capacity.</p>
<p>At its mills, huge piles of trees await processing. Although the company previously claimed to only use “sawdust and waste wood,” a 2022 investigation by BBC Panorama found evidence that Drax was also sourcing directly from primary forests. Drax responded to the BBC investigation by saying that 80% of its source material is “sawmill residues” and the rest is “waste material” from forests at risk of fire or disease.</p>
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<div class="imgCaption">A pile of timber waste following a clearcut near Mackenzie, British Columbia, that had been designated for Pinnacle Renewable Energy, a pellet producer that was later taken over by Drax. |<span> </span><span class="image-credit">CONSERVATION NORTH</span></div>
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<p>“In Canada, good forest management includes managed removals, which create less dense stands of trees and reduce what’s left lying on the forest floor, helping to protect from fires, pests and diseases, and preserving biodiversity,” a Drax spokesperson told The Japan Times in an email. “We support good forest management by providing a market for this material and turning it into something useful — sustainable biomass — which can be used as fuel for renewable, low carbon power.”</p>
<p>During her trip to Japan, Connolly felt that Japanese audiences — including wood pellet stakeholders, media and members of the general public — were puzzled and disappointed to learn how BC’s primary forests are being turned into wood pellets.</p>
<p>“It was actually really emotional for me to see people’s faces fall,” Connolly says.</p>
<h3>A finite amount of wood</h3>
<p>Although wood pellets are often billed as a “sustainable” resource, there may be a limit on the amount of pellets BC can provide Japan, warned Ben Parfitt, a resource policy analyst for the Canadian Center for Policy Alternatives who also covered forestry in BC for many years as a journalist. Parfitt traveled to Japan with Connolly to speak about wood pellets.</p>
<p>BC’s logging industry, which pellet manufacturers rely on, is shrinking. Roughly 51.3 million cubic meters of timber were logged in 2022, down from 76.6 million in 2013, according to data Parfitt compiled from government statistics. Many companies are moving their operations to the southern U.S., where trees grow faster in a milder climate on already extensive forest plantations. The number of sawmills in BC is also decreasing, down from 111 in 2005 to 64 in 2023.</p>
<p>In Parfitt’s view, the logging industry is contracting primarily because it logged too much, too quickly. “They have run out of the easiest-to-access and cheapest fiber,” he said.</p>
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<div class="imgCaption">Ben Parfitt (right) stand outside Renova’s Sendai Gamo Biomass power plant. The round tanks on the left are for storing biomass fuel. |<span> </span><span class="image-credit">MIGHTY EARTH</span></div>
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<p>With logging in decline, Parfitt predicted increasing competition for resources going forward.</p>
<p>“That’s pretty much where, I think, the rubber hits the road,” he concludes. “There’s a finite amount (of wood) out there.”</p>
<p>In a public event during his visit to Japan, Parfitt highlighted both Drax’s overwhelming control of BC’s wood pellet industry and the fact that the company itself consumes vast quantities of wood pellets at its own power plant in the U.K. As competition for resources intensifies, the decisions Drax makes going forward could potentially have a big impact on Japan’s wood pellet supply, Parfitt warned.</p>
<p>The company itself brushed off such concerns, saying in its statement to The Japan Times that it responsibly manages its commercial agreements and closely analyzes market issues affecting itself and its suppliers.</p>
<p>“The majority of the sustainable biomass we supply to Japan is sourced from British Columbia in Canada where the forests are sustainably managed and subject to environmental regulation, careful management and third-party certification,” the Drax representative wrote.</p>
<p>Still, Parfitt is not alone in his concern over the future of Japan’s supply of BC wood pellets. Weaver too sees BC’s relatively slow-growing forest resources as “mismatched” with the wood pellet industry and its eager customers in Japan. Wood pellets aren’t anything more than a “short-term fix” for the country’s energy needs, he said.</p>
<p>Going forward, Weaver suggested that Japan, known abroad as a nation of innovators, could show more international leadership in renewable energy.</p>
<p>“Burning wood is literally what our ancestors and Neanderthals did many hundred thousands of years ago,” he says. “Surely we’re better than that.”</p>
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<div class="imgCaption">A satellite view of clearcuts in the vicinity of Prince George, British Columbia. |<span> </span><span class="image-credit">GOOGLE EARTH</span></div>
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<title>Take out dams and keep the Snake River salmon’s last, best place</title>
<link>https://sdgtalks.ai/take-out-dams-and-keep-the-snake-river-salmons-last-best-place</link>
<guid>https://sdgtalks.ai/take-out-dams-and-keep-the-snake-river-salmons-last-best-place</guid>
<description><![CDATA[ The upper Snake river of the PNW is one of the last great habitats for Pacific Salmon. However, its pristine waters are blocked by a multitude of dams used for power, irrigation, and shipping. With the population of Salmon dwindling to near extinction levels due to these dams, there is only one thing left to safe them: remove the dams. ]]></description>
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<pubDate>Tue, 23 Apr 2024 12:06:45 -0500</pubDate>
<dc:creator>Elias Shiffman</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<div class="article-byline">
<div class="byline-text single_author u-dib">In the face of relentlessly dire headlines for Pacific salmon and steelhead — 28 populations listed as threatened or endangered, emergency fisheries closures in California, Oregon and Washington, tribal assessments that some wild Chinook runs are approaching “quasi-extinction” levels — the Snake River’s thousands of miles of pristine wilderness habitat make it the last, best place for America to save wild Pacific salmon and steelhead.</div>
</div>
<div id="article-content" class="article-content entry-content">
<p>But until the White House and Congress tackle the heart of the problem — four dams on the Snake in Eastern Washington that are, quite literally, blocking the way to recovery — these once-epic populations will continue to slide toward extinction.</p>
<p>A<span> </span><a href="https://hds.harvard.edu/people/harvey-g-cox" target="_blank" class="content-link external" rel="noopener">famous theologian</a><span> </span>once said, “Not to decide is to decide.” That seems to be the approach of these policymakers as they ignore the free-falling decline on the Snake.  </p>
<p>Three years ago, U.S. Rep. Mike Simpson, R-Idaho, said what conservationists have long known. We can remove the dams, reopen hundreds of miles of rivers to salmon and steelhead, and replace the dams’ socio-economic benefits: irrigation, power, barging for agricultural products. Gov. Jay Inslee and U.S. Sen. Patty Murray affirmed this conclusion.   </p>
<p>But building on decades of senseless inaction, their fellow elected leaders and policymakers are fumbling away the most promising opportunity to recover imperiled salmon and steelhead, and in the process failing to make good on America’s treaty obligations to tribal nations.</p>
<p>The Snake is a five-star hotel for salmon and steelhead. Forty percent of its lands and waters are wilderness quality, and it possesses 50% of the remaining habitat for these fish in the West.</p>
<p>The four dams on the lower Snake are relics of the 1950s, concrete anchors locking us into anachronistic thinking and destined to be tombstones for wild salmon and steelhead runs if we do not change course.</p>
<p>My life in conservation began many years ago when I witnessed the wonder-inspiring journey that salmon make, returning sometimes thousands of miles from the ocean to their natal streams to spawn and die, their decaying bodies providing the nutrients that power the cycle of life.</p>
<p>In a free-flowing system, their progeny, known as smolts, would be flushed downstream by high spring flows in a few days.</p>
<p>Instead, they face a two-week journey through 140 miles of warm reservoirs created by the Snake dams.</p>
<p>These small fish — carrying genetic code thousands of generations old — die in turbines. They are attacked by predators in the stagnant water above the dams. They perish in the tanks of barges that attempt to move them past the dams. More than 50% never make it past the dams. Fewer than 1% return to spawn, which is not a sustainable number.</p>
<p>We have spent $25 billion in a failed effort to recover these fish. For 50 years, we have barged salmon past the dams, created fish ladders, spilled more water over the dams, built hatcheries and deployed dozens of other mitigation strategies.</p>
<p>But we now know that the only way to recover wild Snake River salmon and steelhead is to remove the dams. So<span> </span><a href="https://media.fisheries.noaa.gov/2022-09/rebuilding-interior-columbia-basin-salmon-steelhead.pdf" target="_blank" class="content-link external" rel="noopener">say scientists at the National Marine Fisheries Service</a>, calling dam-breaching “the centerpiece action.”</p>
<p>We could keep waiting. We could conduct more studies. We could stand by as elected leaders issue platitudes praising salmon but refuse to aid in their recovery and refuse to make good on treaties with tribes that relied on these fish for thousands of years.</p>
<p>Or we can decide to demand dam removal and salmon recovery. We can decide to stand with the tribes. We can decide to act.</p>
<div id="userMessagingInset" class="user-messaging animate"></div>
<p>Something will have been lost from our humanity if we allow these fish to slip into extinction. Will we walk away as a nation knowing we could have intervened? What a loss. What a stain on our nation; to humanity, really.</p>
<p>We can replace every social and economic benefit provided by the Snake River dams.</p>
<p>But the salmon and steelhead? They need a free-flowing river. We just need to decide — decide that we want to give them one.</p>
<div id="userMessagingIn-story"></div>
<div class="extended-byline" data-gtm-vis-recent-on-screen707840_184="75903" data-gtm-vis-first-on-screen707840_184="75903" data-gtm-vis-total-visible-time707840_184="100" data-gtm-vis-has-fired707840_184="1" data-gtm-vis-recent-on-screen707840_237="75905" data-gtm-vis-first-on-screen707840_237="75905" data-gtm-vis-total-visible-time707840_237="100" data-gtm-vis-has-fired707840_237="1" data-gtm-vis-recent-on-screen707840_236="75905" data-gtm-vis-first-on-screen707840_236="75905" data-gtm-vis-total-visible-time707840_236="100" data-gtm-vis-has-fired707840_236="1">
<div class="single-byline"><span class="name"><span class="name"><span class="byline-copy">By<span> </span></span></span></span>
<div class="name vcard"><span itemprop="author" itemscope="" itemtype="https://schema.org/Person"><a itemprop="url" href="https://www.seattletimes.com/author/chris-wood/" rel="author" class="p-author h-card hcard url fn"><span itemprop="name">Chris Wood</span></a></span></div>
<div class="title vcard"><span class="p-author fn">Special to The Seattle Times</span></div>
</div>
<div class="single-byline"><span class="name">Chris Wood<span> </span></span><span>worked on the roadless rule for the Forest Service and is now president and CEO of Trout Unlimited.</span></div>
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<title>Navigating the State of Recycling in 2024 and Beyond</title>
<link>https://sdgtalks.ai/navigating-the-state-of-recycling-in-2024-and-beyond</link>
<guid>https://sdgtalks.ai/navigating-the-state-of-recycling-in-2024-and-beyond</guid>
<description><![CDATA[ This article explores current recycling trends, challenges, and solutions, advocating for sustainable practices to protect the environment and marine life ]]></description>
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<pubDate>Wed, 17 Apr 2024 00:31:51 -0500</pubDate>
<dc:creator>Todd Osborn</dc:creator>
<media:keywords>recycling, sustainability, environment, waste management, marine conservation, reduce reuse recycle, innovation, government regulations, consumer awareness</media:keywords>
<content:encoded><![CDATA[<p>As the world grapples with the environmental challenges of today, recycling stands out as a key solution to mitigate waste and protect our planet. Here's a breakdown of the current state of recycling and what lies ahead:</p>
<p><strong>Key Insights:</strong></p>
<ul>
<li>Governments worldwide are ramping up recycling targets and diversion goals to combat landfill overflow and address growing environmental concerns.</li>
<li>China's 'National Sword' policy continues to impact the global recycling industry, prompting countries to find new solutions for managing recyclable materials.</li>
<li>While the United States has made strides in recycling, there's still ample room for improvement, particularly in reducing waste generation.</li>
<li>Not all products are equal in their recyclability or environmental impact, emphasizing the importance of understanding and prioritizing reuse and donation over traditional recycling methods.</li>
<li>Consumer demand for sustainability is driving businesses to adopt eco-friendly practices, leading to the rise of brands committed to environmental stewardship.</li>
</ul>
<p><strong>Protecting Life Below Water:</strong> One crucial aspect of recycling is its impact on marine ecosystems. With millions of tons of plastic waste ending up in oceans each year, recycling plays a vital role in mitigating this environmental threat. By properly managing and recycling plastic waste, we can prevent further pollution of marine habitats and protect marine life.</p>
<p>Incorporating the principles of reduce, reuse, and recycle into everyday life can significantly contribute to this effort. For example, opting for shampoo and conditioner bars eliminates the need for plastic bottles, reducing plastic waste that could eventually find its way into the ocean.</p>
<p><strong>Changing Government Regulations:</strong> As public awareness of environmental issues grows, governments are responding with stricter regulations on recycling and waste management. Cities and states are implementing ambitious goals to reduce waste and increase recycling rates, signaling a shift towards more sustainable practices.</p>
<p><strong>New Technologies and Processes:</strong> Innovative technologies are emerging to improve recycling efficiency and handle sustainability challenges. From advanced sorting robots to chemical recycling processes, these innovations offer promising solutions to enhance recycling capabilities and reduce environmental impact.</p>
<p><strong>What You Can Do:</strong> Individuals and businesses alike can take action to support recycling efforts and promote sustainability:</p>
<ul>
<li>Reduce waste by minimizing consumption and opting for eco-friendly alternatives.</li>
<li>Reuse products whenever possible to extend their lifespan and reduce the need for new materials.</li>
<li>Recycle responsibly and educate others about the importance of proper waste management.</li>
<li>Support brands and initiatives that prioritize sustainability and environmental stewardship.</li>
</ul>
<p>By embracing these principles and incorporating sustainable practices into daily life, we can all contribute to a healthier planet for future generations.</p>]]> </content:encoded>
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<item>
<title>A Quick Guide to a Sustainable Wardrobe: How to Shop Ethically</title>
<link>https://sdgtalks.ai/a-quick-guide-to-a-sustainable-wardrobe-how-to-shop-ethically</link>
<guid>https://sdgtalks.ai/a-quick-guide-to-a-sustainable-wardrobe-how-to-shop-ethically</guid>
<description><![CDATA[ Advice on choosing clothing to promote sustainable consumption. ]]></description>
<enclosure url="https://encrypted-tbn0.gstatic.com/images" length="49398" type="image/jpeg"/>
<pubDate>Sun, 07 Apr 2024 17:31:19 -0500</pubDate>
<dc:creator>kagonz</dc:creator>
<media:keywords>fast fashion, thrifting, ethical shopping, second-hand</media:keywords>
<content:encoded><![CDATA[<p>First and foremost: the best thing you can do for the environment related to fashion is to buy as little as you can. It's not the materials that harm the Earth necessarily, but the rate at which we buy and discard our clothes. Changing your mindset to resist trendy and short-lived purchases is important, but it doesn't mean you can't love clothes or buy anything new:</p>
<p>If you do decide a new item of clothing is desired or necessary, look towards second-hand first. It may take more work to thrift than to online shop, but the activity can be fun and much less expensive, as well as supportive of a local economy.</p>
<p>Consider repairable items of clothing. Small tears, broken zippers, or slightly large/long pieces of clothing are easily repaired at home or by a tailor. Most people don't know that local tailors specialize in these small adjustments and are affordable!</p>
<p>Embrace clothing exchanges with friends. Breaking stigmas about hand-me-downs or out-of-season clothing can be better for your wallet and your friendships! </p>
<p>If you must buy something new, know what you're buying beforehand. Infrequent purchasing habits allow a buyer to save up for higher-quality, longer-lasting items that may not need to be replaced for up to a lifetime. Use this time to determine exactly what item fits you and your needs.</p>
<p>If shopping online, research sustainable brands and order in as few shipments as possible. Less deliveries means less resources expended delivering a purchase.</p>]]> </content:encoded>
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<title>Boiling water might mitigate microplastics</title>
<link>https://sdgtalks.ai/boiling-water-might-mitigate-microplastics</link>
<guid>https://sdgtalks.ai/boiling-water-might-mitigate-microplastics</guid>
<description><![CDATA[ A new study suggests that boiling tap water might destroy microplastics in water to make it safer to drink ]]></description>
<enclosure url="https://media-cldnry.s-nbcnews.com/image/upload/t_fit-1500w,f_auto,q_auto:best/rockcms/2022-04/220407-microplastics-stock-ac-756p-83361f.jpg" length="49398" type="image/jpeg"/>
<pubDate>Wed, 28 Feb 2024 22:43:51 -0500</pubDate>
<dc:creator>Noah Link</dc:creator>
<media:keywords>Microplastics, Environment, Solution</media:keywords>
<content:encoded><![CDATA[<h1 dir="ltr" style="text-align: left;"><strong>Concerned About Microplastics in Your Water?</strong></h1>
<h1 dir="ltr" style="text-align: left;"><strong>Consider Boiling It First</strong></h1>
<p dir="ltr" style="text-align: left;"><span>Boiling tap water traps nano- and microplastic particles inside limescale deposits, a new study has found.</span></p>
<p dir="ltr" style="text-align: left;"></p>
<p dir="ltr" style="text-align: left;"><strong>Worried about microplastic particles in your tap water? Just boil it. </strong></p>
<p dir="ltr" style="text-align: left;"><span>At least, that’s the suggestion put forward by researchers at Guangzhou Medical University and Jinan University, China. </span></p>
<p dir="ltr" style="text-align: left;"><span>In a new study, published in Environmental Science &amp; Technology Letters, the team tested whether boiling your water might have any effect on the tiny nanoplastics and microplastics that are sometimes present in tap water. They found that boiling water effectively traps the plastic particles inside the limescale deposits that build up on a kettle’s inner surfaces.</span></p>
<p dir="ltr" style="text-align: left;"><span>Could boiling your drinking water reduce exposure to microplastics?</span></p>
<p dir="ltr" style="text-align: left;"><span>Numerous studies have found evidence of microplastics in real-world tap water samples, but the health effects of ingesting microplastics from drinking water are still unclear. Early studies suggest these microplastics can accumulate in the body and affect the gut microbiome.</span></p>
<p dir="ltr" style="text-align: left;"><span>Despite the best efforts of water treatment plants, microplastics and nanoplastics remain tricky to remove from water using standard treatment methods. While there are some advanced water treatment technologies that can tackle this problem, they  can be prohibitively expensive for less developed areas.</span></p>
<p dir="ltr" style="text-align: left;"><span>But what if a common household water treatment technique could already be slashing your exposure to microplastics?</span></p>
<p dir="ltr" style="text-align: left;"><span>“Drinking boiled water, an ancient tradition in some Asian countries, is supposedly beneficial for human health, as boiling can remove some chemicals and most biological substances,” the researchers wrote. “However, it remains unclear whether boiling is effective in removing NMPs [nano- and microplastics] in tap water.”</span></p>
<p dir="ltr" style="text-align: left;"><span>In their new study, the researchers used fluorescent particles of polystyrene plastic and examined how they behaved as they were heated in different types of water.</span></p>
<p dir="ltr" style="text-align: left;"><span>Boiling and filtering slashes microparticle levels by 90%</span></p>
<p dir="ltr" style="text-align: left;"><span>Tap water can either be considered “hard” or “soft”, depending on how rich it is in calcium and magnesium minerals. These minerals are also responsible for the formation of limescale inside kettles, which is why kettles need to be treated with descaler more frequently in areas with hard water.</span></p>
<p dir="ltr" style="text-align: left;"><span>The researchers found that when microplastic-containing water was brought closer to boiling temperatures, the added polystyrene NMPs began to co-precipitate out of the water alongside the minerals, becoming trapped in the crusty limescale deposits formed. </span></p>
<p dir="ltr"><span>Boiling was able to remove 84% of the NMPs added to hard water samples containing around 180 milligrams of calcium carbonate (CaCO3). This rose to 90% for very hard water samples, containing around 300 mg/L of the mineral.</span></p>
<p dir="ltr"><span> </span><span>The boiling practice was also able to remove up to 25% of the NMPs when done on soft water samples (containing less than 60 mg/L CaCO3), suggesting this simple practice may be more broadly applicable.</span></p>
<p dir="ltr"><span>“Because the occurrence of NMPs and water quality are uneven globally, the efficacy of boiling water in reducing NMPs may vary from region to region,” wrote the researchers. “Nonetheless, our results have ratified a highly feasible strategy to reduce human NMP exposure and established the foundation for further investigations with a much larger number of samples.”</span></p>
<p dir="ltr"><span> </span></p>
<p dir="ltr"><span>Reference: Yu Z, Wang JJ, Liu LY, Li Z, Zeng EY. Drinking boiled tap water reduces human intake of nanoplastics and microplastics. Environ Sci Technol Lett. 2024. doi: 10.1021/acs.estlett.4c00081</span></p>
<p dir="ltr"><span>This article is a rework of a press release issued by the American Chemical Society. Material has been edited for length and content.</span></p>
<p dir="ltr"><span></span></p>
<p dir="ltr"><span>Published: February 28, 2024</span></p>
<p dir="ltr"><span>Meet the Author:</span></p>
<p dir="ltr"><span>Alexander Beadle</span></p>
<p dir="ltr"><span>Alexander Beadle is a science writer and editor for Technology Networks. Prior to this, he worked as a freelance science writer. Alexander holds an MChem in materials chemistry from the University of St Andrews, where he won a Chemistry Purdie Scholarship and conducted research into zeolite crystal growth mechanisms and the action of single-molecule transistors.</span></p>
<p style="text-align: left;"><b id="docs-internal-guid-f524700f-7fff-0685-d017-7d414710ccaf"><br><br></b></p>]]> </content:encoded>
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<title>VeganBottle</title>
<link>https://sdgtalks.ai/veganbottle</link>
<guid>https://sdgtalks.ai/veganbottle</guid>
<description><![CDATA[ VeganBottle is a biodegradable and plant-based alternative to traditional plastic bottles, offering an eco-friendly solution to reduce plastic pollution and environmental impact. ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202402/image_430x256_65d51f0cbae03.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 20 Feb 2024 16:52:24 -0500</pubDate>
<dc:creator>jordanlarese</dc:creator>
<media:keywords>waste, biodegradable, vegan, plant-based</media:keywords>
<content:encoded><![CDATA[<p><span>VeganBottle is a sustainable and environmentally-friendly alternative to traditional plastic water bottles. Created by French designer and entrepreneur, Clémentine Sandner, VeganBottle is made from sugar cane, making it 100% biodegradable and compostable.</span><br><br><span>The production process for VeganBottle starts with extracting the sugar from sugar cane. The sugar is then fermented and turned into a green plastic material called polyethylene, which is used to create the bottles. This not only eliminates the use of fossil fuels, but it also reduces carbon emissions and plastic waste.</span><br><br><span>The main advantage of VeganBottle is its eco-friendliness. Unlike traditional plastic bottles, which can take up to 1,000 years to decompose, VeganBottle will break down in just a few months in compost conditions. This makes it a sustainable and environmentally-conscious choice for those looking to reduce their plastic consumption.</span><br><br><span>Moreover, VeganBottle promotes biodiversity by using sugar cane as its raw material. Sugar cane grows quickly and requires little water, making it a renewable and sustainable crop. It also provides habitat and food for various animals and contributes to a healthy and diverse ecosystem.</span><br><br><span>In addition to being environmentally-friendly, VeganBottle also provides health benefits for those who use it. Traditional plastic bottles can contain harmful chemicals such as BPA, which can be transferred to the water we drink. VeganBottle, on the other hand, is BPA-free and non-toxic, making it a safe alternative for both the environment and our health.</span><br><br><span>VeganBottle has also been recognized for its design and usability. The bottles are lightweight and durable, making them ideal for everyday use. They are also leak-proof and have a flip-top cap, making them convenient for on-the-go use.</span><br><br><span>In conclusion, VeganBottle is a sustainable, eco-friendly, and healthy alternative to traditional plastic water bottles. With its innovative use of sugar cane, it has the potential to significantly reduce plastic waste and promote responsible consumption and production.</span></p>]]> </content:encoded>
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<item>
<title>AirCarbon</title>
<link>https://sdgtalks.ai/aircarbon</link>
<guid>https://sdgtalks.ai/aircarbon</guid>
<description><![CDATA[ AirCarbon is a new innovative technology designed to catch carbon in the air using varieties of resources such as air and greenhouse gases. ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202402/image_430x256_65d51a212747f.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 20 Feb 2024 16:31:27 -0500</pubDate>
<dc:creator>jordanlarese</dc:creator>
<media:keywords>Carbon, air, environment</media:keywords>
<content:encoded><![CDATA[<p><span>Aircarbon is a groundbreaking technology that turns air pollution into a valuable resource. Developed by the US-based company, Newlight Technologies, Aircarbon uses a process called carbon capture to convert carbon emissions into a durable and sustainable bioplastic material.</span><br><br><span>The production process involves capturing carbon emissions from local sources, such as landfills and factories, and feeding them into a bioreactor. The bioreactor contains microorganisms that consume the carbon and convert it into a bioplastic material. This material, known as AirCarbon, can then be used to make various products, including packaging, straws, and cutlery.</span><br><br><span>Not only does Aircarbon provide a solution for reducing carbon emissions, but it also offers a sustainable alternative to traditional plastic products. Unlike traditional plastics, which are made from fossil fuels and take hundreds of years to decompose, AirCarbon is biodegradable. This means it will break down naturally in the environment without leaving harmful microplastics behind.</span><br><br><span>Moreover, the production of AirCarbon has a significantly lower carbon footprint than traditional plastics. The process captures more carbon than it emits, making it a carbon-negative material. Additionally, the bioreactors are powered by renewable energy sources, further reducing the environmental impact of Aircarbon production.</span><br><br><span>The versatility of AirCarbon allows it to be used in a variety of industries, from packaging to fashion. Companies such as Dell and Virgin Airlines have already started incorporating Aircarbon into their products, making a positive impact on their carbon footprint.</span><br><br><span>Additionally, Aircarbon has also been recognized for its potential in the fight against single-use plastics. In 2020, Newlight Technologies won the prestigious INDEX Award for its innovative solution to tackling plastic pollution.</span><br><br><span>But Aircarbon is not just about producing a sustainable material. It also has the potential to create jobs and support local economies. By capturing carbon emissions from local sources, Aircarbon production can be decentralized and provide opportunities for small businesses in their communities.</span><br><br><span>Overall, Aircarbon is a game-changing technology that not only helps to reduce carbon emissions and plastic pollution but also offers a sustainable and economically beneficial solution for communities around the world. With the increasing need for sustainable and eco-friendly alternatives, Aircarbon is paving the way for a greener and more sustainable future.</span></p>]]> </content:encoded>
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<item>
<title>Membrane&#45;based carbon capture: Recent progress, challenges, and their role in achieving the sustainable development goals</title>
<link>https://sdgtalks.ai/membrane-based-carbon-capture-recent-progress-challenges-and-their-role-in-achieving-the-sustainable-development-goals</link>
<guid>https://sdgtalks.ai/membrane-based-carbon-capture-recent-progress-challenges-and-their-role-in-achieving-the-sustainable-development-goals</guid>
<description><![CDATA[ The rapid growth in the consumption of fossil fuels resulted in climate change and severe health issues. Among the different proposed methods to control climate change, carbon capture technologies are the best choice in the current stage. In this study, the various membrane technologies used for carbon capture and their impact on achieving sustainable development goals (SDGs) are discussed. Membrane-based carbon capture processes in pre-combustion and post-combustion, which are known as membrane gas separation (MGS) and membrane contactor (MC), respectively, along with the process of fabrication and the different limitations that hinder their performances are discussed. Additionally, the 17 SDGs, where each representing a crucial topic in the current global task of a sustainable future, that are impacted by membrane-based carbon capture technologies are discussed. Membrane-based carbon capture technologies showed to have mixed impacts on different SDGs, varying in intensity and usefulness. It was found that the membrane-based carbon capture technologies had mostly influenced SDG 7 by enhancement in the zero-emission production, SDG 9 by providing 38–42% cost savings compared to liquid absorption, SDG 3 through reducing pollution and particulate matter emissions by 23%, and SDG 13, with SDG 13 being the most positively influenced by membrane-based carbon capture technologies, as they significantly reduce the CO2 emissions and have high CO2 capture yields (80–90%), thus supporting the objectives of SDG 13 in combatting climate change. ]]></description>
<enclosure url="https://encrypted-tbn0.gstatic.com/images" length="49398" type="image/jpeg"/>
<pubDate>Tue, 23 Jan 2024 18:23:06 -0500</pubDate>
<dc:creator>njvahlberg</dc:creator>
<media:keywords>Membrane, Carbon capture, Gas separation, Contactor, Challenges and barriers, Sustainable development goals</media:keywords>
<content:encoded><![CDATA[<section id="sec1">
<h2 id="sectitle0035" class="u-h4 u-margin-l-top u-margin-xs-bottom">1.<span> </span>Introduction</h2>
<p id="p0040">The rapid growth of the population and the progression of industries across various sectors have propelled the need for fossil fuels drastically during the last century (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib117" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib117"><span class="anchor-text">Poblete et al., 2022</span></a>). Fossil fuel has the leisure of providing intensive amounts of energy through combustion processes to accommodate various applications with lucrative performance parameters and efficiencies. However, there are adverse effects that accompany the usage of fossil fuel, transportation modes such as air or ocean freight (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib144" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib144"><span class="anchor-text">van Fan et al., 2018</span></a>), and domestic power consumption (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib18" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib18"><span class="anchor-text">Bastida et al., 2019</span></a><span>) with the emission of greenhouse gasses that contribute to <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/global-warming" title="Learn more about global warming from ScienceDirect's AI-generated Topic Pages" class="topic-link">global warming</a> being of upmost concern. Furthermore, concerns regarding the quality of the environment which affects various aspects of our daily lives such as health, agriculture and water purity, have acted as a wakeup call for environmentalists across the globe to reconsider the options regarding energy resources and reduce the emissions that intensify the effects of global warming (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib45" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib45"><span class="anchor-text">Gopinathan et al., 2022</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib104" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib104"><span class="anchor-text">Olabi et al., 2022a</span></a>).</p>
<p id="p0045"><span>Some methods and solutions have been utilized to attenuate the effects of global warming on various scales, including laboratory and industrial scales alike. Some of the methods include the improvement of the efficiency of pre-established <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/science-and-technology" title="Learn more about technologies from ScienceDirect's AI-generated Topic Pages" class="topic-link">technologies</a> which will reduce the amount of fuel required for their operation with the addition of <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/waste-heat-recovery" title="Learn more about waste heat recovery from ScienceDirect's AI-generated Topic Pages" class="topic-link">waste heat recovery</a> means (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib99" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib99"><span class="anchor-text">Olabi et al., 2021a</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib2" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib2"><span class="anchor-text">Abdelkareem et al., 2022</span></a>), implementing an effective energy management strategy, reconsidering the need for relatively subordinate devices or processes, and the integration of recycled parts in production lines to reduce the impact of material extraction throughout a product or a process's lifetime. Moreover, investing in environmentally friendly devices can have a large positive impact in the long run, such as fuel cells, and various effective cooling systems such as district cooling and absorption chillers.</p>
<p id="p0050">Fortunately, alternative technologies such as those renewable energy based, have countered the adverse effects posed by their predecessors and can potentially significantly reduce global warming effects (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib156" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib156"><span class="anchor-text">Inay id="crosref1062"at et al., 2010</span></a><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib157" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib157"><span class="anchor-text">Shahbaz et al., 2020</span></a>). Technologies such as solar photovoltaics (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib7" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib7"><span class="anchor-text">Alami et al., 2022a</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib20" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib20"><span class="anchor-text">Beni and Esmaeili, 2020</span></a><span>) and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/wind-turbine" title="Learn more about wind turbines from ScienceDirect's AI-generated Topic Pages" class="topic-link">wind turbines</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib100" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib100"><span class="anchor-text">Olabi et al., 2021b</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib15" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib15"><span class="anchor-text">Amjith and Bavanish, 2022</span></a>) have been under development for a substantial amount of time and have crossed the barrier between lab-scale and commercial applications. However, the infrastructure that is available on a global scale has yet to accommodate these technologies and utilize them as a primary source of daily operation, as well as the dependency on variable weather patterns (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib28" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib28"><span class="anchor-text">Chew et al., 2021</span></a>).</p>
<p id="p0055"><span>As such, <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/carbon-capture-and-storage" title="Learn more about carbon capture technologies from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbon capture technologies</a> (CCT), currently pose as a favorite candidate to lessen the emissions that contribute to the worsening of global warming and climate change (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib34" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib34"><span class="anchor-text">de Oliveira Maciel et al., 2022a</span></a>) (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib1" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib1"><span class="anchor-text">Abdelkareem et al., 2021</span></a>)– (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib35" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib35"><span class="anchor-text">de Oliveira Maciel et al., 2022b</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib105" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib105"><span class="anchor-text">Olabi et al., 2022b</span></a><span>). There are three main types of carbon technologies, pre-combustion, post-combustion, power plant and industrial processes, respectively, and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/oxyfuel" title="Learn more about oxyfuel from ScienceDirect's AI-generated Topic Pages" class="topic-link">oxyfuel</a> carbon capture. Additionally, membrane-based technologies, which depend on external imposed conditions such as an induced pressure difference which can be supplied from electricity generated by renewable energy technologies such as solar photovoltaic modules or wind turbines, for carbon capture have been recently put under the spotlight for the effective capture of carbon within natural and flue gasses in power plants and the purification of <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/gas-streams" title="Learn more about gas streams from ScienceDirect's AI-generated Topic Pages" class="topic-link">gas streams</a> that exist in industrial production processes.</span></p>
<p id="p0060"><span>In 2015, the UNs “United Nations” established 17 <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/sustainable-development-goals" title="Learn more about SDGs from ScienceDirect's AI-generated Topic Pages" class="topic-link">SDGs</a> “Sustainable Development Goals” to be reached in 2030 to achieve healthy living and a clean and safe environment sustainably (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib76" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib76"><span class="anchor-text">Majumdar et al., 2023</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib12" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib12"><span class="anchor-text">Aljaghoub et al., 2022</span></a>). Because they are designed to simultaneously improve the world's social, economic, and environmental conditions, the 17 SDGs are extremely important. To ensure that these Sustainable Development Goals are put into action, efforts on a global scale are required. Carbon capture technologies are significantly essential for combatting climate change and global warming. Nevertheless, it is important to explore the sustainability of these technologies and to check if their impacts on the environment and planet are positive. Thus, an assessment is critical to explore the positive impact membrane-based carbon capture technologies have on the achievement of the United Nations (UN) SDGs established to be accomplished by 2030. In 2021,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib80" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib80"><span class="anchor-text">Mikunda et al. (2021a)</span></a><span> </span>assessed the impacts of carbon capture and storage on the SDGs. The authors found out that carbon capture and storage can successfully attain the objectives of the SDGs. Furthermore, the authors reported that the most affected SDG by carbon capture and storage is SDG 13 which enforces the combat against climate change. Moreover, the study showed that carbon capture and storage have both negative and positive impacts on the SDGs. On a similar note, another study conducted by<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib106" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib106"><span class="anchor-text">Olabi et al. (2022c)</span></a><span> </span>demonstrates that in general carbon capture technologies have significant contributions to the SDGs. However, it was found that carbon capture technologies most significantly impact SDG 7, which focuses on promoting affordable and clean energy, and SDG 13, which aims at promoting climate action. As a result, it is important to focus on membrane-based carbon capture technologies and map their contributions to the SDGs, which presents a gap in the recent research conducted in their scopes. The current work discusses the progress done in membrane-based carbon capture technologies, the challenges facing membrane-based carbon capture, and finally discusses in detail the role of membrane-based carbon capture technologies in achieving the 17 SDGs.</p>
</section>
<section id="sec2">
<h2 id="sectitle0040" class="u-h4 u-margin-l-top u-margin-xs-bottom">2.<span> </span>Carbon capture and membrane-based technologies</h2>
<div>
<p id="p0065"><span>Due to the unprecedented effects of <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/global-warming" title="Learn more about global warming from ScienceDirect's AI-generated Topic Pages" class="topic-link">global warming</a>, <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/carbon-capture-and-storage" title="Learn more about carbon capture and storage from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbon capture and storage</a> (CCS) <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/science-and-technology" title="Learn more about technologies from ScienceDirect's AI-generated Topic Pages" class="topic-link">technologies</a> have been sought out (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib3" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib3"><span class="anchor-text">Abuelnoor et al., 2021</span></a>), a table summarizing the advantages and disadvantages and a flow chart categorizing these technologies is shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#tbl1" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="tbl1"><span class="anchor-text">Table 1</span></a><span> </span>and<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig1" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig1"><span class="anchor-text">Fig. 1</span></a>. CO<sub>2</sub><span> </span>separation and capture using membrane-based technologies (MBT) have been put under the spotlight as a potential candidate for large-scale CO<sub>2</sub><span> </span>capture systems. Given how energy-intensive thermal-based CO<sub>2</sub><span> </span>capture technologies are, which use energy as a mass separating agent, MBT offers a suitable alternative that can be incorporated in pre- and post-combustion stages of a CO<sub>2</sub><span> </span>emitting processes, given that maintaining the separating conditions for MBT (i.e., concentration or pressure difference), is far less energy intensive than thermal separation processes that require the addition of high amounts of energy (i.e., solvent boiling). Membranes that are used for CO<sub>2</sub><span> </span>capture have stringent requirements that need to be accounted for such as (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib69" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib69"><span class="anchor-text">Luis et al., 2012</span></a>).</p>
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0070">High CO<sub>2</sub><span> <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/selectivity" title="Learn more about selectivity from ScienceDirect's AI-generated Topic Pages" class="topic-link">selectivity</a></span></p>
</li>
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0075">Thermal stability (∼400<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-1-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="1.162ex" height="1.971ex" viewBox="0 -796.9 500.5 848.5" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-B0"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mo is="true">°</mo></mrow></math></span></span></span><span> </span>C)</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0080">Mechanical stability under high pressures (∼950 PSI)</p>
</li>
</ul>
<p></p>
<div class="tables frame-topbot colsep-0 rowsep-0" id="tbl1">
<p id="tspara0010"><span class="label">Table 1</span>.<span> </span>Carbon capture technologies - advantages and disadvantages.</p>
<span class="captions text-s"><span id="cap0140"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<td scope="col"><span class="screen-reader-only">Empty Cell</span></td>
<th scope="col">Advantages</th>
<th scope="col">Disadvantages</th>
<th scope="col">References</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<th class="align-left" scope="row">Clathrate Hydrate</th>
<td class="align-left">Can store large amounts of gas molecules such as methane, carbon dioxide and ethane</td>
<td class="align-left">Requires high pressures and low temperatures to reach a thermodynamically stable condition of operation (∼1.3 MPA at 273.8 K)</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib86" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib86"><span class="anchor-text">Nagashima et al. (2016)</span></a></td>
</tr>
<tr class="valign-top">
<th class="align-left" scope="row">Calcium Looping</th>
<td class="align-left">Usage of a cheap and environmentally sorbent<br>Has been successfully implemented in pilot-scale plants from 3 kW to 1.7 MW</td>
<td class="align-left">Carbonation and calcination steps are heavily dependent on the high temperature requirement<br>The deactivation of the sorbent material with the number of cycles that the particles undergo</td>
<td class="align-left">(<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib30" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib30"><span class="anchor-text">Coppola and Scala, 2020</span></a>)– (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib25" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib25"><span class="anchor-text">Cebrucean and Ionel, 2022</span></a>) (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib37" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib37"><span class="anchor-text">Dieter et al., 2015</span></a>)</td>
</tr>
<tr class="valign-top">
<th class="align-left" scope="row">Oxyfuel</th>
<td class="align-left">The flue gas produced consists mainly of CO<sub>2</sub><span> </span>and H<sub>2</sub>O which are easily separated.</td>
<td class="align-left">The high energy required to produce high-purity oxygen and the high temperature produced by combustion under the pure oxygen atmosphere</td>
<td class="align-left">(<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib4" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib4"><span class="anchor-text">Adams, 2014</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib83" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib83"><span class="anchor-text">Miller, 2017</span></a>)</td>
</tr>
</tbody>
</table>
</div>
</div>
<figure class="figure text-xs" id="fig1"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr1.jpg" height="290" alt="Fig. 1" aria-describedby="cap0010"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr1_lrg.jpg" target="_blank" download="" title="Download high-res image (467KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (467KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr1.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="fspara0010"><span class="label">Fig. 1</span>.<span> </span>CO<sub>2</sub><span> </span>capture technologies.</p>
<span class="captions text-s"><span id="cap0010"></span></span></figure>
</div>
<div>
<p id="p0085">MBT are traced back to the unit component of hollow fibers. To obtain asymmetric hollow fibers, polymer powders are dissolved in a solvent which is then extruded to form a bundle of hollow fibers. The hollow fibers are cooled off in a water bath to set their structure. After the hollow fibers are dried and rid of any excess solvent or water, they are woven into sheets of fabric, or onto a cylindrical tube for a modular structure integration (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib155" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib155"><span class="anchor-text">US Patent for Loom processing, 1997</span></a>), the process is shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig2" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig2"><span class="anchor-text">Fig. 2</span></a>. MBT have matured through stages of suitable polymer selection for gas separation, by studying the permeability and selectivity for different membrane materials that suit different gasses, the process of synthesizing the membrane material as well as the manufacturing of modules for practical applications. However, membrane treatments for pre- and post-usage require further investigations in research and development.</p>
<figure class="figure text-xs" id="fig2"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr2.jpg" height="388" alt="Fig. 2" aria-describedby="cap0015"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr2_lrg.jpg" target="_blank" download="" title="Download high-res image (458KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (458KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr2.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="fspara0015"><span class="label">Fig. 2</span>.<span> </span>Membrane for gas separation fabrication.</p>
<span class="captions text-s"><span id="cap0015"></span></span></figure>
</div>
<p id="p0090">MBT are used to separate CO<sub>2</sub><span> from natural gas and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/flue-gas" title="Learn more about flue gas from ScienceDirect's AI-generated Topic Pages" class="topic-link">flue gas</a> returns due to their low cost of operation (while maintaining a high capital cost due to the complexity of manufacturing of the membranes), flexibility as well as modularity, which is the ability to stack up multiple membranes to increase the surface area and the interface between different phases (gas-gas, gas-liquid). Moreover, MBT requires less chemicals in comparison with other technologies (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib26" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib26"><span class="anchor-text">Chen et al., 2022a</span></a>) as well as its ability to overcome thermodynamic limitations (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib147" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib147"><span class="anchor-text">Xing et al., 2021</span></a>). The utilization of MBT in pre-combustion stages has the aim of separating CO<sub>2</sub><span> </span>from a CO<sub>2</sub>/H<sub>2</sub><span> </span>mixture stream and has the advantage of being used parallel to a water-gas shift unit. Post-combustion separation deals with CO<sub>2</sub>/N<sub>2</sub><span> </span>mixture streams while other MBT applications require the separation of CO<sub>2</sub><span> </span>from CO<sub>2</sub>/CH<sub>4</sub><span> </span>mixture streams (natural gas feed stream separation). The way MBT works is that the membrane allows preferential permeation of a certain gas molecule or species while acting as a blocking layer for untargeted species, with different behaviors according to the technologies in question.</p>
<section id="sec2.1">
<h3 id="sectitle0045" class="u-h4 u-margin-m-top u-margin-xs-bottom">2.1.<span> </span>Membrane gas separation (MGS)</h3>
<div>
<p id="p0095">Membrane gas separation (MGS) is a pre-combustion technology, such as shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig3" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig3"><span class="anchor-text">Fig. 3</span></a><span> </span>that is utilized in various sectors including and not limited to the extraction of nitrogen from ambient air, hydrogen recovery from ammonia plants (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib120" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib120"><span class="anchor-text">Ramírez-Santos et al., 2018</span></a>) as well as hydrogen recovery from hydrocarbons used in petrochemical applications, organic vapor removal from air streams and CO<sub>2</sub><span> capture from natural <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/gas-streams" title="Learn more about gas streams from ScienceDirect's AI-generated Topic Pages" class="topic-link">gas streams</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib153" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib153"><span class="anchor-text">Membranes for Gas Separation, 2022</span></a>). In this technology of CO<sub>2</sub><span> </span>capture, a feed stream containing CO<sub>2</sub><span> </span>is flown adjacent to the membrane, where gas molecules are absorbed on one side of the dense membrane, diffuse across the membrane and finally desorb on the other side to a gas end phase, such as shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig4" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig4"><span class="anchor-text">Fig. 4</span></a>.</p>
<figure class="figure text-xs" id="fig3"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr3.jpg" height="654" alt="Fig. 3" aria-describedby="cap0020"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr3_lrg.jpg" target="_blank" download="" title="Download high-res image (418KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (418KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr3.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="fspara0020"><span class="label">Fig. 3</span>.<span> </span>Pre-combustion carbon capture.</p>
<span class="captions text-s"><span id="cap0020"></span></span></figure>
<figure class="figure text-xs" id="fig4"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr4.jpg" height="266" alt="Fig. 4" aria-describedby="cap0025"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr4_lrg.jpg" target="_blank" download="" title="Download high-res image (382KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (382KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr4.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="fspara0025"><span class="label">Fig. 4</span>.<span> </span>Membrane gas separation.</p>
<span class="captions text-s"><span id="cap0025"></span></span></figure>
</div>
<section id="sec2.1.1">
<h4 id="sectitle0050" class="u-margin-m-top u-margin-xs-bottom">2.1.1.<span> </span>Physical limitation and operation</h4>
<div>
<p id="p0100">Two main key parameters are considered for gas separation which are the permeability of a single species in the gas mixture and the separation factor (selectivity). These two parameters share a tradeoff relationship as the separation factor has been observed to decrease with the increase of the permeability (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib123" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib123"><span class="anchor-text">Robeson, 2008</span></a>). Which is why an upper boundary limit relationship is followed to classify and compare the performance of different membranes according to the permeability and the selectivity, which follows this equation (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib123" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib123"><span class="anchor-text">Robeson, 2008</span></a>):<span class="display"><span id="fd1" class="formula"><span class="label">(1)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-2-Frame" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"><svg xmlns:xlink="http://www.w3.org/1999/xlink" width="10.147ex" height="3.009ex" viewBox="0 -747.2 4368.8 1295.7" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHI-50"></use></g><g is="true" transform="translate(642,-150)"><use transform="scale(0.707)" xlink:href="#MJMATHI-69"></use></g></g><g is="true" transform="translate(1264,0)"><use xlink:href="#MJMAIN-3D"></use></g><g is="true" transform="translate(2320,0)"><use xlink:href="#MJMATHI-6B"></use></g><g is="true"></g><g is="true" transform="translate(3092,0)"><g is="true"><use xlink:href="#MJMATHI-3B1"></use></g><g is="true" transform="translate(640,352)"><use transform="scale(0.707)" xlink:href="#MJMATHI-6E"></use></g><g is="true" transform="translate(640,-304)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHI-69"></use></g><g is="true" transform="translate(244,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-6A"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mi is="true">�</mi><mi is="true">�</mi></msub><mo linebreak="badbreak" is="true">=</mo><mi is="true">�</mi><mspace width="0.25em" is="true"></mspace><msubsup is="true"><mi is="true">�</mi><mrow is="true"><mi is="true">�</mi><mi is="true">�</mi></mrow><mi is="true">�</mi></msubsup></mrow></math></span></span></span></span></span>Where P<sub>i</sub><span> </span>is the permeability of the targeted species, k is the front factor,<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-3-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="1.488ex" height="1.394ex" viewBox="0 -498.8 640.5 600.2" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMATHI-3B1"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi is="true">�</mi></mrow></math></span></span></span><span> </span>is the selectivity, and n is the slope of the resultant log-log graph (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib123" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib123"><span class="anchor-text">Robeson, 2008</span></a>), just as shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig5" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig5"><span class="anchor-text">Fig. 5</span></a>.</p>
<figure class="figure text-xs" id="fig5"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr5.jpg" height="363" alt="Fig. 5" aria-describedby="cap0030"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr5_lrg.jpg" target="_blank" download="" title="Download high-res image (1MB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (1MB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr5.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="fspara0030"><span class="label">Fig. 5</span>.<span> </span>CO<sub>2</sub><span> </span>upper bound limit plot (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib123" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib123"><span class="anchor-text">Robeson, 2008</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib115" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib115"><span class="anchor-text">Park et al., 2007</span></a>), data adapted from (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib115" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib115"><span class="anchor-text">Park et al., 2007</span></a>) – Alpha: represents the CO<sub>2</sub><span> </span>selectivity.</p>
<span class="captions text-s"><span id="cap0030"></span></span></figure>
</div>
<p id="p0105"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig5" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig5"><span class="anchor-text">Fig. 5</span></a><span> </span>shows the relationship between the permeability of CO<sub>2</sub><span> (log-scale X-axis) and the selectivity of the membrane (log-scale Y-axis) and it shows the tradeoff between increasing one side and the effect it bears on the other. Having a largely permeable membrane arrangement decreases the selectivity and the purity of the output stream of the membrane. It is also observed that through development of membrane materials for gas separation applications, the upper bound limit has been shifted slightly upwards, leaving room for membranes to attain both better permeability and selectivity. What the upper bound limit also indicates, is that for a specific material and a given selectivity, the permeability can be increased to right of the X-axis until it reaches the upper bound limit, where it is no longer physically possible for that given selectivity, and vice versa. An ideal position on the graph would be on the right-middle region of the canvas on the boundaries of the upper bound limit. Additionally, there are membrane materials that have facilitated the surpassing of the Robenson upper bound limit, such as thermally rearranged polymers. It is noted that these polymers are fabricated by in-situ thermal conversion of <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/polyimide" title="Learn more about polyimides from ScienceDirect's AI-generated Topic Pages" class="topic-link">polyimides</a> with ortho-functional groups. Thermally rearranged polymers suffer from the incapability of being processed, however their precursors are easily dissolved in organic solvents, which allows for their fabrication into hollow fibers/membranes. These membranes are thermally, mechanically, and chemically stable, along with lucrative gas separation abilities (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib60" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib60"><span class="anchor-text">Kim and Lee, 2012</span></a>).</p>
</section>
<section id="sec2.1.2">
<h4 id="sectitle0055" class="u-margin-m-top u-margin-xs-bottom">2.1.2.<span> </span>Applications</h4>
<div>
<p id="p0110">There are various materials that have been synthesized for CO<sub>2</sub><span> capture. Polymer of Intrinsic <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/microporosity" title="Learn more about Microporosity from ScienceDirect's AI-generated Topic Pages" class="topic-link">Microporosity</a> (PIM-1) is a polymer that can be synthesized at both high temperature and short time (∼180 °C – 2 h) or low temperature long time (∼70 °C–96 h) (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib51" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib51"><span class="anchor-text">He et al., 2022</span></a>)– (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib24" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib24"><span class="anchor-text">BUDD et al., 2008</span></a>),<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib41" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib41"><span class="anchor-text">Foster et al., 2020</span></a>, which strongly affects the molecular weight and chain packing that influences the gas permeability and selectivity of the fabricated membrane. PIM-1 can be incorporated with additives such as a metal-organic framework (MOF) nanosheets, due to their good porosity and crystalline structure, to form a mixed matrix membrane (MMM) (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib150" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib150"><span class="anchor-text">Zhang et al., 2019</span></a><span>). MOF is an organic-inorganic hybrid crystalline porous material which comprises of <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/metal-ion" title="Learn more about metal ions from ScienceDirect's AI-generated Topic Pages" class="topic-link">metal ions</a> that are surrounded by organic molecules (linkers) (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib154" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib154"><span class="anchor-text">MOF Metal Organic Framework, 2022</span></a>), and due to its high surface area, high CO<sub>2</sub><span> </span>uptake and porosity, it facilitates a good CO<sub>2</sub><span> </span>separation, with a wide variety of materials that can be used (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib5" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib5"><span class="anchor-text">Ahmad et al., 2018</span></a>)– (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib66" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib66"><span class="anchor-text">Li et al., 2021a</span></a>). Carbon based membranes (carbon hollow fibers (CHF)) are also used for CO<sub>2</sub><span> </span>gas separation due to their high permeability and selectivity in comparison to other present MOF-based technologies (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib10" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib10"><span class="anchor-text">Ali et al., 2019</span></a>)– (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib62" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib62"><span class="anchor-text">Lei et al., 2020</span></a>). PIM-1-based membranes maintained high permeability values at high and low pressures, and a higher CO<sub>2</sub><span> </span>selectivity for CO<sub>2</sub>/N<sub>2</sub><span> </span>and a relatively lower selectivity for CO<sub>2</sub>/CH<sub>4</sub><span> </span>mixtures as shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#tbl2" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="tbl2"><span class="anchor-text">Table 2</span></a>. Moreover, MOF-based membranes showed better CO<sub>2</sub><span> </span>selectivity performances at both low and high pressures ranging from 100 to 800 at 0 bar and 100–400 at 40 bar. Carbon molecular sieves (CMS) show a relatively higher selectivity for CO<sub>2</sub><span> </span>in a CO<sub>2</sub>/CH<sub>4</sub><span> </span>mixture, however at the cost of temperatures reaching 1000<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-4-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="1.162ex" height="1.971ex" viewBox="0 -796.9 500.5 848.5" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-B0"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mo is="true">°</mo></mrow></math></span></span></span><span> </span>C.</p>
<div class="tables frame-topbot colsep-0 rowsep-0" id="tbl2">
<p id="tspara0015"><span class="label">Table 2</span>.<span> </span>CO<sub>2</sub><span> </span>permeability and selectivity results for different membrane gas separation technologies and feed gasses.</p>
<span class="captions text-s"><span id="cap0145"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col">Membrane</th>
<th scope="col">Gas Mixture</th>
<th scope="col">CO<sub>2</sub><span> </span>Selectivity</th>
<th scope="col">CO<sub>2</sub><span> </span>Permeability (GPU)</th>
<th scope="col">References</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">PIM-1</td>
<td class="align-left" rowspan="3">–</td>
<td class="align-left" rowspan="3">–</td>
<td class="align-left">7510<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-5-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 12.6px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="1.808ex" height="1.987ex" viewBox="0 -740.1 778.5 855.6" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-B1"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mo linebreak="goodbreak" linebreakstyle="after" is="true">±</mo></mrow></math></span></span></span><span> </span>200</td>
<td class="align-left" rowspan="3"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib17" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib17"><span class="anchor-text">Balçık et al. (2021)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">PIM-1 22% DMAc</td>
<td class="align-left">7510<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-6-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 12.6px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="1.808ex" height="1.987ex" viewBox="0 -740.1 778.5 855.6" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-B1"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mo linebreak="goodbreak" linebreakstyle="after" is="true">±</mo></mrow></math></span></span></span><span> </span>200</td>
</tr>
<tr class="valign-top">
<td class="align-left">PIM-1 33% DMAc</td>
<td class="align-left">9530<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-7-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 12.6px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="1.808ex" height="1.987ex" viewBox="0 -740.1 778.5 855.6" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-B1"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mo linebreak="goodbreak" linebreakstyle="after" is="true">±</mo></mrow></math></span></span></span><span> </span>110</td>
</tr>
<tr class="valign-top">
<td class="align-left">PIM-1</td>
<td class="align-left">N<sub>2</sub>/CO<sub>2</sub></td>
<td class="align-left">10@0 bar - ∼40@50 bar</td>
<td class="align-left">7000 @ 0 bar - 5000@50 bar</td>
<td class="align-left" rowspan="4"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib118" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib118"><span class="anchor-text">Pu et al. (2022)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">NUS-8-NH<sub>2</sub>/PIM-1 13.2% loading</td>
<td class="align-left">N<sub>2</sub>/CO<sub>2</sub></td>
<td class="align-left">20@ 0 bar - ∼40 @ 50 bar</td>
<td class="align-left">10,000@0 bar - 7000@50 bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">PIM-1</td>
<td class="align-left">CH<sub>4</sub>/CO<sub>2</sub></td>
<td class="align-left">13@0 bar - 6@50 bar</td>
<td class="align-left">∼6000 @ 0 bar - 2000@ 50 bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">NUS-8-NH<sub>2</sub>/PIM-1 13.2% loading</td>
<td class="align-left">CH<sub>4</sub>/CO<sub>2</sub></td>
<td class="align-left">13@0 bar - 7@ 50 bar</td>
<td class="align-left">11,000@0 bar- 6000 @ 50 bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">PIM-1-MOF-74-Ni based TFC (wt% 5 and 20)</td>
<td class="align-left">N<sub>2</sub>/CO<sub>2</sub></td>
<td class="align-left">34–20</td>
<td class="align-left">4600–6000</td>
<td class="align-left" rowspan="2"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib68" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib68"><span class="anchor-text">Liu et al. (2020)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">PIM-1-NH2-UiO-66 based TFC (wt% 5 and 20)</td>
<td class="align-left">N<sub>2</sub>/CO<sub>2</sub></td>
<td class="align-left">30–17</td>
<td class="align-left">4900–8200</td>
</tr>
<tr class="valign-top">
<td class="align-left">PIM-1/Matrimid (10:90)<br>Bore fill (95/5 N-methyl-2-pyrrolidone (NMP)/Water</td>
<td class="align-left">CH<sub>4</sub>/CO<sub>2</sub></td>
<td class="align-left">20.1</td>
<td class="align-left">277</td>
<td class="align-left" rowspan="2"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib149" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib149"><span class="anchor-text">Yong et al. (2013)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">PIM-1/Matrimid (10:90)<br>Bore fill (80/20 (NMP)/Water)</td>
<td class="align-left">CH<sub>4</sub>/CO<sub>2</sub></td>
<td class="align-left">21.5</td>
<td class="align-left">11.3</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="2">Ni-4PyC (MOF)</td>
<td class="align-left">80H<sub>2</sub>/20CO<sub>2</sub></td>
<td class="align-left">300@10 bar–250@40 bar</td>
<td class="align-left" rowspan="2">–</td>
<td class="align-left" rowspan="2"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib87" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib87"><span class="anchor-text">Nandi et al. (2015)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">60H<sub>2</sub>/50CO<sub>2</sub></td>
<td class="align-left">250@10 bar–200@40 bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">Mg<sub>2</sub><span> </span>(dobdc)</td>
<td class="align-left" rowspan="5">80H<sub>2</sub>/20CO<sub>2</sub></td>
<td class="align-left">800@0 bar–400@ 40 bar</td>
<td class="align-left" rowspan="5">–</td>
<td class="align-left" rowspan="5"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib52" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib52"><span class="anchor-text">Herm et al. (2011)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Cu-BTTri</td>
<td class="align-left">100@0 bar–100@40 bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">MOF-177</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="mailto:7.5@0bar" target="_blank" rel="noreferrer noopener"><span class="anchor-text">7.5@0bar</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a>–<a class="anchor u-display-inline anchor-paragraph" href="mailto:7.5@40" target="_blank" rel="noreferrer noopener"><span class="anchor-text">7.5@40</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a><span> </span>bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">Co(BDP)</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="mailto:2.5@0bar" target="_blank" rel="noreferrer noopener"><span class="anchor-text">2.5@0bar</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a>–<a class="anchor u-display-inline anchor-paragraph" href="mailto:7.5@40" target="_blank" rel="noreferrer noopener"><span class="anchor-text">7.5@40</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a><span> </span>bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">Be-BTB</td>
<td class="align-left">5@0 bar–5@40 bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">SBFDA-DMN (Carbon Molecular Sieve) Membrane</td>
<td class="align-left">CO<sub>2</sub>/CH<sub>4</sub></td>
<td class="align-left">14.4</td>
<td class="align-left">4700</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib72" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib72"><span class="anchor-text">Ma et al. (2015)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="2">SBFDA-DMN - Different Pyrolysisi Temperatures for CMS formation</td>
<td class="align-left">CO<sub>2</sub>/CH<sub>4</sub></td>
<td class="align-left">21@ 550 C<br>1475@1000C</td>
<td class="align-left">1500@550<br>30@1000c</td>
<td class="align-left" rowspan="2"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib48" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib48"><span class="anchor-text">Hazazi et al. (2019)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">He/CO<sub>2</sub></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="mailto:0.3@550" target="_blank" rel="noreferrer noopener"><span class="anchor-text">0.3@550</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a><br><a class="anchor u-display-inline anchor-paragraph" href="mailto:3.25@1000" target="_blank" rel="noreferrer noopener"><span class="anchor-text">3.25@1000</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a></td>
<td class="align-left">–</td>
</tr>
<tr class="valign-top">
<td class="align-left">CHF (Carbon hollow fiber)</td>
<td class="align-left" rowspan="2">CO<sub>2</sub>/CH<sub>4</sub></td>
<td class="align-left">6</td>
<td class="align-left">1.5E-04</td>
<td class="align-left" rowspan="2"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib46" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib46"><span class="anchor-text">Haider et al. (2018)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">MCHF (Modifiied “pore tailored")</td>
<td class="align-left">249</td>
<td class="align-left">7.748</td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</section>
</section>
<section id="sec2.2">
<h3 id="sectitle0060" class="u-h4 u-margin-m-top u-margin-xs-bottom">2.2.<span> </span>Membrane contactor (MC)</h3>
<div>
<p id="p0115">A membrane contactor (MC) is mostly a post-combustion-based technology, such as shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig6" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig6"><span class="anchor-text">Fig. 6</span></a><span>, which separates gaseous and liquid phase materials and provides a higher surface area to promote a better mass transfer between the two. It is a highly flexible technology due to the freedom in controlling the flowrates of both the gas and liquid (absorbent) that are separated. MC also provides a controllable interfacial area that can be modified according to each application. As the case in MGS, MC can also be modulated for more demanding processes and to accommodate scaling-up requirements. Chemical, thermal and mechanical stabilities are essential to maintain high performance and ensure the longevity of the membrane that is used. Given that this membrane is utilized in a wet environment (an absorber in the liquid phase), the membrane material must have a high level of <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/hydrophobicity" title="Learn more about hydrophobicity from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrophobicity</a>. According to (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib135" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib135"><span class="anchor-text">Siagian et al., 2019</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib96" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib96"><span class="anchor-text">Nieminen et al., 2020</span></a><span>), polytetrafluorethylene (PTFE), <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/vinylidene" title="Learn more about polyvinylidene from ScienceDirect's AI-generated Topic Pages" class="topic-link">polyvinylidene</a> fluoride (PVDF), Polyethersulfone (PES) and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/polypropylene" title="Learn more about polypropylene from ScienceDirect's AI-generated Topic Pages" class="topic-link">polypropylene</a> (PP), are desirable materials for membranes in MC applications. The process for MC CO</span><sub>2</sub><span> </span>capture is shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig7" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig7"><span class="anchor-text">Fig. 7</span></a></p>
<figure class="figure text-xs" id="fig6"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr6.jpg" height="506" alt="Fig. 6" aria-describedby="cap0035"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr6_lrg.jpg" target="_blank" download="" title="Download high-res image (374KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (374KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr6.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="fspara0035"><span class="label">Fig. 6</span>.<span> </span>Post-combustion carbon capture.</p>
<span class="captions text-s"><span id="cap0035"></span></span></figure>
<figure class="figure text-xs" id="fig7"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr7.jpg" height="295" alt="Fig. 7" aria-describedby="cap0040"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr7_lrg.jpg" target="_blank" download="" title="Download high-res image (429KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (429KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr7.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="fspara0040"><span class="label">Fig. 7</span>.<span> </span>Membrane contactor CO<sub>2</sub><span> </span>capture.</p>
<span class="captions text-s"><span id="cap0040"></span></span></figure>
</div>
<section id="sec2.2.1">
<h4 id="sectitle0065" class="u-margin-m-top u-margin-xs-bottom">2.2.1.<span> </span>Physical operation and applications</h4>
<p id="p0120">The two parameters that define the membrane in such a system are the pore size and porosity. Moreover, given that the main focus of this technology is to separate a specific species of gas in a gas mixture through its permeation within the membrane, the pores of the membrane must be hydrophobic, to not elevate the values of mass transfer resistance and to allow for a better gas/absorbent mass transfer at the pores’ boundaries. The mass transfer of CO<sub>2</sub><span> </span>is given in the following equation (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib69" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib69"><span class="anchor-text">Luis et al., 2012</span></a>):<span class="display"><span id="fd2" class="formula"><span class="label">(2)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-8-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="28.601ex" height="3.009ex" viewBox="0 -796.9 12314.2 1295.7" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHI-4E"></use></g><g is="true" transform="translate(803,-155)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHI-43"></use></g><g is="true" transform="translate(537,0)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHI-4F"></use></g><g is="true" transform="translate(539,-107)"><use transform="scale(0.5)" xlink:href="#MJMAIN-32"></use></g></g></g></g><g is="true" transform="translate(2579,0)"><use xlink:href="#MJMAIN-3D"></use></g><g is="true" transform="translate(3636,0)"><g is="true"><use xlink:href="#MJMATHI-4B"></use></g><g is="true" transform="translate(849,-155)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHI-4F"></use></g><g is="true" transform="translate(539,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-76"></use></g><g is="true" transform="translate(883,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-65"></use></g><g is="true" transform="translate(1213,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-72"></use></g><g is="true" transform="translate(1532,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-61"></use></g><g is="true" transform="translate(1906,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-6C"></use></g><g is="true" transform="translate(2117,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-6C"></use></g></g></g><g is="true" transform="translate(7136,0)"><use xlink:href="#MJMAIN-D7"></use></g><g is="true" transform="translate(8137,0)"><use xlink:href="#MJMAIN-394"></use></g><g is="true" transform="translate(8970,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHI-43"></use></g><g is="true" transform="translate(715,-155)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHI-43"></use></g><g is="true" transform="translate(537,0)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHI-4F"></use></g><g is="true" transform="translate(539,-107)"><use transform="scale(0.5)" xlink:href="#MJMAIN-32"></use></g></g></g></g><g is="true" transform="translate(2214,-297)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2C"></use></g><g is="true" transform="translate(196,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-6C"></use></g><g is="true" transform="translate(408,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-6D"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mi is="true">�</mi><mrow is="true"><mi is="true">�</mi><msub is="true"><mi is="true">�</mi><mn is="true">2</mn></msub></mrow></msub><mo linebreak="badbreak" is="true">=</mo><msub is="true"><mi is="true">�</mi><mrow is="true"><mi is="true">�</mi><mi is="true">�</mi><mi is="true">�</mi><mi is="true">�</mi><mi is="true">�</mi><mi is="true">�</mi><mi is="true">�</mi></mrow></msub><mo linebreak="goodbreak" is="true">×</mo><mo is="true">Δ</mo><msub is="true"><msub is="true"><mi is="true">�</mi><mrow is="true"><mi is="true">�</mi><msub is="true"><mi is="true">�</mi><mn is="true">2</mn></msub></mrow></msub><mrow is="true"><mo is="true">,</mo><mi is="true">�</mi><mi is="true">�</mi></mrow></msub></mrow></math></span></span></span></span></span>Where 1/k<sub>Overall</sub><span> </span>is the overall mass transfer resistance, and<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-9-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="9.32ex" height="2.548ex" viewBox="0 -796.9 4012.8 1096.9" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-394"></use></g><g is="true" transform="translate(833,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHI-43"></use></g><g is="true" transform="translate(715,-155)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHI-43"></use></g><g is="true" transform="translate(537,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-4F"></use></g><g is="true" transform="translate(1077,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(2247,-207)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHI-6C"></use></g><g is="true" transform="translate(211,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-6D"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mo is="true">Δ</mo><msub is="true"><msub is="true"><mi is="true">�</mi><mrow is="true"><mi is="true">�</mi><mi is="true">�</mi><mn is="true">2</mn></mrow></msub><mrow is="true"><mi is="true">�</mi><mi is="true">�</mi></mrow></msub></mrow></math></span></span></span><span> </span>is the logarithmic mean difference of the concentrations of CO<sub>2</sub><span> </span>entering and leaving the MC.</p>
<div>
<p id="p0125">Contrary to MSG technologies, the selectivity that controls the separation of a certain species over the other has no relation to the membrane material, rather than the properties of the absorbent that is used. Furthermore, given that this technology is mainly used in post-combustion processes, the transition of the CO<sub>2</sub><span> </span>molecules from the gas stream to the absorbent stream does not drastically affect the flow rate of the flue gas.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#tbl3" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="tbl3"><span class="anchor-text">Table 3</span></a><span> </span>shows the effect of MC material, absorbent, gas flow rate and liquid flow rate on the CO<sub>2</sub><span> </span>removal efficiency. PTFE-based MC achieved CO<sub>2</sub><span> removal efficiencies bordering 98% with water-based solvents, whereas it reached efficiencies as close to 99.97% with the utilization of <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/ionic-liquid" title="Learn more about ionic liquids from ScienceDirect's AI-generated Topic Pages" class="topic-link">ionic liquids</a> (IL) within the water solvent, and deep euticitc solvents (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib127" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib127"><span class="anchor-text">Saeed et al., 2021</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib55" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib55"><span class="anchor-text">Ishaq et al., 2020</span></a>). PVDF, PES, PP and commercial ceramic membranes (CCM) harbor eficiencies of 98–99%.</p>
<div class="tables frame-topbot colsep-0 rowsep-0" id="tbl3">
<p id="tspara0020"><span class="label">Table 3</span>.<span> </span>CO<sub>2</sub><span> </span>removal efficiencies based on different factors.</p>
<span class="captions text-s"><span id="cap0150"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col">MC</th>
<th scope="col">Gas Mixture</th>
<th scope="col">Absorbent</th>
<th scope="col">CO<sub>2</sub><span> </span>Removal Efficiency</th>
<th scope="col">Gas Flow Rate</th>
<th scope="col">Liquid Flow Rate</th>
<th scope="col">References</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left" rowspan="3">PTFE Hollow fiber membrane contactor (HFMC)</td>
<td class="align-left" rowspan="3">80 N<sub>2</sub>:20 CO<sub>2</sub></td>
<td class="align-left" rowspan="3">0.8–2 M NaOH – water</td>
<td class="align-left">Up to 90.8%</td>
<td class="align-left">–</td>
<td class="align-left" rowspan="2">–</td>
<td class="align-left" rowspan="3"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib125" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib125"><span class="anchor-text">Ruan et al. (2022)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">88.36%–57.99%</td>
<td class="align-left">0.2–0.8 L/min</td>
</tr>
<tr class="valign-top">
<td class="align-left">70.11%–74.55%</td>
<td class="align-left">–</td>
<td class="align-left">20–200 ml/min</td>
</tr>
<tr class="valign-top">
<td></td>
<td class="align-left" rowspan="25">85 N<sub>2</sub>:15 CO<sub>2</sub></td>
<td class="align-left">ILs in water 50:50 vol/vol</td>
<td colspan="3"></td>
<td class="align-left" rowspan="25"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib59" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib59"><span class="anchor-text">Khan Swati et al. (2022)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="6">PTFE</td>
<td class="align-left">[EMIM][EtSO4]</td>
<td class="align-left">84.67%</td>
<td class="align-left" rowspan="24">–</td>
<td class="align-left" rowspan="24">–</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][Ac]</td>
<td class="align-left">84.81%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][TFA]</td>
<td class="align-left">92.64%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][TF2N]</td>
<td class="align-left">94.06%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[BMIM][BF6]</td>
<td class="align-left">98.9%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[OMIM][BF4]</td>
<td class="align-left">99.97%</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="6">PVDF</td>
<td class="align-left">[EMIM][EtSO4]</td>
<td class="align-left">84.86%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][Ac]</td>
<td class="align-left">88.39%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][TFA]</td>
<td class="align-left">92.86%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][TF2N]</td>
<td class="align-left">94.21%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[BMIM][BF6]</td>
<td class="align-left">99.2%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[OMIM][BF4]</td>
<td class="align-left">99.67%</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="6">PES</td>
<td class="align-left">[EMIM][EtSO4]</td>
<td class="align-left">82.79%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][Ac]</td>
<td class="align-left">87.19%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][TFA]</td>
<td class="align-left">93.16%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][TF2N]</td>
<td class="align-left">94.5%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[BMIM][BF6]</td>
<td class="align-left">98.53%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[OMIM][BF4]</td>
<td class="align-left">98.79%</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="6">PP</td>
<td class="align-left">[EMIM][EtSO4]</td>
<td class="align-left">80.83%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][Ac]</td>
<td class="align-left">85.2%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][TFA]</td>
<td class="align-left">89.73%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[EMIM][TF2N]</td>
<td class="align-left">93.02%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[BMIM][BF6]</td>
<td class="align-left">97.59%</td>
</tr>
<tr class="valign-top">
<td class="align-left">[OMIM][BF4]</td>
<td class="align-left">99.08%</td>
</tr>
<tr class="valign-top">
<td class="align-left">PTFE</td>
<td class="align-left">60 CH<sub>4</sub>:40 CO<sub>2</sub></td>
<td class="align-left">Water</td>
<td class="align-left">98.12%</td>
<td class="align-left">Gas Velocity 0.093 m/s</td>
<td class="align-left">Liquid Velocity 0.034 m/s</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib67" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib67"><span class="anchor-text">Li et al. (2021b)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">PP</td>
<td class="align-left">Air + 2% H<sub>2</sub>S + 2% CO<sub>2</sub></td>
<td class="align-left">NaOH in water</td>
<td class="align-left">100%–10% for 0 and 1 saturation levels</td>
<td class="align-left">–</td>
<td class="align-left">–</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib116" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib116"><span class="anchor-text">Petukhov et al. (2022)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="6">Commercial Ceramic Membrane</td>
<td class="align-left" rowspan="6">80 N2:20 CO<sub>2</sub></td>
<td class="align-left" rowspan="6">Monoethanolamine</td>
<td class="align-left">98%</td>
<td class="align-left">8 L/min</td>
<td class="align-left" rowspan="3">200 L/min</td>
<td class="align-left" rowspan="6"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib151" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib151"><span class="anchor-text">Zhang et al. (2021)</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">65%</td>
<td class="align-left">12.5 L/min</td>
</tr>
<tr class="valign-top">
<td class="align-left">87%</td>
<td class="align-left">13.5 L/min</td>
</tr>
<tr class="valign-top">
<td class="align-left">87%</td>
<td class="align-left" rowspan="3">13.5 L/min</td>
<td class="align-left">200 L/min</td>
</tr>
<tr class="valign-top">
<td class="align-left">97%</td>
<td class="align-left">325 L/min</td>
</tr>
<tr class="valign-top">
<td class="align-left">98%</td>
<td class="align-left">450 L/min</td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</section>
</section>
</section>
<section id="sec3">
<h2 id="sectitle0070" class="u-h4 u-margin-l-top u-margin-xs-bottom">3.<span> </span>Challenges faced by carbon capture using membrane technologies</h2>
<div>
<p id="p0130">The challenges that are faced by membranes that hold back their commercialization and hinders the optimum quality of their application in carbon capture systems are summarized into three categories, economic and financial, technical, and social, which are summarized in the following section (see<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig8" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig8"><span class="anchor-text">Fig. 8</span></a>).</p>
<figure class="figure text-xs" id="fig8"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr8.jpg" height="353" alt="Fig. 8" aria-describedby="cap0045"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr8_lrg.jpg" target="_blank" download="" title="Download high-res image (850KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (850KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr8.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="fspara0045"><span class="label">Fig. 8</span>.<span> </span>Economic, technical and social challenges that are posed for membrane CO2 capture technologies (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib69" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib69"><span class="anchor-text">Luis et al., 2012</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib135" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib135"><span class="anchor-text">Siagian et al., 2019</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib132" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib132"><span class="anchor-text">Scholes, 2020</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib40" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib40"><span class="anchor-text">Favre, 2011</span></a>).</p>
<span class="captions text-s"><span id="cap0045"></span></span></figure>
</div>
<section id="sec3.1">
<h3 id="sectitle0075" class="u-h4 u-margin-m-top u-margin-xs-bottom">3.1.<span> </span>Economic and financial</h3>
<p id="p0135"><span>There is a physical tradeoff between the <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/selectivity" title="Learn more about selectivity from ScienceDirect's AI-generated Topic Pages" class="topic-link">selectivity</a> and permeability in MGS-based carbon capture, which affects the overall economics of the system. Additionally, the permeability and selectivity of the membrane determines the area required for the membrane which directly affects the cost at large-scale implementation of this technology. Moreover, a phenomenon known as plasticization, which is a membrane pore swelling, halts the operation of MGS are requires costly substitutions of the membrane stack (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib69" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib69"><span class="anchor-text">Luis et al., 2012</span></a>). A stable MC operation is dictated by the solvent membrane interaction and their compatibility, otherwise an imminent wetting of the membrane occurs that demands a substitution of both components. Similarly, fouling which is the accumulation of dust and contaminants (i.e., flue gasses), also requires the substitution of the membrane (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib132" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib132"><span class="anchor-text">Scholes, 2020</span></a>).</p>
</section>
<section id="sec3.2">
<h3 id="sectitle0080" class="u-h4 u-margin-m-top u-margin-xs-bottom">3.2.<span> </span>Technical</h3>
<p id="p0140">The permeability and selectivity tradeoff arises as a barrier in the context of dictating the operating levels of the overall inlet and outlet of the system (pressure difference applied). Additionally, plasticization limits the choices of membrane materials as this selection must be optimized to accommodate certain applications based on the corrosivity of the environment and the mixture of the gas (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib69" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib69"><span class="anchor-text">Luis et al., 2012</span></a><span>). However, it is worthy to note that the fabrication of S-PEEKM-based membranes which are made from the direct polymerization of sulfonated <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/monomer" title="Learn more about monomers from ScienceDirect's AI-generated Topic Pages" class="topic-link">monomers</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib57" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib57"><span class="anchor-text">Khan et al., 2011a</span></a>), have shown excellent anti-plasticization properties with superior gas separation performances (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib58" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib58"><span class="anchor-text">Khan et al., 2011b</span></a>). Moreover, in an MC operation, the solvent/membrane interactions have to be chemically stable and must go through an optimization process for a smooth operation. fouling treatment techniques must be developed and regular maintenance of the membrane material is required (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib132" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib132"><span class="anchor-text">Scholes, 2020</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib40" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib40"><span class="anchor-text">Favre, 2011</span></a>).</p>
</section>
<section id="sec3.3">
<h3 id="sectitle0085" class="u-h4 u-margin-m-top u-margin-xs-bottom">3.3.<span> </span>Social</h3>
<p id="p0145">In an MGS pre-combustion operation, the selectivity of the membrane determines the loss of important gas species such as CH<sub>4</sub><span> </span>in a gas mixture with CO<sub>2</sub>, as the tradeoff between the permeability and selectivity will hinder the quality of the fuel (CH<sub>4</sub>) which will adversely affect the environment (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib69" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib69"><span class="anchor-text">Luis et al., 2012</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib123" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib123"><span class="anchor-text">Robeson, 2008</span></a>). Similarly, plasticization hinders the quality of the CO<sub>2</sub><span> <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/gas-purification" title="Learn more about gas purification from ScienceDirect's AI-generated Topic Pages" class="topic-link">gas purification</a> process over time (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib135" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib135"><span class="anchor-text">Siagian et al., 2019</span></a>). On the other hand, in MC applications commonly used solvents pose health and safety hazards for both the environment and the people involved in the operating plants such as mono-chlorobenzene (CB) and dimethylformamide (DMF) (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib69" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib69"><span class="anchor-text">Luis et al., 2012</span></a>)., (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib40" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib40"><span class="anchor-text">Favre, 2011</span></a>)</p>
</section>
</section>
<section id="sec4">
<h2 id="sectitle0090" class="u-h4 u-margin-l-top u-margin-xs-bottom">4.<span> </span>Role of membrane-based carbon capture technologies in achieving the sustainable development goals (SDGs)</h2>
<p id="p0150">The following section discusses in detail the positive or negative contributions of membrane-based carbon capture technologies to the 17 SDGs.</p>
<section id="sec4.1">
<h3 id="sectitle0095" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.1.<span> </span>SDG 1 “no poverty”</h3>
<p id="p0155">It was estimated that about 10% of the population was living in poverty in 2015. However, after the recent COVID-19 pandemic it was evident that the number of people living in severe poverty will increase. Hence, nowadays more than 10% of the global population is suffering from severe poverty. That is more than 700,000 people are incapable of meeting their basic needs in life such as education, health, and food. Around 17.2% of these people are living in rural areas where people earn a living of less than 1.90$ per day. As a result, 8% of the people with low income are struggling with extreme poverty. It was reported that one child out of five children suffers from severe poverty. Consequently, in order to protect these children, global poverty must be reduced. In the past, the number of people living in extreme poverty decreased from 36% to 10% of the global population. This reduction indicates that it is possible to significantly reduce global poverty (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib88" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib88"><span class="anchor-text">Nationsa</span></a>). For this reason, SDG 1 has been directed to end worldwide poverty in all its forms everywhere by the year 2030 (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib111" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib111"><span class="anchor-text">Oliveira et al., 2022</span></a>). SDG 1 is associated with several targets, where each target is allocated with multiple indicators. These indicators provide guidance on how to accomplish each target related to SDG 1.</p>
<p id="p0160">Membrane-based carbon capture can bestow numerous advantages by capturing the CO<sub>2</sub><span> </span>in the atmosphere and combatting climate change. Nevertheless, it is not feasible to deploy carbon capture technologies in underdeveloped and developing countries with low incomes. According to target 1.3 which focuses on nationally appropriate social protection systems and measures for all, it is only possible to deploy nationally suitable social protection systems. Hence, it is not appropriate to employ carbon capture technologies in such countries where they cannot afford the high costs associated with the development and implementation of these technologies. However, there are other positive aspects to the deployment of carbon capture technologies on the poverty levels in developing countries. The development and implementation of carbon capture technologies require large sums of money which can be externally financed. This, in return, allows for the development of innovative energy solutions without any incurred costs (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib109" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib109"><span class="anchor-text">Olfe-Kräutlein, 2020a</span></a>). On the other hand, the deployment of such technologies in developed countries might indirectly deter the goal of ending worldwide poverty. This occurs as these technologies evolve and advance in developed countries which in return might strengthen the current level of global poverty (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib38" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib38"><span class="anchor-text">Dollar, 1993</span></a>).</p>
<p id="p0165"><span>Job creation is one of the significant advantages carbon capture projects provide. As huge investments and finances are offered for deploying carbon capture projects, more job opportunities will be available. Hence, carbon capture technologies reduce unemployment levels and improve human well-being. Based on the International Energy Agency (IEA), by the year 2050, around 2000 carbon capture storage plants need to be built to combat the increasing <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/carbon-dioxide-emission" title="Learn more about carbon emissions from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbon emissions</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib22" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib22"><span class="anchor-text">Birol, 2010</span></a>)– (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib56" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib56"><span class="anchor-text">Jarraud and Steiner, 2012</span></a>). The construction, operation, and development of these plants will require around 100,000 employees by the year 2050. Jobs related to logistics and transportation, material and machine supplies, and various other jobs will be created. These jobs will eventually substantially reduce the unemployment rate and decrease poverty (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib107" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib107"><span class="anchor-text">Olabi et al., 2022d</span></a>). Moreover, according to<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib142" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib142"><span class="anchor-text">Turner et al. (2021)</span></a>, the development of carbon capture technologies and facilities will add 1.8 billion dollars in GDP per year and create around 17,000 jobs in the UK (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib142" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib142"><span class="anchor-text">Turner et al., 2021</span></a>).</p>
</section>
<section id="sec4.2">
<h3 id="sectitle0100" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.2.<span> </span>SDG 2 “zero hunger”</h3>
<p id="p0170"><span>Frequently, carbon capture products in the industrial processes are not engaged directly in the production of food and the difficulties associated with it, as demonstrated by SDG 2. However, the following applications lead to increasing impact on <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/food-production" title="Learn more about food production from ScienceDirect's AI-generated Topic Pages" class="topic-link">food production</a> in the future, such as taking advantage of the captured CO</span><sub>2</sub><span> </span>to increase organic process yield, either in greenhouses or processed into fertilizers. This could be important for some agricultural industries, as using CO<sub>2</sub><span> </span>could enhance yields by up to 30%, which would have an immediate impact on commercial volumes and supplies. Some examples of utilizing CO<sub>2</sub><span> </span>for food production include Omega 3 which is produced by the Norwegian business CO<sub>2</sub>Bio for fish food and using CO<sub>2</sub><span> </span>by the Finnish company Solar Foods to develop proteins for human diets (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a><span>). Through higher <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/soil-organic-carbon" title="Learn more about soil organic carbon from ScienceDirect's AI-generated Topic Pages" class="topic-link">soil organic carbon</a> (SOC) content in the soil, organic farming immediately improves biological resources. In comparison to traditional farming, organic farming provides 50% more crops on average, has better <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/soil-fertility" title="Learn more about soil fertility from ScienceDirect's AI-generated Topic Pages" class="topic-link">soil fertility</a>, less <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/soil-erosion" title="Learn more about soil erosion from ScienceDirect's AI-generated Topic Pages" class="topic-link">soil erosion</a>, healthier crops, and superior farm management abilities (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib112" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib112"><span class="anchor-text">Onwonga, 2019</span></a>).</p>
</section>
<section id="sec4.3">
<h3 id="sectitle0105" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.3.<span> </span>SDG 3 “good health and wellbeing”</h3>
<p id="p0175">Ensuring and promoting the health and well-being of all people of all ages is significantly important for sustainable development. Prior to the COVID-19 pandemic, significant progress was sustained in enhancing the health of numerous people. Several targets were allocated to increase life expectancy and hinder the spread of diseases. However, further efforts are required to completely inhibit the spread of diseases and address all health problems. This is feasible by investing more in health facilities and systems, enhancing sanitation, and offering smooth access to health employees (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib89" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib89"><span class="anchor-text">Nationsb</span></a>). Hence, SDG 3, which promotes the health and well-being of all people, has been put forth to establish clear targets and indicators for achieving all the former objectives.</p>
<p id="p0180">Membrane-based carbon capture technologies do not directly influence some of the SDG 3 targets, such as targets 3.1 and 3.2 which discuss the reduction in worldwide maternity mortality rates and the end of numerous diseases, respectively. Nevertheless, several technologies employed for CO<sub>2</sub><span> </span>capture adversely influence the health and well-being of people. For instance, CO<sub>2</sub><span> </span>separation utilizes amine scrubbing which might potentially lead to several health complications (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib32" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib32"><span class="anchor-text">Dautzenberg and Bruhn, 2013</span></a>). Moreover, mineralization processes require waste materials that might contain hazardous elements such as heavy metals (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib129" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib129"><span class="anchor-text">Sanna et al., 2014</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib79" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib79"><span class="anchor-text">Masson-Delmotte et al., 2018b</span></a>). Additionally, based on the location of the carbon capture facility, the transportation of CO<sub>2</sub><span> </span>stored in pipelines poses a risk to the surrounding residents. Even though the risk of CO<sub>2</sub><span> <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/leakage" title="Learn more about leakage from ScienceDirect's AI-generated Topic Pages" class="topic-link">leakage</a> is low, where it is estimated that lower than 0.0008% of CO</span><sub>2</sub><span> </span>will be leaked in 10,000 years (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib9" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib9"><span class="anchor-text">Alcalde et al., 2018</span></a>), the public still perceives this as a potential danger to society (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib71" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib71"><span class="anchor-text">Lyons et al., 2021</span></a>). However, even small amounts of CO<sub>2</sub><span> </span>leakage from geographical locations near aquatic mediums might contaminate rivers, soil, lakes, air, and clean water which in turn leads to adverse impacts on the ecosystem and the people's health (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib64" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib64"><span class="anchor-text">Li and Liu, 2016</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib145" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib145"><span class="anchor-text">Wei et al., 2016</span></a>). Where it has been reported that the emissions of carbon capture technologies cause a 10-fold increase in the toxins found in freshwater (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib27" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib27"><span class="anchor-text">Chen et al., 2022b</span></a>). On the other hand, there are positive impacts of membrane-based carbon capture technologies on SDG 3. These positive effects include the usage of stored CO<sub>2</sub><span> </span>for producing sustainable pharmaceutical products (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a><span>). Moreover, carbon capture technologies reduce <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/atmospheric-aerosol" title="Learn more about particulate matter from ScienceDirect's AI-generated Topic Pages" class="topic-link">particulate matter</a>, CO</span><sub>2</sub>, SO<sub>2</sub>, and NO<sub>2</sub><span> </span>pollutants from the atmosphere. The availability of these pollutants in the atmosphere has led to various health issues for people, most specifically related to respiratory diseases (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib134" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib134"><span class="anchor-text">Shaw et al., 2018</span></a>). Particulate matter emissions only have led to the mortality of around 2804 to 8249 people in 2010 and approximately 9870 and 23,100 people in 2020. However, according to<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib148" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib148"><span class="anchor-text">Yang et al. (2021)</span></a>, the deployment of carbon capture technologies helps in mitigating air pollution; this, in return reduces the global mortalities associated with pollution and particulate matter emissions by 23%, which means around 289,000 people will be saved between the year 2015 and 2030.</p>
</section>
<section id="sec4.4">
<h3 id="sectitle0110" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.4.<span> </span>SDG 4 “quality education”</h3>
<p id="p0185">In order to meet the requirements of SDG 4's targets, which include guaranteeing free, equitable, and high-quality education for boys and girls (target 4.1) and equal opportunities for men and women to higher education (target 4.3), authorities, mainly nations and regions, and their organizations, are also needed to enhance the educational situation in their areas of accountability (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a>). Developing and implementing carbon capture technologies call for specialized knowledge in a variety of academic fields and industries. There is an indirect relationship with SDG 4 by employing students and trainees in carbon capture-related learning processes to help provide high-quality education. In addition, through transferring technology, knowledge can be made available to countries that lack the resources or infrastructure to do so (capacity building). This could be viewed as an unintentional good result (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a>). One of the indirect positive effects of the development of the various carbon capture systems including membrane-based ones on SDG 4 is the increase in the income (SDG1) that will eventually positively affect SDG 4.</p>
</section>
<section id="sec4.5">
<h3 id="sectitle0115" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.5.<span> </span>SDG 5 “gender equality”</h3>
<p id="p0190">SDG 5 aims at achieving equality between both genders and empower women and girls by removing discrimination, violence, and gender inequality against women mainly in the workplace. In addition to the ability to make her own decisions and authority over her own life (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib39" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib39"><span class="anchor-text">Eden and Wagstaff, 2021</span></a>). Carbon capture technologies including membrane-based ones are not anticipated to have any effect on achieving this goal. It is not specifically related to carbon capture and can be affected slightly by encouraging growth and development, which could then result in increasing opportunities for girls and women (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a>).</p>
</section>
<section id="sec4.6">
<h3 id="sectitle0120" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.6.<span> </span>SDG 6 “clean water and sanitation”</h3>
<p id="p0195">Considerable progress has been carried out to increase access to clean water and sanitation. Nevertheless, billions of people still do not have access to clean water. Globally, one out of three people still cannot access clean and safe water, while two in five people do not have access to sanitation facilities (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib90" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib90"><span class="anchor-text">Nationsc</span></a><span>). About one-third of the global population is influenced by <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/water-scarcity" title="Learn more about water scarcity from ScienceDirect's AI-generated Topic Pages" class="topic-link">water scarcity</a> induced by climate change and global warming. Nevertheless, since 1990, about 2.1 billion people have gained the access to clean water and sanitation facilities. However, water scarcity is still a primary issue numerous people are facing (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib128" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib128"><span class="anchor-text">Sanitation Statistics - UNICEF DATA</span></a>). As a result, SDG 6 was developed to focus on providing clean and safe water and sanitation for all people (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib108" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib108"><span class="anchor-text">Olabi et al., 2022e</span></a>).</p>
<p id="p0200">Carbon capture technologies adversely impact the achievement of target 6.3 which emphasizes the improvement of water quality through pollution reduction. The energy needed for carbon capture in power plants negatively influences the efficiency of power plants and produces pollutants and chemicals in the environment. The produced pollutants, wastes, and chemicals increase the toxicity and pollution of freshwater. On the other hand, carbon capture positively impacts target 6.4 which focuses on the sustainable increase of water utilization efficiency. This is reflected by the new designs of carbon capture technologies which lower the utilization of water (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib152" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib152"><span class="anchor-text">Zhu et al., 2021</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib44" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib44"><span class="anchor-text">Giannaris et al., 2020</span></a>). Moreover, the utilization of captured CO<sub>2</sub><span> can be utilized for the removal of dissolved solids from brine water into <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/potable-water" title="Learn more about potable water from ScienceDirect's AI-generated Topic Pages" class="topic-link">potable water</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib14" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib14"><span class="anchor-text">Al‒Mamoori et al., 2017</span></a>). Captured CO<sub>2</sub><span> can be efficiently utilized in <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/desalination-plant" title="Learn more about desalination plants from ScienceDirect's AI-generated Topic Pages" class="topic-link">desalination plants</a> for generating fresh water. However, few desalination plants employ captured CO</span><sub>2</sub><span> </span>due to their economic disadvantages (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib31" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib31"><span class="anchor-text">Cuéllar-Franca and Azapagic, 2015</span></a>).</p>
</section>
<section id="sec4.7">
<h3 id="sectitle0125" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.7.<span> </span>SDG 7 “affordable and clean energy”</h3>
<p id="p0205">SDG 7 focuses on providing clean and affordable energy to all people. SDG 7 focuses on increasing energy efficiency, allowing for smooth accessibility to energy, and enhancing the integration of renewable energy (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib119" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib119"><span class="anchor-text">Rabaia et al., 2021</span></a>),(<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib130" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib130"><span class="anchor-text">Sayed et al., 2021a</span></a>) (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib101" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib101"><span class="anchor-text">Olabi et al., 2021c</span></a><span>). It is essential to achieve this goal as 13% of the global population does not have access to electricity. The current sources of energy lead to climate change, responsible for 60% of the total <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/greenhouse-gas-emission" title="Learn more about greenhouse gas emissions from ScienceDirect's AI-generated Topic Pages" class="topic-link">greenhouse gas emissions</a>. Consequently, alternative energy sources which do not adversely impact the environment were explored, such as <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/renewable-energy-source" title="Learn more about renewable energy sources from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable energy sources</a>, including solar energy (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib8" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib8"><span class="anchor-text">Alami et al., 2022b</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib73" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib73"><span class="anchor-text">Maghrabie et al., 2021</span></a><span>), <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/windpower-utilization" title="Learn more about wind energy from ScienceDirect's AI-generated Topic Pages" class="topic-link">wind energy</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib102" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib102"><span class="anchor-text">Olabi et al., 2021d</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib103" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib103"><span class="anchor-text">Olabi et al., 2021e</span></a><span>), <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/bioenergy" title="Learn more about biomass energy from ScienceDirect's AI-generated Topic Pages" class="topic-link">biomass energy</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib146" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib146"><span class="anchor-text">Wilberforce et al., 2021</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib131" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib131"><span class="anchor-text">Sayed et al., 2021b</span></a><span>), <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/geothermal-energy" title="Learn more about geothermal energy from ScienceDirect's AI-generated Topic Pages" class="topic-link">geothermal energy</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib74" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib74"><span class="anchor-text">Mahmoud et al., 2021a</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib75" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib75"><span class="anchor-text">Mahmoud et al., 2021b</span></a>), and hydro energy (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib13" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib13"><span class="anchor-text">Alnaqbi et al., 2022</span></a>). Since 2016, the share of renewable energy has rapidly increased, resulting in tremendous growth in solar and wind energy sources (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib91" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib91"><span class="anchor-text">Nationsd</span></a><span>). Renewable energy sources on their own are not as reliable as <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/fossil" title="Learn more about fossil from ScienceDirect's AI-generated Topic Pages" class="topic-link">fossil</a> fuel power generation. Renewable energy sources require energy storage systems to account for the frequent fluctuations and intermittencies. Nevertheless, a connection between renewable energy sources and fossil fuel power generation must be made to enhance grid stability. This can be facilitated by the adoption of carbon capture and storage technologies integrated with other energy storage systems. Consequently, carbon capture technologies enhance the performance and generation of renewable energy sources. Thus, integrating carbon capture technologies have strong relations to SDG 7 (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib47" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib47"><span class="anchor-text">Hanak and Manovic, 2020</span></a>) Furthermore, the main goal of carbon capture technologies is to enhance the production of zero-emission hydrogen and fuel. This enhancement in the zero-emission production positively contributes to SDG 7 (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib61" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib61"><span class="anchor-text">Lee et al., 2020</span></a>). For instance, in a study conducted by khan et al. (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib11" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib11"><span class="anchor-text">Ali Khan et al., 2021</span></a><span>) the usage of carbon capture technologies with steam methane reforming for <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/hydrogen-production" title="Learn more about hydrogen production from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen production</a> has significantly reduced the release of emissions. Similarly, </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib53" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib53"><span class="anchor-text">Hu et al. (2015)</span></a><span> </span>proposed integrating carbon capture technologies to an in-situ steam gasification hydrogen production method to enhance the production of clean and renewable energy. The proposed system helped to produce around 277.67 ml/g of hydrogen.</p>
<p id="p0210"><span>The main goal of carbon capture by <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/membrane-technology" title="Learn more about membrane technologies from ScienceDirect's AI-generated Topic Pages" class="topic-link">membrane technologies</a> is to ultimately generate clean and reliable energy sources, which in turn increases the accessibility to clean energy. The ultimate goal of carbon capture technologies is to capture CO</span><sub>2</sub><span> </span>from the atmosphere to limit its contribution to global warming and climate change (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib108" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib108"><span class="anchor-text">Olabi et al., 2022e</span></a>). However, the addition of carbon technologies in conventional coal-based power plants increases the Levelized cost of electricity by 35–40%. Due to the high costs of membrane-based carbon capture, the goal of producing clean and affordable energy for all people is hindered (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib126" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib126"><span class="anchor-text">Rubin et al., 2015</span></a>). On the other hand, the addition of carbon capture technologies to coal-based power plants ensures a reliable supply of energy. This in return satisfies the goal of sustaining an uninterrupted and consistent supply of energy to meet the required energy demand (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib81" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib81"><span class="anchor-text">Mikunda et al., 2021b</span></a><span>). Nevertheless, membrane-based carbon capture technologies are energy-intensive, and this leads to a substantial reduction in <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/combustion-efficiency" title="Learn more about combustion efficiency from ScienceDirect's AI-generated Topic Pages" class="topic-link">combustion efficiency</a> and inflation in the electricity price (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib6" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib6"><span class="anchor-text">Al-Mamoori et al., 2017</span></a>). According to<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib137" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib137"><span class="anchor-text">Song et al. (2017)</span></a><span> </span>the energy utilization of the mostly utilized carbon capture technology, chemical absorption, is from 2.5 to 3.5 MJ/kg CO<sub>2</sub><span> </span>(<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib133" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib133"><span class="anchor-text">Shakerian et al., 2015</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib98" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib98"><span class="anchor-text">Oh et al., 2016</span></a>), while the energy utilization of membrane technology for carbon capture is 3 MJ/kg CO<sub>2</sub><span> </span>for a membrane area of 70 m<sup>2</sup><span> </span>and 3.6 MJ/kg CO<sub>2</sub><span> </span>for a membrane area of 30 m<sup>2</sup>. However, according to the European Union, the target energy utilization is only at 2 MJ/kg CO<sub>2</sub><span> </span>(<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib19" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib19"><span class="anchor-text">Belaissaoui et al., 2012</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib36" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib36"><span class="anchor-text">Dechamps and Pilavachi, 2004</span></a>).</p>
</section>
<section id="sec4.8">
<h3 id="sectitle0130" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.8.<span> </span>SDG 8 “decent work and economic growth”</h3>
<p id="p0215">The unemployment rate in 2000 was at 6.4%, and due to global economic growth, the unemployment rate decreased to 5.6% in 2017. However, the high unemployment rate is still a global issue that must be tackled. Hence, SDG 8 was developed to promote sustainable economic growth and employment for all people. Sustainable economic growth generates job opportunities for all people (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib92" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib92"><span class="anchor-text">Nationse</span></a>). SDG 8 revolves around the concepts of economic growth, employment rates, decent work, resource efficiency, high productivity, and environmental protection (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib108" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib108"><span class="anchor-text">Olabi et al., 2022e</span></a>).</p>
<p id="p0220"><span>The significant investments and a large number of carbon capture projects have resulted in lower environmental impacts of conventional power plants, and thus in higher growth of the implemented number of power plants. Where it was witnessed that up to 65 large-scale carbon capture projects were developed by 2020. Around 38 of these projects are in the United States, 13 projects are in Europe, 10 are in <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/asia" title="Learn more about Asia from ScienceDirect's AI-generated Topic Pages" class="topic-link">Asia</a>, and 3 are in the Middle East. The total rated capacity of these projects is 40 mt-CO</span><sub>2</sub>/year (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib114" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib114"><span class="anchor-text">Page et al., 2020</span></a>). It is expected that by 2050 the rated capacity will increase to 5635 mt-CO<sub>2</sub>/year and the number of carbon capture projects is anticipated to increase to 2000 projects (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib33" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib33"><span class="anchor-text">de Mello Delgado et al., 2021</span></a>). Furthermore, the impacts of carbon capture technologies on the economy have been thoroughly evaluated in a UK carbon capture storage investment report. The report discussed the influence of carbon capture storage technologies on the economy, job creation, and gross profits. The report indicated that carbon capture storage technologies bring numerous advantages from the imports and exports related to carbon capture storage technologies and job opportunities (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib138" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib138"><span class="anchor-text">Summit, 2017</span></a>). Due to these advantages, the UK government decided to invest at least 780 million dollars in the promotion and advancement of carbon capture storage technologies. This investment has led to more economic growth as it opened up 3850 full-time equivalent jobs in just the first year (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib141" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib141"><span class="anchor-text">Turner et al., 2020</span></a>). According to<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib43" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib43"><span class="anchor-text">Franz et al. (2014)</span></a>, the average salary for jobs related to carbon capture technologies in the UK is around 6800 dollars per month.</p>
</section>
<section id="sec4.9">
<h3 id="sectitle0135" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.9.<span> </span>SDG 9 “industry, innovation and infrastructure”</h3>
<p id="p0225">The scope of SDG 9 is to encourage innovation, advance equitable and sustainable industrialization, and construct resilient infrastructure (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib85" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib85"><span class="anchor-text">MONTES, 2017</span></a>). Developed nations have offered to help developing and undeveloped nations with their economies. Achieving sustainable economic growth, social and environmental development, and battling climate change within the context of this SDG, requires developing and underdeveloped nations for long-lasting infrastructure investments, sustainable industrial advances, and new technologies. Encouragement of sustainable industries, technical research, and innovation funding could all contribute to sustainable development (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib42" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib42"><span class="anchor-text">Franco et al., 2020</span></a>).</p>
<p id="p0230"><span>Target 9.4 aims to improve efficiency in resource utilization and expand the implementation of clean, environmentally friendly technologies and industries. Achieving target 9.4 requires concentrating on forest-based ecological systems like <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/carbon-sequestration" title="Learn more about carbon storage from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbon storage</a>, watershed restoration, and outdoor leisure can boost local economies while preventing material development. Limiting carbon and other greenhouse gas emissions might not only slow down climate change but will also lessen its negative effects on the health of ecosystems, such as the increased levels of forest fires in both temperate and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/boreal-forest" title="Learn more about boreal forests from ScienceDirect's AI-generated Topic Pages" class="topic-link">boreal forests</a> and the elevated chance of the <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/amazon" title="Learn more about Amazon from ScienceDirect's AI-generated Topic Pages" class="topic-link">Amazon</a> rainforest becoming unstable if certain temperature limits are exceeded (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib140" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib140"><span class="anchor-text">Tomaselli et al., 2019</span></a>).</p>
<p id="p0235">Carbon capture using membranes has a direct impact on infrastructure and industry. The economic effects of carbon capture may vary by area, industry, and a nation's reliance on fossil fuels (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib82" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib82"><span class="anchor-text">Mikunda et al., 2021c</span></a>). Developed membrane materials reduce costs associated with carbon capture, which is for the membrane technology highly depends on the CO<sub>2</sub><span> </span>capture ratio. Post-combustion CO<sub>2</sub><span> </span>capture utilizing the membrane technology can have an advantage from a reduced CO<sub>2</sub><span> </span>capture ratio with a 55% drop in cost. The improvement of the membrane performance is recommended to lower the CO<sub>2</sub><span> </span>capture costs down to $20/tonne CO<sub>2</sub>. Membrane systems could one day be an eco-friendly solution for CO<sub>2</sub><span> </span>capture from power plants and other energy-intensive process sectors because they don't require chemicals, are simple to scale up, and have a comparatively low energy requirement (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib49" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib49"><span class="anchor-text">He, 2018a</span></a>). Compared to the issues encountered with the use of liquid absorption such as corrosion and foaming, utilization of membrane technology in post-combustion carbon capture, benefits the whole process by cost savings reported as 38–42% and equipment weight reduction of 34–40% (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib70" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib70"><span class="anchor-text">Luliano et al., 2020</span></a>).</p>
</section>
<section id="sec4.10">
<h3 id="sectitle0140" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.10.<span> </span>SDG 10 “reduced inequality”</h3>
<p id="p0240">The target of SDG 10 is to reduce inequality within and among countries. Similar to how poverty has been acknowledged as having multiple dimensions, inequality also has a social, economic, and ecological component. The negative impacts on people when inequality is (excessively) high within a nation have been the subject of extensive research in recent decades. Inequality is considered to be one of our most critical social issues (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib23" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib23"><span class="anchor-text">Breting-Garcia, 2021</span></a>).</p>
<p id="p0245">Carbon capture can lessen cities' carbon footprints, improve their sustainability (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib50" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib50"><span class="anchor-text">He, 2018b</span></a><span>) and help in reducing inequality. For the general public, carbon capture facilities might also offer sources of revenue and employment. This contrasts with the lopsided advantage enjoyed by nations with plentiful fossil resources, which has recently affected international <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/geopolitics" title="Learn more about geopolitics from ScienceDirect's AI-generated Topic Pages" class="topic-link">geopolitics</a>. As a result, carbon capture and storage technologies may make up for the disadvantages experienced by nations and regions without independent access to fossil fuels. Together, these elements could indirectly help to lessen inequality between countries and regions (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a>). Berdowska and Skorek-Osikowska examined the deployment of membrane carbon capture technology with a cryogenic distillation module for a 600 MW coal power plant employing oxy-combustion technology. The reference system without applying separation and compression of CO<sub>2</sub><span> </span>and with an air-fired pulverized bed boiler had an electricity break-even price of €94.5/MWh. For a membrane costing €0.7/m<sup>2</sup>, the breakeven price of power for the two technologies under consideration is €81.2/MWh. It should be noted that the effectiveness of the hybrid system is significantly impacted by the membrane selection. The membranes' permeability and oxygen selectivity determine how well the system functions and how much it costs to operate. The hybrid systems’ profitability will increase owing to the projected developments in membrane technology in the coming years. Thus, all of these factors will contribute to higher income and revenue and indirectly to reducing inequality (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib21" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib21"><span class="anchor-text">Berdowska and Skorek-Osikowska, 2013</span></a>).</p>
</section>
<section id="sec4.11">
<h3 id="sectitle0145" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.11.<span> </span>SDG 11 “sustainable cities and communities”</h3>
<p id="p0250">Making cities and communities, safe, resilient, and sustainable is the main goal of SDG 11. Cities contain 55% of the world's population, generate 85% of its GDP, and are yet also responsible for 75% of its greenhouse gas emissions (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib143" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib143"><span class="anchor-text">Vaidya and Chatterji, 2020</span></a>).</p>
<p id="p0255">Encouraging CO<sub>2</sub>-based fuel and chemical production could be seen as a step in the right direction towards creating more environmentally friendly communities and enhancing sustainability (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a>) and leading to improved air quality (Target 11.6). Carbon capture has both favorable and unfavorable effects on the environment. The most noticeable result of carbon capture is a 60–80% reduction in greenhouse gas emissions. Lowering the climate change caused by the energy and products utilized by various cities and communities can lead to significant contributions (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib107" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib107"><span class="anchor-text">Olabi et al., 2022d</span></a>). The sustainability of fossil fuel power plants can be improved by deploying optimal membrane carbon capture technologies that lower their energy consumption and operational expenses. According to Asadi and Kazempoor, at ideal design and operating parameters, the CO<sub>2</sub><span> </span>capture cost and energy penalties were respectively 13.1$/tCO<sub>2</sub><span> </span>and 10% by studying a multi-stage membrane system. As the CO<sub>2</sub><span> </span>content in the gas rises, the cost of CO<sub>2</sub><span> </span>capture greatly falls and CO<sub>2</sub><span> </span>removal is improved (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib16" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib16"><span class="anchor-text">Asadi and Kazempoor, 2022</span></a>).</p>
</section>
<section id="sec4.12">
<h3 id="sectitle0150" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.12.<span> </span>SDG 12 “responsible consumption and production”</h3>
<p id="p0260"><span>Around one-third, estimated as 1.3 billion tonnes of the globally produced food is wasted every year. This could potentially mean that not only are there insufficient natural sources to meet the future generation's needs but also most of the currently available resources are being wasted due to inefficient transportation and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/harvesting-strategy" title="Learn more about harvesting strategies from ScienceDirect's AI-generated Topic Pages" class="topic-link">harvesting strategies</a>. According to the UN, if the global population increases to 9.6 billion by the year 2050, the number of <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/natural-resource" title="Learn more about natural resources from ScienceDirect's AI-generated Topic Pages" class="topic-link">natural resources</a> needed will be threefold the number of natural resources acquired from this planet. All these issues call for responsible and sustainable consumption and production practices. As a result, SDG 12 was developed to drive the need for consuming and producing natural resources without constituting any adverse effects on the planet. SDG 12 thrives on doing more with fewer resources to sustain the current resources for future generations. Furthermore, SDG 12 promotes sustainable consumption and production patterns and practices. Sustainable consumption and production significantly reduce poverty and allow for the transition towards a green and low-carbon society (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib93" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib93"><span class="anchor-text">Nationsf</span></a>). SDG 12 thrives to enhance the adopted consumption and production practices in companies to enhance the sustainability of natural resources and deflate the waste streams that are allocated on land, water, or air.</p>
<p id="p0265">The role of carbon capture technologies is to reduce CO<sub>2</sub><span> </span>emissions and thus contribute to target 12.4 which focuses on reducing chemical and waste released to the atmosphere. Companies can integrate carbon capture technologies to reduce CO<sub>2</sub><span> </span>emissions. Even though carbon capture technologies might generate waste into the atmosphere, the technologies reduce greenhouse gas emissions for fossil fuel plants by 75–90%. Moreover, employing carbon capture technologies in companies significantly contributes to target 12.6 which stresses the adoption of sustainable practices. On the other hand, the accomplishment of target 12.2 is hindered by carbon capture technologies. Target 12.2 strives for sustainable management and efficient utilization of natural resources. As carbon capture technologies need energy for their operation and materials for their development. These requirements reduce the efficiencies of power plants integrating carbon capture technologies. It is found that carbon capture-based power plants have efficiencies 20–25% lower than conventional coal-based power plants. Moreover, the number of materials required for fossil-fuel plants with carbon capture technologies is far superior to that of conventional fossil-fuel plants. Additionally, carbon capture operations produce chemical waste which adversely influences the environment. Hence, deploying carbon capture projects can potentially increase the produced wastes from the carbon capture process. The carbon capture process might result in the emission of ash, NO<sub>x</sub>, sulfur, and NH<sub>3</sub>. These consequences hinder the achievement of target 12.5 which focuses on reducing waste generation (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib82" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib82"><span class="anchor-text">Mikunda et al., 2021c</span></a>). Another negative consequence of the utilization of membrane-based carbon capture technologies is the release of toxins into the environment as a result of integrating amines for membrane absorption (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib63" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib63"><span class="anchor-text">Li and Chen, 2005</span></a>).</p>
</section>
<section id="sec4.13">
<h3 id="sectitle0155" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.13.<span> </span>SDG 13 “climate change”</h3>
<p id="p0270"><span>In 2019, the highest temperatures and the highest levels of greenhouse gas emissions were recorded. The levels of greenhouse gas emissions dropped by 6% in 2020 due to travel restrictions induced by the COVID-19 pandemic (Nationsg). However, this improvement is temporary, and levels of greenhouse gas emissions are yet to increase again when the economy starts recovering from the COVID-19 pandemic. The high levels of greenhouse gas emissions are significantly contributing to global warming and climate change. Climate change is negatively influencing the global population. Climate change is inducing changes in weather patterns, resulting in higher sea levels, and causing more frequent extreme weather conditions. Due to these negative impacts of climate change, it became imperative to take extreme measures for addressing these climate issues. In 2015, the <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/paris-agreement" title="Learn more about Paris Agreement from ScienceDirect's AI-generated Topic Pages" class="topic-link">Paris Agreement</a> was created to focus on strengthening the global reaction to the risks of climate change by reducing global temperatures below 2 °C (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib94" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib94"><span class="anchor-text">Nationsg</span></a>). SDG 13 has been developed to take urgent action to battle climate change and its effects.</p>
<p id="p0275">Carbon capture technologies combat climate change by significantly contributing to the achievement of SDG 13 (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib108" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib108"><span class="anchor-text">Olabi et al., 2022e</span></a>). After the Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report in 2007, carbon capture technologies have been acknowledged as the primary prevention technologies for reducing CO<sub>2</sub><span> </span>emissions (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib54" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib54"><span class="anchor-text">IPCC, 2007</span></a>). The Fifth Assessment Report of IPCC further highlighted the importance of carbon capture technologies as it was estimated that by 2100 the greenhouse gas emissions cannot be reduced below 450 ppm CO<sub>2</sub>eq without the utilization of carbon capture technologies. Additionally, the Paris Agreement of reducing temperatures by 2 °C includes carbon capture technologies as key enablers for combatting climate change by significantly reducing CO<sub>2</sub><span> </span>emissions (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib124" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib124"><span class="anchor-text">Rogelj et al. Masson-Delmotte et al., 2018</span></a>). Through these integrations of carbon capture technologies into global and national strategies, plans, and policies for combatting climate change the accomplishment of target 13.2 becomes more feasible. Moreover, carbon capture technologies facilitate the accomplishment of target 13.1 which focuses on strengthening resilience to natural disasters related to climate change by reducing 90% of the CO<sub>2</sub><span> </span>emissions in coal-based power plants (Rubin et al., 2015). Especially, membrane-based carbon capture technologies have high CO<sub>2</sub><span> </span>capture yields (80–90%) (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib84" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib84"><span class="anchor-text">Mondal et al., 2012</span></a>). It is essential to focus on CO<sub>2</sub><span> </span>reduction due to the high CO<sub>2</sub><span> </span>emissions from anthropogenic activities. It is estimated that the CO<sub>2</sub><span> </span>emissions from anthropogenic activities will increase to 43.22 billion tonnes by the year 2040 (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib136" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib136"><span class="anchor-text">Sieminski, 2013</span></a>). However, carbon capture technologies are capable of capturing 33.4 million tonnes per year of CO<sub>2</sub><span> </span>by 2020 which amounts to only 0.09% of the CO<sub>2</sub><span> </span>emissions (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib139" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib139"><span class="anchor-text">Theo et al., 2016</span></a>).</p>
</section>
<section id="sec4.14">
<h3 id="sectitle0160" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.14.<span> </span>SDG 14 “life below water”</h3>
<p id="p0280"><span>SDG 14 emphasizes the significance of ocean monitoring in a situation where major pressures are threatening the ocean's capacity to provide economic, social, and benefits to the community. Oceans are a vital part of the mechanisms that keep the Earth's ecosystems alive. With the ability to cycle 93% of the world's carbon dioxide and capture 30% of exhaust emissions, the oceans serve as the principal climate controller. Additionally, over the past few decades, the seas have absorbed 90% of the Earth's heat. The provision of services by healthy <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/aquatic-ecosystem" title="Learn more about aquatic ecosystems from ScienceDirect's AI-generated Topic Pages" class="topic-link">aquatic ecosystems</a> includes water filtering, <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/nutrient-uptake" title="Learn more about nutrient uptake from ScienceDirect's AI-generated Topic Pages" class="topic-link">nutrient uptake</a>, and biodiversity preservation. Concerning climate change, the oceans are becoming 10 times more acidic today than they were 65 million years ago due to the absorption of CO</span><sub>2</sub><span> from the atmosphere, which harms marine species' welfare, calcification, growth, and diversity. The adverse <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/climate-change-impact" title="Learn more about effects of climate change from ScienceDirect's AI-generated Topic Pages" class="topic-link">effects of climate change</a> also include changes in ocean circulation and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/salinity" title="Learn more about salinity from ScienceDirect's AI-generated Topic Pages" class="topic-link">salinity</a>, as well as an increase in the frequency and severity of weather and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/climate-variation" title="Learn more about climate variations from ScienceDirect's AI-generated Topic Pages" class="topic-link">climate variations</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib122" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib122"><span class="anchor-text">Recuero Virto, 2018</span></a>). The aquatic ecosystem and life underwater can benefit significantly from carbon capture. This is mainly a result of the carbonate/bicarbonate/hydrogen system in oceans and seas, being in equilibrium with CO<sub>2</sub><span> </span>in the atmosphere (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib106" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib106"><span class="anchor-text">Olabi et al., 2022c</span></a>).</p>
</section>
<section id="sec4.15">
<h3 id="sectitle0165" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.15.<span> </span>SDG 15 “life on land”</h3>
<p id="p0285"><span>Nature is essential to the survival of all living things as it provides oxygen and crops, and controls climatic conditions. Even though nature is key to the survival of the population, people have modified about 75% of the earth's surface, reducing the available land for nature and wildlife. As a result, about 1 million species of animals and plants are about to go extinct. Based on the Global Assessment Report about biodiversity and ecosystems, it is now imperative to take transformative actions to shield and restore nature. Nevertheless, the state of nature is rapidly deteriorating, negatively influencing the economy, food security, quality of life, health, and livelihood. The need for sustaining and protecting the nature and ecosystem has paved the way for the development of SDG 15 which highlights the criticality of life on land. SDG 15 sustainably manages ecosystems and wildlife and mitigates biodiversity loss, <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/deforestation" title="Learn more about deforestation from ScienceDirect's AI-generated Topic Pages" class="topic-link">deforestation</a>, <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/land-degradation" title="Learn more about land degradation from ScienceDirect's AI-generated Topic Pages" class="topic-link">land degradation</a>, and desertification (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib95" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib95"><span class="anchor-text">Nationsh</span></a>). SDG 15 protects life on land by reducing waste on land and promoting efficient resource utilization of forests, soil, and aquatic ecosystems.</p>
<p id="p0290">The implementation of carbon capture technologies has positive and negative interactions with the objectives of SDG 15. Target 15.5 is positively correlated with the reduction of CO<sub>2</sub><span> </span>emissions due to carbon capture technologies. It has been estimated that by 2050, carbon capture technologies will facilitate the capture of 10 to 2.8 GtCO<sub>2</sub><span> </span>eq per year. The tremendous reductions in CO<sub>2</sub><span> </span>emissions will eventually hinder the temperature rise by 1.5–2 °C (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib121" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib121"><span class="anchor-text">Ramón and Guillena, 2020</span></a>). Hence, carbon capture technologies capture CO<sub>2</sub><span> emissions that would have been otherwise released into the atmosphere and potentially led to air and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/water-pollution" title="Learn more about water pollution from ScienceDirect's AI-generated Topic Pages" class="topic-link">water pollution</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib108" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib108"><span class="anchor-text">Olabi et al., 2022e</span></a>). Moreover, the reduction of CO<sub>2</sub><span> </span>emissions in the atmosphere mitigates extreme climatic changes and hence reduces biodiversity loss (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib82" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib82"><span class="anchor-text">Mikunda et al., 2021c</span></a><span>). On the other hand, carbon capture technologies are negatively influencing the objectives of target 15.1 which promotes sustainable usage of terrestrial and inland <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/freshwater-ecosystem" title="Learn more about freshwater ecosystems from ScienceDirect's AI-generated Topic Pages" class="topic-link">freshwater ecosystems</a>. Carbon capture technologies have high utilization of energy (as mentioned in SDG 7); this, in return results in the production of wastes, pollutants, and chemicals that could spread to nearby water bodies. Other than polluting water bodies, carbon capture technologies have high water consumption, these technologies generate wastewater due to the toxins and heavy metals intoxicating the water (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib113" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib113"><span class="anchor-text">Oreggioni et al., 2017</span></a>), (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib29" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib29"><span class="anchor-text">Chisalita et al., 2019</span></a>).</p>
</section>
<section id="sec4.16">
<h3 id="sectitle0170" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.16.<span> </span>SDG 16 “peace, justice and strong institutions”</h3>
<p id="p0295">SDG 16 is more than just a moral agenda, and it is also more than just developing technical capability. It outlines the key responsibility for covering both the purpose of institutions and their philosophy and reasoning place politics at the center of institutions. SDG 16 reflects these issues of attitude by putting importance on both whether institutions function and how they function (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib97" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib97"><span class="anchor-text">OECDWhaites, 2016</span></a><span>). SDG 16 goals are unlikely to be directly impacted by the adoption of carbon capture technologies. However, under specific circumstances, indirect beneficial impacts may happen in terms of preserving and furthering the development of a peaceful world. While wealthier countries are primarily responsible for global warming's emissions, developing countries are already taking on the majority of its effects since they are more at risk from both desertification and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/sea-level-rise" title="Learn more about sea level rise from ScienceDirect's AI-generated Topic Pages" class="topic-link">sea level rise</a>. Therefore, all actions that industrialized nations do to avoid, reduce, or even harvest CO</span><sub>2</sub><span> </span>from the atmosphere (known as “negative emission technology,” or NET) may be viewed as actions that promote peace (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a>).</p>
</section>
<section id="sec4.17">
<h3 id="sectitle0175" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.17.<span> </span>SDG 17 “partnership for the goals”</h3>
<p id="p0300">SDG 17 demands funding the international alliance for achieving sustainable development on a global scale. In order to carry out the goals of Agenda (2030), collaborations between the public, private, and civil society must be strengthened. It will also be necessary to improve the coordination of policies and actions both locally and globally and to increase international collaboration. SDG 17 calls for efforts to strengthen the abilities for achieving the SDGs and fulfil these requirements (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib77" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib77"><span class="anchor-text">Maltais et al., 2018</span></a>).</p>
<p id="p0305"><span>Working with another commercial, governmental, and municipal entities or authorities is a requirement of carbon capture projects. Along with this cooperation, the project management team should budget the necessary funds and take into account how to connect firm policies with the SDGs. Defining and carefully monitoring related metrics is also necessary. All businesses may contribute to the SDGs as part of their <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/sustainable-development-goals" title="Learn more about sustainable development goals from ScienceDirect's AI-generated Topic Pages" class="topic-link">sustainable development goals</a>, regardless of the size of their respective industries. On the one hand, although the scope and size of the global targets are unmatched, there are several fundamental aspects that any firm may still contribute (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib108" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib108"><span class="anchor-text">Olabi et al., 2022e</span></a>). SDG 17 calls for extra assistance from the developed countries to the less developed ones which can include improved international collaboration in the field of carbon capture that is created to equally fulfill the requirements of less developed countries (targets 17.3 and 17.5). It is unclear whether carbon capture will positively contribute to SDG 17 due to numerous essential, possibly partially altruistic prerequisites (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#bib110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="bib110"><span class="anchor-text">Olfe-Kräutlein, 2020b</span></a>).</p>
<div>
<p id="p0310">The summary of the assessment done on the contribution of membrane-based carbon capture technologies for achieving the 17 SDGs is shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig26" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig26"><span class="anchor-text">Fig. 26</span></a>, which depicts the most influenced SDGs by membrane-based carbon capture technologies (see<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig9" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig9"><span class="anchor-text">Fig. 9</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig10" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig10"><span class="anchor-text">Fig. 10</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig11" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig11"><span class="anchor-text">Fig. 11</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig12" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig12"><span class="anchor-text">Fig. 12</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig13" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig13"><span class="anchor-text">Fig. 13</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig14" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig14"><span class="anchor-text">Fig. 14</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig15" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig15"><span class="anchor-text">Fig. 15</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig16" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig16"><span class="anchor-text">Fig. 16</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig17" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig17"><span class="anchor-text">Fig. 17</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig18" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig18"><span class="anchor-text">Fig. 18</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig19" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig19"><span class="anchor-text">Fig. 19</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig20" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig20"><span class="anchor-text">Fig. 20</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig21" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig21"><span class="anchor-text">Fig. 21</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig22" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig22"><span class="anchor-text">Fig. 22</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig23" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig23"><span class="anchor-text">Fig. 23</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig24" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig24"><span class="anchor-text">Fig. 24</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0045653523002631#fig25" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="fig25"><span class="anchor-text">Fig. 25</span></a>). The figure shows that SDGs 13, 9, 7, and 8 are the most influenced SDGs by carbon capture technologies. The CO<sub>2</sub><span> </span>reductions and the sustainable energy production by these technologies have led to great contributions to SDG 13 and SDG 7. Moreover, as carbon capture technologies are becoming more advanced, they are being adopted by more countries and institutions. These consequences lead to the creation of more jobs and significant economic growth and developments. Due to these positive impacts, SDG 8, SDG 1, and SDG 3 are perceived to be positively correlated with carbon capture technologies.</p>
<figure class="figure text-xs" id="fig9"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr9.jpg" height="141" alt="Fig. 9" aria-describedby="cap0050"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr9_lrg.jpg" target="_blank" download="" title="Download high-res image (243KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (243KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr9.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0050"><span class="label">Fig. 9</span>.<span> </span>Membrane carbon capture SDG 1 impact summary.</p>
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<figure class="figure text-xs" id="fig10"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr10.jpg" height="132" alt="Fig. 10" aria-describedby="cap0055"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr10_lrg.jpg" target="_blank" download="" title="Download high-res image (262KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (262KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr10.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0055"><span class="label">Fig. 10</span>.<span> </span>Membrane carbon capture SDG 2 impact summary.</p>
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<figure class="figure text-xs" id="fig11"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr11.jpg" height="137" alt="Fig. 11" aria-describedby="cap0060"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr11_lrg.jpg" target="_blank" download="" title="Download high-res image (267KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (267KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr11.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0060"><span class="label">Fig. 11</span>.<span> </span>Membrane carbon capture SDG 3 impact summary.</p>
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<figure class="figure text-xs" id="fig12"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr12.jpg" height="138" alt="Fig. 12" aria-describedby="cap0065"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr12_lrg.jpg" target="_blank" download="" title="Download high-res image (232KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (232KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr12.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0065"><span class="label">Fig. 12</span>.<span> </span>Membrane carbon capture SDG 4 impact summary.</p>
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<figure class="figure text-xs" id="fig13"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr13.jpg" height="129" alt="Fig. 13" aria-describedby="cap0070"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr13_lrg.jpg" target="_blank" download="" title="Download high-res image (218KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (218KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr13.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0070"><span class="label">Fig. 13</span>.<span> </span>Membrane carbon capture SDG 5 impact summary.</p>
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<figure class="figure text-xs" id="fig14"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr14.jpg" height="131" alt="Fig. 14" aria-describedby="cap0075"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr14_lrg.jpg" target="_blank" download="" title="Download high-res image (250KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (250KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr14.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0075"><span class="label">Fig. 14</span>.<span> </span>Membrane carbon capture SDG 6 impact summary.</p>
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<figure class="figure text-xs" id="fig15"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr15.jpg" height="135" alt="Fig. 15" aria-describedby="cap0080"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr15_lrg.jpg" target="_blank" download="" title="Download high-res image (278KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (278KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr15.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0080"><span class="label">Fig. 15</span>.<span> </span>Membrane carbon capture SDG 7 impact summary.</p>
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<figure class="figure text-xs" id="fig16"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr16.jpg" height="133" alt="Fig. 16" aria-describedby="cap0085"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr16_lrg.jpg" target="_blank" download="" title="Download high-res image (273KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (273KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr16.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0085"><span class="label">Fig. 16</span>.<span> </span>Membrane carbon capture SDG 8 impact summary.</p>
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<figure class="figure text-xs" id="fig17"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr17.jpg" height="131" alt="Fig. 17" aria-describedby="cap0090"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr17_lrg.jpg" target="_blank" download="" title="Download high-res image (254KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (254KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr17.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0090"><span class="label">Fig. 17</span>.<span> </span>Membrane carbon capture SDG 9 impact summary.</p>
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<figure class="figure text-xs" id="fig18"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr18.jpg" height="134" alt="Fig. 18" aria-describedby="cap0095"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr18_lrg.jpg" target="_blank" download="" title="Download high-res image (236KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (236KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr18.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0095"><span class="label">Fig. 18</span>.<span> </span>Membrane carbon capture SDG 10 impact summary.</p>
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<figure class="figure text-xs" id="fig19"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr19.jpg" height="140" alt="Fig. 19" aria-describedby="cap0100"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr19_lrg.jpg" target="_blank" download="" title="Download high-res image (293KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (293KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr19.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0100"><span class="label">Fig. 19</span>.<span> </span>Membrane carbon capture SDG 11 impact summary.</p>
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<figure class="figure text-xs" id="fig20"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr20.jpg" height="126" alt="Fig. 20" aria-describedby="cap0105"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr20_lrg.jpg" target="_blank" download="" title="Download high-res image (294KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (294KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr20.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0105"><span class="label">Fig. 20</span>.<span> </span>Membrane carbon capture SDG 12 impact summary.</p>
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<figure class="figure text-xs" id="fig21"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr21.jpg" height="133" alt="Fig. 21" aria-describedby="cap0110"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr21_lrg.jpg" target="_blank" download="" title="Download high-res image (236KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (236KB)</span></span></a></li>
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<p id="fspara0110"><span class="label">Fig. 21</span>.<span> </span>Membrane carbon capture SDG 13 impact summary.</p>
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<figure class="figure text-xs" id="fig22"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr22.jpg" height="129" alt="Fig. 22" aria-describedby="cap0115"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr22_lrg.jpg" target="_blank" download="" title="Download high-res image (199KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (199KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr22.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0115"><span class="label">Fig. 22</span>.<span> </span>Membrane carbon capture SDG 14 impact summary.</p>
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<figure class="figure text-xs" id="fig23"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr23.jpg" height="129" alt="Fig. 23" aria-describedby="cap0120"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr23_lrg.jpg" target="_blank" download="" title="Download high-res image (246KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (246KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr23.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0120"><span class="label">Fig. 23</span>.<span> </span>Membrane carbon capture SDG 15 impact summary.</p>
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<figure class="figure text-xs" id="fig24"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr24.jpg" height="129" alt="Fig. 24" aria-describedby="cap0125"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr24_lrg.jpg" target="_blank" download="" title="Download high-res image (247KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (247KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr24.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0125"><span class="label">Fig. 24</span>.<span> </span>Membrane carbon capture SDG 16 impact summary.</p>
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<figure class="figure text-xs" id="fig25"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr25.jpg" height="130" alt="Fig. 25" aria-describedby="cap0130"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr25_lrg.jpg" target="_blank" download="" title="Download high-res image (301KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (301KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr25.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0130"><span class="label">Fig. 25</span>.<span> </span>Membrane carbon capture SDG 17 impact summary.</p>
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<figure class="figure text-xs" id="fig26"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr26.jpg" height="311" alt="Fig. 26" aria-describedby="cap0135"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr26_lrg.jpg" target="_blank" download="" title="Download high-res image (391KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (391KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0045653523002631-gr26.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="fspara0135"><span class="label">Fig. 26</span>.<span> </span>The influence of membrane-based carbon capture technologies on the SDGs.</p>
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</div>
</section>
</section>
<section id="sec5">
<h2 id="sectitle0180" class="u-h4 u-margin-l-top u-margin-xs-bottom">5.<span> </span>Conclusion</h2>
<p id="p0315">Membrane-based technologies pose as a potential candidate, in terms of commercialization, for the application of carbon capture, whether in pre- or post-combustion processes, using MGS or MC technologies, respectively. An optimized fabrication process of hollow fiber membranes allows for a financially feasible option for carbon capture applications. MGS technologies, having a gas-gas interface, harbor the leisure of determining the permeability and selectivity of the CO<sub>2</sub><span> </span>species in a gas mixture, with a tradeoff relationship between the two and adhering to the upper bound limitations, and subject to other drawbacks such as plasticization and deterioration. MC technologies utilize a more complex membrane/gas system with the addition of a solvent, resulting in a gas-liquid interface for the transportation of CO<sub>2</sub><span> </span>gas species to a suitable solvent. The operation of an MC system is subject to various limitations such as the wetting of the membrane pores, fouling and ageing, which requires a thorough optimization process. Moreover, an assessment of the role of membrane-based carbon capture technologies in achieving the 17 SDGs was carried out, which showed both positive and negative impacts accordingly. Membrane-based carbon capture technologies play a critical role in the field of generating affordable and clean energy (SDG 7). The high energy utilization has negatively influenced the main objectives of SDG 7. Furthermore, it was found that membrane-based carbon capture technologies have led to numerous job opportunities and made positive contributions to the economy. These positive impacts support the objectives of both SDG 1 and SDG 8. Additionally, membrane-carbon capture technologies play an essential role in building sustainable and innovative infrastructure developments; thus, supporting the objectives of SDG 9. Most importantly, membrane-based carbon capture technologies significantly reduce CO<sub>2</sub><span> emissions and other <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/pollutant-emission" title="Learn more about pollutant emissions from ScienceDirect's AI-generated Topic Pages" class="topic-link">pollutant emissions</a>. These reductions positively adhere to the objectives of SDG 13. As a result, membrane-based carbon capture technologies have significant impacts on the 17 SDGs. Some of these impacts are quantifiable, such as in SDG 9 by providing 38–42% cost savings compared to liquid absorption, SDG 3 through reducing pollution and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/atmospheric-aerosol" title="Learn more about particulate matter from ScienceDirect's AI-generated Topic Pages" class="topic-link">particulate matter</a> emissions by 23%, and SDG 13 as membrane-based carbon capture significantly reduce the CO</span><sub>2</sub><span> </span>emissions and have high CO<sub>2</sub><span> </span>capture yields (80–90%), while others cannot be quantified and can only be assessed based on qualitative information. To enhance the accuracy of the assessment, it is recommended to assess the impacts of other carbon capture technologies on the SDGs and compare the results. Additionally, these assessments will create a framework for comparing carbon capture technologies based on their potential positive and negative impacts on the achievement of the 17 SDGs. The technologies must be compared based on country-specific economic, environmental, and geographic considerations.</p>
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<title>Recent progress in Green Ammonia: Production, applications, assessment; barriers, and its role in achieving the sustainable development goals</title>
<link>https://sdgtalks.ai/recent-progress-in-green-ammonia-production-applications-assessment-barriers-and-its-role-in-achieving-the-sustainable-development-goals</link>
<guid>https://sdgtalks.ai/recent-progress-in-green-ammonia-production-applications-assessment-barriers-and-its-role-in-achieving-the-sustainable-development-goals</guid>
<description><![CDATA[ Fossil fuels are no longer accepted as the sole energy source with their environmental impacts and fluctuating price. Green hydrogen is considered a potential candidate for fossil fuel soon—however, hydrogen is facing the challenges of storage and transportation. Green ammonia, with its ease of transport and storage, is another promising alternative. Decarbonizing ammonia production is an environmental press toward achieving net-zero emissions by 2050. This work summarizes the up-to-date progress in the green ammonia production methods. An assessment of the different production methods was conducted to highlight the merits and constraints of each approach. Moreover, the promising applications of green ammonia in the energy sectors were discussed. The various barriers, i.e., technical, economic, environmental, and regulations and policies, facing the widespread of green ammonia were also discussed. Finally, the contribution of green ammonia in achieving the different sustainable development goals was elaborated, focusing on the contribution of green ammonia in achieving climate change (SDG 13), clean energy (SDG 7), and other sustainability-related goals. Low efficiencies, high cost, and negative environmental impacts are the common challenges of the various production methods. The progress in green ammonia is essential for achieving SDG2, “Zero hunger”. SDG3 “healthy life and well-being” and SDG13 “Climate action”, will be achieved by eliminating 3.85 kg CO2-eq/kg NH3 emitted from conventional ammonia-based processes. Ease storing of green ammonia in liquid form (at 9 bar or cooling to −33°); makes it the best green energy source, i.e., achieving SDG7 “green and affordable energy”. By 2050, green ammonia is expected to represent 99 % of marine fuel, thus contributing to SDG9 “Industry and Infrastructure”. Moreover, green ammonia production will save 35.2 GJ of natural gas, thus achieving SDG12 “Responsible consumption/production”. ]]></description>
<enclosure url="https://encrypted-tbn0.gstatic.com/images" length="49398" type="image/jpeg"/>
<pubDate>Tue, 23 Jan 2024 18:20:43 -0500</pubDate>
<dc:creator>njvahlberg</dc:creator>
<media:keywords>Green ammonia, Production and assessment, Applications, Barriers, Sustainable development goals</media:keywords>
<content:encoded><![CDATA[<section id="s0005">
<h2 id="st030" class="u-h4 u-margin-l-top u-margin-xs-bottom">1.<span> </span>Introduction</h2>
<p id="p0330">Rapid use of fossil fuels has led to serious health problems and considerable climate change<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0005" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0005"><span class="anchor-text">[1]</span></a><span>. The widespread use of <a href="https://www.sciencedirect.com/topics/engineering/renewable-energy-source" title="Learn more about renewable energy sources from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable energy sources</a> is considered the best available route for controlling climate change and its associated problems </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0010" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0010"><span class="anchor-text">[2]</span></a>. Renewable energy sources are sustainable with minimal or no environmental impact<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0015" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0015"><span class="anchor-text">[3]</span></a><span>. The most common renewable energy sources, wind and solar, are intermittent and have varying intensities. Employing <a href="https://www.sciencedirect.com/topics/engineering/energy-storage-system" title="Learn more about energy storage systems from ScienceDirect's AI-generated Topic Pages" class="topic-link">energy storage systems</a> is considered a valid option to optimize and sustain renewable energy supply, such as <a href="https://www.sciencedirect.com/topics/engineering/thermal-energy-storage" title="Learn more about thermal energy storage from ScienceDirect's AI-generated Topic Pages" class="topic-link">thermal energy storage</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0020" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0020"><span class="anchor-text">[4]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0025" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0025"><span class="anchor-text">[5]</span></a>, mechanical energy storage systems<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0030" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0030"><span class="anchor-text">[6]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0035" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0035"><span class="anchor-text">[7]</span></a>, electrochemical energy storage systems<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0040" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0040"><span class="anchor-text">[8]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0045" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0045"><span class="anchor-text">[9]</span></a>, or chemical energy storage systems<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0050" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0050"><span class="anchor-text">[10]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0055" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0055"><span class="anchor-text">[11]</span></a><span>. <a href="https://www.sciencedirect.com/topics/engineering/green-hydrogen" title="Learn more about Green hydrogen from ScienceDirect's AI-generated Topic Pages" class="topic-link">Green hydrogen</a> integrated with <a href="https://www.sciencedirect.com/topics/engineering/renewable-energy-system" title="Learn more about renewable energy systems from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable energy systems</a> is one of the good choices for achieving this purpose </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0060" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0060"><span class="anchor-text">[12]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0065" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0065"><span class="anchor-text">[13]</span></a><span>. However, the difficulties of <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-storage" title="Learn more about hydrogen storage from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen storage</a> and transport limit its application </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0070" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0070"><span class="anchor-text">[14]</span></a><span>. <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-energy" title="Learn more about Hydrogen energy from ScienceDirect's AI-generated Topic Pages" class="topic-link">Hydrogen energy</a> carriers such as methanol, ammonia, hydrazine, etc., can be applied to overcome the abovementioned challenges. Among the different hydrogen carriers, ammonia has several features, such as ease of transport and storage and can be obtained from renewable energy sources </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0075" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0075"><span class="anchor-text">[15]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0080" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0080"><span class="anchor-text">[16]</span></a>. Therefore, extensive efforts are being made to commercialize it<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0085" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0085"><span class="anchor-text">[17]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0090" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0090"><span class="anchor-text">[18]</span></a>.</p>
<p id="p0335"><span>Today, fossil fuels are used for <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-production" title="Learn more about hydrogen production from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen production</a>, which is combined with nitrogen using the traditional Haber-Bosch process at extremely high temperatures and pressures </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0095" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0095"><span class="anchor-text">[19]</span></a>. Numerous investigations reported hazardous emissions from conventional ammonia synthesis plants<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0100" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0100"><span class="anchor-text">[20]</span></a>. It was estimated that greenhouse gas emitted from ammonia plants ranged from 1.25 to 2.16 kg CO<sub>2-eq.</sub>/kg NH<sub>3</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0105" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0105"><span class="anchor-text">[21]</span></a>. Therefore, regulations regarding CO<sub>2</sub><span> </span>and other harmful emissions, such as NOx and SOx, are mandatory and may yield major technological changes in the ammonia industry. Significant efforts have been made to tackle hazardous emissions from conventional ammonia production plants.</p>
<p id="p0340"><span>Green ammonia, a term used to describe ammonia production that emits no or almost no carbon dioxide into the atmosphere, has piqued the interest of academic institutions, industrial sectors, and national governments. This is due to the reliability, stability and sustainability of green ammonia applications in <a href="https://www.sciencedirect.com/topics/engineering/power-engineering" title="Learn more about power technologies from ScienceDirect's AI-generated Topic Pages" class="topic-link">power technologies</a> like furnaces, fuel cells, <a href="https://www.sciencedirect.com/topics/engineering/gas-turbine" title="Learn more about gas turbines from ScienceDirect's AI-generated Topic Pages" class="topic-link">gas turbines</a>, and <a href="https://www.sciencedirect.com/topics/engineering/internal-combustion-engine" title="Learn more about internal combustion engines from ScienceDirect's AI-generated Topic Pages" class="topic-link">internal combustion engines</a> at different power scales, as well as in the agricultural sector as a fertilizer and many other applications. Green ammonia production mainly depends on renewable energy </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0110"><span class="anchor-text">[22]</span></a>. Much work has been done on green ammonia as a promising hydrogen carrier. The import/export market of green ammonia was described by looking at the pros and cons of using ammonia as a hydrogen carrier, how much it costs to produce and ship ammonia, as well as the limitation of supply and demand<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0115" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0115"><span class="anchor-text">[23]</span></a>. The offshore green ammonia production was analyzed considering, land availability constraints, and transportation to major demand centers<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0120" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0120"><span class="anchor-text">[24]</span></a>. Another study determined the economics of green ammonia production based on the levelised cost of ammonia (LCOA) by considering 534 locations in 70 countries<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0125" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0125"><span class="anchor-text">[25]</span></a><span>. The effect of the hydrogen production route, i.e., <a href="https://www.sciencedirect.com/topics/engineering/alkaline-water-electrolysis" title="Learn more about alkaline water electrolysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">alkaline water electrolysis</a> (AWE), <a href="https://www.sciencedirect.com/topics/engineering/polymer-electrolyte-membrane" title="Learn more about polymer electrolyte membrane from ScienceDirect's AI-generated Topic Pages" class="topic-link">polymer electrolyte membrane</a> WE (PWE), and solid oxide <a href="https://www.sciencedirect.com/topics/engineering/electrolysis-cell" title="Learn more about electrolysis cell from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrolysis cell</a> (SOEC), on the price of green ammonia production (modified Haber-Bosch process) was performed by Lee et al. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0130" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0130"><span class="anchor-text">[26]</span></a>. Results indicated that the SOEC method is the best due to the lower energy consumption. A techno-economic evaluation of hydrogen production from green ammonia reforming was performed and compared with the most common hydrogen production routes<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0135" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0135"><span class="anchor-text">[27]</span></a>. The results indicated that the ammonia route is superior in CO<sub>2</sub><span> </span>reduction, while the price can be significantly decreased by increasing capacity and technical advances.</p>
<p id="p0345">Although numerous reviews have been carried out on green ammonia, including the progress in green ammonia application in the energy sector<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0115" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0115"><span class="anchor-text">[23]</span></a>, thermodynamic analysis of ammonia production<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0140" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0140"><span class="anchor-text">[28]</span></a>, hydrogen production from green ammonia<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0135" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0135"><span class="anchor-text">[27]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0145" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0145"><span class="anchor-text">[29]</span></a>, solar energy integration into low-pressure green ammonia production<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0150" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0150"><span class="anchor-text">[30]</span></a><span>, green ammonia from <a href="https://www.sciencedirect.com/topics/engineering/water-electrolysis" title="Learn more about water electrolysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">water electrolysis</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0130" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0130"><span class="anchor-text">[26]</span></a>, and plasma method for the synthesis of green ammonia<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0155" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0155"><span class="anchor-text">[31]</span></a><span>. The literature missed assessing the different routes for green ammonia, the barriers facing the <a href="https://www.sciencedirect.com/topics/engineering/commercialisation" title="Learn more about commercialization from ScienceDirect's AI-generated Topic Pages" class="topic-link">commercialization</a> of green ammonia, and the role of green ammonia in achieving the SDGs. Hence, this work aims to discuss and analyse the various aspects related to the future of green ammonia, such as unconventional synthesis routes, technical complexities, and environmental and economic barriers. The second part of this work discusses in detail the importance and contribution of green ammonia in <a href="https://www.sciencedirect.com/topics/engineering/achieving-sustainable-development" title="Learn more about achieving sustainable development from ScienceDirect's AI-generated Topic Pages" class="topic-link">achieving sustainable development</a> goals (SDGs). Specifically, this review aims to answer the major research questions: (i) What are green ammonia's environmental and economic performances? (ii) Does the communities need more investment in green ammonia?, (iii) are there any policies or legislative laws that promote green ammonia production on a large scale?, (iv) how will this develop in the future?, and (v) what are the significant impacts of green ammonia on the different SDGs?</span></p>
</section>
<section id="s0010">
<h2 id="st035" class="u-h4 u-margin-l-top u-margin-xs-bottom">2.<span> </span>Ammonia characteristics</h2>
<p id="p0350">Ammonia is a colourless gas with a bitter-burning taste that liquefies at –33.3 °C and freezes to a white crystal at −77.7 °C. It consists of one of the most abundant atoms, i.e., hydrogen and nitrogen forming a chemical structure known as NH<sub>3</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0160" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0160"><span class="anchor-text">[32]</span></a>. As a gas, ammonia is flammable and can react quickly with oxygen forming nitrogen, nitrogen (II), and water. As a liquid, it is found as ammonium hydroxide, a caustic solution, and a weak base with an NH<sub>3</sub><span> </span>percentage that reaches up to 30 %<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0165" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0165"><span class="anchor-text">[33]</span></a>. The form of ammonium hydroxide reveals the features of a weak base neutralizing acid-forming NH<sub>4</sub>Cl (ammonium salts). These salts are water-soluble, volatile, and exposure to it can cause mild effects, including irritation, shortness of breath, cough, nausea, and headache<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0170" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0170"><span class="anchor-text">[34]</span></a>. <span>Ammonium salts reveal weak acids' characteristics, which can spontaneously turn to ammonia due to their proton capability to break down <a href="https://www.sciencedirect.com/topics/engineering/nitrogen-atom" title="Learn more about nitrogen atoms from ScienceDirect's AI-generated Topic Pages" class="topic-link">nitrogen atoms</a> which are bound with their anion (weak acids) </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0175" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0175"><span class="anchor-text">[35]</span></a>. It might also appear as N<sub>2</sub>H<sub>4</sub><span> (hydrazine), a corrosive and volatile fuel ingredient, owing to the ammonia <a href="https://www.sciencedirect.com/topics/engineering/oxidation-reaction" title="Learn more about oxidation from ScienceDirect's AI-generated Topic Pages" class="topic-link">oxidation</a> in solutions </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0180" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0180"><span class="anchor-text">[36]</span></a>. Reacting ammonia with nitric acid produces a porous pellet, a highly used fertiliser known as ammonium nitrite (NH<sub>4</sub>NO<sub>3</sub>), also used in explosives mining<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0185" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0185"><span class="anchor-text">[37]</span></a>.</p>
</section>
<section id="s0015">
<h2 id="st040" class="u-h4 u-margin-l-top u-margin-xs-bottom">3.<span> </span>Sustainable ammonia production from hydrogen</h2>
<p id="p0355">It is crucial to overview the most sustainable methods of ammonia production and how it’s produced. Worldwide ammonia production has seen substantial growth in the last decade, with the top 5 countries (China, Russia, India, USA and Indonesia) accounting for around 60 % of the total market<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0190" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0190"><span class="anchor-text">[38]</span></a><span>. The ammonia synthesis occurs according to the <a href="https://www.sciencedirect.com/topics/engineering/exothermic-reaction" title="Learn more about exothermic reaction from ScienceDirect's AI-generated Topic Pages" class="topic-link">exothermic reaction</a> of Nitrogen and hydrogen as expressed by Eq. 1 </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0195" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0195"><span class="anchor-text">[39]</span></a>:<span class="display"><span id="e0005" class="formula"><span class="label">(1)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-29-Frame" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: 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is="true">�</mi></mrow><mrow is="true"><mn is="true">2</mn></mrow></msub><mo is="true">+</mo><mfrac is="true"><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mn is="true">2</mn></mrow></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mn is="true">2</mn></mrow></msub><mo stretchy="false" is="true">↔</mo><mi mathvariant="bold-italic" is="true">�</mi><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mn is="true">3</mn></mrow></msub><mspace width="3em" is="true"></mspace><mi mathvariant="normal" is="true">Δ</mi><mi mathvariant="bold-italic" is="true">�</mi><mo is="true">=</mo><mo is="true">-</mo><mn is="true">93</mn><mrow is="true"><mfenced open="(" close=")" is="true"><mfrac is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi></mrow></mfrac></mfenced></mrow></mrow></math></span></span></span></span></span></p>
<p id="p0360">Due to global warming, there is a challenge to find an economical and sustainable way for ammonia production. According to MacFarlane et al.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0200" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0200"><span class="anchor-text">[40]</span></a>, different routes are used for producing green ammonia as follows: (1st generation) requires capturing carbon after ammonia production and storage form the Haber-Bosh process which is known as (blue ammonia), (2nd generation) involves the ammonia production from a greener feedstock (nitrogen and hydrogen) it has the advantage to change the current Haber-Bosh process into a renewable source, and (3rd generation) involves the deviation from the Haber-Bosh process through processes that involve high stability, sustainability, and renewable source employment for ammonia production.</p>
<p id="p0365"><span>To date, there are several ways for the indirect synthesis of green ammonia, including <a href="https://www.sciencedirect.com/topics/engineering/microbial-electrolysis-cell" title="Learn more about microbial electrolysis cells from ScienceDirect's AI-generated Topic Pages" class="topic-link">microbial electrolysis cells</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0205" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0205"><span class="anchor-text">[41]</span></a>, photosynthesis<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0210" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0210"><span class="anchor-text">[42]</span></a><span>, <a href="https://www.sciencedirect.com/topics/engineering/dark-fermentation" title="Learn more about dark fermentation from ScienceDirect's AI-generated Topic Pages" class="topic-link">dark fermentation</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0215" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0215"><span class="anchor-text">[43]</span></a>, and electrolysis<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0220" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0220"><span class="anchor-text">[44]</span></a><span>, with the <a href="https://www.sciencedirect.com/topics/engineering/electrochemical-method" title="Learn more about electrochemical methods from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrochemical methods</a> gaining a great interest in many countries </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0225" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0225"><span class="anchor-text">[45]</span></a>. These methods will produce green hydrogen which exothermically<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0230" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0230"><span class="anchor-text">[46]</span></a><span> </span>react with nitrogen for green ammonia production using molten salt synthesis, solid-state synthesis, thermochemical looping, or photocatalytic routes<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0150" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0150"><span class="anchor-text">[30]</span></a>. The common way to produce green ammonia is the power to ammonia<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0205" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0205"><span class="anchor-text">[41]</span></a><span> through Haber Process, which involves using renewable energy to split water for green <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-production" title="Learn more about hydrogen production from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen production</a>. Green ammonia is successfully produced with 83 % efficiency using a hybrid system consisting of a high-temperature operating system with heat integrations </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0235" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0235"><span class="anchor-text">[47]</span></a>.</p>
<section id="s0020">
<h3 id="st045" class="u-h4 u-margin-m-top u-margin-xs-bottom">3.1.<span> </span>Power to ammonia synthesis (Water Electrolysis)</h3>
<div>
<p id="p0370"><span><a href="https://www.sciencedirect.com/topics/engineering/hydrogen-gas" title="Learn more about Hydrogen gas from ScienceDirect's AI-generated Topic Pages" class="topic-link">Hydrogen gas</a> (H</span><sub>2</sub>) and oxygen (O<sub>2</sub><span>) are produced by the <a href="https://www.sciencedirect.com/topics/engineering/electrolysis-of-water" title="Learn more about electrolysis of water from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrolysis of water</a> (H</span><sub>2</sub><span>O). The water-splitting process is done in <a href="https://www.sciencedirect.com/topics/engineering/electrochemical-cell" title="Learn more about electrochemical cells from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrochemical cells</a> which can be categorized according to their configuration, i.e., <a href="https://www.sciencedirect.com/topics/engineering/polymer-electrolyte-membrane" title="Learn more about polymer electrolyte membrane from ScienceDirect's AI-generated Topic Pages" class="topic-link">polymer electrolyte membrane</a> electrolyzers, alkaline electrolyzers, and solid oxide electrolyzers </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0240" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0240"><span class="anchor-text">[48]</span></a><span>. All cells are composed of an anode, cathode, electrolyte, power source (renewable), and sometimes a membrane. Upon passing an electric current through the electrodes (1.23 V in an ideal case), the covalent bonds will start to break down, allowing hydrogen and oxygen gases to be produced. In the case of an alkaline electrolyzer, <a href="https://www.sciencedirect.com/topics/engineering/potassium" title="Learn more about potassium from ScienceDirect's AI-generated Topic Pages" class="topic-link">potassium</a> hydroxide is commonly used as an electrolyte to avoid <a href="https://www.sciencedirect.com/topics/engineering/acid-corrosion" title="Learn more about acid corrosion from ScienceDirect's AI-generated Topic Pages" class="topic-link">acid corrosion</a>; In terms of anodic and cathodic stability, nickel is the most commonly employed electrode </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0245" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0245"><span class="anchor-text">[49]</span></a>. The process of ammonia production using electrolysis includes four units: renewable source (solar or wind), electrolyzer, air separation unit, and Haber Bosch process (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0005" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0005"><span class="anchor-text">Fig. 1</span></a>). The first electrolysis-based ammonia synthesis was introduced in 1920 based in Haber- bosh process with an energy consumption of 46 ± 2 GJ/tNH<sub>3</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0250" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0250"><span class="anchor-text">[50]</span></a>. However, this stopped by the 1990 s owing to the high cost of fossil fuels. Several projects for solar to ammonia electrolysis have been initiated in Europe and America. Today, the current trend toward green ammonia is seeking a direct method for ammonia production under mild operating conditions.</p>
<figure class="figure text-xs" id="f0005"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr1.jpg" height="350" alt="" aria-describedby="cn0005"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr1_lrg.jpg" target="_blank" download="" title="Download high-res image (198KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (198KB)</span></span></a></li>
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</ol>
<p id="sp0015"><span class="label">Fig. 1</span>.<span> </span>Process description for green ammonia production<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0290" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0290"><span class="anchor-text">[58]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.man-es.com/discover/two-stroke-ammonia-engine/green-ammonia-production" target="_blank" rel="noreferrer noopener"><span class="anchor-text">https://www.man-es.com/discover/two-stroke-ammonia-engine/green-ammonia-production</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a>. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)</p>
<span class="captions text-s"><span id="cn0005"></span></span></figure>
</div>
<div>
<p id="p0375">The cost of ammonia synthesis through the water electrolysis route is considered a costly process due to the electrolysers' high capital costs; also, they utilize a large amount of energy to produce green hydrogen as an intermediate stock for green ammonia synthesis through the Haber process.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0005" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0005"><span class="anchor-text">Table 1</span></a><span> </span>compares different technologies used in water electrolysis based on the electrolyzer type.</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0005">
<p id="sp0105"><span class="label">Table 1</span>.<span> </span>Different technologies used in water electrolysis based on the electrolyzer type.</p>
<span class="captions text-s"><span id="cn0095"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">Type of the electrolyzer</th>
<th scope="col" class="align-left">Eff. %</th>
<th scope="col" class="align-left">Cost<br>$/kw</th>
<th scope="col" class="align-left">Pressure (bar)</th>
<th scope="col" class="align-left">Comments</th>
<th scope="col" class="align-left">Ref.</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">AEL “Alkaline electrolyzer”</td>
<td class="align-left">50–60</td>
<td class="align-left">1000–5000</td>
<td class="align-left">1–30</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">1-</span>
<p id="p0005">The lifetime of the stack can reach 55,000 to 120,000 h</p>
<p id="p0010">This method consumes higher electricity (19 % and 46 %) than PEM and SO, respectively.</p>
<p id="p0015">Nickel-coated perforated stainless steel is a typical electrode at the oxygen and hydrogen side with KOH as the electrolyte.</p>
</li>
</ul>
</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0255" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0255"><span class="anchor-text">[51]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0260" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0260"><span class="anchor-text">[52]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0265" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0265"><span class="anchor-text">[53]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0270" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0270"><span class="anchor-text">[54]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">PEM “polymer electrolyte membrane electrolyzer”</td>
<td class="align-left">46–60</td>
<td class="align-left">1500–2100</td>
<td class="align-left">20–50</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">1-</span>
<p id="p0020">One of its main features is their compact design</p>
<p id="p0025">Safe owing to their polymer electrolyte no need for any corrosive electrolytes</p>
<p id="p0030">The lifetime of the stack can reach 55,000 to 100,000 h</p>
<p id="p0035">The typical electrode at the oxygen side is Iridium oxide at the oxygen side and Platinum nanoparticles on carbon black at the hydrogen side</p>
</li>
</ul>
</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0260" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0260"><span class="anchor-text">[52]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0275" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0275"><span class="anchor-text">[55]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0280" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0280"><span class="anchor-text">[56]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">SOE “Solid oxide electrolyzer”</td>
<td class="align-left">Up to 85 %</td>
<td class="align-left">&gt; 2000</td>
<td class="align-left">1–15</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">1-</span>
<p id="p0040">High operating temperature (up to 1000 °C)</p>
<p id="p0045">Their lifetime is lower (up to 18,000 h) owing to their high operating temperature.</p>
<p id="p0050">The typical electrode at the oxygen side is Perovskite-type (e.g., LSCF, LSM) at the oxygen side and Ni/YSZ at the hydrogen side with YSZ “Yttria-stabilized Zirconia” as the electrolyte</p>
</li>
</ul>
</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0095" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0095"><span class="anchor-text">[19]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0260" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0260"><span class="anchor-text">[52]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0285" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0285"><span class="anchor-text">[57]</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</section>
<section id="s0025">
<h3 id="st050" class="u-h4 u-margin-m-top u-margin-xs-bottom">3.2.<span> </span>Emerging ways for ammonia synthesis</h3>
<p id="p0380">Even though the existing technologies for green ammonia synthesis offer many facilities due to the existing equipment’s from the last century, research and development are seeking a route for direct production of green ammonia without involving the intermediate step of hydrogen production. Many research themes imply a new synthesis concept to obtain a pilot-scale green ammonia production. Examples of these emerging methods are photosynthesis, electrochemical methods, heterogenous and homogenous catalysis, molten salt synthesis, solid-state synthesis, and non-thermal plasmatic synthesis. Such methods rely on mild operation conditions and open the way for direct ammonia production<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0295" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0295"><span class="anchor-text">[59]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0300" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0300"><span class="anchor-text">[60]</span></a>.</p>
<section id="s0030">
<h4 id="st055" class="u-margin-m-top u-margin-xs-bottom">3.2.1.<span> </span>Electrochemical ammonia production</h4>
<p id="p0385">The electrochemical production route of ammonia is distinguished from conventional NH<sub>3</sub><span> production by its reaction route, operating conditions, and energy source. The main aspect that distinguishes electrochemical synthesis from electrolysis is the direct synthesis of green ammonia from air and water utilizing <a href="https://www.sciencedirect.com/topics/engineering/renewable-energy-source" title="Learn more about renewable energy sources from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable energy sources</a>, such as tidal or solar energy. A common process involves oxidizing hydrogen or water at the anode, which releases protons that move over a solid or liquid electrolyte to the <a href="https://www.sciencedirect.com/topics/engineering/cathode-side" title="Learn more about cathode side from ScienceDirect's AI-generated Topic Pages" class="topic-link">cathode side</a>. Nitrogen reacts with the protons in the cathode under mild conditions to produce NH</span><sub>3</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0305" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0305"><span class="anchor-text">[61]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0310" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0310"><span class="anchor-text">[62]</span></a><span>. Typically, NRR “the nitrogen reduction reaction” and <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-evolution-reaction" title="Learn more about HER from ScienceDirect's AI-generated Topic Pages" class="topic-link">HER</a> “the hydrogen evolution reaction” compete at the cathode as follows </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0315" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0315"><span class="anchor-text">[63]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0320" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0320"><span class="anchor-text">[64]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0325" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0325"><span class="anchor-text">[65]</span></a>:</p>
<p id="p0390">4 In electrolytes with a pH &lt; 6<span class="display"><span id="e0010" class="formula"><span class="label">(2)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-30-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="33.614ex" height="2.894ex" viewBox="0 -896.2 14472.8 1246" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(950,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(1404,0)"><g is="true"><use xlink:href="#MJMAIN-28" x="0" y="0"></use><g is="true" transform="translate(389,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-67"></use></g></g></g><use xlink:href="#MJMAIN-29" x="935" y="0"></use></g></g><g is="true" transform="translate(2728,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3507,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(4007,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(1041,413)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2B"></use></g></g><g is="true" transform="translate(5921,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(6922,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(7422,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g></g><g is="true" transform="translate(554,362)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g><g is="true" transform="translate(8905,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(10183,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(10684,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(1027,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(2010,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g><g is="true" transform="translate(13148,0)"><g is="true"><use xlink:href="#MJMAIN-28" x="0" y="0"></use><g is="true" transform="translate(389,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-67"></use></g></g></g><use xlink:href="#MJMAIN-29" x="935" y="0"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mrow is="true"><mfenced open="(" close=")" is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow></mfenced></mrow><mo linebreak="badbreak" is="true">+</mo><mn is="true">6</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">+</mo></msup><mo linebreak="badbreak" is="true">+</mo><mn is="true">6</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">-</mo></msup><mo stretchy="false" is="true">→</mo><mn is="true">2</mn><msub is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mn is="true">3</mn></msub><mrow is="true"><mfenced open="(" close=")" is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow></mfenced></mrow></mrow></math></span></span></span></span></span><span class="display"><span id="e0015" class="formula"><span class="label">(3)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-31-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="21.919ex" height="2.894ex" viewBox="0 -896.2 9437.4 1246" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(500,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(1041,413)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2B"></use></g></g><g is="true" transform="translate(2414,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3414,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(3915,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g></g><g is="true" transform="translate(554,362)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g><g is="true" transform="translate(5398,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(6676,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(8112,0)"><g is="true"><use xlink:href="#MJMAIN-28" x="0" y="0"></use><g is="true" transform="translate(389,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-67"></use></g></g></g><use xlink:href="#MJMAIN-29" x="935" y="0"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mn is="true">2</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">+</mo></msup><mo linebreak="badbreak" is="true">+</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">-</mo></msup><mo stretchy="false" is="true">→</mo><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mrow is="true"><mfenced open="(" close=")" is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow></mfenced></mrow></mrow></math></span></span></span></span></span></p>
<p id="p0395">5 In electrolytes with a pH &gt; 8<span class="display"><span id="e0020" class="formula"><span class="label">(4)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-32-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="34.967ex" height="2.779ex" viewBox="0 -846.5 15055.2 1196.3" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(950,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(1404,0)"><g is="true"><use xlink:href="#MJMAIN-28" x="0" y="0"></use><g is="true" transform="translate(389,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-67"></use></g></g></g><use xlink:href="#MJMAIN-29" x="935" y="0"></use></g></g><g is="true" transform="translate(2728,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3507,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(4007,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(5444,0)"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(6504,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(7504,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(8005,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g></g><g is="true" transform="translate(554,362)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g><g is="true" transform="translate(9488,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(10766,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(11266,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(1027,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(2010,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g><g is="true" transform="translate(13730,0)"><g is="true"><use xlink:href="#MJMAIN-28" x="0" y="0"></use><g is="true" transform="translate(389,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-67"></use></g></g></g><use xlink:href="#MJMAIN-29" x="935" y="0"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mrow is="true"><mfenced open="(" close=")" is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow></mfenced></mrow><mo linebreak="badbreak" is="true">+</mo><mn is="true">6</mn><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo linebreak="badbreak" is="true">+</mo><mn is="true">6</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">-</mo></msup><mo stretchy="false" is="true">→</mo><mn is="true">2</mn><msub is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mn is="true">3</mn></msub><mrow is="true"><mfenced open="(" close=")" is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow></mfenced></mrow></mrow></math></span></span></span></span></span><span class="display"><span id="e0025" class="formula"><span class="label">(5)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-33-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="32.116ex" height="2.894ex" viewBox="0 -896.2 13827.8 1246" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(500,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(1936,0)"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(2996,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3997,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(4497,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g></g><g is="true" transform="translate(554,362)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g><g is="true" transform="translate(5980,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(7258,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(8695,0)"><g is="true"><use xlink:href="#MJMAIN-28" x="0" y="0"></use><g is="true" transform="translate(389,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-67"></use></g></g></g><use xlink:href="#MJMAIN-29" x="935" y="0"></use></g></g><g is="true" transform="translate(10019,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(10798,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(11298,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(1878,430)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mn is="true">2</mn><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo linebreak="badbreak" is="true">+</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">-</mo></msup><mo stretchy="false" is="true">→</mo><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mrow is="true"><mfenced open="(" close=")" is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow></mfenced></mrow><mo linebreak="badbreak" is="true">+</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">-</mo></msup></mrow></math></span></span></span></span></span></p>
<p id="p0400"><span>The main issue facing this process is the <a href="https://www.sciencedirect.com/topics/engineering/thermodynamic-stability" title="Learn more about thermodynamic stability from ScienceDirect's AI-generated Topic Pages" class="topic-link">thermodynamic stability</a> of the N</span><sub>2</sub>, which requires high energy to defeat the bonding energy (941 kJ/mol) of<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-34-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="7.226ex" height="1.971ex" viewBox="0 -747.2 3111.1 848.5" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMATHI-4E"></use></g><g is="true" transform="translate(1166,0)"><use xlink:href="#MJMAIN-2261"></use></g><g is="true" transform="translate(2222,0)"><use xlink:href="#MJMATHI-4E"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi is="true">�</mi><mo is="true">≡</mo><mi is="true">�</mi></mrow></math></span></span></span>. Therefore, depending on the operating temperature, various electrochemical green ammonia production can be categorized, including low operating temperature up to 100 °C, mid-operating temperature between 100 and 350 °C, molten salt ammonia synthesis between 100 and 500 °C, solid-state ammonia synthesis &gt; 500 °C, and high operating temperature 350 to 700 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0330" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0330"><span class="anchor-text">[66]</span></a>.</p>
<section id="s0035">
<h5 id="st060" class="u-margin-m-top u-margin-xs-bottom">3.2.1.1.<span> </span>Low-temperature electrochemical ammonia synthesis</h5>
<div>
<p id="p0405">Low-temperature ammonia synthesis receives considerable attention among researchers with more than a hundred publications per annum<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0335" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0335"><span class="anchor-text">[67]</span></a>. A typical cell with low operating conditions consists of a platinum anode<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0330" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0330"><span class="anchor-text">[66]</span></a>, Ru-based cathode<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0340" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0340"><span class="anchor-text">[68]</span></a><span>, and a high conductive proton membrane, usually <a href="https://www.sciencedirect.com/topics/engineering/nafion" title="Learn more about Nafion from ScienceDirect's AI-generated Topic Pages" class="topic-link">Nafion</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0345" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0345"><span class="anchor-text">[69]</span></a>. Most studies are performed at room temperature using liquid aqueous electrolytes such as water that can directly donate the H<sup>+</sup><span> </span>proton. Acidic electrolytes are preferable due to their high proton environment. In contrast, in basic electrolytes, there is a high competition between hydrogen evolution reactions and nitrogen reduction reactions, as shown in (equations 3 &amp; 4)<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0350" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0350"><span class="anchor-text">[70]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0355" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0355"><span class="anchor-text">[71]</span></a>. Temperature plays a key role in enhancing NH<sub>3</sub><span> </span>production rate (10<sup>−8</sup>- 10<sup>−5</sup><span> </span>mol s<sup>−1</sup><span> </span>cm<sup>−2</sup>) at an operating temperature up to 90 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0325" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0325"><span class="anchor-text">[65]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0360" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0360"><span class="anchor-text">[72]</span></a>. Another key factor affecting the overall performance of ammonia production is the type of catalyst. Today, numerous types of catalysts have been studied including noble metals<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0365" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0365"><span class="anchor-text">[73]</span></a>, metal (oxides<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0370" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0370"><span class="anchor-text">[74]</span></a>, sulfides<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0375" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0375"><span class="anchor-text">[75]</span></a><span>, and <a href="https://www.sciencedirect.com/topics/engineering/nitride" title="Learn more about nitrides from ScienceDirect's AI-generated Topic Pages" class="topic-link">nitrides</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0380" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0380"><span class="anchor-text">[76]</span></a>), organometallic complexes<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0385" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0385"><span class="anchor-text">[77]</span></a><span> </span>etc. A study performed by Zhang et al.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0390" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0390"><span class="anchor-text">[78]</span></a><span> </span>involved using a bi-metallic oxide (CoMoO<sub>4</sub>) for NH<sub>3</sub><span> synthesis at atmospheric pressure and room temperature. High <a href="https://www.sciencedirect.com/topics/engineering/faradic-efficiency" title="Learn more about faradic efficiency from ScienceDirect's AI-generated Topic Pages" class="topic-link">faradic efficiency</a> and ammonia yield of 22.86 % and 7.98 mol h</span><sup>−1</sup><span> </span>g<sub>cat</sub><sup>−1</sup><span> </span>are higher than those obtained using mono metallic oxides.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0010" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0010"><span class="anchor-text">Table 2</span></a><span> </span>summarizes the progress done in preparing ammonia at low-temperature.</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0010">
<p id="sp0110"><span class="label">Table 2</span>.<span> </span>Different experimental works on low-temperature ammonia synthesis.</p>
<span class="captions text-s"><span id="cn0100"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">T (°C)</th>
<th scope="col" class="align-left">Electrolyte</th>
<th scope="col" class="align-left">Cathode</th>
<th scope="col" class="align-left">Ammonia Yield (mol/s cm<sup>−2</sup>)</th>
<th scope="col" class="align-left">Ref.</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">50</td>
<td class="align-left">AEM</td>
<td class="align-left">Fe</td>
<td class="align-left">380 × 10<sup>−12</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0395" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0395"><span class="anchor-text">[79]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">80</td>
<td class="align-left">Nafion</td>
<td class="align-left">SmBaCuMO<sup>5+</sup></td>
<td class="align-left">870 × 10<sup>−10</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0400" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0400"><span class="anchor-text">[80]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">80</td>
<td class="align-left">Nafion</td>
<td class="align-left">Sm<sub>1.5</sub>Sr<sub>0.5</sub>NiO<sub>4</sub></td>
<td class="align-left">105 × 10<sup>−10</sup></td>
<td class="align-left" rowspan="2"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0405" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0405"><span class="anchor-text">[81]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">80</td>
<td class="align-left">SPSF</td>
<td class="align-left">Sm<sub>1.5</sub>Sr<sub>0.5</sub>NiO<sub>4</sub></td>
<td class="align-left">103 × 10<sup>−10</sup></td>
</tr>
<tr class="valign-top">
<td class="align-left">Room T</td>
<td class="align-left">Nafion</td>
<td class="align-left">Fe/Fe<sub>3</sub>O<sub>4</sub></td>
<td class="align-left">111 × 10<sup>−10</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0410" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0410"><span class="anchor-text">[82]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Room T</td>
<td class="align-left">AEM</td>
<td class="align-left">Fe–CuS/C</td>
<td class="align-left">686 × 10<sup>−12</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0375" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0375"><span class="anchor-text">[75]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">50</td>
<td class="align-left">AEM</td>
<td class="align-left">RuPt</td>
<td class="align-left">635 × 10<sup>−12</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0415" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0415"><span class="anchor-text">[83]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Room T</td>
<td class="align-left">Nafion</td>
<td class="align-left">Au nanorods</td>
<td class="align-left">27 × 10<sup>−12</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0420" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0420"><span class="anchor-text">[84]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Room T</td>
<td class="align-left">Nafion</td>
<td class="align-left">Fe2O3-CNT</td>
<td class="align-left">36 × 10<sup>−12</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0355" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0355"><span class="anchor-text">[71]</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</section>
<section id="s0040">
<h5 id="st065" class="u-margin-m-top u-margin-xs-bottom">3.2.1.2.<span> </span>Molten-salt ammonia synthesis (Moderate Temperature)</h5>
<div>
<p id="p0410"><span>The main challenge facing many aqueous systems for ambient ammonia synthesis is the high hydrogen evolution and <a href="https://www.sciencedirect.com/topics/engineering/slow-kinetics" title="Learn more about slow kinetics from ScienceDirect's AI-generated Topic Pages" class="topic-link">slow kinetics</a>. Molten salt electrolytes revealed a promising result with enhanced faradic efficiency. For moderate NH</span><sub>3</sub><span> </span>synthesis, in the range of 100 to 400 °C, it utilizes ammonia using a molten state electrolyte. In a typical process, a strong competition of HER during NH<sub>3</sub><span> </span>synthesis owing to the<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-35-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="7.226ex" height="1.971ex" viewBox="0 -747.2 3111.1 848.5" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMATHI-4E"></use></g><g is="true" transform="translate(1166,0)"><use xlink:href="#MJMAIN-2261"></use></g><g is="true" transform="translate(2222,0)"><use xlink:href="#MJMATHI-4E"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi is="true">�</mi><mo is="true">≡</mo><mi is="true">�</mi></mrow></math></span></span></span><span> </span>bonding which can be migrated if H<sub>2</sub><span> </span>at a gaseous state reacts with nitride ions. A typical cell consists of an electrolyte (molten salt), a porous cathode, and a permeable anode (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0010" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0010"><span class="anchor-text">Fig. 2</span></a>).</p>
<figure class="figure text-xs" id="f0010"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr2.jpg" height="416" alt="" aria-describedby="cn0010"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr2_lrg.jpg" target="_blank" download="" title="Download high-res image (254KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (254KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr2.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0020"><span class="label">Fig. 2</span>.<span> </span><span>Illustration of molten-salt <a href="https://www.sciencedirect.com/topics/engineering/ammonia-synthesis" title="Learn more about ammonia synthesis from ScienceDirect's AI-generated Topic Pages" class="topic-link">ammonia synthesis</a>, adapted from </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0425" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0425"><span class="anchor-text">[85]</span></a><span> </span>with permission No. 5441990967119.</p>
<span class="captions text-s"><span id="cn0010"></span></span></figure>
</div>
<div>
<p id="p0415">Murakami<span> </span><a class="anchor u-display-inline anchor-paragraph" href="http://et.al/" target="_blank" rel="noreferrer noopener"><span class="anchor-text">et.al</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0430" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0430"><span class="anchor-text">[86]</span></a><span> were the first investigators for the electrochemical molten-salt ammonia synthesis at atmospheric pressure. The <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-source" title="Learn more about hydrogen source from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen source</a> for this type of synthesis could be gaseous hydrogen or water molecules. Depending on the electrolyte, there are three different configure of this type: molten chloride salts </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0435" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0435"><span class="anchor-text">[87]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0440" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0440"><span class="anchor-text">[88]</span></a>, molten hydroxide salts<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0445" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0445"><span class="anchor-text">[89]</span></a>, and composite electrodes<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0450" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0450"><span class="anchor-text">[90]</span></a>. Molten chloride salt started to receive great attention owing to the fast dissolution of Li<sub>3</sub>N in molten electrolytes as a source of nitride ions. For this type of electrolyte, protons (H<sup>+</sup>) is favourable from water instead of hydrogen gas. However, the low faradic efficiency is observed owing to the possibility of hydroxide ions and carbon dioxide formation<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0435" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0435"><span class="anchor-text">[87]</span></a><span>. On the other hand, hydroxide molten operates at a lower temperature (200 °C) and is less corrosive with a faradic efficiency up to 35 % at <a href="https://www.sciencedirect.com/topics/engineering/low-current-density" title="Learn more about low current density from ScienceDirect's AI-generated Topic Pages" class="topic-link">low current density</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0455" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0455"><span class="anchor-text">[91]</span></a><span>. However, at a <a href="https://www.sciencedirect.com/topics/engineering/high-current-density" title="Learn more about higher current density from ScienceDirect's AI-generated Topic Pages" class="topic-link">higher current density</a> the faradic efficiency reveals a sharp decline owing to H</span><sub>2</sub><span> </span>evolution. To tackle the lower efficiency problem, some researchers investigated the integration of a sub fuel cell to recycle the produced hydrogen; others suggested supporting activated carbons to inhibit H<sub>2</sub><span> </span>evolution for metal-based catalysts<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0445" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0445"><span class="anchor-text">[89]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0460" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0460"><span class="anchor-text">[92]</span></a>.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0015" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0015"><span class="anchor-text">Table 3</span></a><span> </span>shows the progress done in Molten-salt ammonia synthesis (@ Moderate Temperature), while<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0020" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0020"><span class="anchor-text">Table 4</span></a><span> </span>shows the progress done at high temperature.</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0015">
<p id="sp0115"><span class="label">Table 3</span>.<span> </span>Molten-salt ammonia synthesis (Moderate Temperature).</p>
<span class="captions text-s"><span id="cn0105"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">T (°C)</th>
<th scope="col" class="align-left">Electrolyte</th>
<th scope="col" class="align-left">Cathode</th>
<th scope="col" class="align-left">Ammonia Yield (mol/s cm<sup>−2</sup>)</th>
<th scope="col" class="align-left">Ref</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">450</td>
<td class="align-left">SDC-ternary carbonate composite electrolyte</td>
<td class="align-left">La<sub>0.6</sub>Sr<sub>0.4</sub>Fe<sub>0.8</sub>Cu<sub>0.2</sub>O<sub>3−δ</sub></td>
<td class="align-left">539 × 10<sup>−11</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0465" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0465"><span class="anchor-text">[93]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">450</td>
<td class="align-left">LiAlO<sub>2</sub><span> </span>– (Li/Na/K)<sub>2</sub>CO<sub>3</sub></td>
<td class="align-left">Co<sub>3</sub>Mo<sub>3</sub>N-Ag</td>
<td class="align-left">327 × 10<sup>−12</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0470" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0470"><span class="anchor-text">[94]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">400</td>
<td class="align-left">LiAlO<sub>2</sub><span> </span>– (Li/Na/K)<sub>2</sub>CO<sub>3</sub></td>
<td class="align-left">CoFe<sub>2</sub>O<sub>4</sub>-Ag</td>
<td class="align-left">232 × 10<sup>−12</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0475" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0475"><span class="anchor-text">[95]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">400</td>
<td class="align-left">LiCl-KCl-CsCl + Li<sub>3</sub>N</td>
<td class="align-left">Porous Ni/Ni</td>
<td class="align-left">333 × 10<sup>−11</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0430" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0430"><span class="anchor-text">[86]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">300</td>
<td class="align-left">LiCl-KCl-CsCl + Li<sub>3</sub>N</td>
<td class="align-left">Porous Ni/C</td>
<td class="align-left">200 × 10<sup>−10</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0435" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0435"><span class="anchor-text">[87]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">200</td>
<td class="align-left">NaOH/KOH (Nano-Fe<sub>2</sub>O<sub>3</sub>)</td>
<td class="align-left">Ni</td>
<td class="align-left">100 × 10<sup>−10</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0250" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0250"><span class="anchor-text">[50]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">400</td>
<td class="align-left">LiCl, KCl, CsCl + Li<sub>3</sub>N</td>
<td class="align-left">Al</td>
<td class="align-left">333 × 10<sup>−10</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0480" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0480"><span class="anchor-text">[96]</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0020">
<p id="sp0120"><span class="label">Table 4</span>.<span> </span>High-temperature ammonia synthesis.</p>
<span class="captions text-s"><span id="cn0110"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">T (°C)</th>
<th scope="col" class="align-left">Electrolyte</th>
<th scope="col" class="align-left">Cathode</th>
<th scope="col" class="align-left">Ammonia Yield<br>(mol/s cm-2)</th>
<th scope="col" class="align-left">Ref.</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">550</td>
<td class="align-left">BaZr<sub>0.7</sub>Ce<sub>0.2</sub>Y<sub>0.1</sub>O<sub>3 − δ</sub></td>
<td class="align-left">Ni-BZCY<sub>72</sub></td>
<td class="align-left">286 × 10<sup>−11</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0510" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0510"><span class="anchor-text">[102]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">550</td>
<td class="align-left">BZCY72<br>“BaZr<sub>0.8</sub>Y<sub>0.2</sub>O<sub>3 − δ</sub><span> </span>“</td>
<td class="align-left">La<sub>0.6</sub>Sr<sub>0.4</sub>Co<sub>0.2</sub>Fe<sub>0.8</sub>O<sub>3-δ</sub><span> </span>(LSCF)</td>
<td class="align-left">850 × 10<sup>−13</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0515" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0515"><span class="anchor-text">[103]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">500</td>
<td class="align-left">BCY10<br>“BaCe<sub>0.9</sub>Y<sub>0.1</sub>O<sub>3 − δ</sub>“</td>
<td class="align-left">Ag-Pd</td>
<td class="align-left">300 × 10<sup>−13</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0520" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0520"><span class="anchor-text">[104]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">620</td>
<td class="align-left">BZCY72<br>“BaZr<sub>0.7</sub>Ce<sub>0.2</sub>Y<sub>0.1</sub>O<sub>3 – δ</sub>”</td>
<td class="align-left">Ni-BZCY<sub>72</sub></td>
<td class="align-left">170 × 10<sup>−11</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0525" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0525"><span class="anchor-text">[105]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">600</td>
<td class="align-left">GDC “Ce<sub>0.9</sub>Gd<sub>0.1</sub>O<sub>2 − δ</sub><span> </span>“</td>
<td class="align-left">Pt</td>
<td class="align-left">367 × 10<sup>−13</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0530" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0530"><span class="anchor-text">[106]</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</section>
<section id="s0045">
<h5 id="st070" class="u-margin-m-top u-margin-xs-bottom">3.2.1.3.<span> </span>Solid-State ammonia production (High Temperature)</h5>
<div>
<p id="p0420">To increase the solid electrolyte's conductivity, ammonia synthesis utilizing solid-state electrolytes is typically carried out at high temperatures. As it is clear from (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0015" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0015"><span class="anchor-text">Fig. 3</span></a><span>), a dense electrolyte is inserted between a porous <a href="https://www.sciencedirect.com/topics/engineering/anodes-and-cathode" title="Learn more about anode and cathode from ScienceDirect's AI-generated Topic Pages" class="topic-link">anode and cathode</a> electrodes with H</span><strong><sup>+</sup></strong><span> </span>or O<sup>2</sup><strong><sup>–</sup></strong>, depending on the ceramic type, migrating through the dense electrolyte<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0485" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0485"><span class="anchor-text">[97]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0490" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0490"><span class="anchor-text">[98]</span></a>. The merit of high operating temperature gives the advantage of higher reaction kinetics and better N<sub>2</sub><span> activation. However, the <a href="https://www.sciencedirect.com/topics/engineering/thermodynamic-equilibrium" title="Learn more about thermodynamic equilibrium from ScienceDirect's AI-generated Topic Pages" class="topic-link">thermodynamic equilibrium</a> at high temperatures might negatively impact the yield of ammonia yield and <a href="https://www.sciencedirect.com/topics/engineering/materials-degradation" title="Learn more about material degradation from ScienceDirect's AI-generated Topic Pages" class="topic-link">material degradation</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0495" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0495"><span class="anchor-text">[99]</span></a>.</p>
<figure class="figure text-xs" id="f0015"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr3.jpg" height="352" alt="" aria-describedby="cn0015"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr3_lrg.jpg" target="_blank" download="" title="Download high-res image (478KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (478KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr3.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0025"><span class="label">Fig. 3</span>.<span> </span><span>Direct <a href="https://www.sciencedirect.com/topics/engineering/ammonia-synthesis" title="Learn more about ammonia synthesis from ScienceDirect's AI-generated Topic Pages" class="topic-link">ammonia synthesis</a> (a) proton conductive ceramic membrane and (b) </span><a href="https://www.sciencedirect.com/topics/engineering/oxygen-ion" title="Learn more about oxygen ion from ScienceDirect's AI-generated Topic Pages" class="topic-link">oxygen ion</a><span> </span>conductive ceramic membrane.</p>
<span class="captions text-s"><span id="cn0015"></span></span></figure>
</div>
<div>
<p id="p0425">Different electrode materials were investigated for ammonia synthesis based on noble metals (Pt, Pd, Pd-Ag, Ru). For example, the first investigation involving solid-state ammonia synthesis used Pd as a porous cathode with a production rate of 450 × 10<sup>−11</sup><span> </span>mol/s cm<sup>−2</sup><span>. At 500 °C and <a href="https://www.sciencedirect.com/topics/engineering/ambient-pressure" title="Learn more about ambient pressure from ScienceDirect's AI-generated Topic Pages" class="topic-link">ambient pressure</a>, Yuan et al. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0500" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0500"><span class="anchor-text">[100]</span></a><span> </span>successfully produced NH<sub>3</sub><span> </span>@ 307 × 10<sup>−11</sup><span> </span>mol/s cm<sup>−2</sup><span> </span>using yttrium-doped barium zirconate (BZY) as an electrolyte and α-Fe<sub>2</sub>O<sub>3</sub>/BZY as a cathode. A reasonable ammonia production rate was reported using SrCe<sub>0.95</sub>Yb<sub>0.05</sub>O<sub>3−δ</sub> electrolyte and Pd electrodes at 570 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0505" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0505"><span class="anchor-text">[101]</span></a>. A summary of different experimental works concerned with solid state NH<sub>3</sub><span> </span>synthesis is shown in table 4, and the various electrolytes used for ammonia synthesis are shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0020" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0020"><span class="anchor-text">Fig. 4</span></a>.</p>
<figure class="figure text-xs" id="f0020"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr4.jpg" height="282" alt="" aria-describedby="cn0020"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr4_lrg.jpg" target="_blank" download="" title="Download high-res image (232KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (232KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr4.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0030"><span class="label">Fig. 4</span>.<span> </span>Different electrolytes used for electrochemical ammonia synthesis.</p>
<span class="captions text-s"><span id="cn0020"></span></span></figure>
</div>
</section>
</section>
<section id="s0050">
<h4 id="st075" class="u-margin-m-top u-margin-xs-bottom">3.2.2.<span> </span>Electrochemical lithium metal cycling</h4>
<p id="p0430">Electrochemical Lithium metal cycling is an electrochemical approach that takes advantage of the spontaneous reaction of lithium nitridation (N<sup>3–</sup>), which then reacts with protons to form ammonia with an initial efficiency of 88 %<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0535" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0535"><span class="anchor-text">[107]</span></a>. A typical synthesis process involves three reactions as follows<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0540" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0540"><span class="anchor-text">[108]</span></a>: (a) formation of Li<sup>+</sup><span> through <a href="https://www.sciencedirect.com/topics/engineering/molten-salt-electrolysis" title="Learn more about molten salt electrolysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">molten salt electrolysis</a> at 400 °C (Eq. 6–8) followed by (b) nitridation, lithium reaction with nitrogen at 100 °C (Eq. 9), and (c) finally, a spontaneous split of Li</span><sub>3</sub>N in the presence of water or any proton source to ammonia and the recovery of LiOH (Eq. 10)<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0545" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0545"><span class="anchor-text">[109]</span></a>.</p>
<p id="p0435">Step 1: The electrolysis of lithium hydroxide<span class="display"><span id="e0030" class="formula"><span class="label">(6)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-36-Frame" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"><svg xmlns:xlink="http://www.w3.org/1999/xlink" width="32.888ex" height="2.432ex" viewBox="0 -896.2 14159.9 1047.3" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-41"></use></g><g is="true" transform="translate(750,0)"><use xlink:href="#MJMAIN-74"></use></g><g is="true"></g><g is="true" transform="translate(1306,0)"><use xlink:href="#MJMAIN-63"></use></g><g is="true" transform="translate(1751,0)"><use xlink:href="#MJMAIN-61"></use></g><g is="true" transform="translate(2251,0)"><use xlink:href="#MJMAIN-74"></use></g><g is="true" transform="translate(2641,0)"><use xlink:href="#MJMAIN-68"></use></g><g is="true" transform="translate(3197,0)"><use xlink:href="#MJMAIN-6F"></use></g><g is="true" transform="translate(3698,0)"><use xlink:href="#MJMAIN-64"></use></g><g is="true" transform="translate(4254,0)"><use xlink:href="#MJMAIN-65"></use></g><g is="true" transform="translate(4976,0)"><use xlink:href="#MJMAIN-3A"></use></g><g is="true"></g><g is="true" transform="translate(5699,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(6200,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4C"></use></g></g><g is="true" transform="translate(756,0)"><g is="true"><use xlink:href="#MJMATHBI-69"></use></g></g></g><g is="true" transform="translate(1162,421)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2B"></use></g></g><g is="true" transform="translate(8235,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(9235,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(9736,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g></g><g is="true" transform="translate(554,362)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g><g is="true" transform="translate(11219,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(12497,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(12997,0)"><g is="true"><use xlink:href="#MJMATHBI-4C"></use></g></g><g is="true" transform="translate(13754,0)"><g is="true"><use xlink:href="#MJMATHBI-69"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi mathvariant="normal" is="true">A</mi><mi mathvariant="normal" is="true">t</mi><mspace width="0.166667em" is="true"></mspace><mi mathvariant="normal" is="true">c</mi><mi mathvariant="normal" is="true">a</mi><mi mathvariant="normal" is="true">t</mi><mi mathvariant="normal" is="true">h</mi><mi mathvariant="normal" is="true">o</mi><mi mathvariant="normal" is="true">d</mi><mi mathvariant="normal" is="true">e</mi><mo is="true">:</mo><mspace width="0.166667em" is="true"></mspace><mn is="true">6</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">+</mo></msup><mo linebreak="badbreak" is="true">+</mo><mn is="true">6</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">-</mo></msup><mo stretchy="false" is="true">→</mo><mn is="true">6</mn><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow></math></span></span></span></span></span><span class="display"><span id="e0035" class="formula"><span class="label">(7)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-37-Frame" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"><svg xmlns:xlink="http://www.w3.org/1999/xlink" width="42.695ex" height="3.24ex" viewBox="0 -945.9 18382.6 1395" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-41"></use></g><g is="true" transform="translate(750,0)"><use xlink:href="#MJMAIN-74"></use></g><g is="true"></g><g is="true" transform="translate(1306,0)"><use xlink:href="#MJMAIN-61"></use></g><g is="true" transform="translate(1807,0)"><use xlink:href="#MJMAIN-6E"></use></g><g is="true" transform="translate(2363,0)"><use xlink:href="#MJMAIN-6F"></use></g><g is="true" transform="translate(2864,0)"><use xlink:href="#MJMAIN-64"></use></g><g is="true" transform="translate(3420,0)"><use xlink:href="#MJMAIN-65"></use></g><g is="true" transform="translate(4142,0)"><use xlink:href="#MJMAIN-3A"></use></g><g is="true"></g><g is="true" transform="translate(4865,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(5366,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(1878,430)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g><g is="true" transform="translate(8117,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(9118,0)"><use xlink:href="#MJMAIN-33"></use></g><g is="true" transform="translate(9618,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(11055,0)"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(12170,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(13171,0)"><g transform="translate(397,0)"><rect stroke="none" width="473" height="60" x="0" y="220"></rect><g is="true" transform="translate(60,419)"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g><g is="true" transform="translate(60,-375)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(14162,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(15676,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(16677,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(17177,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g></g><g is="true" transform="translate(554,362)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi mathvariant="normal" is="true">A</mi><mi mathvariant="normal" is="true">t</mi><mspace width="0.166667em" is="true"></mspace><mi mathvariant="normal" is="true">a</mi><mi mathvariant="normal" is="true">n</mi><mi mathvariant="normal" is="true">o</mi><mi mathvariant="normal" is="true">d</mi><mi mathvariant="normal" is="true">e</mi><mo is="true">:</mo><mspace width="0.166667em" is="true"></mspace><mn is="true">6</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">-</mo></msup><mo linebreak="badbreak" is="true">+</mo><mn is="true">3</mn><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo stretchy="false" is="true">→</mo><mfrac is="true"><mn is="true">3</mn><mn is="true">2</mn></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mo linebreak="badbreak" is="true">+</mo><mn is="true">6</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mo is="true">-</mo></msup></mrow></math></span></span></span></span></span><span class="display"><span id="e0040" class="formula"><span class="label">(8)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-38-Frame" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"><svg xmlns:xlink="http://www.w3.org/1999/xlink" width="50.743ex" height="3.24ex" viewBox="0 -945.9 21847.6 1395" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-4F"></use></g><g is="true" transform="translate(778,0)"><use xlink:href="#MJMAIN-76"></use></g><g is="true" transform="translate(1307,0)"><use xlink:href="#MJMAIN-65"></use></g><g is="true" transform="translate(1751,0)"><use xlink:href="#MJMAIN-72"></use></g><g is="true" transform="translate(2144,0)"><use xlink:href="#MJMAIN-61"></use></g><g is="true" transform="translate(2644,0)"><use xlink:href="#MJMAIN-6C"></use></g><g is="true" transform="translate(2923,0)"><use xlink:href="#MJMAIN-6C"></use></g><g is="true"></g><g is="true" transform="translate(3368,0)"><use xlink:href="#MJMAIN-72"></use></g><g is="true" transform="translate(3760,0)"><use xlink:href="#MJMAIN-65"></use></g><g is="true" transform="translate(4205,0)"><use xlink:href="#MJMAIN-61"></use></g><g is="true" transform="translate(4705,0)"><use xlink:href="#MJMAIN-63"></use></g><g is="true" transform="translate(5150,0)"><use xlink:href="#MJMAIN-74"></use></g><g is="true" transform="translate(5539,0)"><use xlink:href="#MJMAIN-69"></use></g><g is="true" transform="translate(5818,0)"><use xlink:href="#MJMAIN-6F"></use></g><g is="true" transform="translate(6318,0)"><use xlink:href="#MJMAIN-6E"></use></g><g is="true" transform="translate(7152,0)"><use xlink:href="#MJMAIN-3A"></use></g><g is="true"></g><g is="true" transform="translate(7875,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(8376,0)"><g is="true"><use xlink:href="#MJMATHBI-4C"></use></g></g><g is="true" transform="translate(9132,0)"><g is="true"><use xlink:href="#MJMATHBI-69"></use></g></g><g is="true" transform="translate(9538,0)"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(10375,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(11681,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(12959,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(13459,0)"><g is="true"><use xlink:href="#MJMATHBI-4C"></use></g></g><g is="true" transform="translate(14216,0)"><g is="true"><use xlink:href="#MJMATHBI-69"></use></g></g><g is="true" transform="translate(14844,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(15844,0)"><use xlink:href="#MJMAIN-33"></use></g><g is="true" transform="translate(16345,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(17781,0)"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(18841,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(19620,0)"><g transform="translate(342,0)"><rect stroke="none" width="473" height="60" x="0" y="220"></rect><g is="true" transform="translate(60,419)"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g><g is="true" transform="translate(60,-375)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(20556,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi mathvariant="normal" is="true">O</mi><mi mathvariant="normal" is="true">v</mi><mi mathvariant="normal" is="true">e</mi><mi mathvariant="normal" is="true">r</mi><mi mathvariant="normal" is="true">a</mi><mi mathvariant="normal" is="true">l</mi><mi mathvariant="normal" is="true">l</mi><mspace width="0.166667em" is="true"></mspace><mi mathvariant="normal" is="true">r</mi><mi mathvariant="normal" is="true">e</mi><mi mathvariant="normal" is="true">a</mi><mi mathvariant="normal" is="true">c</mi><mi mathvariant="normal" is="true">t</mi><mi mathvariant="normal" is="true">i</mi><mi mathvariant="normal" is="true">o</mi><mi mathvariant="normal" is="true">n</mi><mo is="true">:</mo><mspace width="0.166667em" is="true"></mspace><mn is="true">6</mn><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo stretchy="false" is="true">→</mo><mn is="true">6</mn><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo linebreak="badbreak" is="true">+</mo><mn is="true">3</mn><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo linebreak="badbreak" is="true">+</mo><mfrac is="true"><mn is="true">3</mn><mn is="true">2</mn></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub></mrow></math></span></span></span></span></span></p>
<p id="p0440">Step 2: Direct nitridation of Li<span class="display"><span id="e0045" class="formula"><span class="label">(9)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-39-Frame" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"><svg xmlns:xlink="http://www.w3.org/1999/xlink" width="40.141ex" height="2.779ex" viewBox="0 -747.2 17282.7 1196.3" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-36"></use></g><g is="true"></g><g is="true" transform="translate(667,0)"><g is="true"><use xlink:href="#MJMATHBI-4C"></use></g></g><g is="true" transform="translate(1423,0)"><g is="true"><use xlink:href="#MJMATHBI-69"></use></g></g><g is="true" transform="translate(2051,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true"></g><g is="true" transform="translate(3218,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(950,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true"></g><g is="true" transform="translate(5067,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true"></g><g is="true" transform="translate(6512,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(7013,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4C"></use></g></g><g is="true" transform="translate(756,0)"><g is="true"><use xlink:href="#MJMATHBI-69"></use></g></g></g><g is="true" transform="translate(1162,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g><g is="true" transform="translate(8628,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(950,-187)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-28"></use></g><g is="true" transform="translate(275,0)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHBI-67"></use></g></g><g is="true" transform="translate(661,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-29"></use></g></g></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g><g is="true"></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mn is="true">6</mn><mspace width="0.166667em" is="true"></mspace><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo linebreak="badbreak" is="true">+</mo><mspace width="0.166667em" is="true"></mspace><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mspace width="0.166667em" is="true"></mspace><mo stretchy="false" is="true">→</mo><mspace width="0.166667em" is="true"></mspace><mn is="true">2</mn><msub is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mn is="true">3</mn></msub><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo stretchy="false" is="true">(</mo><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo stretchy="false" is="true">)</mo></mrow></msub><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace><mspace width="0.166667em" is="true"></mspace></mrow></math></span></span></span></span></span></p>
<p id="p0445">Step 3: Ammonia released by the reaction of Li<sub>3</sub>N with water<span class="display"><span id="e0050" class="formula"><span class="label">(10)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-40-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="40.347ex" height="2.894ex" viewBox="0 -796.9 17371.7 1246" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(500,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4C"></use></g></g><g is="true" transform="translate(756,0)"><g is="true"><use xlink:href="#MJMATHBI-69"></use></g></g></g><g is="true" transform="translate(1162,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g><g is="true" transform="translate(2116,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(950,-187)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-28"></use></g><g is="true" transform="translate(275,0)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMATHBI-67"></use></g></g><g is="true" transform="translate(661,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-29"></use></g></g></g><g is="true" transform="translate(4325,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(5326,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(5826,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(7263,0)"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(8378,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(9656,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(10157,0)"><g is="true"><use xlink:href="#MJMATHBI-4C"></use></g></g><g is="true" transform="translate(10913,0)"><g is="true"><use xlink:href="#MJMATHBI-69"></use></g></g><g is="true" transform="translate(11319,0)"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(12156,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(13406,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(14407,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(14907,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(1027,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(2010,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mn is="true">2</mn><msub is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mn is="true">3</mn></msub><msub is="true"><mrow is="true"><mi 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mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mn is="true">3</mn></msub></mrow></math></span></span></span></span></span></p>
<p id="p0450">Lithium-mediated ammonia synthesis was first investigated in the early 19th century by Fichter and his colleagues<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0550" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0550"><span class="anchor-text">[110]</span></a>. Jain et al.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0555" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0555"><span class="anchor-text">[111]</span></a><span> investigated the nitridation properties of lithium as the starting material for ammonia synthesis. Their study revealed a promising result for ammonia synthesis; however, their method still needs further investigation to be commercially viable owing to the lack of reproducing lithium metal at the end of the process. Likewise other <a href="https://www.sciencedirect.com/topics/engineering/electrochemical-technique" title="Learn more about electrochemical techniques from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrochemical techniques</a>, lithium-mediated ammonia synthesis is achieved at ambient conditions with a faradic efficiency of around 20 % </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0560" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0560"><span class="anchor-text">[112]</span></a>. A step forward in the faradic efficiency up 57.2 % and ammonia production rate of 1.21 × 10<sup>−9</sup><span> </span>mol/s cm<sup>−2</sup><span> using a novel membrane-less electrochemical cell. The main challenge of this process is forming a lithium layer on the <a href="https://www.sciencedirect.com/topics/engineering/solid-electrolyte-interface" title="Learn more about solid electrolyte interface from ScienceDirect's AI-generated Topic Pages" class="topic-link">solid electrolyte interface</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0560" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0560"><span class="anchor-text">[112]</span></a>. This will result a restriction in the current flow from the lithium reaction with the organic solvent. Another limitation of this method is the high reduction potential of Li<sup>+</sup><span> </span>to lithium which was achieved at –3 V vs (SHE), and stability issues<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0565" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0565"><span class="anchor-text">[113]</span></a>. The switch between the Li<sup>+</sup><span> </span>solution and lithium deposition region revealed a promising result in overcoming the lithium layer formation<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0570" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0570"><span class="anchor-text">[114]</span></a>.</p>
</section>
<section id="s0055">
<h4 id="st080" class="u-margin-m-top u-margin-xs-bottom">3.2.3.<span> </span>Photocatalytic ammonia synthesis</h4>
<p id="p0455">Photocatalytic conversion of H<sup>+</sup><span> </span>and nitrogen into NH<sub>3</sub><span> </span>has attracted widespread attention for its crucial role in water's direct green ammonia production<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0575" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0575"><span class="anchor-text">[115]</span></a>. Unlike electrochemical routes that use electro-catalyst, this method uses a semiconductor. In a typical process, any radiation source such as sunlight or UV is absorbed by a semiconductor, generating electrons that are consolidated from VB, “the valence band” to CB “the conduction band”. This will allow the photo-generation of electrons while leaving holes (h<sup>+</sup>) on the VB<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0580" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0580"><span class="anchor-text">[116]</span></a>. Then, photo-reduction of N<sub>2</sub><span> </span>and photo-oxidation of water take place simultaneously in the photochemical cell to produce ammonia<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0585" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0585"><span class="anchor-text">[117]</span></a>.</p>
<p id="p0460"><span>The <a href="https://www.sciencedirect.com/topics/engineering/photocatalysts" title="Learn more about photocatalyst from ScienceDirect's AI-generated Topic Pages" class="topic-link">photocatalyst</a> should reveal excellent intrinsic properties, a small band gap to maximize photon absorption, and a higher <a href="https://www.sciencedirect.com/topics/engineering/rate-kinetics" title="Learn more about kinetics rate from ScienceDirect's AI-generated Topic Pages" class="topic-link">kinetics rate</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0590" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0590"><span class="anchor-text">[118]</span></a><span>. Due to their low cost and high chemical stability, titanium dioxide has been extensively used as a photocatalyst for NRR and HER. The most demanding challenge in NRR <a href="https://www.sciencedirect.com/topics/engineering/photocatalysis" title="Learn more about photocatalysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">photocatalysis</a> is developing a highly active site for nitrogen reduction at low temperatures. To realize this target, carbon doping in titanium dioxide has shown outstanding results in enhancing the splitting of the triple nitrogen bond and reducing the band gap of the TiO</span><sub>2</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0595" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0595"><span class="anchor-text">[119]</span></a>. For example, Han et al.,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0600" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0600"><span class="anchor-text">[120]</span></a><span> </span>reported highly active sites (Ti<sup>3+</sup>) porous carbon-doped TiO<sub>x</sub> (C-TiO<sub>x</sub><span>) <a href="https://www.sciencedirect.com/topics/engineering/nanosheet" title="Learn more about nanosheets from ScienceDirect's AI-generated Topic Pages" class="topic-link">nanosheets</a>. Under visible light irradiation, they achieved an NH</span><sub>3</sub><span> </span>production rate of 303.6 × 10<sup>−10</sup><span> </span>mol g<sup>−1</sup><span> </span>s<sup>−1</sup>. Fe doping was firstly proposed by Shrauzer and Guth<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0605" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0605"><span class="anchor-text">[121]</span></a>. Their prepared photocatalyst reduced nitrogen to ammonia under light radiation with a solar to the chemical conversion of 0.02 %. However, Fe doping revealed a decrease in the holes and electrons recombination of exceeded 0.2 %<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0610" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0610"><span class="anchor-text">[122]</span></a>. Besides iron doping, other transition metals (Co, Mo, Ni) have shown an excellent N<sub>2</sub><span> </span>reduction<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0615" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0615"><span class="anchor-text">[123]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0620" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0620"><span class="anchor-text">[124]</span></a>.</p>
<div>
<p id="p0465">Apart from transition metal doping, different catalysts, including g-C<sub>3</sub>N<sub>4</sub>, CdS, Ta<sub>3</sub>N<sub>5</sub>, BiVO<sub>4</sub><span>, and <a href="https://www.sciencedirect.com/topics/engineering/mxene" title="Learn more about MXene from ScienceDirect's AI-generated Topic Pages" class="topic-link">MXene</a>, have also been considered as an effective photocatalysts for ammonia synthesis. Liu et al. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0625" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0625"><span class="anchor-text">[125]</span></a><span> </span>reported an enhanced NH<sub>3</sub><span> </span>production by using g-C<sub>3</sub>N<sub>4</sub><span> </span>as a support for Ru-based catalyst, which was denoted as (Ru-K/B-g-C<sub>3</sub>N<sub>4</sub><span> </span>and Ru-K/E-g-C<sub>3</sub>N<sub>4</sub><span>) depending on their forms bulk and exfoliated, respectively. Owing to their high porosity and <a href="https://www.sciencedirect.com/topics/engineering/interlayer" title="Learn more about interlayer from ScienceDirect's AI-generated Topic Pages" class="topic-link">interlayer</a> spacing, derived MXene based on TiO</span><sub>2</sub>@C/g-C<sub>3</sub>N<sub>4</sub><span> </span>was investigated by Liu and his research group<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0630" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0630"><span class="anchor-text">[126]</span></a>. Under Xe lamp 300 W (λ &gt; 420 nm), a maximum ammonia production rate of 250.6 mol g<sub>cat</sub><sup>−1</sup>h<sup>−1</sup><span> </span>at ambient conditions was obtained. To sum up, the photocatalysts for direct ammonia synthesis should reveal: high active sites, low band gap for a broader range of the spectrum, high stability, and inhibition of hydrogen evolution. Photochemical ammonia synthesis offers a process that could contribute to energy saving with a potential contribution to sustainability and economic development in the energy sector. The main upside of this method is utilizing solar energy for NH<sub>3</sub><span> </span>synthesis; thus, it is entirely a carbon-free process. However, their lower efficiency and stability make this process far from practical applications. Breakthroughs in research and project support are required to address the photocatalyst bandgap's challenges. More active, efficient, stable, cost-effective, and environmentally friendly photocatalysts are required to capture solar energy at larger scale production<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0635" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0635"><span class="anchor-text">[127]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0640" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0640"><span class="anchor-text">[128]</span></a>.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0025" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0025"><span class="anchor-text">Table 5</span></a><span> </span>lists some important studies for ammonia production using photocatalytic reactions implementing different catalysts and light radiation sources.</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0025">
<p id="sp0125"><span class="label">Table 5</span>.<span> </span>Summary of experimental photocatalytic ammonia synthesis.</p>
<span class="captions text-s"><span id="cn0115"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">T (°C)</th>
<th scope="col" class="align-left">Catalyst</th>
<th scope="col" class="align-left">Light radiation</th>
<th scope="col" class="align-left">Ammonia Yield<br>(µmol g<sub>cat</sub><sup>−1</sup>h<sup>−1</sup>)</th>
<th scope="col" class="align-left">Ref.</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">40</td>
<td class="align-left">TiO<sub>2</sub></td>
<td class="align-left">Hg-Arc Lamp (UV)</td>
<td class="align-left">4.17</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0605" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0605"><span class="anchor-text">[121]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">40</td>
<td class="align-left">0.2 wt% Fe-TiO<sub>2</sub></td>
<td class="align-left">Hg-Arc Lamp (UV)</td>
<td class="align-left">11.5</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0605" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0605"><span class="anchor-text">[121]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">25</td>
<td class="align-left">Fe-doped TiO<sub>2</sub></td>
<td class="align-left">UV lamp</td>
<td class="align-left">400</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0645" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0645"><span class="anchor-text">[129]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">n/a</td>
<td class="align-left">0.5 wt% Cr-TiO<sub>2</sub></td>
<td class="align-left">HWL lamp</td>
<td class="align-left">2.12 µg m<sup>−2</sup>h<sup>−1</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0615" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0615"><span class="anchor-text">[123]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">25</td>
<td class="align-left">5 % RuCl<sub>3</sub>/TiO<sub>2</sub></td>
<td class="align-left">Xe lamp</td>
<td class="align-left">4 μM·cm<sup>−2</sup>h<sup>−1</sup></td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0650" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0650"><span class="anchor-text">[130]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">30</td>
<td class="align-left">g-C<sub>3</sub>N<sub>4</sub></td>
<td class="align-left">sodium lamp</td>
<td class="align-left">83.6</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0655" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0655"><span class="anchor-text">[131]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">25</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="mailto:TiO2@c/g-C3N" target="_blank" rel="noreferrer noopener"><span class="anchor-text">TiO2@C/g-C3N</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a><sub>4</sub></td>
<td class="align-left">Xe lamp</td>
<td class="align-left">250.6</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0630" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0630"><span class="anchor-text">[126]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">38</td>
<td class="align-left">Pt/TiO<sub>2</sub></td>
<td class="align-left">Hg lamp</td>
<td class="align-left">9.3</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0660" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0660"><span class="anchor-text">[132]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">38</td>
<td class="align-left">Pt-CdS</td>
<td class="align-left">Hg lamp</td>
<td class="align-left">16.3</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0660" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0660"><span class="anchor-text">[132]</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</section>
<section id="s0060">
<h4 id="st085" class="u-margin-m-top u-margin-xs-bottom">3.2.4.<span> </span>Nonthermal plasma ammonia synthesis</h4>
<p id="p0470">The concept of non-thermal plasmatic ammonia synthesis involves the use of electrically ionized gas with electrons, photons, and activated molecules, which is thermodynamically unstable for N<sub>2</sub><span> activation. Compared to conventional methods that involve high temperatures for nitrogen activation, plasma with a catalyst is utilized to promote the reaction kinetics for ammonia production at room temperature. The mean <a href="https://www.sciencedirect.com/topics/engineering/electron-energy" title="Learn more about electron energies from ScienceDirect's AI-generated Topic Pages" class="topic-link">electron energies</a> of non-thermal plasma, which is around 20 eV </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0665" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0665"><span class="anchor-text">[133]</span></a>, help in the dissociation of the<span> </span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-41-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="7.226ex" height="1.971ex" viewBox="0 -747.2 3111.1 848.5" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMATHI-4E"></use></g><g is="true" transform="translate(1166,0)"><use xlink:href="#MJMAIN-2261"></use></g><g is="true" transform="translate(2222,0)"><use xlink:href="#MJMATHI-4E"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi is="true">�</mi><mo is="true">≡</mo><mi is="true">�</mi></mrow></math></span></span></span><span> </span>bonds. After the formation of the N radical with the support of plasma and catalyst, the N radical would react with H<sub>2</sub><span> </span>molecules to form NH<sub>3</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0670" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0670"><span class="anchor-text">[134]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0675" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0675"><span class="anchor-text">[135]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0680" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0680"><span class="anchor-text">[136]</span></a>.</p>
<p id="p0475">Peng et al.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0685" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0685"><span class="anchor-text">[137]</span></a><span> </span>suggested a detailed mechanism initiated by the N<sub>2</sub><span> </span>and H<sub>2</sub><span> </span>dissociation into free radicals, followed by three radical reactions for the N and H combinations to form ammonia, as shown in equations 11 to 15:<span class="display"><span id="e0055" class="formula"><span class="label">(11)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-42-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="11.656ex" height="2.548ex" viewBox="0 -846.5 5018.6 1096.9" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(950,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(1682,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(2960,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(3460,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g></g><g is="true" transform="translate(1050,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAINB-2217"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mo stretchy="false" is="true">→</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mrow is="true"><mo mathvariant="bold" is="true">∗</mo></mrow></msup></mrow></math></span></span></span></span></span><span class="display"><span id="e0060" class="formula"><span class="label">(12)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-43-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="11.708ex" height="2.548ex" viewBox="0 -846.5 5041 1096.9" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(1714,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(2992,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(3492,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAINB-2217"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mn is="true">2</mn></msub><mo stretchy="false" is="true">→</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mrow is="true"><mo mathvariant="bold" is="true">∗</mo></mrow></msup></mrow></math></span></span></span></span></span><span class="display"><span id="e0065" class="formula"><span class="label">(13)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-44-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="18.44ex" height="2.317ex" viewBox="0 -846.5 7939.6 997.6" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g></g><g is="true" transform="translate(1050,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAINB-2217"></use></g></g></g><g is="true" transform="translate(1779,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(2780,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAINB-2217"></use></g></g></g><g is="true" transform="translate(4606,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(5884,0)"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(6912,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mrow is="true"><mo mathvariant="bold" is="true">∗</mo></mrow></msup><mo linebreak="badbreak" is="true">+</mo><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mrow is="true"><mo mathvariant="bold" is="true">∗</mo></mrow></msup><mo stretchy="false" is="true">→</mo><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow></math></span></span></span></span></span><span class="display"><span id="e0070" class="formula"><span class="label">(14)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-45-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="20.805ex" height="2.663ex" viewBox="0 -846.5 8957.5 1146.6" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(1027,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(2277,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3277,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAINB-2217"></use></g></g></g><g is="true" transform="translate(5103,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(6381,0)"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(7409,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAINB-2217"></use></g></g><g is="true" transform="translate(982,-248)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo linebreak="badbreak" is="true">+</mo><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mrow is="true"><mo mathvariant="bold" is="true">∗</mo></mrow></msup><mo stretchy="false" is="true">→</mo><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><msubsup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mn is="true">2</mn></mrow><mrow is="true"><mo mathvariant="bold" is="true">∗</mo></mrow></msubsup></mrow></math></span></span></span></span></span><span class="display"><span id="e0075" class="formula"><span class="label">(15)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-46-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="21.754ex" height="2.663ex" viewBox="0 -846.5 9366.4 1146.6" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(1027,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAINB-2217"></use></g></g><g is="true" transform="translate(982,-248)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(2797,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3798,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAINB-2217"></use></g></g></g><g is="true" transform="translate(5624,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(6902,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(1027,0)"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g></g><g is="true" transform="translate(2010,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><msubsup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mn is="true">2</mn></mrow><mrow is="true"><mo mathvariant="bold" is="true">∗</mo></mrow></msubsup><mo linebreak="badbreak" is="true">+</mo><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mrow is="true"><mo mathvariant="bold" is="true">∗</mo></mrow></msup><mo stretchy="false" is="true">→</mo><msub is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mn is="true">3</mn></msub></mrow></math></span></span></span></span></span></p>
<div>
<p id="p0480">Recently, a study performed by Hong and his research group<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0690" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0690"><span class="anchor-text">[138]</span></a><span> </span>proved the significant importance of free radical and vibrational excited molecules on the reaction rate of ammonia synthesis. In another study Mehta et al.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0695" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0695"><span class="anchor-text">[139]</span></a>, induced plasmatic vibrational excitation enhances ammonia synthesis without interfering with intermediate hydrogenation and desorption steps. Plasmatic-induced ammonia synthesis has the advantage of continuously producing ammonia at ambient conditions making it convenient for the production at a local level for fast distribution. For instance, in 2017, the University of West Virginia received a 3 M$ award for utilizing renewable energy to produce ammonia induced by plasma<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0700" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0700"><span class="anchor-text">[140]</span></a>. The main advantages of this process are a simple design, mild conditions, and low pressure, which facilitate the use of renewable energy. Different studies on plasmatic ammonia synthesis are concise in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0025" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0025"><span class="anchor-text">Table 6</span></a>:</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0030">
<p id="sp0130"><span class="label">Table 6</span>.<span> </span>The main parameters and ammonia yields in plasma-based ammonia synthesis.</p>
<span class="captions text-s"><span id="cn0120"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">Plasma reactor type</th>
<th scope="col" class="align-left">Operating conditions</th>
<th scope="col" class="align-left">Type of electrode</th>
<th scope="col" class="align-left">NH<sub>3</sub><span> </span>rate</th>
<th scope="col" class="align-left">Ref</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">DBD discharge</td>
<td class="align-left">N/A</td>
<td class="align-left">Cu tangled</td>
<td class="align-left">250 (ml min<span> </span><sup>−1</sup>)</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0705" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0705"><span class="anchor-text">[141]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">DBD discharge</td>
<td class="align-left">200</td>
<td class="align-left">Co–Ni Bimetal</td>
<td class="align-left">1500 (μmol g<sup>−1</sup>h<sup>−1</sup>)</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0710" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0710"><span class="anchor-text">[142]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Advanced plasma reactor</td>
<td class="align-left">Ambient conditions</td>
<td class="align-left">(Ru) catalyst</td>
<td class="align-left">2.67 (mmol g<sub>cat</sub>.<sup>−1</sup> h<sup>−1</sup>)</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0715" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0715"><span class="anchor-text">[143]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Microwave plasma</td>
<td class="align-left">327 to 427 °C</td>
<td class="align-left">N/A</td>
<td class="align-left">1.5 (mmol g<sup>−1</sup>)</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0720" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0720"><span class="anchor-text">[144]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">DBD discharge</td>
<td class="align-left">Ambient conditions</td>
<td class="align-left">(Ru) catalyst</td>
<td class="align-left">1.7 (g kWh<sup>−1</sup>)</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0725" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0725"><span class="anchor-text">[145]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">DBD discharge</td>
<td class="align-left">Ambient conditions</td>
<td class="align-left">Au, Pt, Pd, Ag, or Cu electrodes</td>
<td class="align-left">41.0 (μmol min<sup>−1</sup>) (Cu)</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0730" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0730"><span class="anchor-text">[146]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">DBD discharge</td>
<td class="align-left">140 °C</td>
<td class="align-left">Ni supported on silica</td>
<td class="align-left">N/A</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0735" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0735"><span class="anchor-text">[147]</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</section>
</section>
<section id="s0065">
<h3 id="st090" class="u-h4 u-margin-m-top u-margin-xs-bottom">3.3.<span> </span>Assessment and comparison of different NH<sub>3</sub><span> </span>technologies</h3>
<div>
<p id="p0485">With the increasing focus on green energies, ammonia has become a globally important energy source and energy carrier. Moreover, ammonia is used in preparing various products such as fertilizer, plastics, fibers, explosives, pharmaceuticals, and others. Ammonia is mainly produced from the reaction of nitrogen and hydrogen from natural gas (brown ammonia) using a conventional technique called the Haber-Bosch process. As it is clear from (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0025" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0025"><span class="anchor-text">Fig. 5</span></a>), this process accounts for CO<sub>2</sub><span> </span>footprint (releasing 1.9 tons CO<sub>2</sub><span> </span>for each ton of green NH<sub>3</sub><span> </span>produced and increased significantly in case of blue and brown ammonia). It is estimated that NH<sub>3</sub><span> </span>production contributed to 1.8 % of the global CO<sub>2</sub><span> </span>emissions<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0740" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0740"><span class="anchor-text">[148]</span></a>.</p>
<figure class="figure text-xs" id="f0025"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr5.jpg" height="292" alt="" aria-describedby="cn0025"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr5_lrg.jpg" target="_blank" download="" title="Download high-res image (114KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (114KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr5.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0035"><span class="label">Fig. 5</span>.<span> </span>Energy requirements and CO<sub>2</sub><span> </span>footprint for brown, blue, and green Ammonia<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0750" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0750"><span class="anchor-text">[150]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0755" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0755"><span class="anchor-text">[151]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0760" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0760"><span class="anchor-text">[152]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0765" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0765"><span class="anchor-text">[153]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0770" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0770"><span class="anchor-text">[154]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0775" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0775"><span class="anchor-text">[155]</span></a>. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)</p>
<span class="captions text-s"><span id="cn0025"></span></span></figure>
</div>
<p id="p0490">The transition to green ammonia production through hydropower electrolysis was realized since 1920 in Norway. However, replacing the Haber process with electrolysis from renewable sources requires further consideration regarding the costs, production capacity, material development, and excess renewable energy source<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0745" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0745"><span class="anchor-text">[149]</span></a>. Theoretically, the energy needed for green ammonia production through conventional high-pressure synthesis is 30 ± 5 GJ/tNH<sub>3</sub>. This has given priority to the transition toward direct NH<sub>3</sub><span> </span>production under milder conditions.</p>
<div>
<p id="p0495">Current trends for NH<sub>3</sub><span> production are driven toward the transition to mild temperature and direct ammonia synthesis. In the past few years, research and development paid considerable attention to electrochemical and photochemical ammonia synthesis because ammonia synthesis from water and nitrogen eliminates the intermediate hydrogen production step. It offers a route to store <a href="https://www.sciencedirect.com/topics/engineering/excess-energy" title="Learn more about excess energy from ScienceDirect's AI-generated Topic Pages" class="topic-link">excess energy</a> produced by solar or wind. Also, non-thermal plasma has shown promising results toward low temperature and pressure ammonia synthesis owing to their elevated electron temperature. Moreover, if the challenges toward this production method are appropriately handled, the process will be cost-effective and has zero carbon dioxide footprint. However, these methods still have many limitations that require further investigation to be viable for pilot and large-scale applications. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0035" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0035"><span class="anchor-text">Table 7</span></a><span> </span>represents the pros, and cons of different routes for ammonia synthesis.</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0035">
<p id="sp0135"><span class="label">Table 7</span>.<span> </span>Ammonia synthesis different technologies comparison.</p>
<span class="captions text-s"><span id="cn0125"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">Technology</th>
<th scope="col" class="align-left">Pros.</th>
<th scope="col" class="align-left">Cons.</th>
<th scope="col" class="align-left">Comments</th>
<th scope="col" class="align-left">Ref.</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">Electrochemical High-temperature NH<sub>3</sub><span> </span>production (Solid state)</td>
<td class="align-left">1- Possibility for direct ammonia production from water and nitrogen;<br>2- The design of the cell is easy;<br>3- Low pressure required;<br>4- Zero carbon emissions and reactants can be generated on the same cell</td>
<td class="align-left">1- Low durability for the electrodes owing to high temperature;<br>2- Low formation rate and faradic efficiency;<br>3- High temperature require high power consumption;<br>4- Challenges related to the nitrogen triple bond dissociation on the surface catalyst</td>
<td class="align-left">This system reveals a potential for direct ammonia synthesis; however, many considerations with the cell and catalyst are still required</td>
<td class="align-left" rowspan="3"><br><br><br><br><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0420" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0420"><span class="anchor-text">[84]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0455" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0455"><span class="anchor-text">[91]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0315" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0315"><span class="anchor-text">[63]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0780" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0780"><span class="anchor-text">[156]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0785" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0785"><span class="anchor-text">[157]</span></a><br><br><br></td>
</tr>
<tr class="valign-top">
<td class="align-left">Electrochemical Medium-temperature NH<sub>3</sub><span> </span>Production (Molten state)</td>
<td class="align-left">1- Possibility for direct ammonia production from water and nitrogen;<br>2- Lower operation temperatures;<br>3- Zero carbon emissions and reactants can be generated on the same cell</td>
<td class="align-left">1- Limited faradic efficiency and ammonia production rate;<br>2- The electrolyte is corrosive for the electrodes;<br>3- Environmental issues due to the corrosive electrolytes;<br>4- Challenges related to the nitrogen triple bond dissociation on the surface catalyst</td>
<td class="align-left">It is considered a clean energy direct ammonia synthesis; however, consideration should be taken with the electrolytes</td>
</tr>
<tr class="valign-top">
<td class="align-left">Electrochemical Low-temperature ammonia synthesis</td>
<td class="align-left">1- Direct ammonia production at very low temperatures &lt; 100 °C;<br>2- Variant of electrolytes can be used;<br>3- Zero carbon emissions and reactants can be generated on the same cell</td>
<td class="align-left">1- Higher voltage is needed to overcome the overpotential;<br>2- low NH<sub>3</sub><span> </span>production rate and limited FE;<br>3- High capital cost of the technology;<br>4-Challenges related to the nitrogen triple bond dissociation on the surface catalyst</td>
<td class="align-left">Still not viable for industrial applications</td>
</tr>
<tr class="valign-top">
<td class="align-left">Photochemical NH<sub>3</sub><span> </span>Production</td>
<td class="align-left">1- Possibility for direct ammonia production from water and nitrogen;<br>2- The reactor design is already an existing technology;<br>3- Low temperature synthesis;<br>4- Zero-carbon emission</td>
<td class="align-left">1- The main issue for this is the competing toward hydrogen evolution reaction;<br>2- Ammonia production rate is very low; 3- Challenges related to supply electrons through light</td>
<td class="align-left">It reveals the potential of using solar energy to transform water and nitrogen into O<sub>2</sub><span> </span>and NH<sub>3</sub>; however, considerable attention should be taken for developing photocatalyst that can reduce the band gap with a high active site and capable to inhibit HER. Furthermore, new reactor system design should be taken on consideration.</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0790" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0790"><span class="anchor-text">[158]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0795" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0795"><span class="anchor-text">[159]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0800" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0800"><span class="anchor-text">[160]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0805" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0805"><span class="anchor-text">[161]</span></a><br><br><br></td>
</tr>
<tr class="valign-top">
<td class="align-left">Plasmatic NH<sub>3</sub><span> </span>Synthesis</td>
<td class="align-left">1- The mean electron energies of non-thermal plasma, which is around 20 eV, make it ideal for room temperature synthesis;<br>2- Clean and carbon free production;<br>3- Small scale production at the site on interest</td>
<td class="align-left">1- The efficiency and conversion are very low;<br>2- Many challenges would face large scale production</td>
<td class="align-left">Still this method requires more investigation to be viable for large scale production</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0810" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0810"><span class="anchor-text">[162]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0815" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0815"><span class="anchor-text">[163]</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left" colspan="4"><br>INDIRECT AMMONIA PRODUCTION FROM HYDROGEN</td>
<td class="align-left"></td>
</tr>
<tr class="valign-top">
<td class="align-left">Water electrolysis</td>
<td class="align-left">1- Lower complexity;<br>2- High purity of hydrogen;<br>3- Absence of emission during the process without taking the consideration of electricity source</td>
<td class="align-left">1- Indirect ammonia synthesis causing a lower ammonia efficiency around 70 % for electrolysis to produce hydrogen and then the efficiency associated to NH<sub>3</sub><span> </span>production;<br>2- The average energy consumption is between 52.5 and 70.1 kWh;<br>3- The environmental effects are 0.5 to 1.5 kg CO<sub>2-eq.</sub><span> </span>/kg H<sub>2</sub><span> </span>for wind electricity, 1.3–3 kg CO<sub>2-eq.</sub><span> </span>/kg H<sub>2</sub><span> </span>for solar electricity, and 0.5 to 1 kg CO<sub>2-eq.</sub><span> </span>/kg H<sub>2</sub><span> </span>for nuclear electricity.</td>
<td class="align-left">The availability of this technology gives it the potential for direct industrial application</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0820" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0820"><span class="anchor-text">[164]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0825" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0825"><span class="anchor-text">[165]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0830" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0830"><span class="anchor-text">[166]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0835" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0835"><span class="anchor-text">[167]</span></a><br><br><br></td>
</tr>
<tr class="valign-top">
<td class="align-left">Dark Fermentation</td>
<td class="align-left">1- Simple reactor design;<br>2-Continous high yield of H<sub>2</sub><span> </span>production;<br>3- No light is needed for this process</td>
<td class="align-left">1- Indirect ammonia synthesis causing a lower ammonia efficiency around 70 % for electrolysis to produce hydrogen and then the efficiency associated to NH<sub>3</sub><span> </span>production;<br>2- Contribution on the CO<sub>2</sub><span> </span>emission 0.5 mol CO<sub>2</sub>/mole H<sub>2</sub>;<br>3- Production of volatile fatty acid;<br>4- Further gases separation is needed owing to the CO<sub>2</sub></td>
<td class="align-left">Biological technologies might contribute to the sustainable development of green hydrogen production if the CO<sub>2</sub><span> </span>produced is properly handled</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0490" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0490"><span class="anchor-text">[98]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0840" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0840"><span class="anchor-text">[168]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0845" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0845"><span class="anchor-text">[169]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0850" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0850"><span class="anchor-text">[170]</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
<p id="p0500">Although all the synthesis routes still have considerable challenges, such as low efficiencies, high cost and negative environmental impacts. The indirect processes for ammonia production from hydrogen show promising results, and further research and development will accelerate green ammonia synthesis to achieve sustainable development. Investment, legislative laws and international/national policies also play significant roles in this matter.</p>
</section>
</section>
<section id="s0070">
<h2 id="st095" class="u-h4 u-margin-l-top u-margin-xs-bottom">4.<span> </span>Applications of ammonia in the energy sector</h2>
<div>
<p id="p0505">Besides the usage of ammonia in the chemical industry and as a fertilizer, it is a carbon-free fuel that has the potential in several energy sectors; that is summarized briefly in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0030" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0030"><span class="anchor-text">Fig. 6</span></a>, and will be summarized in this section:</p>
<figure class="figure text-xs" id="f0030"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr6.jpg" height="376" alt="" aria-describedby="cn0030"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr6_lrg.jpg" target="_blank" download="" title="Download high-res image (481KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (481KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr6.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0040"><span class="label">Fig. 6</span>.<span> </span>Schematic diagram briefly describes the most promising application of ammonia rather than chemicals and fertilizer.</p>
<span class="captions text-s"><span id="cn0030"></span></span></figure>
</div>
<section id="s0075">
<h3 id="st100" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.1.<span> </span>Ammonia-based fuel cells</h3>
<p id="p0510"><span><a href="https://www.sciencedirect.com/topics/engineering/renewable-energy-resources" title="Learn more about Renewable energy resources from ScienceDirect's AI-generated Topic Pages" class="topic-link">Renewable energy resources</a> such as geothermal, hydro, solar, tidal and wind energies have been considered eco-friendly technologies. However, these resources are sporadic as they depend on geological parameters, solar availability and intensity, wind speed, altitude, etc. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0855" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0855"><span class="anchor-text">[171]</span></a><span>. Efficient <a href="https://www.sciencedirect.com/topics/engineering/energy-storage-and-conversion" title="Learn more about energy storage and conversion from ScienceDirect's AI-generated Topic Pages" class="topic-link">energy storage and conversion</a> devices are the best choices to store and convert such energies for energy-deficient periods. Fuel cells are energy conversion systems that are eco-friendly, compact, efficient, available in different sizes, and demonstrated promising results in different applications </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0860" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0860"><span class="anchor-text">[172]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0865" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0865"><span class="anchor-text">[173]</span></a><span>. Various <a href="https://www.sciencedirect.com/topics/engineering/fuel-cell-types" title="Learn more about fuel cell types from ScienceDirect's AI-generated Topic Pages" class="topic-link">fuel cell types</a> depend on the operating temperature, membrane type, applications, or fuel type. Due to its simple structure, carbon-free, and sustainable energy source, hydrogen is considered the best fuel for fuel cells </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0870" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0870"><span class="anchor-text">[174]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0875" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0875"><span class="anchor-text">[175]</span></a>. Several studies demonstrated the effectiveness of the integration of the fuel cell in renewable energy resources within periods of low energy output<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0880" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0880"><span class="anchor-text">[176]</span></a>. But there are two main challenges facing the utilization of hydrogen as fuel, consisting of its transportation and storage<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0070" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0070"><span class="anchor-text">[14]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0885" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0885"><span class="anchor-text">[177]</span></a>. Hydrogen carriers such as methanol, ethanol, ammonia, hydrazine, etc., have been proposed to overcome such challenges. Among them, ammonia is considered a carbon-free hydrogen carrier with high hydrogen content (17.6 wt%). In contrast to hydrogen, ammonia is easier to transport and store. Thus ammonia could be used directly or indirectly as fuel in Fuel cells. Indirect ammonia fuel cell depends on converting ammonia to hydrogen, which is fuel in the fuel cells. The electrolysis of ammonia at 250 °C produced high-purity hydrogen that can be used directly at the fuel cell's anode<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0890" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0890"><span class="anchor-text">[178]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0895" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0895"><span class="anchor-text">[179]</span></a><span>. A system that consists of a <a href="https://www.sciencedirect.com/topics/engineering/combustion-engine" title="Learn more about combustion engine from ScienceDirect's AI-generated Topic Pages" class="topic-link">combustion engine</a> fueled with ammonia and hydrogen (produced from the dissociation of ammonia) was used to power a vehicle </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0900" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0900"><span class="anchor-text">[180]</span></a><span>. The overall energy efficiency of that system reached 61.89 %. A <a href="https://www.sciencedirect.com/topics/engineering/direct-ammonia-fuel-cell" title="Learn more about Direct ammonia fuel cell from ScienceDirect's AI-generated Topic Pages" class="topic-link">Direct ammonia fuel cell</a> is a system that transforms the <a href="https://www.sciencedirect.com/topics/engineering/chemical-energy" title="Learn more about chemical energy from ScienceDirect's AI-generated Topic Pages" class="topic-link">chemical energy</a> contained in ammonia directly to electrical energy with high efficiency. With the widespread production of green ammonia, the interest in ammonia-based fuel cells increases. Fuel cells are considered the most efficient device to extract ammonia's energy with low or no environmental impact </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0905" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0905"><span class="anchor-text">[181]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0910" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0910"><span class="anchor-text">[182]</span></a><span>. There are four categories of ammonia-based fuel cells, i.e., alkaline ammonia fuel cell (MAFC “Molten alkaline ammonia fuel cell”), ammonia-based SOFC-H “Proton conducting electrolyte based solid oxide fuel cell”, and ammonia-base SOFC-O “oxygen anion conducting electrolyte based solid oxide fuel cell”, AAEFC “ammonia-based <a href="https://www.sciencedirect.com/topics/engineering/alkaline-electrolyte" title="Learn more about alkaline electrolyte from ScienceDirect's AI-generated Topic Pages" class="topic-link">alkaline electrolyte</a> fuel cells”, and ammonia-based MFC “microbial fuel cell”.</span></p>
<section id="s0080">
<h4 id="st105" class="u-margin-m-top u-margin-xs-bottom">4.1.1.<span> </span>Ammonia-based SOFC</h4>
<p id="p0515">Ammonia-based SOFC operates at high temperatures (500–1000 °C). At such high temperatures, ammonia cracking and power generation are consolidated<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0915" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0915"><span class="anchor-text">[183]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0920" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0920"><span class="anchor-text">[184]</span></a><span>. The cost of such FCs is relatively low as there is no need for separate ammonia cracking unit. Moreover, such high temperatures increase the <a href="https://www.sciencedirect.com/topics/engineering/enzymatic-activity" title="Learn more about catalytic activity from ScienceDirect's AI-generated Topic Pages" class="topic-link">catalytic activity</a>, so a non-precious catalyst is used. Also, such a high temperature enhances the electrolyte's ionic conductivity </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0925" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0925"><span class="anchor-text">[185]</span></a>. Ammonia-based SOFCs are classified into two types according to the electrolyte type; SOFC-H “proton-conducting electrolyte SOFC” and SOFC-O “oxygen anion conducting electrolyte SOFC”<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0930" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0930"><span class="anchor-text">[186]</span></a>.</p>
<section id="s0085">
<h5 id="st110" class="u-margin-m-top u-margin-xs-bottom">4.1.1.1.<span> </span>ASOFC-O “Ammonia-fed oxygen anion conducting electrolyte-based SOFC”</h5>
<div>
<p id="p0520"><span>In this type of fuel cell, ammonia is fed at the anode of the FC, where it thermally decomposes over the anode catalyst into hydrogen, while air or oxygen is fed on the <a href="https://www.sciencedirect.com/topics/engineering/cathode-side" title="Learn more about cathode side from ScienceDirect's AI-generated Topic Pages" class="topic-link">cathode side</a>. <a href="https://www.sciencedirect.com/topics/engineering/oxygen-reduction-reaction" title="Learn more about Oxygen reduction from ScienceDirect's AI-generated Topic Pages" class="topic-link">Oxygen reduction</a> into <a href="https://www.sciencedirect.com/topics/engineering/oxygen-ion" title="Learn more about oxygen ions from ScienceDirect's AI-generated Topic Pages" class="topic-link">oxygen ions</a> occurs at the cathode/electrolyte interface. The oxygen ions transfer to the <a href="https://www.sciencedirect.com/topics/engineering/anode-side" title="Learn more about anode side from ScienceDirect's AI-generated Topic Pages" class="topic-link">anode side</a> via the electrolyte, where electrochemical reactions occur at the anode/electrolyte interface, producing water vapour. The nitrogen production during the <a href="https://www.sciencedirect.com/topics/engineering/ammonia-decomposition" title="Learn more about ammonia decomposition from ScienceDirect's AI-generated Topic Pages" class="topic-link">ammonia decomposition</a> reduces the reversible reaction as it dilutes the hydrogen concentration, as can be seen in </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0035" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0035"><span class="anchor-text">Fig. 7</span></a>.</p>
<figure class="figure text-xs" id="f0035"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr7.jpg" height="220" alt="" aria-describedby="cn0035"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr7_lrg.jpg" target="_blank" download="" title="Download high-res image (189KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (189KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr7.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0045"><span class="label">Fig. 7</span>.<span> </span>Schematic diagram showing the principles of the asofc-o.</p>
<span class="captions text-s"><span id="cn0035"></span></span></figure>
</div>
<p id="p0525"><span>First, ammonia decomposed at the inlet of the <a href="https://www.sciencedirect.com/topics/engineering/anode-surface" title="Learn more about anode surface from ScienceDirect's AI-generated Topic Pages" class="topic-link">anode surface</a> as follows:</span><span class="display"><span id="e0080" class="formula"><span class="label">(16)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-47-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="22.091ex" height="3.24ex" viewBox="0 -945.9 9511.5 1395" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g><g is="true" transform="translate(1027,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g></g><g is="true" transform="translate(2741,0)"><use xlink:href="#MJMAIN-2194"></use></g><g is="true" transform="translate(3742,0)"><g transform="translate(397,0)"><rect stroke="none" width="473" height="60" x="0" y="220"></rect><g is="true" transform="translate(60,419)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g><g is="true" transform="translate(60,-375)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g><g is="true" transform="translate(4733,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(6392,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(7170,0)"><g transform="translate(342,0)"><rect stroke="none" width="473" height="60" x="0" y="220"></rect><g is="true" transform="translate(60,403)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-31"></use></g></g><g is="true" transform="translate(60,-375)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g><g is="true" transform="translate(8107,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(950,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">3</mtext></mrow></msub><mo stretchy="false" is="true">↔</mo><mfrac is="true"><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mn is="true">2</mn></mrow></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mo is="true">+</mo><mfrac is="true"><mrow is="true"><mn is="true">1</mn></mrow><mrow is="true"><mn is="true">2</mn></mrow></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub></mrow></math></span></span></span></span></span></p>
<p id="p0530">Then, the electrochemical reactions and overall reactions are shown in Eq. 17–19.</p>
<p id="p0535">@ anode:<span class="display"><span id="e0085" class="formula"><span class="label">(17)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-48-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="26.151ex" height="2.894ex" viewBox="0 -995.6 11259.6 1246" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(1658,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(2659,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,430)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(353,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g><g is="true" transform="translate(4779,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(6057,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(7493,0)"><use xlink:href="#MJMATHBI-4F"></use></g><g is="true" transform="translate(8553,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(9554,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(10054,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g><g is="true" transform="translate(554,362)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mo is="true">+</mo><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mn is="true">2</mn><mo is="true">-</mo></mrow></msup><mo stretchy="false" is="true">→</mo><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mi mathvariant="bold-italic" is="true">�</mi><mo is="true">+</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup></mrow></math></span></span></span></span></span></p>
<p id="p0540">@ cathode:<span class="display"><span id="e0090" class="formula"><span class="label">(18)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-49-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="19.351ex" height="3.355ex" viewBox="0 -995.6 8331.7 1444.7" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g transform="translate(120,0)"><rect stroke="none" width="473" height="60" x="0" y="220"></rect><g is="true" transform="translate(60,403)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-31"></use></g></g><g is="true" transform="translate(60,-375)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g><g is="true" transform="translate(713,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(2227,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3228,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(3728,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g><g is="true" transform="translate(554,362)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g><g is="true" transform="translate(5211,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(6489,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,430)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(353,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mfrac is="true"><mrow is="true"><mn is="true">1</mn></mrow><mrow is="true"><mn is="true">2</mn></mrow></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mo is="true">+</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup><mo stretchy="false" is="true">→</mo><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mn is="true">2</mn><mo is="true">-</mo></mrow></msup></mrow></math></span></span></span></span></span></p>
<p id="p0545">The overall reaction is:<span class="display"><span id="e0095" class="formula"><span class="label">(19)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-50-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="33.814ex" height="3.24ex" viewBox="0 -945.9 14558.6 1395" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(1658,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(2437,0)"><g transform="translate(342,0)"><rect stroke="none" width="473" height="60" x="0" y="220"></rect><g is="true" transform="translate(60,403)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-31"></use></g></g><g is="true" transform="translate(60,-375)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g><g is="true" transform="translate(3373,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(4942,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(6220,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(7657,0)"><use xlink:href="#MJMATHBI-4F"></use></g><g is="true" transform="translate(8716,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(9717,0)"><use xlink:href="#MJMATHBI-65"></use></g><g is="true" transform="translate(10272,0)"><use xlink:href="#MJMATHBI-6C"></use></g><g is="true" transform="translate(10620,0)"><use xlink:href="#MJMATHBI-65"></use></g><g is="true" transform="translate(11175,0)"><use xlink:href="#MJMATHBI-63"></use></g><g is="true" transform="translate(11688,0)"><use xlink:href="#MJMATHBI-74"></use></g><g is="true" transform="translate(12104,0)"><use xlink:href="#MJMATHBI-72"></use></g><g is="true" transform="translate(12633,0)"><use xlink:href="#MJMATHBI-63"></use></g><g is="true" transform="translate(13147,0)"><use xlink:href="#MJMATHBI-69"></use></g><g is="true" transform="translate(13552,0)"><use xlink:href="#MJMATHBI-74"></use></g><g is="true" transform="translate(13968,0)"><use xlink:href="#MJMATHBI-79"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mo is="true">+</mo><mfrac is="true"><mrow is="true"><mn is="true">1</mn></mrow><mrow is="true"><mn is="true">2</mn></mrow></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mo stretchy="false" is="true">→</mo><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mi mathvariant="bold-italic" is="true">�</mi><mo is="true">+</mo><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi><mi mathvariant="bold-italic" is="true">�</mi></mrow></math></span></span></span></span></span></p>
<p id="p0550">ASOFC-O is composed of the YSZ “Yittria stabilized zirconia” electrolyte doped with SDC “Samarium doped ceria”, SSC “Sm<sub>0.5</sub>Sr<sub>0.5</sub>Co<sub>3-δ</sub>” cathode, and nickel anode. The ASOFC-O could produce 168.1 mW/cm<sup>2</sup><span> </span>at 600 °C, compared with 191.8 mW/cm<sup>2</sup><span> in the case of hydrogen-based SOFC-O. With the slightly lower <a href="https://www.sciencedirect.com/topics/engineering/power-output" title="Learn more about power output from ScienceDirect's AI-generated Topic Pages" class="topic-link">power output</a> in the case of the ASOFC-O would be related to the dilution effect of the nitrogen produced ta the anode from the ammonia dissociation </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0935" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0935"><span class="anchor-text">[187]</span></a>. This power increased with the operating temperature and/or efficient cell components. For instance, ASOFC-O fabricated of SSC cathode, nickel oxide anode, and SDC electrolyte (24 µm thick), generated a 467 mW/cm<sup>2</sup><span> </span>at 650 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0940" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0940"><span class="anchor-text">[188]</span></a>. ASOFC-O with a nickel-based anode, BSCF “Ba<sub>0.5</sub>Sr<sub>0.5</sub>Co<sub>0.8</sub>Fe<sub>0.2</sub>O<sub>3-δ</sub>” cathode, and SDC electrolyte (10 µm) operated at 650 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0945" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0945"><span class="anchor-text">[189]</span></a>. This ASOFC-O showed high power densities of 1190 and 1872 mW/cm<sup>2</sup> using ammonia and hydrogen. YSZ electrolyte was also investigated in ASOFC-O but showed lower performance than those using SDC electrolyte. ASOFC-O with YSZ electrolyte, silver-based cathode and platinum-based anode was operated at 800 and 1000 °C, achieving 50 and 125 mW/cm<sup>2</sup><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0950" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0950"><span class="anchor-text">[190]</span></a>. The thickness of the electrolyte also affected the cell performance; for instance, an ASOFC-O using YSZ electrolyte (15 µm), LSM cathode, and nickel anode showed a 202 mW/cm<sup>2</sup><span> </span>at 800 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0955" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0955"><span class="anchor-text">[191]</span></a>. Several studies have been done to check the effect of the electrolyte on cell performance<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0960" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0960"><span class="anchor-text">[192]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0965" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0965"><span class="anchor-text">[193]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0970" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0970"><span class="anchor-text">[194]</span></a>.</p>
</section>
<section id="s0090">
<h5 id="st115" class="u-margin-m-top u-margin-xs-bottom">4.1.1.2.<span> </span>ASOFC-H “ammonia-fed proton-conducting electrolyte-based solid oxide fuel cells”</h5>
<p id="p0555">Similar to the case of the ASOFC-O, ammonia decomposed at the inlet of the anode catalyst into hydrogen and nitrogen. However, in this case, the produced hydrogen is oxidized at the anode/electrolyte interface into hydrogen protons (H<sup>+</sup>), that migrate via the electrolyte membrane to the cathode side, as they combine with oxygen at the cathode/electrolyte interface producing water as can be seen in Eq. 20–22:</p>
<p id="p0560">At the anode, the hydrogen generated from the dissociation of ammonia is oxidized, Eq. 20:<span class="display"><span id="e0100" class="formula"><span class="label">(20)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-51-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="18.843ex" height="2.663ex" viewBox="0 -896.2 8112.9 1146.6" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(1714,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(2992,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(3492,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2B"></use></g></g></g><g is="true" transform="translate(5406,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(6407,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(6907,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g><g is="true" transform="translate(554,362)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mo stretchy="false" is="true">→</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">+</mo></mrow></msup><mo is="true">+</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup></mrow></math></span></span></span></span></span></p>
<p id="p0565">These protons combine with oxygen at the cathode/electrolyte interface as follows, Eq. 21:<span class="display"><span id="e0105" class="formula"><span class="label">(21)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-52-Frame" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"><svg xmlns:xlink="http://www.w3.org/1999/xlink" width="29.834ex" height="3.24ex" viewBox="0 -945.9 12845.3 1395" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g transform="translate(120,0)"><rect stroke="none" width="473" height="60" x="0" y="220"></rect><g is="true" transform="translate(60,403)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-31"></use></g></g><g is="true" transform="translate(60,-375)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g><g is="true" transform="translate(713,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g><g is="true"></g></g></g><g is="true" transform="translate(2560,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true"></g><g is="true" transform="translate(3894,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(4395,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2B"></use></g></g></g><g is="true" transform="translate(6309,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(7309,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(7810,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g><g is="true" transform="translate(554,362)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g><g is="true" transform="translate(9293,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(10571,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(12007,0)"><use xlink:href="#MJMATHBI-4F"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mfrac is="true"><mrow is="true"><mn is="true">1</mn></mrow><mrow is="true"><mn is="true">2</mn></mrow></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext><mspace width="0.333333em" is="true"></mspace></mrow></msub><mo is="true">+</mo><mspace width="0.333333em" is="true"></mspace><mn is="true">2</mn><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">+</mo></mrow></msup><mo is="true">+</mo><mn is="true">2</mn><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup><mo stretchy="false" is="true">→</mo><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mi mathvariant="bold-italic" is="true">�</mi></mrow></math></span></span></span></span></span></p>
<div>
<p id="p0570">The overall reaction is similar to that in the case of the ASOFC-O, Eq. 19.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0040" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0040"><span class="anchor-text">Fig. 8</span></a><span> </span>shows the schematic of the operating principles of ASOFC-H.</p>
<figure class="figure text-xs" id="f0040"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr8.jpg" height="218" alt="" aria-describedby="cn0040"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr8_lrg.jpg" target="_blank" download="" title="Download high-res image (211KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (211KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr8.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0050"><span class="label">Fig. 8</span>.<span> </span>Schematic diagram showing the principles of the asofc-h.</p>
<span class="captions text-s"><span id="cn0040"></span></span></figure>
</div>
<p id="p0575">Compared to ASOFC-O, the formation of nitrogen oxides is avoided in the ASOFC-H, but the produced power is lower. BCG “gadolinium-doped <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/barium-cerate" target="_blank" rel="noreferrer noopener"><span class="anchor-text">barium cerate</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a>” is mainly used as the electrolyte in ASOFC-H. The performance of ASOFC-H with two different electrolytes BCG or BCGP “<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/gadolinium" target="_blank" rel="noreferrer noopener"><span class="anchor-text">Gadolinium</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> and Praseodymium-doped <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/barium-cerate" target="_blank" rel="noreferrer noopener"><span class="anchor-text">barium Cerate</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a><span>”, was investigated at 700 °C using <a href="https://www.sciencedirect.com/topics/engineering/platinum-electrode" title="Learn more about platinum electrodes from ScienceDirect's AI-generated Topic Pages" class="topic-link">platinum electrodes</a> showing 25 and 35 mW cm</span><sup>−2</sup><span> </span>for BCG and BCGP, respectively<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0975" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0975"><span class="anchor-text">[195]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0980" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0980"><span class="anchor-text">[196]</span></a><span>. A mixed ionic and electronic conducting <a href="https://www.sciencedirect.com/topics/engineering/cermet" title="Learn more about cermet from ScienceDirect's AI-generated Topic Pages" class="topic-link">cermet</a> anode (Ni-BCE) was investigated in platinum-based cathode ASOFC-H with BCGP electrolyte </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0985" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0985"><span class="anchor-text">[197]</span></a><span>. Compared to the platinum anode, The Ni-BCE anode showed superior catalytic activity toward ammonia <a href="https://www.sciencedirect.com/topics/engineering/oxidation-reaction" title="Learn more about oxidation from ScienceDirect's AI-generated Topic Pages" class="topic-link">oxidation</a>, achieving a <a href="https://www.sciencedirect.com/topics/engineering/peak-power-density" title="Learn more about peak power density from ScienceDirect's AI-generated Topic Pages" class="topic-link">peak power density</a> of 28 mW cm</span><sup>−2</sup><span> </span>(at 600 °C), while Pt anode showed 23 mW cm<sup>−2</sup><span> </span>at the same operating temperature. ASOFC-H incorporated with Ni-BCE anode realized a very stable performance for&gt;500 h. The performance of ASOFC-H with BCGO “BaCe<sub>0.8</sub><span> </span>Gd<sub>0.2</sub><span> </span>O<sub>2.9</sub>” electrolyte, LCSO “La<sub>0.5</sub><span> </span>Sr<sub>0.5</sub><span> </span>CoO<sub>3– δ</sub>” cathode and Ni-based anode was investigated at a temperature ranging from 600 to 750 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0990" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0990"><span class="anchor-text">[198]</span></a>. The cell's power output increased from 96 mW cm<sup>−2</sup> @ 600 °C to 384 mW cm<sup>−2</sup><span> </span>@ 750 °C. A thin BCGO electrolyte (30 µm) was tested in ASOFC-H operated @ 600 °C, using CGO (Ce<sub>0.8</sub>Gd<sub>0.2</sub>O<sub>1.9</sub>)-Ni anode, and BSCFO “Ba<sub>0.5</sub>Sr<sub>0.5</sub>Co<sub>0.8</sub>Fe<sub>0.2</sub>O<sub>3−δ</sub>” -CGO cathode attained an OCV of 1.12 V and peak power of 147 mW cm<sup>−2</sup><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0995" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0995"><span class="anchor-text">[199]</span></a>. A BZCY “BaZr<sub>0.1</sub>Ce<sub>0.7</sub>Y<sub>0.2</sub>O<sub>3−</sub><em><sub>δ</sub></em>” based electrolyte (35 μm) was also investigated in ASOFC-H using Ni-based anode and BSCF “Ba<sub>0.5</sub>Sr<sub>0.5</sub>Co<sub>0.8</sub>Fe<sub>0.2</sub>O<sub>3-δ</sub>” cathode acquired 420 mW cm<sup>−2</sup><span> </span>@ 700 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1000" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1000"><span class="anchor-text">[200]</span></a>. The ASOFCs-H with the same electrolyte but using different electrolyte thicknesses and different cathodes were also examined. ASOFC-H with a thin electrolyte of 10 μm and GdBaCo<sub>2</sub>O<sub>5+</sub><em><sub>x</sub></em> cathode achieved a 266 mW cm<sup>−2</sup> <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1005" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1005"><span class="anchor-text">[201]</span></a>, ASOFC-H with electrolyte thickness of 50 μm and LSC “La<sub>0.5</sub>Sr<sub>0.5</sub>CoO<sub>3−</sub><em><sub>δ</sub></em>” cathode attained 330 mW cm<sup>−2</sup> <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1010" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1010"><span class="anchor-text">[202]</span></a>, and ASOFC-H with electrolyte thickness of 65 μm and BPY “Ba(Ce<sub>0.4</sub>Pr<sub>0.4</sub>Y<sub>0.2</sub>)O<sub>3−</sub><em><sub>δ</sub>”</em> cathode attained 270 mW cm<sup>−2</sup> <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1015" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1015"><span class="anchor-text">[203]</span></a>. Moreover, BCNO “BaCe<sub>0.9</sub>Nd<sub>0.1</sub>O<sub>3−</sub><em><sub>δ</sub></em>” electrolyte of 20 µm thickness was tested in ASOFC-H using nickel oxide-based anode, and LCSO cathode @ 700 °C attained 315 mW cm<sup>−2</sup><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1020" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1020"><span class="anchor-text">[204]</span></a>.</p>
</section>
</section>
<section id="s0095">
<h4 id="st120" class="u-margin-m-top u-margin-xs-bottom">4.1.2.<span> </span>AAMFC “Ammonia alkaline molten fuel cell” and AAEFC “ammonia alkaline electrolyte fuel cell”.</h4>
<p id="p0580">In these ammonia-based fuel cells, oxygen from the air reacts with water at the cathode side forming hydroxide ions (anions). These ions transfer to the anode side via the electrolyte. The alkaline electrolyte may be aqueous in the case of AAEFC, such as sodium hydroxide or molten potassium hydroxide, as in the case of AAMFC. At the anode side of the molten or aqueous alkaline electrolyte fuel cell, the anions react with the fuel (ammonia), producing water, nitrogen, and electrons, as seen in Eq. 22 and 23:</p>
<p id="p0585">@ anode<span class="display"><span id="e0110" class="formula"><span class="label">(22)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-53-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="39.724ex" height="2.663ex" viewBox="0 -896.2 17103.1 1146.6" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(500,0)"><use xlink:href="#MJMATHBI-4E"></use></g><g is="true" transform="translate(1528,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g></g><g is="true" transform="translate(3186,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(4187,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(4687,0)"><use xlink:href="#MJMATHBI-4F"></use></g><g is="true" transform="translate(5525,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g><g is="true" transform="translate(7494,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(8772,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4E"></use></g></g><g is="true" transform="translate(950,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(10399,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(11400,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(11900,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(13337,0)"><use xlink:href="#MJMATHBI-4F"></use></g><g is="true" transform="translate(14396,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(15397,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(15898,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g><g is="true" transform="translate(554,362)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mn is="true">2</mn><mi mathvariant="bold-italic" is="true">�</mi><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">3</mtext></mrow></msub><mo is="true">+</mo><mn is="true">6</mn><mi mathvariant="bold-italic" is="true">�</mi><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup><mo stretchy="false" is="true">→</mo><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mo is="true">+</mo><mn is="true">6</mn><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mi mathvariant="bold-italic" is="true">�</mi><mo is="true">+</mo><mn is="true">6</mn><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup></mrow></math></span></span></span></span></span></p>
<p id="p0590">@ cathode<span class="display"><span id="e0115" class="formula"><span class="label">(23)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-54-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="31.394ex" height="3.24ex" viewBox="0 -945.9 13516.7 1395" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g transform="translate(120,0)"><rect stroke="none" width="473" height="60" x="0" y="220"></rect><g is="true" transform="translate(60,419)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g><g is="true" transform="translate(60,-375)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g><g is="true" transform="translate(713,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(2227,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3228,0)"><use xlink:href="#MJMAIN-33"></use></g><g is="true" transform="translate(3728,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(5165,0)"><use xlink:href="#MJMATHBI-4F"></use></g><g is="true" transform="translate(6224,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(7225,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(7726,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-65"></use></g></g><g is="true" transform="translate(554,362)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g><g is="true" transform="translate(9208,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(10487,0)"><use xlink:href="#MJMAIN-36"></use></g><g is="true" transform="translate(10987,0)"><use xlink:href="#MJMATHBI-4F"></use></g><g is="true" transform="translate(11825,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mfrac is="true"><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mn is="true">2</mn></mrow></mfrac><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mo is="true">+</mo><mn is="true">3</mn><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mi mathvariant="bold-italic" is="true">�</mi><mo is="true">+</mo><mn is="true">6</mn><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup><mo stretchy="false" is="true">→</mo><mn is="true">6</mn><mi mathvariant="bold-italic" is="true">�</mi><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup></mrow></math></span></span></span></span></span></p>
<p id="p0595">One of the main drawbacks of the hydroxide ions that it could react with CO<sub>2</sub><span>, producing <a href="https://www.sciencedirect.com/topics/engineering/carbonate-ion" title="Learn more about carbonate ions from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbonate ions</a>, thereby decreasing the available hydroxide ions, and hence, reducing the ionic conductivity of the electrolyte, hence decreasing the <a href="https://www.sciencedirect.com/topics/engineering/fuel-cell-performance" title="Learn more about fuel cell performance from ScienceDirect's AI-generated Topic Pages" class="topic-link">fuel cell performance</a> as seen in Eq. 24. Furthermore, carbonate compounds precipitates are formed in ammonia alkaline aqueous or molten electrolyte fuel cell.</span><span class="display"><span id="e0120" class="formula"><span class="label">(24)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-55-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="32.864ex" height="3.125ex" viewBox="0 -995.6 14149.7 1345.3" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-43"></use></g><g is="true" transform="translate(855,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(2369,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(3369,0)"><use xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(3870,0)"><use xlink:href="#MJMATHBI-4F"></use></g><g is="true" transform="translate(4707,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(1041,413)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g></g><g is="true" transform="translate(6677,0)"><use xlink:href="#MJMAIN-2192"></use></g><g is="true" transform="translate(7955,0)"><use xlink:href="#MJMATHBI-43"></use></g><g is="true" transform="translate(8810,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-4F"></use></g></g><g is="true" transform="translate(837,430)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g><g is="true" transform="translate(353,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g></g><g is="true" transform="translate(837,-279)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-33"></use></g></g></g><g is="true" transform="translate(10875,0)"><use xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(11875,0)"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-48"></use></g></g><g is="true" transform="translate(982,-150)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g><g is="true" transform="translate(13312,0)"><use xlink:href="#MJMATHBI-4F"></use></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mn is="true">2</mn></mrow></msub><mo is="true">+</mo><mn is="true">2</mn><mi mathvariant="bold-italic" is="true">�</mi><msup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mo is="true">-</mo></mrow></msup><mo stretchy="false" is="true">→</mo><mi mathvariant="bold-italic" is="true">�</mi><msubsup is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mn is="true">3</mn></mrow><mrow is="true"><mn is="true">2</mn><mo is="true">-</mo></mrow></msubsup><mo is="true">+</mo><msub is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mtext is="true">2</mtext></mrow></msub><mi mathvariant="bold-italic" is="true">�</mi></mrow></math></span></span></span></span></span></p>
<p id="p0600">Ammonia-based fuel cell with molten hydroxide electrolyte and porous nickel electrodes was constructed and operated at 200 to 450 °C. The cells showed 16 mW cm<sup>−2</sup>, which increased to 40 mW cm<sup>−2</sup><span> </span>@ 450 °C<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1025" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1025"><span class="anchor-text">[205]</span></a><span>. The same electrolyte was investigated using <a href="https://www.sciencedirect.com/topics/engineering/pt-electrode" title="Learn more about Pt electrodes from ScienceDirect's AI-generated Topic Pages" class="topic-link">Pt electrodes</a> operated at 200–220 °C </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1030" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1030"><span class="anchor-text">[206]</span></a>. A 10.5 mW cm<sup>−2</sup><span> </span>was realized at 200 °C and increased to 16 mW cm<sup>−2</sup><span> </span>at 220 °C. AAMFC operated at room temperature using CPPO “Chloroacetyl poly, 2,6-dimethyl-1,4-phenylene oxide”, PVA “<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/polyvinyl-alcohol" target="_blank" rel="noreferrer noopener"><span class="anchor-text">polyvinyl alcohol</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a>” (CPPO-PVA) electrolyte membrane, MnO<sub>2</sub>/C cathode, and Chromium decorated nickel/carbon anode achieved 16 mW cm<sup>−2</sup><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1035" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1035"><span class="anchor-text">[207]</span></a>.</p>
</section>
<section id="s0100">
<h4 id="st125" class="u-margin-m-top u-margin-xs-bottom">4.1.3.<span> </span>AMFC “Ammonia-based microbial fuel Cell”</h4>
<p id="p0605"><span>MFC “microbial fuel cell” is a bio-electrochemical device used for simultaneous <a href="https://www.sciencedirect.com/topics/engineering/wastewater-treatment" title="Learn more about wastewater treatment from ScienceDirect's AI-generated Topic Pages" class="topic-link">wastewater treatment</a> and <a href="https://www.sciencedirect.com/topics/engineering/energy-harvesting" title="Learn more about harvesting energy from ScienceDirect's AI-generated Topic Pages" class="topic-link">harvesting energy</a> from wastes in the form of electricity </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1040" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1040"><span class="anchor-text">[208]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1045" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1045"><span class="anchor-text">[209]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1050" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1050"><span class="anchor-text">[210]</span></a><span>. Although the low power output of MFC, it has several advantages as the fuel is the wastewater that is contaminated with various organic materials, simple in design, operates at room temperature, uses the microbes in wastewater as the <a href="https://www.sciencedirect.com/topics/engineering/biocatalyst" title="Learn more about biocatalyst from ScienceDirect's AI-generated Topic Pages" class="topic-link">biocatalyst</a>, and no need for precious cathode catalyst. The microorganism on the anaerobic <a href="https://www.sciencedirect.com/topics/engineering/anode-chamber" title="Learn more about anode chamber from ScienceDirect's AI-generated Topic Pages" class="topic-link">anode chamber</a> metabolites the organic wastes, generating electrons and protons that move to the cathode side, reacting with oxidant-producing water at the cathode side. Electrical energy is generated as the electrons flow from anode to the cathode. Ammonia-polluted wastewater could be used effectively as a substrate in MFC to obtain electricity. The ammonia-polluted wastewater was used as substrate in HND-ACMFC “heterotrophic nitrifying/denitrifying air–cathode fuel cell” </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1055" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1055"><span class="anchor-text">[211]</span></a>. The HND-ACMFC was investigated for long-term operation, 197 days, repeatedly, and it demonstrated an efficient removal of total nitrogen , ammonia, and COD of 95 %, 99 % and 91 %, respectively, with continuous electricity generation of 0.72 A m<sup>−3</sup><span> </span>and peak power of 100 mW m<sup>−3</sup>. Another study examined IVCW-MFC “integrated vertical flow constructed wetland microbial fuel cell”, for electricity generation and swine wastewater treatment<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1060" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1060"><span class="anchor-text">[212]</span></a>. The IVCW-MFC achieved 456 mW m<sup>−3</sup><span>, <a href="https://www.sciencedirect.com/topics/engineering/steady-voltage" title="Learn more about steady voltage from ScienceDirect's AI-generated Topic Pages" class="topic-link">steady voltage</a> output between 598 and 713 mV, and average removal efficiencies of 77.5 %, 75.13 % and 79.65 %, for NH</span><sub>4</sub><sup>+</sup>–N, NO<sub>3</sub>–N, and COD, respectively.</p>
</section>
</section>
<section id="s0105">
<h3 id="st130" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.2.<span> </span>Ammonia-based battery</h3>
<p id="p0610"><span>S-TEGs “Solid state <a href="https://www.sciencedirect.com/topics/engineering/thermoelectrics" title="Learn more about thermoelectric from ScienceDirect's AI-generated Topic Pages" class="topic-link">thermoelectric</a> generators” are commonly used to transfer waste heat (thermal energy) to electrical power; however, the high cost of S-TEGs hinders their large-scale applications </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1065" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1065"><span class="anchor-text">[213]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1070" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1070"><span class="anchor-text">[214]</span></a>. Recently, TRBs “Thermally regenerative batteries” demonstrated an ability to convert heat (including waste heat resources) to electricity efficiently and at a reasonable price. TRAB “thermally regenerative ammonia-based battery” utilizes thermal distillation and redox reactions to transform the low-grade waste heat (&lt;130 °C) to electricity using thermally regenerated electrolytes<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1075" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1075"><span class="anchor-text">[215]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1080" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1080"><span class="anchor-text">[216]</span></a>. Metal electrodes and ammonia combine to form a complex during the discharge process, which results in a potential difference that generates energy. During charging, the waste heat is utilized to extract ammonia from the anolyte and move it to the catholyte<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1085" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1085"><span class="anchor-text">[217]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1090" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1090"><span class="anchor-text">[218]</span></a><span>. There are two types of TRABs according to the <a href="https://www.sciencedirect.com/topics/engineering/electrode-type" title="Learn more about electrode type from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrode type</a>, i.e., S-TRAB “single metallic” where both electrodes are made of the same metal </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1095" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1095"><span class="anchor-text">[219]</span></a>, B-TRAB “bimetallic” where the two electrodes are made of different metals<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1100" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1100"><span class="anchor-text">[220]</span></a>.</p>
<p id="p0615"><span>Cu-TRAB was constructed of copper <a href="https://www.sciencedirect.com/topics/engineering/meshes" title="Learn more about mesh from ScienceDirect's AI-generated Topic Pages" class="topic-link">mesh</a> electrodes where 2 M ammonia was added to the anolyte using <a href="https://www.sciencedirect.com/topics/engineering/redox-couple" title="Learn more about redox couples from ScienceDirect's AI-generated Topic Pages" class="topic-link">redox couples</a> of “Cu(NH</span><sub>3</sub>)<sub>4</sub><sup>2+</sup>/Cu and Cu<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1105" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1105"><span class="anchor-text">[221]</span></a>/Cu”<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1110"><span class="anchor-text">[222]</span></a>. Copper-based S-TRAB generated 115 ± 1 W m<sup>−2</sup>, which increased to 136 ± 3 W m<sup>−2</sup><span> </span>by increasing the ammonia concentration to 3 M. The power doubled when another cell was added. Cu-TRAB was also constructed and examined at different operating temperatures<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1080" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1080"><span class="anchor-text">[216]</span></a>. The Cu-TRAB generated 95 ± 5 W m<sup>−2</sup> and 236 ± 8 W m<sup>−2</sup><span> </span>at 23 °C and 72 °C, respectively. The enhancement of the power at higher temperatures was related to the decreased electrode overpotentials and the adequate copper oxidation at the anode. Moreover, the effect of flow rate, reactor design, and electrode pore density on the performance of Cu-TRAB was investigated<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1115" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1115"><span class="anchor-text">[223]</span></a><span>. The various reactor designs demonstrated varying <a href="https://www.sciencedirect.com/topics/engineering/mass-transfer-effect" title="Learn more about mass transfer effects from ScienceDirect's AI-generated Topic Pages" class="topic-link">mass transfer effects</a> and various powers. The Cu-TRAB with a flow-through electrode on both sides (Cu-TRAB-FT) showed the highest peak power of 22.9 W m</span><sup>−2</sup><span> </span>due to the improved mass transfer of this electrode. Moreover, the optimum electrolyte flow rate and electrode pore density of Cu-TRAB-FT were 15 mL min<sup>−1</sup><span> </span>and 100 PPI “pores per linear inch”. Also, Cu-AFB “Copper-based ammonia flow battery” was designed and operated at different temperatures<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1105" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1105"><span class="anchor-text">[221]</span></a>. The Cu-AFB demonstrated power densities of 204 W m<sup>−2</sup> and 280 W m<sup>−2</sup> at 25 °C and 55 °C, respectively. The influence of operating parameters, including membrane type, electrode distance, electrode type, electrode area, ammonia and NH<sub>4</sub>NO<sub>3</sub><span> </span>concentrations on the performance of S-TRAB was assessed<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1120" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1120"><span class="anchor-text">[224]</span></a><span>. Different membranes, i.e., cation and <a href="https://www.sciencedirect.com/topics/engineering/anion-exchange-membrane" title="Learn more about anion exchange membranes from ScienceDirect's AI-generated Topic Pages" class="topic-link">anion exchange membranes</a> of the same thickness (0.45 ± 0.025 mm), were tested. Different electrode types including Cobalt, copper or nickel sheets of the same dimensions (20 × 8 × 1 mm), were utilized as electrodes using NH</span><sub>4</sub>NO<sub>3</sub> solution (5 mol·L<sup>−1</sup> ) mixed with 0.1 mol·L<sup>−1</sup> of Co(NO<sub>3</sub>)<sub>2</sub>, Cu(NO<sub>3</sub>)<sub>2</sub>, or Ni (NO<sub>3</sub>), respectively. Furthermore, different copper electrodes distances of 1.5, 4, 6, 8, 10, 12, and 14 cm, and different electrode areas of 1, 2, 6, 8, 10, 20, and 25 cm<sup>2</sup><span> </span>were also tested. The results exhibited that among different electrodes, the copper electrodes achieved the highest peak power density of 40 W·m<sup>−2</sup><span>. anion exchange membrane showed better Cu-TRAB performance than <a href="https://www.sciencedirect.com/topics/engineering/cation-exchange-membrane" title="Learn more about cation exchange membranes from ScienceDirect's AI-generated Topic Pages" class="topic-link">cation exchange membrane</a>. The peak power density of Cu-TRAB increased with increasing electrode areas, ammonia and <a href="https://www.sciencedirect.com/topics/engineering/electrolyte-concentration" title="Learn more about electrolyte concentrations from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrolyte concentrations</a> over certain ranges. Additionally, definite concentrations of NH</span><sub>3</sub> created tradeoffs between energy and power densities<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1125" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1125"><span class="anchor-text">[225]</span></a>. Increasing the NH<sub>3</sub><span> </span>concentration from 1 to 5 M decreases the energy density from 0.56 to 0.31 Wh/L, while the power increases from 11.2 to 28.5 mW cm<sup>−2</sup>. The decrease in energy density was related to NH<sub>3</sub> crossover through the membrane during the Self-discharge of Cu-TRAB. A membrane-less microfluidic TRAB was also designed and operated at batch mode using pure copper electrodes or thick deposits of copper over compact graphite support electrodes<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1130" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1130"><span class="anchor-text">[226]</span></a><span>. Membrane-less microfluidic Cu- TRAB showed better power density than conventional Cu-TRAB operating under the same operating mode and conditions. The performance of membrane-less microfluidic TRAB was enhanced by replacing the pure copper electrodes with copper deposited on <a href="https://www.sciencedirect.com/topics/engineering/graphite-electrode" title="Learn more about graphite electrodes from ScienceDirect's AI-generated Topic Pages" class="topic-link">graphite electrodes</a> that increased the power to 3.4 W m</span><sup>−2</sup> at 50 °C. Cu/Ni composite electrodes were synthesized by electrodeposition of copper on nickel foams and investigated in TRABs<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1135" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1135"><span class="anchor-text">[227]</span></a>. Compared to Cu-TRAB, Cu/Ni-TRAB achieved the same power of 6.5 mW, but with higher anodic coulombic efficiency, 94 %, and considerably extended electrode operation time (&gt;55 h).</p>
<p id="p0620"><span>Cu-TRABs suffered from unbalanced cathode deposition and <a href="https://www.sciencedirect.com/topics/engineering/anode-dissolution" title="Learn more about anode dissolution from ScienceDirect's AI-generated Topic Pages" class="topic-link">anode dissolution</a> rates during discharging cycles. To overcome such challenges, a Cu-TRAB using ligands was developed to stabilize Cu(I) and Cu</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1105" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1105"><span class="anchor-text">[221]</span></a><span> </span>ions·NH<sub>3</sub>(aq) and Br<sup>−</sup>(aq) ligands were used in Cu-TRAB operated at 25 °C achieving a cell potential difference of 695 ± 2 mV, 350 W m<sup>−2</sup><span> </span>and high Coulombic efficiency (&gt;90 %)<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1140" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1140"><span class="anchor-text">[228]</span></a><span>. The system's <a href="https://www.sciencedirect.com/topics/engineering/energy-storage-density" title="Learn more about energy storage density from ScienceDirect's AI-generated Topic Pages" class="topic-link">energy storage density</a> was twice that reported for alternated Cu-TRAB chemistries and can reach four times higher. A steady and reversible electrode reaction was also accomplished using inert carbon electrodes and <a href="https://www.sciencedirect.com/topics/engineering/silver" title="Learn more about silver from ScienceDirect's AI-generated Topic Pages" class="topic-link">silver</a> salts throughout a number of cycles </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1145" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1145"><span class="anchor-text">[229]</span></a>. Under bath mode test, 23 W m<sup>−2</sup><span> </span>was achieved, which is 64 % higher than that generated using Cu-TRAB. Furthermore, a 30 W m<sup>−2</sup> <span>was stable over 100 cycles under continuous flow operation, realizing superior <a href="https://www.sciencedirect.com/topics/engineering/reversibility" title="Learn more about reversibility from ScienceDirect's AI-generated Topic Pages" class="topic-link">reversibility</a>. Cu/Zn-TRAB, using copper and <a href="https://www.sciencedirect.com/topics/engineering/zinc-electrode" title="Learn more about zinc electrodes from ScienceDirect's AI-generated Topic Pages" class="topic-link">zinc electrodes</a> was constructed and examined at different temperatures (10–45 °C) </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1090" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1090"><span class="anchor-text">[218]</span></a>. Peak power of 389 W m<sup>−2</sup><span> </span>was achieved and increased to 723 ± 45 W m<sup>−2</sup> <span>by increasing the temperature from 10 to 40 °C with linear slope of 12.25 W m − 2 °C − 1. However, further increases in the temperature resulted in decreasing the power output. Copper/zinc bimetallic TRA based <a href="https://www.sciencedirect.com/topics/engineering/flow-battery" title="Learn more about flow battery from ScienceDirect's AI-generated Topic Pages" class="topic-link">flow battery</a> (Cu/Zn-TRAFB) was also developed, realizing a voltage discharge of 1.38 V and 535 W m</span><sup>−2</sup><span> </span>with redox couples [Cu<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1105" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1105"><span class="anchor-text">[221]</span></a>/Cu and Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>/Zn]<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1150" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1150"><span class="anchor-text">[230]</span></a>. A power of 1070 (535 W m<sup>−2</sup>) could be achieved by connecting two cells (parallel or series).</p>
</section>
<section id="s0110">
<h3 id="st135" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.3.<span> </span>Ammonia as fuel in ignition engines (AIE)</h3>
<p id="p0625"><span>The automobile industry is one of the most pollutant sectors of the environment where it is based on combustion engines powered by fossil fuels. The decarbonization of power generation, marine and automotive markets is compulsory for limiting global warming and meeting the emissions of greenhouse gases. Hydrogen is considered a carbonless fuel that could be implemented with diesel in IE to decrease carbon emissions. But hydrogen is compressed at high pressure, and thus, it is a dangerous and expensive approach. Therefore, hydrogen carriers are considered a good candidate for diesel-based engines. Ammonia is deemed a hydrogen carrier and could be used effectively as an <a href="https://www.sciencedirect.com/topics/engineering/alternative-fuel" title="Learn more about alternative fuel from ScienceDirect's AI-generated Topic Pages" class="topic-link">alternative fuel</a> in CIE. Ammonia could be burned with any fuels with low auto-ignition temperature or diesel (dual fuel combustion, DFC), thereby decreasing the carbon-based emissions. But NOx emissions and high unburned ammonia are the main demerits of the DFC approach, and thus the after-treatment system is needed. Consequently, </span><a href="https://www.sciencedirect.com/topics/engineering/compression-ignition" title="Learn more about compression ignition from ScienceDirect's AI-generated Topic Pages" class="topic-link">compression ignition</a><span> </span>using ammonia could be a proper solution for heavy-duty, marine and power generation applications. marine.</p>
<p id="p0630">In 2007, Ammonia and gasoline-powered vehicle were designed and tested from Detroit to San Francisco<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1155" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1155"><span class="anchor-text">[231]</span></a>. In 2013, Toyota “Marangoni GT86 ECO” developed the first ammonia-fueled racing car that operated with ammonia fuel up to 2800 rpm while gasoline fuel was used at a higher speed<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0805" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0805"><span class="anchor-text">[161]</span></a>. In 2014, a vehicle that was partly fuelled with 70 % ammonia “ port injection” and 30 % gasoline “direct injection” was designed and operated successfully by the Korean Institute of Energy Research<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1160" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1160"><span class="anchor-text">[232]</span></a>. In the same year, a carbon-free hydrogen ammonia tractor was evolved by a Nevada corporation, “HEC Inc.”<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1165" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1165"><span class="anchor-text">[233]</span></a>. Newly, ammonia/hydrogen-fueled vehicles were developed using carbon-free hybrid system as hydrogen was produced by the electrochemical ammonia splitting<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1170" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1170"><span class="anchor-text">[234]</span></a>.</p>
<p id="p0635">Ammonia is the perfect fuel for marine and power generation applications<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1175" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1175"><span class="anchor-text">[235]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1180" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1180"><span class="anchor-text">[236]</span></a><span>. Marine and power generation are not space-constrained compared to <a href="https://www.sciencedirect.com/topics/engineering/automotive-application" title="Learn more about automotive applications from ScienceDirect's AI-generated Topic Pages" class="topic-link">automotive applications</a> as they could be implemented with <a href="https://www.sciencedirect.com/topics/engineering/auxiliary-equipment" title="Learn more about auxiliary equipment from ScienceDirect's AI-generated Topic Pages" class="topic-link">auxiliary equipment</a> to reduce NOx emissions. Ammonia has been proposed as a favourable power-to-liquid approach for establishing a <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-economy" title="Learn more about hydrogen economy from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen economy</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1185" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1185"><span class="anchor-text">[237]</span></a><span>. Moreover, A company, “MAN Energy Solutions multinational company” plans to replace the dual-fuel <a href="https://www.sciencedirect.com/topics/engineering/marine-engines" title="Learn more about marine engine from ScienceDirect's AI-generated Topic Pages" class="topic-link">marine engine</a> (fueled with liquefied petroleum gas and diesel) with an ammonia-based engine </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1190" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1190"><span class="anchor-text">[238]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1195" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1195"><span class="anchor-text">[239]</span></a>.</p>
</section>
</section>
<section id="s0115">
<h2 id="st140" class="u-h4 u-margin-l-top u-margin-xs-bottom">5.<span> </span>Key barriers toward green ammonia:</h2>
<div>
<p id="p0640">Scaling up direct green ammonia synthesis needs a new infrastructure framework and policies to support and overcome their barriers. The most obvious barrier to green ammonia synthesis is the capital investment costs. Green ammonia is produced through the Haber process using green hydrogen and nitrogen. Therefore, the main contributor to the capital cost is the cost of the electrolyzer and the cost of building wind and solar farms. Furthermore, there are many barriers to the evolution of green ammonia, such as technical, environmental, social and economic barriers that need policies and regulations to support limitations. The main barriers affecting the growth of green ammonia and policy support for them is shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0045" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0045"><span class="anchor-text">Fig. 9</span></a>. Although there are many orientations toward green energy production, the percentage is still very small compared to conventional ways, mainly due to some barriers and challenges that must be solved for their industrial-scale applications.</p>
<figure class="figure text-xs" id="f0045"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr9.jpg" height="709" alt="" aria-describedby="cn0045"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr9_lrg.jpg" target="_blank" download="" title="Download high-res image (721KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (721KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr9.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0055"><span class="label">Fig. 9</span>.<span> </span>Different barriers affecting the growth of green ammonia and policy support for them. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)</p>
<span class="captions text-s"><span id="cn0045"></span></span></figure>
</div>
<section id="s0120">
<h3 id="st145" class="u-h4 u-margin-m-top u-margin-xs-bottom">5.1.<span> </span>Environmental barriers</h3>
<p id="p0645">The direct environmental effect of ammonia is related to its level in the environment. Ammonia has severe health issues for humans and other living creatures. Therefore, the exposure to ammonia, whether as a gas in the atmosphere, liquid, or fertilizer, must be within a definite limit. Another environmental impact of ammonia is related to its production method, usually associated with CO<sub>2</sub><span> </span>emissions from fossil fuels being used for hydrogen production, N<sub>2</sub><span> </span>separation from the air, and nitrogen reduction into ammonia NH<sub>3</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0490" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0490"><span class="anchor-text">[98]</span></a>. Furthermore, ammonia as a chemical has several environmental impacts that must be considered during handling and storage<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1200" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1200"><span class="anchor-text">[240]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1205" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1205"><span class="anchor-text">[241]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1210" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1210"><span class="anchor-text">[242]</span></a>. The environmental impacts of ammonia are seriously considered as there is rapid growth and a need for ammonia as an energy source that is competitive with fossil fuels. The different environmental impacts of ammonia are summarized as follows:</p>
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0650"><strong>Green House Gases (GHGs) contribution</strong>: Industrial ammonia production has increased to reach&gt;170,000 tons of produced ammonia, contributing as the second most produced chemical. However, most of the current ammonia production methods depend on conventional fuel-burning yielding ammonia, contributing to CO<sub>2</sub><span> </span>emissions at around 1.8 %<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1215" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1215"><span class="anchor-text">[243]</span></a>. For instance, in the case of using conventional fuel for NH<sub>3</sub><span> </span>production, the amount of CO<sub>2</sub><span> </span>produced is around 2.2 kg CO<sub>2</sub>/ kg NH<sub>3</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0490" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0490"><span class="anchor-text">[98]</span></a>. Therefore, CO<sub>2</sub><span> emissions plus the unreacted methane (source of hydrogen) will directly affect global warming by increasing the GHG. On the other hand, the main contribution of producing green ammonia from a direct and clean energy source could reduce the carbon footprint by around 90 %, contributing to about 1.7 % of the global carbon dioxide <a href="https://www.sciencedirect.com/topics/engineering/emission-footprint" title="Learn more about emissions footprint from ScienceDirect's AI-generated Topic Pages" class="topic-link">emissions footprint</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0225" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0225"><span class="anchor-text">[45]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1220" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1220"><span class="anchor-text">[244]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1225" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1225"><span class="anchor-text">[245]</span></a>.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">•</span>
<div>
<p id="p0655"><strong>Marine and ground life contribution (disturbance of ecological balance)</strong>: The release of ammonia into the atmosphere will react with moisture producing ammonium that fall back to the earth as rainfall. Such ammonium in the rainfall will be converted to nitrates by the soil's bacteria, causing an increase in the soil's osmotic concentration<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1230" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1230"><span class="anchor-text">[246]</span></a><span>. Another aspects of ammonia gas at the atmosphere is the formation of <a href="https://www.sciencedirect.com/topics/engineering/ammonium-sulfate" title="Learn more about ammonium sulphate from ScienceDirect's AI-generated Topic Pages" class="topic-link">ammonium sulphate</a> casued by the reaction of ammonia gas with sulfuric or nitric acid vapours at the atmosphere to form small particles known as aerosols </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1235" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1235"><span class="anchor-text">[247]</span></a><span>. This will cause an increase in the soil pH, soil acidification, and direct toxic damage to essential nutrients found in the soil. Moving to ammonia effect to the <a href="https://www.sciencedirect.com/topics/engineering/aquatic-ecosystem" title="Learn more about aquatic ecosystem from ScienceDirect's AI-generated Topic Pages" class="topic-link">aquatic ecosystem</a> if it is directly spilt to surface water or its vapor cloud is allowed to reach water (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0050" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0050"><span class="anchor-text">Fig. 10</span></a>). A concentration of only 0.02 ppm is enough to kill sensitive marine creatures<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1240" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1240"><span class="anchor-text">[248]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1245" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1245"><span class="anchor-text">[249]</span></a>. This can be mitigated during the production of green ammonia by following proper safety strategies, including fast detection, leak detection, emission capture and treatment.</p>
<figure class="figure text-xs" id="f0050"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr10.jpg" height="347" alt="" aria-describedby="cn0050"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr10_lrg.jpg" target="_blank" download="" title="Download high-res image (225KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (225KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr10.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0060"><span class="label">Fig. 10</span>.<span> </span>A schematic diagram for the impact of ammonia on surface water and marine life.</p>
<span class="captions text-s"><span id="cn0050"></span></span></figure>
</div>
</li>
<li class="react-xocs-list-item"><span class="list-label">•</span>
<div>
<p id="p0660"><strong>Human life contribution:</strong><span> </span>Ammonia is corrosive, and its impact on human health depends on the average weighted time and exposure dose (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0040" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0040"><span class="anchor-text">Table 8</span></a>). Ammonia can significantly impact human health and the environment because it forms a strong basic solution that irritates the skin, the respiratory system, and the eyes. A 5 ppm of ammonia is the threshold limit for the pungent order; this can act as a warning of NH<sub>3</sub><span> </span>presence in the environment. Below 50 ppm, there is no recorded effect on the human; however, severe noise and throat irritation are recorded at 134 ppm. Above 2000 ppm, the person might die within a minute owing to a lack of oxygen and severe skin blisters and burns<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1250" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1250"><span class="anchor-text">[250]</span></a>. The experimental findings by Franks et al.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1255" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1255"><span class="anchor-text">[251]</span></a><span> </span>shows that the broad use of dangerous toxic load for ammonia toxicity could be calculated from the following equation (Eq. 16):</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0040">
<p id="sp0140"><span class="label">Table 8</span>.<span> </span>Exposure effect on human beings<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1260" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1260"><span class="anchor-text">[252]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1265" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1265"><span class="anchor-text">[253]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1270" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1270"><span class="anchor-text">[254]</span></a>.</p>
<span class="captions text-s"><span id="cn0130"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">Exposure (ppm)</th>
<th scope="col" class="align-left">Body effect</th>
<th scope="col" class="align-left">Permissible Exposure</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">50 ppm</td>
<td class="align-left">No recorded effect</td>
<td class="align-left">No effect</td>
</tr>
<tr class="valign-top">
<td class="align-left">134 ppm</td>
<td class="align-left">Rhinitis symptoms</td>
<td class="align-left">8 h</td>
</tr>
<tr class="valign-top">
<td class="align-left">700 ppm</td>
<td class="align-left">Severe rhinitis symptoms and possible loss of sight</td>
<td class="align-left">1 h</td>
</tr>
<tr class="valign-top">
<td class="align-left">1,700 ppm</td>
<td class="align-left">Death if not treated urgently owing to severe lung damage</td>
<td class="align-left">Not permitted</td>
</tr>
<tr class="valign-top">
<td class="align-left">2,000 ppm</td>
<td class="align-left">Chemical burns</td>
<td class="align-left">Not permitted</td>
</tr>
<tr class="valign-top">
<td class="align-left">5,000 ppm</td>
<td class="align-left">Suffocation might die directly</td>
<td class="align-left">Not permitted</td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</li>
</ul>
<span class="display"><span id="e0125" class="formula"><span class="label">(16)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-56-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="22.911ex" height="2.779ex" viewBox="0 -945.9 9864.2 1196.3" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-63"></use></g></g></g><g is="true" transform="translate(513,362)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g><g is="true" transform="translate(967,0)"><g is="true"><use xlink:href="#MJMATHBI-74"></use></g></g><g is="true" transform="translate(1660,0)"><use xlink:href="#MJMAIN-3D"></use></g><g is="true" transform="translate(2716,0)"><g is="true"><g is="true"><use xlink:href="#MJMAIN-33"></use><use xlink:href="#MJMAIN-2E" x="500" y="0"></use><use xlink:href="#MJMAIN-37" x="779" y="0"></use><use xlink:href="#MJMAIN-36" x="1279" y="0"></use></g><g is="true" transform="translate(2002,0)"><use xlink:href="#MJMAIN-D7"></use></g><g is="true" transform="translate(3002,0)"><use xlink:href="#MJMAIN-31"></use><use xlink:href="#MJMAIN-30" x="500" y="0"></use></g></g><g is="true" transform="translate(4003,403)"><use transform="scale(0.707)" xlink:href="#MJMAIN-38"></use></g></g><g is="true" transform="translate(7174,0)"><g is="true"><g is="true"><g is="true"><use xlink:href="#MJMATHBI-70"></use></g></g><g is="true" transform="translate(601,0)"><g is="true"><use xlink:href="#MJMATHBI-70"></use></g></g><g is="true" transform="translate(1203,0)"><g is="true"><use xlink:href="#MJMATHBI-6D"></use></g></g></g><g is="true" transform="translate(2235,362)"><use transform="scale(0.707)" xlink:href="#MJMAIN-32"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mn is="true">2</mn></msup><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mo linebreak="goodbreak" is="true">=</mo><msup is="true"><mrow is="true"><mn is="true">3.76</mn><mo is="true">×</mo><mn is="true">10</mn></mrow><mn is="true">8</mn></msup><msup is="true"><mrow is="true"><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow><mrow is="true"><mi mathvariant="bold-italic" is="true">�</mi></mrow></mrow><mn is="true">2</mn></msup></mrow></math></span></span></span></span></span>
<p></p>
<p id="p0665">Where c is the concentration of ammonia in ppm and t is the exposure time.</p>
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0670">Land availability: the available land for new green ammonia production and storage is limited; therefore, expanding an existing plant is highly recommended. Hence, future studies should focus on developing and upgrading conventional ammonia production plants.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0675">Landscape and visual impact: This requires a technical study to assess the potential impact on the visual environment that ammonia projects can cause on the local community. It is about studying different locational installations, visual characterization, and the social life of the place. For example, a simple development was suggested based on the method of the landscape and visual impact of ammonia at the Yara Pilbara ammonia plant<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1275" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1275"><span class="anchor-text">[255]</span></a>.</p>
</li>
</ul>
<p></p>
</section>
<section id="s0125">
<h3 id="st150" class="u-h4 u-margin-m-top u-margin-xs-bottom">5.2.<span> </span>Technical barriers</h3>
<p id="p0680">Technical barriers are not only referred to the capacity, feasibility, infrastructure, and viability but also the lack of technical expertise and labour. For instance, a capacity barrier- producing green ammonia at a large scale would create an inability to handle and store the large capacity of ammonia which can cause severe problems to the ammonia infrastructure. The potential of renewable energy, wind and solar, to produce green ammonia is the major contribution to its green synthesis. This will raise another technical barrier because of the need to implement renewable energy projects for ammonia synthesis. Some other barriers, such as efficiency for direct green NH<sub>3</sub><span> </span>synthesis, availability, reliability, and maturity, are also worth mentioning. The technical criteria for green ammonia can be summarized as follows:</p>
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">o</span>
<p id="p0685"><strong>Efficiency:</strong><span> It is defined as the ratio of the input energy over the output energy. The current trends are moving toward producing green ammonia through renewable sources (solar, tidal, or wind) to power an electrolyzer and air separation unit. The process efficiency can reach up to 83 % by involving a hybrid system consisting of <a href="https://www.sciencedirect.com/topics/engineering/high-operating-temperature" title="Learn more about high temperature operating from ScienceDirect's AI-generated Topic Pages" class="topic-link">high temperature operating</a> system with heat integrations </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0235" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0235"><span class="anchor-text">[47]</span></a><span>. However, unconventional methods for direct ammonia (photosynthesis, <a href="https://www.sciencedirect.com/topics/engineering/electrochemical-method" title="Learn more about electrochemical methods from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrochemical methods</a>, low-temperature synthesis, and non-thermal plasmatic synthesis) are preferable. The main challenge facing these methods is their low efficiency. Fortunately, research and development are progressing toward increasing their efficiency up to 60 % using electrochemical methods </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1280" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1280"><span class="anchor-text">[256]</span></a>.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">o</span>
<p id="p0690"><strong>Availability:</strong><span> Green ammonia synthesis has existed from 1920s to the 1970s in Norway using a hydro-powered electrolysis plant. Nowadays, the switch to green synthesis is mainly concerned with the <a href="https://www.sciencedirect.com/topics/engineering/electrolyser" title="Learn more about electrolyser's from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrolyser's</a> production cost and capacity </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0745" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0745"><span class="anchor-text">[149]</span></a>. However, the direct unconventional methods for green ammonia synthesis are still not viable for industrial applications, which requires further research.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">o</span>
<p id="p0695"><strong>Decentralization</strong>; a locality of renewable energies where renewable energy differs from one country to another and even in the same country from one region to another. This puts the burden on the feasibility and economic studies where the accuracy of each study is mandatory to investigate each plant independently.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">o</span>
<p id="p0700"><strong>Capacity barriers:</strong><span> </span>Currently, the main barriers to green ammonia production are directly related to the production of green hydrogen because the available methods utilize hydrogen as an intermediate feedstock to produce green ammonia. Therefore, their capacity barriers would be concerned with electrolyzer capacity if power to ammonia synthesis was used.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">o</span>
<p id="p0705"><strong>Storage:</strong><span> </span>This is one of the main barriers. Commonly, ammonia is transferred and stored as a liquified compressed gas in either compressed gas at atmospheric temperature, refrigerated at atmospheric pressure, or intermediate pressure and temperature (semi-refrigerated state). Most importantly, the storage areas should be free from flammable materials and oxidiser sparks and must be well ventilated<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1285" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1285"><span class="anchor-text">[257]</span></a>. There are three methods for storing ammonia:</p>
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">1-</span>
<p id="p0710">Storing ammonia under high pressure (15–18 bars) at room temperature using spherical or<span> </span><a href="https://www.sciencedirect.com/topics/engineering/cylindrical-tank" title="Learn more about cylindrical vessels from ScienceDirect's AI-generated Topic Pages" class="topic-link">cylindrical vessels</a><span> </span>with a capacity up to 2000 tons.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">2-</span>
<p id="p0715">Storage of ammonia at low temperatures (– 33 °C) and a pressure around (1.1 to 1.2 bar) using insulated vertical cylindrical tanks with a capacity up to 50,000 tons.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">3-</span>
<p id="p0720">Intermediate pressure storage at 0 °C using insulated reduced-pressure spherical vessels with a capacity up to 2500 tons.</p>
</li>
</ul>
</li>
</ul>
<p></p>
<p id="p0725"><span>Compressed gas at atmospheric temperature and refrigerated at atmospheric pressure are the most common ways used to store ammonia. Initially, a high-pressure system (bullets and Horton spheres) was the dominant method to store ammonia, with a capacity reaching up to 2000 tons. However, low-pressure storage was later preferable to high-pressure for two reasons: 1- Capital requirements are lower per unit volume, and 2- Considerably safer than spherical ammonia storage under high pressure. Currently, the large industrial scale has shown a great interest in refrigerated ammonia storage at <a href="https://www.sciencedirect.com/topics/engineering/ambient-pressure" title="Learn more about ambient pressure from ScienceDirect's AI-generated Topic Pages" class="topic-link">ambient pressure</a> owing to the high-capacity storage </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1290" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1290"><span class="anchor-text">[258]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1295" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1295"><span class="anchor-text">[259]</span></a>.</p>
<p id="p0730"><span>For pressure storage, cylindrical tanks can upstand up to 25 bar pressure. Compared to spherical tanks, maximum design pressure should not exceed 16 bar to prevent a wall thickness above 30 mm. Pressure storage is very economical for low quantities of ammonia needed in down streams unit processing ammonia and for services that require loading and unloading pressurized ammonia using <a href="https://www.sciencedirect.com/topics/engineering/tank-cars" title="Learn more about tank cars from ScienceDirect's AI-generated Topic Pages" class="topic-link">tank cars</a>, trucks, rail, and marine </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1300" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1300"><span class="anchor-text">[260]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1305" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1305"><span class="anchor-text">[261]</span></a>.</p>
<p id="p0735">Currently, refrigerated ammonia storage is preferred owing to its lower capital cost per unit volume compared to other methods and the higher volume capacity. Furthermore, this method is very convenient for loading and unloading refrigerated vehicles in ammonia synthesis plants. For refrigerated storage at –33 °C, many tanks configuration are available for a storage capacity up to 50,000 tons<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1310" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1310"><span class="anchor-text">[262]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1315" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1315"><span class="anchor-text">[263]</span></a>. The main types of atmospheric ammonia storage tanks are:</p>
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">1-</span>
<p id="p0740">Single-wall steel tanks with external insulation (made of rockwool or foam insulation) are sometimes surrounded by concrete bunds to prevent pollution.</p>
</li>
<li class="react-xocs-list-item"><span class="list-label">2-</span>
<div>
<p id="p0745"><span>Steel tanks with double walls and perlite insulation in between the walls (double wall tanks). This type of tank can also be found in two different configurations depending on the insulation type. The first one is with insulation on the <a href="https://www.sciencedirect.com/topics/engineering/annular-space" title="Learn more about annular space from ScienceDirect's AI-generated Topic Pages" class="topic-link">annular space</a> that needs a full shutdown in case of an inner tank frailer. The second type, which contains outer insulation, offers a longer operational time in case of inside tank failure. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0045" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0045"><span class="anchor-text">Table 9</span></a><span> </span>provides a summary of the different ammonia energy storage systems.</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0045">
<p id="sp0145"><span class="label">Table 9</span>.<span> </span>Summary of different storage techniques for ammonia<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1290" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1290"><span class="anchor-text">[258]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1295" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1295"><span class="anchor-text">[259]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1300" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1300"><span class="anchor-text">[260]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1305" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1305"><span class="anchor-text">[261]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1310" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1310"><span class="anchor-text">[262]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1315" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1315"><span class="anchor-text">[263]</span></a>.</p>
<span class="captions text-s"><span id="cn0135"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">Property</th>
<th scope="col" class="align-left">Comments</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left" colspan="2">Pressure Storage</td>
</tr>
<tr class="valign-top">
<td class="align-left">System suitability</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">1-</span>
<p id="p0055">Small amount of ammonia</p>
<p id="p0060">Entrance or exist from system pipelines.</p>
<p id="p0065">When it is used as an intermediate chemical stock</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">Typical Pressure storage</td>
<td class="align-left">16–18 bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">Storage capacity</td>
<td class="align-left">Up to 2000 tons</td>
</tr>
<tr class="valign-top">
<td class="align-left">Design temperature</td>
<td class="align-left">25 °C</td>
</tr>
<tr class="valign-top">
<td class="align-left" colspan="2">Refrigerated Storage</td>
</tr>
<tr class="valign-top">
<td class="align-left">System suitability</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">1-</span>
<p id="p0070">Large scale ammonia storage.</p>
<p id="p0075">Marine transportation of large amount of ammonia.</p>
<p id="p0080">In facilities that require ammonia to be cooled.</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">Typical Pressure storage</td>
<td class="align-left">1.1–1.3 bar</td>
</tr>
<tr class="valign-top">
<td class="align-left">Storage capacity</td>
<td class="align-left">Up to 50,000 tons</td>
</tr>
<tr class="valign-top">
<td class="align-left">Design temperature</td>
<td class="align-left">–33 °C</td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</li>
<li class="react-xocs-list-item"><span class="list-label">o</span>
<p id="p0750"><strong>Research</strong><span> </span>and<span> </span><strong>development</strong><span> Lack of comparative studies between green ammonia and conventional ones equipped with carbon capture and storage. Indirect research is also required, such as <a href="https://www.sciencedirect.com/topics/engineering/life-cycle-assessment" title="Learn more about life cycle assessments from ScienceDirect's AI-generated Topic Pages" class="topic-link">life cycle assessments</a> of resources used in renewable energies, such as <a href="https://www.sciencedirect.com/topics/engineering/terbium" title="Learn more about terbium from ScienceDirect's AI-generated Topic Pages" class="topic-link">terbium</a> and <a href="https://www.sciencedirect.com/topics/engineering/dysprosium" title="Learn more about dysprosium from ScienceDirect's AI-generated Topic Pages" class="topic-link">dysprosium</a> in wind generation, <a href="https://www.sciencedirect.com/topics/engineering/germanium" title="Learn more about germanium from ScienceDirect's AI-generated Topic Pages" class="topic-link">germanium</a>, tellurium, <a href="https://www.sciencedirect.com/topics/engineering/indium" title="Learn more about indium from ScienceDirect's AI-generated Topic Pages" class="topic-link">indium</a> and selenium in solar energy, etc. Intensive studies are needed before transitioning from the conventional Haber-Bosch process to modern electrochemical synthesis. The <a href="https://www.sciencedirect.com/topics/engineering/thermodynamic-potential" title="Learn more about thermodynamic potential from ScienceDirect's AI-generated Topic Pages" class="topic-link">thermodynamic potential</a> to activate nitrogen gas needs efficient catalysts that do not simultaneously accelerate hydrogen evolution </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0940" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0940"><span class="anchor-text">[188]</span></a>. There is a research gap in ammonia technology, such as the difficulty in separating from unreacted materials and, thus, low yield of ammonia at low pressure and searching for unconventional, highly selective and efficient catalysts.</p>
</li>
</ul>
<p></p>
</section>
<section id="s0130">
<h3 id="st155" class="u-h4 u-margin-m-top u-margin-xs-bottom">5.3.<span> </span>Economic Barriers:</h3>
<p id="p0755">Compared with other competing technologies, the economic barriers to green ammonia production are mainly concerned with its high capital and operational costs (CAPEX and OPEX). The capital cost includes the electrolysis for hydrogen production, air separation unit, renewable energy, purification units, Harber-Bosch ammonia facility, storage units, plant auxiliaries, and civil works. Operational cost includes the availability of water, power source, labor cost, maintenance, land leasing, etc. The following are the main points that are related to the economic barriers:</p>
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">o</span>
<p id="p0760"><strong>Investment cost:</strong><span> </span>This includes CAPEX cost, electricity, labor, maintenance, land lease or purchase. Guerra and his research group<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1320" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1320"><span class="anchor-text">[264]</span></a><span> </span>did a technical–economic analysis for green ammonia synthesis (123,400 t year<sup>−1</sup><span>) using an electrolyzer stack of 164.21 MW. The investment cost for an ammonia production plant was estimated to be 144,375,000 €, plus OPEX of more than a million per year. However, 7.2 year <a href="https://www.sciencedirect.com/topics/engineering/payback-period" title="Learn more about payback period from ScienceDirect's AI-generated Topic Pages" class="topic-link">payback period</a> was estimated with a net present value of 88,300,000 €.</span></p>
</li>
<li class="react-xocs-list-item"><span class="list-label">o</span>
<p id="p0765"><strong>Energy cost:</strong><span> </span>One of green ammonia's main challenges is the high cost of renewable sources (CAPEX of the renewable energy plant). This concern is seriously considered when considering the price of energy from conventional fuels. Sanchez and Martin<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1325" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1325"><span class="anchor-text">[265]</span></a><span> </span>developed a model for green ammonia synthesis from air and water. Their study estimated that the project cost of green ammonia could be lower to 1.36 € kg<sup>−1</sup>. However, the high CAPEX and OPEX of producing green ammonia are still higher, almost triple using conventional fuel; thus, using green ammonia in the energy sector is nearly-four times higher in price than conventional fuel<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1330" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1330"><span class="anchor-text">[266]</span></a><span>. Green ammonia production has to be trustable to receive funds from all over the world, not only limited to developing countries. Still, several countries consider the support of green ammonia projects is non-economical compared to those powered by fossil fuels. Luke and <a href="https://www.sciencedirect.com/topics/engineering/alcantara" title="Learn more about Alcantara from ScienceDirect's AI-generated Topic Pages" class="topic-link">Alcantara</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0125" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0125"><span class="anchor-text">[25]</span></a><span> </span>investigated the Levelized cost of electricity (LOCE) for green ammonia synthesis using electrolyzer power by renewable energy (wind and solar) in 534 locations in over 70 countries. They expected a lower LOCE to be achieved by 2030 up to 310 $ t<sup>−1</sup><span> </span>with a price of 16.6 $ GJ<sup>−1</sup><span> </span>compared to a current price of 25.4 $ GJ<sup>−1</sup>. This study shows that green ammonia might be comparable to conventional fuels, i.e., Kerosene (8.7 – 18.3 $ GJ<sup>−1</sup>). Public and private finance can significantly promote investment in green ammonia]<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0935" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0935"><span class="anchor-text">[187]</span></a>.</p>
</li>
</ul>
<p></p>
</section>
<section id="s0135">
<h3 id="st160" class="u-h4 u-margin-m-top u-margin-xs-bottom">5.4.<span> </span>Policies and regulations</h3>
<p id="p0770">Green ammonia is still at its earliest stages of satisfying the global need for ammonia and its application in the energy sector. Some of these barriers are economic, financial, technical, and social. Therefore, it needs policy support to help in removing/decreasing these barriers and thus transfer green ammonia into a viable production method.</p>
<p id="p0775"><span>The main barriers to green ammonia synthesis are the high investment cost and energy requirements. According to the International Renewable Energy Agency, by 2050, the demand for green hydrogen will significantly increase to (134 to 159 million tons) which will require 1,775 GW of <a href="https://www.sciencedirect.com/topics/engineering/offshore-wind-farms" title="Learn more about offshore wind farms from ScienceDirect's AI-generated Topic Pages" class="topic-link">offshore wind farms</a>, 2,243 GW of <a href="https://www.sciencedirect.com/topics/engineering/onshore-wind" title="Learn more about onshore wind from ScienceDirect's AI-generated Topic Pages" class="topic-link">onshore wind</a>, 4,240 GW of solar PV to satisfy this amount of green hydrogen production </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1335" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1335"><span class="anchor-text">[267]</span></a>. This is also true for green ammonia production because the main feedstock for its synthesis is hydrogen, and NH<sub>3</sub><span> </span>is considered a feasible way to store and transport green hydrogen. The high electrolyzers' CAPEX and renewable energy costs can be overcome by establishing a proper supporting policy. For example, tackling electrolysers' high costs can support research, economic scale, and innovation. The most important policy is closing the significant cost gaps between brown and green ammonia production. There are also many technical barriers affecting the infrastructure of green ammonia. One of the most significant barriers is direct ammonia synthesis without the need for the intermediate step for hydrogen production. Direct green ammonia production from water and air would be a significant step toward minimizing the production cost of ammonia. Another important policy is supporting green ammonia production in countries with plenty of renewable energy sources.</p>
<p id="p0780">Ammonia is essential in energy as a zero-carbon fuel source, hydrogen carrier, and potential fuel in marine transport. According to the International Renewable Energy Agency, the insertion of green ammonia in the energy sector will significantly impact the global temperature rise by 1.5 °C and contribute toward a zero-carbon emission energy policy<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1340" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1340"><span class="anchor-text">[268]</span></a><span>. Like other sectors, cost plays the most obstacles to the development of the green ammonia sector. For instance, there is a gap between conventional and <a href="https://www.sciencedirect.com/topics/engineering/renewable-fuel" title="Learn more about renewable fuels from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable fuels</a> in terms of energy content and price. Unfortunately, green ammonia is almost four times higher than that grey ammonia (produced from natural gas). Therefore, there should be policies that consider the cost of the reserved CO</span><sub>2</sub><span> </span>emissions in the case of using green ammonia. Furthermore, safe policy attention should be taken to satisfy the obstacles of shipping and storing green ammonia.</p>
</section>
</section>
<section id="ce.section_axn_nkh_zvb">
<h2 id="ce.section-title_fkr_nkh_zvb" class="u-h4 u-margin-l-top u-margin-xs-bottom">6.<span> </span>Contribution of green ammonia to sustainable development goals, SDGs</h2>
<div>
<p id="p0790">In 2015, The United Nations reported 17 SDGs to be targeted by 2030 (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0055" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0055"><span class="anchor-text">Fig. 11</span></a>). These goals are interconnected to ensure a safe and healthy life for everybody. The SDGs aim to end all forms of hunger and poverty everywhere and protect the ecosystems and conserve natural resources for future generations. In this context, The UN's strategy is to protect life on land and even below the water, produce green renewable energy, mitigate climate change and finally consolidate the relationship between the above SDGs<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1345" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1345"><span class="anchor-text">[269]</span></a>. The SGDs can be classified into three main categories; group 1 (SDG1-SDG6): SDGs focus on humans; group 2 (SDG7-SDG12): SDGs related to community and group 3 (SDG13-SDG17): SDGs related to the whole planet.</p>
<figure class="figure text-xs" id="f0055"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr11.jpg" height="303" alt="" aria-describedby="cn0055"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr11_lrg.jpg" target="_blank" download="" title="Download high-res image (373KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (373KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr11.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0065"><span class="label">Fig. 11</span>.<span> </span>The sustainable development goals (SDGs),<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://sdgs.un.org/goals" target="_blank" rel="noreferrer noopener"><span class="anchor-text"><u>https://sdgs.un.org/goals</u></span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a>.</p>
<span class="captions text-s"><span id="cn0055"></span></span></figure>
</div>
<p id="p0795">Green ammonia is directly related to some of these goals, namely; SDG2 “zero hunger”, SDG3 “good health and well-being”, SDG6 “clean water and sanitation”, SDG7 “affordable and clean energy”, SDG8 “decent work and economic growth”, SDG9 “industry and infrastructure”, SDG12 “responsible consumption/production” and SDG13 “climate action”. The following sections discuss the contribution of green ammonia to these SDGs.</p>
<section id="s0140">
<h3 id="st165" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.1.<span> </span>Impact of green ammonia on SDG2; zero hunger</h3>
<div>
<p id="p0800">All crops utilize nitrogen, with a special focus on wheat, maize and rice, where they account for higher than 50 % of the total demand for nitrogen-based fertilizer Globally (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0060" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0060"><span class="anchor-text">Fig. 12</span></a>). Maize and rice have the widest application rates for the nitrogen-based fertilizer range, with an average of 98 and 96 kg N/ha, respectively. Some crops can directly fix nitrogen from the atmosphere, such as soybeans, peanuts, palm and clover, leading to less or zero fertilizer requirements<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1350" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1350"><span class="anchor-text">[270]</span></a>.</p>
<figure class="figure text-xs" id="f0060"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr12.jpg" height="227" alt="" aria-describedby="cn0060"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr12_lrg.jpg" target="_blank" download="" title="Download high-res image (132KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (132KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr12.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0070"><span class="label">Fig. 12</span>.<span> </span>Nitrogen-based fertilizer demand and application rate of the main crop, , .</p>
<span class="captions text-s"><span id="cn0060"></span><span>adapted from <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1350" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1350"><span class="anchor-text">[270]</span></a><a class="anchor u-display-inline anchor-paragraph" href="https://iea.blob.core.windows.net/assets/6ee41bb9-8e81-4b64-8701-2acc064ff6e4/AmmoniaTechnologyRoadmap.pdf" target="_blank" rel="noreferrer noopener"><span class="anchor-text">https://iea.blob.core.windows.net/assets/6ee41bb9-8e81-4b64-8701-2acc064ff6e4/AmmoniaTechnologyRoadmap.pdf</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a></span></span></figure>
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<div>
<p id="p0805"><span>Feeding ∼80 % of the population worldwide depends mainly on ammonia-based fertilizer (ABF). Recently, the focus has been to transform the production process from the Haber-Bosch process, which consumes intensive -capital cost and -energy and uses fossil <a href="https://www.sciencedirect.com/topics/engineering/feedstock" title="Learn more about feedstock from ScienceDirect's AI-generated Topic Pages" class="topic-link">feedstock</a> such as coal, to green ammonia technology, which depends on renewable energy such as hydropower, solar, and wind. Production of green ammonia yields social and economic benefits, such as producing fertilizers locally using the localized resources of renewable energy instead of importing fertilizers. Additionally, green ammonia served as a buffer to balance the seasonal variations of renewable energies, yielding consistent power needed for the development foundation. The possibility of combining renewable electricity with Haber-Bosch could occur via developing hydrogen from <a href="https://www.sciencedirect.com/topics/engineering/water-electrolysis" title="Learn more about water electrolysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">water electrolysis</a> and separating nitrogen from the air via pressure-based adsorption. Haber–Bosch process is the traditional route for ABF production at a large scale. Agricultural production is significantly dropped due to soil nutrient depletion (nitrogen, phosphorous, and potassium). For this reason, around 80 % of 160 million tons/y of ammonia is utilized in fertilizers production, contributing to feeding &gt; 70 % of the world's population, which nearly represents 50 % of the nitrogen in the human body. On the other hand, green ammonia plays a significant indirect role in nutrition. Animal production is directly proportional to grasses and plants, whose productivity is related to ABF. However, increasing grass production has lower environmental effects and higher efficiency than feed concentration; owning to that feed concentration needs considerably higher resources than pasture to yield and generate higher emissions. It was estimated that the farm had the lowest carbon footprint when sequestration was included </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1355" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1355"><span class="anchor-text">[271]</span></a>.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0065" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0065"><span class="anchor-text">Fig. 13</span></a><span> </span>concludes the main factors that control the impact of green ammonia on SDG2.</p>
<figure class="figure text-xs" id="f0065"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr13.jpg" height="193" alt="" aria-describedby="cn0065"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr13_lrg.jpg" target="_blank" download="" title="Download high-res image (114KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (114KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr13.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="sp0075"><span class="label">Fig. 13</span>.<span> </span>Inputs, outputs and the main factors for green ammonia contribution in SDG2. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)</p>
<span class="captions text-s"><span id="cn0065"></span></span></figure>
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</section>
<section id="s0145">
<h3 id="st170" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.2.<span> </span>Impact of green ammonia on SDG3; healthy life and well-being</h3>
<p id="p0810"><span>The impact of green ammonia on human health could be assessed by evaluating its acidification, human toxicity, eco-toxicity, carcinogens, <a href="https://www.sciencedirect.com/topics/engineering/ozone-depletion-potential" title="Learn more about ozone depletion potential from ScienceDirect's AI-generated Topic Pages" class="topic-link">ozone depletion potential</a>, and <a href="https://www.sciencedirect.com/topics/engineering/abiotic-depletion" title="Learn more about abiotic depletion from ScienceDirect's AI-generated Topic Pages" class="topic-link">abiotic depletion</a> impacts. Ammonia deposition yields eutrophication and acidification, and it is highly recommended to consider these values for accuracy purposes and subsequent <a href="https://www.sciencedirect.com/topics/engineering/mitigation-strategy" title="Learn more about mitigation strategies from ScienceDirect's AI-generated Topic Pages" class="topic-link">mitigation strategies</a>. For example, NH</span><sub>3</sub><span> </span>contributes to ∼ 95.5 in farm acidification. However, intensification increased NH<sub>3</sub><span> </span>emissions owing to the increase in fertilizer quantities. The eutrophication and NH<sub>3</sub><span> </span>emissions were reported as 86 %–94 % and 41 %–42 %, respectively<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1355" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1355"><span class="anchor-text">[271]</span></a><span>. Ammonia emissions which act for 13 % of agricultural emissions, increase the population's exposure to <a href="https://www.sciencedirect.com/topics/engineering/atmospheric-aerosol" title="Learn more about particulate matter from ScienceDirect's AI-generated Topic Pages" class="topic-link">particulate matter</a> by 0.36 μg /m</span><sup>3</sup> on average<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1360" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1360"><span class="anchor-text">[272]</span></a>. However, lowering air pollution yielded a reduction in the particulate matters-based avoidable deaths by 2,804–8,249 in the year 2010 and 9,870–23,100 in 2020, pollution control policies have numerous advantages that minimize PM -and O<sub>3</sub><span> </span>-based mortalities by about 23 % during the period from 2015 to 2030<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1365" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1365"><span class="anchor-text">[273]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1370" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1370"><span class="anchor-text">[274]</span></a><span>. It was reported that the <a href="https://www.sciencedirect.com/topics/engineering/global-warming-potential" title="Learn more about potential global warming from ScienceDirect's AI-generated Topic Pages" class="topic-link">potential global warming</a> yields from <a href="https://www.sciencedirect.com/topics/engineering/coal-gasification" title="Learn more about coal gasification from ScienceDirect's AI-generated Topic Pages" class="topic-link">coal gasification</a> and steam methane reformation are 3.85 and 3.03 kg CO</span><sub>2</sub>-eq/kg NH<sub>3</sub><span> produced, respectively. The minimum global warming (0.378 kg/kg ammonia) is recorded by <a href="https://www.sciencedirect.com/topics/engineering/biomass-gasification" title="Learn more about biomass gasification from ScienceDirect's AI-generated Topic Pages" class="topic-link">biomass gasification</a>, while steam methane reformation yields high abiotic depletion compared with other synthesis routes: 0.026 kg Sb-eq/kg NH</span><sub>3</sub><span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1375" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1375"><span class="anchor-text">[275]</span></a>. Replacing conventional ammonia with green ones will minimize these negative impacts since green technology is based on renewable energies.</p>
</section>
<section id="s0150">
<h3 id="st175" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.3.<span> </span>Impact of green ammonia on SDG6; clean water and sanitation</h3>
<p id="p0815"><span>The ammonia production could occur via a coal-based ammonia synthesis approach which involves <a href="https://www.sciencedirect.com/topics/engineering/coal-mining" title="Learn more about coal mining from ScienceDirect's AI-generated Topic Pages" class="topic-link">coal mining</a>, washing, transportation, and ammonia production. The system is similar to the first approach for the coke oven gas-based ammonia synthesis route, with an additional <a href="https://www.sciencedirect.com/topics/engineering/coking-coal" title="Learn more about coal coking from ScienceDirect's AI-generated Topic Pages" class="topic-link">coal coking</a> stage. The system includes natural gas exploitation and transportation and ammonia production for the natural gas-based ammonia synthesis approach. It is worth noting that, for all conventional approaches to ammonia synthesis, there is wastewater polluted with contaminants released into the ecosystem </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0905" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0905"><span class="anchor-text">[181]</span></a><span>. The <a href="https://www.sciencedirect.com/topics/engineering/eutrophication-potential" title="Learn more about eutrophication potential from ScienceDirect's AI-generated Topic Pages" class="topic-link">eutrophication potential</a> is calculated from electricity consumption, the coal-burning, which generates nitrogen oxide, and wastewater discharged from the <a href="https://www.sciencedirect.com/topics/engineering/coking-process" title="Learn more about coking process from ScienceDirect's AI-generated Topic Pages" class="topic-link">coking process</a> that involves numerous contaminants such as <a href="https://www.sciencedirect.com/topics/engineering/chemical-oxygen-demand" title="Learn more about chemical oxygen demand from ScienceDirect's AI-generated Topic Pages" class="topic-link">chemical oxygen demand</a>, phosphorus, and nitrogen. All of these constituents increased the eutrophication potential. The eutrophication potentials of natural gas-, coal- and coke oven gas-based ammonia are 0.0012, 0.0012</span> <span>and 0.0016 kg phosphate-eq. The <a href="https://www.sciencedirect.com/topics/engineering/photochemical-ozone-creation-potential" title="Learn more about photochemical ozone creation potentials from ScienceDirect's AI-generated Topic Pages" class="topic-link">photochemical ozone creation potentials</a> of natural gas-, coal- and coke oven gas-based ammonia are 0.599, 0.871 and</span> 1.10 g ethene-eq<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0905" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0905"><span class="anchor-text">[181]</span></a>. The emissions related to water pollution and acidification (kg SO<sub>2</sub>-eq) are increased as more nitrogen-based fertilizers are applied in the agricultural sector<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0910" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0910"><span class="anchor-text">[182]</span></a>. Hence, consuming much more conventional ammonia should be replaced by green one to mitigate the negative impact on the ecosystem with a special focus on agricultural wastewater.</p>
</section>
<section id="s0155">
<h3 id="st180" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.4.<span> </span>Impact of green ammonia on SDG7; green and affordable energy</h3>
<div>
<p id="p0820"><span>Green ammonia is the synthesis of ammonia using renewable energy, air and water. This zero-carbon energy storage vector has significant <a href="https://www.sciencedirect.com/topics/engineering/energy-application" title="Learn more about energy applications from ScienceDirect's AI-generated Topic Pages" class="topic-link">energy applications</a> owing to its availability in different geographies and low cost of transporting and storing compared to the requirements of <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-underground-storage" title="Learn more about underground hydrogen storage from ScienceDirect's AI-generated Topic Pages" class="topic-link">underground hydrogen storage</a> or geological storage of captured carbon, </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0070" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0070"><span class="anchor-text">Fig. 14</span></a><span>. Ammonia can be easily stored as a liquid via pressurizing at 9 bar ambient temperature or cooling to –33 °C; the process doesn’t involve significant losses. Ammonia can be easily and safely transported in carbon-steel pipelines, ships, rail cars, and trucks. Also, plants' conversion from natural gas and oil into green ammonia is easy since the latter is used in the same pipelines with minor modifications. Moreover, 50 % much more energy could be delivered in case of the replacement of natural gas with <a href="https://www.sciencedirect.com/topics/engineering/liquid-ammonia" title="Learn more about liquid ammonia from ScienceDirect's AI-generated Topic Pages" class="topic-link">liquid ammonia</a> owing to the higher <a href="https://www.sciencedirect.com/topics/engineering/volumetrics" title="Learn more about volumetric from ScienceDirect's AI-generated Topic Pages" class="topic-link">volumetric</a> <a href="https://www.sciencedirect.com/topics/engineering/flux-density" title="Learn more about energy density from ScienceDirect's AI-generated Topic Pages" class="topic-link">energy density</a> of ammonia </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1380" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1380"><span class="anchor-text">[276]</span></a>. The typical storage tank has a capacity of liquefied NH<sub>3</sub><span> </span>up to 30,000 Mt, equivalent to 190 GW (H<sub>2</sub><span> </span>reformation from NH<sub>3</sub>), corresponding to 0.1 US$/kWh capital cost<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1385" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1385"><span class="anchor-text">[277]</span></a>.</p>
<figure class="figure text-xs" id="f0070"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr14.jpg" height="293" alt="" aria-describedby="cn0070"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr14_lrg.jpg" target="_blank" download="" title="Download high-res image (175KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (175KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr14.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="sp0080"><span class="label">Fig. 14</span>.<span> </span>The main contributions of green ammonia in the energy sector. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)</p>
<span class="captions text-s"><span id="cn0070"></span></span></figure>
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<p id="p0825">The power2ammonia2power technology is based on multidisciplinary connections where the battolysers provide the grid with power. The grid can also provide the ammonia production plant with power when the battolysers are discharged or/and the wind is weak in order to maintain the system heated and pressurized. However, no backup system is required. The system is characterized by flexibility, where excess ammonia can be introduced from an external source<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1390" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1390"><span class="anchor-text">[278]</span></a>.</p>
<p id="p0830"><span>Green ammonia can be directly combusted in <a href="https://www.sciencedirect.com/topics/engineering/gas-turbine" title="Learn more about gas turbines from ScienceDirect's AI-generated Topic Pages" class="topic-link">gas turbines</a>, reciprocating engines, or electrochemically dissociated in fuel cells. Although there is a limitation in its implementation in current <a href="https://www.sciencedirect.com/topics/engineering/otto-cycle-engine" title="Learn more about Otto cycle engines from ScienceDirect's AI-generated Topic Pages" class="topic-link">Otto cycle engines</a> owing to its narrow flammability range, the NH</span><sub>3</sub>-based engine was designed and constructed for bus engines during the 2nd World War. To eliminate nitrous oxide formation during NH<sub>3</sub><span> combustion, <a href="https://www.sciencedirect.com/topics/engineering/catalytic-cracking" title="Learn more about catalytic cracking from ScienceDirect's AI-generated Topic Pages" class="topic-link">catalytic cracking</a> and sodium-amide processes are suggested for the NH</span><sub>3</sub><span> </span>decomposition into its elements. The developed hydrogen can be efficiently combusted in gas turbines or fuel cells<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1385" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1385"><span class="anchor-text">[277]</span></a>.</p>
</section>
<section id="s0160">
<h3 id="st185" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.5.<span> </span>Impact of green ammonia on SDG8; economic growth</h3>
<p id="p0835"><span>Transforming hydrogen into ammonia is essential to decrease the final cost of highly tumbling renewable electricity in an entirely green <a href="https://www.sciencedirect.com/topics/engineering/energy-systems" title="Learn more about energy system from ScienceDirect's AI-generated Topic Pages" class="topic-link">energy system</a> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1395" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1395"><span class="anchor-text">[279]</span></a>. By 2040, green ammonia will be an economic competitor fuel for zero-carbon electricity using efficient gas <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/turbines" target="_blank" rel="noreferrer noopener"><span class="anchor-text">turbine</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> power plants. The estimated <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/levelized-cost-of-electricity" target="_blank" rel="noreferrer noopener"><span class="anchor-text">Levelized cost of electricity</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> (LCOE) for green ammonia at a power plant capacity of 25 % is 156–185 €/MWh in 2040, assuming a fuel price of 355 €/t. This cost of electricity is considerably less than bio-energy and coal plants coupled with carbon capture and storage and nuclear power. Also, it is comparable with natural gas-based power plants with post-combustion carbon capture and storage. The additional costs of 28 €/MWh owning to cracking of ammonia to <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/hydrogen-fuel" target="_blank" rel="noreferrer noopener"><span class="anchor-text">hydrogen</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> in gas turbines recommends the development of turbine technologies which are compatible with ammonia in the long term.</p>
<p id="p0840"><span>It was estimated that the Levelized cost of green ammonia ranges from 208 €/t to 450 €/t in 2040 according to the capital cost, solar PV cost, and <a href="https://www.sciencedirect.com/topics/engineering/electrolyzer" title="Learn more about electrolyzer from ScienceDirect's AI-generated Topic Pages" class="topic-link">electrolyzer</a> costs. The local price of electricity is the main indicator of economic competitiveness for replacing traditional ammonia with green one. However, the economic impact of green ammonia could be clear by integrating its production plant with the national grid. This is attributed to the variation in prices of locally available or/and imported fuels. Also, some grids need varied capacity-utilization rates of dispatchable energy resources. Future research should focus on the considerations of these factors for the localized grid and regional scale as well as addressing other aspects such as a contradiction between electricity demand and cheap renewable supply such as in <a href="https://www.sciencedirect.com/topics/engineering/japan" title="Learn more about Japan from ScienceDirect's AI-generated Topic Pages" class="topic-link">Japan</a>, variation of seasonable <a href="https://www.sciencedirect.com/topics/engineering/renewable-energy-resource" title="Learn more about renewable resources from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable resources</a>, the price of alternative approaches such as the low cost of gas in the USA which promote</span> carbon capture and storage technologies, flexibility requirements, and legislative laws towards decarbonization.</p>
<p id="p0845">The economic impacts of developing green ammonia-based fertilizer with the aid of hydropower show that the process determines ∼216 M€, equivalent to ∼165 % investment return for a net present value of 30 years compared to imported fertilizers. For example, this yields a saving of at least 50 M US dollars for importing rice. Additionally, green ammonia can compensate for seasonal fluctuations of hydropower ranging from 900 to 50 MW and provide additional power up to 370 MW<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1400" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1400"><span class="anchor-text">[280]</span></a>. A techno-economic analysis showed that transforming from small-scale (10 kW) to large-scale (10 MW) reduces the minimum hydrogen selling prices from 7.03 USD/kg to 3.98 USD/kg. Moreover, sensitivity analyses showed that H<sub>2</sub><span> </span>selling prices might be minimized by 50 %. The H<sub>2</sub><span> </span>produced from green NH<sub>3</sub> reported significant CO<sub>2</sub> reduction by 78–95 % (kg CO<sub>2</sub>/kg H<sub>2</sub>) compared to <span>traditional methods such as <a href="https://www.sciencedirect.com/topics/engineering/methane-steam-reforming" title="Learn more about steam methane reforming from ScienceDirect's AI-generated Topic Pages" class="topic-link">steam methane reforming</a>, biomass gasification, etc. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1390" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1390"><span class="anchor-text">[278]</span></a>.</p>
</section>
<section id="s0165">
<h3 id="st190" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.6.<span> </span>Impact of green ammonia on SDG9; industry and infrastructure</h3>
<p id="p0850">Ammonia is the second largest product in the chemical industry sector worldwide after sulfuric acid. Also, it is the main precursor for synthetic fertilizers (urea, ammonium phosphate, and ammonium nitrate). Moreover, it is one of the raw materials for the production of numerous nitrogen-based chemicals (hydrazine (N<sub>2</sub>H<sub>4</sub>), urea (CO(NH<sub>2</sub>)<sub>2</sub>), ammonia carbonate ((NH<sub>4</sub>)<sub>2</sub>CO<sub>3</sub><span>), nitric acid, and <a href="https://www.sciencedirect.com/topics/engineering/ammonia-boranes" title="Learn more about ammonia borane from ScienceDirect's AI-generated Topic Pages" class="topic-link">ammonia borane</a> (NH</span><sub>3</sub>BH<sub>3</sub><span>)), and capturing agent for acidic gaseous. Also, it is used in refrigerators and air-conditioners, manufacturing of acids, explosives, fibers, papers, plastics, polymers, and <a href="https://www.sciencedirect.com/topics/engineering/alternative-fuel" title="Learn more about alternative fuel from ScienceDirect's AI-generated Topic Pages" class="topic-link">alternative fuel</a> in ICE and FCs for <a href="https://www.sciencedirect.com/topics/engineering/power-generation" title="Learn more about power generation from ScienceDirect's AI-generated Topic Pages" class="topic-link">power generation</a> with/or without reforming. Ammonia production increased from 137 Mtons in 2012 to 140 Mtons in 2018; China, Russia, USA and India recorded the highest ammonia production with 31.4 %, 10 %, 8.9 %, and 7.8 %, respectively. To achieve sustainability, <a href="https://www.sciencedirect.com/topics/engineering/green-hydrogen" title="Learn more about green hydrogen from ScienceDirect's AI-generated Topic Pages" class="topic-link">green hydrogen</a> derived from renewable energy should be promoted to minimize greenhouse gas emissions and fossil fuel consumption </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1405" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1405"><span class="anchor-text">[281]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1410" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1410"><span class="anchor-text">[282]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1415" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1415"><span class="anchor-text">[283]</span></a>. Green hydrogen could be supplied from renewable energy-based water electrolysis and biomass gasification<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0065" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0065"><span class="anchor-text">[13]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1420" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1420"><span class="anchor-text">[284]</span></a><span>. A biomass-based ammonia production plant was compared to a natural gas-based. The <a href="https://www.sciencedirect.com/topics/engineering/exergy-efficiency" title="Learn more about exergy efficiencies from ScienceDirect's AI-generated Topic Pages" class="topic-link">exergy efficiencies</a> of the biomass- and natural gas-based ammonia plants are 41.3 % and 65.8 %, respectively. Also, the elevated-temperature electrolysis achieved better integration with ammonia production facilities than low-temperature-based technologies owing to their high electrical efficiencies and heat integration. A techno-economic <a href="https://www.sciencedirect.com/topics/engineering/feasibility-study" title="Learn more about feasibility study from ScienceDirect's AI-generated Topic Pages" class="topic-link">feasibility study</a> of green ammonia production versus traditional one with a reference capacity 50 kton/y showed that biomass-to-ammonia is the most exothermic process with considerable limitations because of the immense heat required for acid gas scavenges. The power-to-ammonia recorded the maximum efficiency (74 %) compared to biomass-to-ammonia (44 %) and methane-to-ammonia (61 %). The production cost of one ton of ammonia using a biomass-based plant achieved 450 US $, equivalent to a payback higher than six years, while the cost of one ton of ammonia developed from a methane-based plant is 400 US $, with a payback of 5 years. The power-based plant wasn’t economically feasible because of high electricity and stack costs. However, the power-based ammonia production plant can be a competitor when the <a href="https://www.sciencedirect.com/topics/engineering/payback-time" title="Learn more about payback time from ScienceDirect's AI-generated Topic Pages" class="topic-link">payback time</a> is &lt; 5 years; production of solid oxide could occur at full scale and increment of renewable power penetration </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1425" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1425"><span class="anchor-text">[285]</span></a>.</p>
<p id="p0855">The recent interest in using green ammonia for decarbonization shipping is a clear indicator of the numerous advantages of green ammonia that can be implemented in full-scale power generation involving scalable production at an economical cost, enhanced energy density, and safe use in industrial environments and simple storage needs. By 2050, the forecast for green ammonia as a fuel in the marine sector is 99 %. Although green methanol is also considered a significant fuel for the shipping sector, green ammonia is considered the first one<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1430" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1430"><span class="anchor-text">[286]</span></a><span>. Production of hydrogen from ammonia is favorable since the reformation process requires low energy (46.22 kJ/mol), and strong catalysts could enhance the efficiency of cracking. Ammonia is also a flexible energy barrier that can be utilized as green fuel in <a href="https://www.sciencedirect.com/topics/engineering/direct-ammonia-fuel-cell" title="Learn more about direct ammonia fuel cells from ScienceDirect's AI-generated Topic Pages" class="topic-link">direct ammonia fuel cells</a> and solid oxide fuel cells. The advantages of these two fuel cells are their low cost, medium operating temperature, high efficiency, very robustness, and they can be fueled with various fuels </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1435" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1435"><span class="anchor-text">[287]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1440" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1440"><span class="anchor-text">[288]</span></a>.</p>
</section>
<section id="s0170">
<h3 id="st195" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.7.<span> </span>Impact of green ammonia on SDG11; sustainable cities and communities</h3>
<div>
<p id="p0860">Implementation of ammonia in power plants and transportation in cities has been environmentally assessed by studying its impacts on acidification, global warming potential, ozone layer depletion and abiotic depletion. The results have proved a reduction in the GHGs, showing eco-friendly performance because of the absence of carbon in such fuel. The environmental impacts of replacing conventional fuels (diesel, gasoline and natural gas) with ammonia were investigated in power generation plants and transportation via wind energy-based ammonia production plants. The<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/greenhouse-gas-emission" target="_blank" rel="noreferrer noopener"><span class="anchor-text">GHGs</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> from ammonia implemented in transportation are 0.1 kg CO<sub>2</sub>-eq/km, significantly less than diesel (0.230 kg) and gasoline (0.270 kg) driven vehicles. Moreover, ammonia implementation in power plants can substantially reduce the corresponding<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/global-warming-potential" target="_blank" rel="noreferrer noopener"><span class="anchor-text">b</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a>y 60 % compared to natural gas-based power plants<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1445" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1445"><span class="anchor-text">[289]</span></a>. Production of ammonia from wind-based <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/water-electrolysis" target="_blank" rel="noreferrer noopener"><span class="anchor-text">water electrolysis</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> using <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/molten-salt-electrolytes" target="_blank" rel="noreferrer noopener"><span class="anchor-text">molten salt electrolyte</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a><span> </span>in an electrochemical reactor has shown that clean and abundant wind energy can be applied in green ammonia production that significantly lower the environmental impacts. The ammonia-based car can suppress the GHGs to 0.1 kg/km compared to gasoline-based cars (0.27 kg/km). This yields a high lowering in the total GHG emissions in cities. The ammonia-based power plant generates about 83 g CO<sub>2</sub> eq.; in contrast, the natural gas-based power plant develops 130 g CO<sub>2</sub> eq. per MJ electricity production<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1445" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1445"><span class="anchor-text">[289]</span></a>. Such small amounts of the CO2 accompanied by ammonia can be significantly decreased or even eliminated by the use of green ammonia.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0075" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0075"><span class="anchor-text">Fig. 15</span></a><span> </span>shows the contribution of green ammonia in sustainable communities.</p>
<figure class="figure text-xs" id="f0075"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr15.jpg" height="191" alt="" aria-describedby="cn0075"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr15_lrg.jpg" target="_blank" download="" title="Download high-res image (113KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (113KB)</span></span></a></li>
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<p id="sp0085"><span class="label">Fig. 15</span>.<span> </span>contribution of green ammonia in green cities via transportation,<span> </span><a href="https://www.sciencedirect.com/topics/engineering/power-generation" title="Learn more about power generation from ScienceDirect's AI-generated Topic Pages" class="topic-link">power generation</a><span> </span>with zero or near-zero carbon emissions, agricultural, and industrial sectors. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)</p>
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</section>
<section id="s0175">
<h3 id="st200" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.8.<span> </span>Impact of green ammonia on SDG12; responsible consumption/production</h3>
<div>
<p id="p0865">During the last 50 years, ammonia synthesis technology has been dramatically developed. However, there are significant changes in the consumed amounts of natural resources such as coal, oil, and natural gas (as shown in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0080" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0080"><span class="anchor-text">Fig. 16</span></a>)<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1450" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1450"><span class="anchor-text">[290]</span></a>. Natural gas is consumed during conventional ammonia-fertilizer production, where it is consumed as energy supply and processing gas. It was estimated that producing one ton of NH<sub>3</sub><span> </span>consumes 35.2 GJ of natural gas<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1385" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1385"><span class="anchor-text">[277]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1455" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1455"><span class="anchor-text">[291]</span></a><span>. Therefore, natural gas consumption is increased per ton of agricultural products. Still, there is an urgent need for responsible consumption of natural resources and energy conservation. Replacing traditional ammonia with green ones will significantly save these resources since green ammonia production is based on <a href="https://www.sciencedirect.com/topics/engineering/renewable-energy-resources" title="Learn more about renewable energy resources from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable energy resources</a>. The lowest potential for abiotic depletion is recorded by ammonia-based cars (0.76 g Sb eq/km). In the life cycle of ammonia implemented in transportation, four materials are being depleted: hard coal, nylon, <a href="https://www.sciencedirect.com/topics/engineering/lignite" title="Learn more about lignite from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignite</a>, and natural gas by 41, 8, 7, and 6 %, respectively. The main source of abiotic depletion is ammonia-based production (44.7 %), which utilizes grid mix electricity. Around 29 % is developed during electricity production from the wind, with a particular focus on materials production </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1445" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1445"><span class="anchor-text">[289]</span></a>. The advantage of green ammonia as an energy vector is that the main feedstock, nitrogen, is locally abundant everywhere in the atmosphere, while methanol (the main competitor for ammonia) requires CO<sub>2</sub><span> </span>for its production process. However, CO<sub>2</sub><span> </span>can be supplied from different point sources if additional purification stages are applied to eliminate catalyst degradation<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1385" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1385"><span class="anchor-text">[277]</span></a>.</p>
<figure class="figure text-xs" id="f0080"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr16.jpg" height="435" alt="" aria-describedby="cn0080"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr16.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
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<p id="sp0090"><span class="label">Fig. 16</span>.<span> </span>The applications and the main natural resources consumed during the production of ammonia (a)<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1460" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1460"><span class="anchor-text">[292]</span></a><span>, and <a href="https://www.sciencedirect.com/topics/engineering/feedstock" title="Learn more about feedstock from ScienceDirect's AI-generated Topic Pages" class="topic-link">feedstock</a> sources of ammonia production worldwide as percentage (b) </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1380" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1380"><span class="anchor-text">[276]</span></a><span> </span>(with permission No. 5444930989758), and energy requirements in ammonia production in various region worldwide (c) adopted from<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1465" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1465"><span class="anchor-text">[293]</span></a>, open access.</p>
<span class="captions text-s"><span id="cn0080"></span></span></figure>
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</section>
<section id="s0180">
<h3 id="st205" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.9.<span> </span>Impact of green ammonia on SDG13; climate action</h3>
<p id="p0870">The major source of NH<sub>3</sub><span> </span>emissions is the agriculture sector, with a contribution ranging from 55 to 56 % of the emissions worldwide. The climate change impact of N<sub>2</sub>O emissions from artificial fertilizer spreading 10 %<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1355" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1355"><span class="anchor-text">[271]</span></a>. It was recorded that 94 % of NH<sub>3</sub><span> </span>emissions in Europe are developed from the agriculture sector only. Synthetic fertilizers are responsible for 10 % of these values. An annual assessment of ammonia emissions is carried out to monitor the reduction in NH<sub>3</sub><span> </span>emissions. Although there was a significant drop in these emissions by 23 % from 1990 to 2015, in Europe, more efforts are still needed. Not attributed only to the impact on humans and the ecosystems, these emissions also affect the generation of particulate matter, as mentioned above<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1470" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1470"><span class="anchor-text">[294]</span></a>.</p>
<div>
<p id="p0875">There is increasing motivation to address any change in the climate; however, nitrogen-based fertilizer is responsible for around 1 % of greenhouse gas emissions globally. Environmental legislation and investments are moving towards green technologies that support minimizing these harmful emissions. Lately, emissions from ammonia production plants (CO<sub>2</sub>, SO<sub>x</sub><span> </span>and NO<sub>x</sub>) recorded a significant reduction due to the optimization of the operating conditions, the feedstock mix, heat integration, energy conservation, enhanced CO<sub>2</sub><span> <a href="https://www.sciencedirect.com/topics/engineering/absorption-system" title="Learn more about absorption systems from ScienceDirect's AI-generated Topic Pages" class="topic-link">absorption systems</a>, and legislative laws </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1450" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1450"><span class="anchor-text">[290]</span></a>. Synthesis of ammonia using coke oven gas recorded the maximum GHG emissions (3.97 kg CO<sub>2</sub><span>-eq). This is attributed to the methane needing heat during the conversion process, which is supplied by burning fuel gas that is provided from the excess gas in <a href="https://www.sciencedirect.com/topics/engineering/pressure-swing-adsorption" title="Learn more about pressure swing adsorption from ScienceDirect's AI-generated Topic Pages" class="topic-link">pressure swing adsorption</a>; it contains specific amounts of CO</span><sub>2</sub>, CH<sub>4</sub>, etc. This gas is one of the most significant causes of high carbon emissions. The GHG emissions were 0.197–0.211 kg CO<sub>2</sub>-eq in the mining stage. However, the emissions during the transportation of natural gas in pipelines were 0.003 kg CO<sub>2</sub>-eq<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0905" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0905"><span class="anchor-text">[181]</span></a>, which is much less than that of coal railage (0.01687 kg CO<sub>2</sub>-eq). Another investigation reported a <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/global-warming-potential" target="_blank" rel="noreferrer noopener"><span class="anchor-text">global warming potential</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> for coal gasification and steam methane reformation of 3.85 and 3.03 and kg CO<sub>2</sub>-eq/kg ammonia developed<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1375" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1375"><span class="anchor-text">[275]</span></a><span>. The <a href="https://www.sciencedirect.com/topics/engineering/acidification-potential" title="Learn more about acidification potentials from ScienceDirect's AI-generated Topic Pages" class="topic-link">acidification potentials</a> of natural gas-, coal- and coke oven gas-based ammonia are 0.008, 0.0105 and 0.0138 kg SO</span><sub>2</sub>-eq<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0905" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0905"><span class="anchor-text">[181]</span></a>. The <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/acidification-potential" target="_blank" rel="noreferrer noopener"><span class="anchor-text">acidification potentials</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> of gasoline-, diesel-, and ammonia-based cars are 0.7, 0.44 and 0.9 g SO<sub>2</sub> eq/km, respectively<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1445" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1445"><span class="anchor-text">[289]</span></a>. Combustion of ammonia causes a low global warming potential (6 %). On the other hand, the combustion of natural gas causes 97 % of GHG in natural gas-based power plants, and CO<sub>2</sub><span> </span>act for 98.6 % of these emissions. Production of ammonia from wind-based <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/engineering/water-electrolysis" target="_blank" rel="noreferrer noopener"><span class="anchor-text">water electrolysis</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a> using <a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/molten-salt-electrolytes" target="_blank" rel="noreferrer noopener"><span class="anchor-text">molten salt electrolyte</span><svg focusable="false" viewBox="0 0 8 8" aria-label="Opens in new window" width="8px" height="8px" class="icon icon-arrow-up-right-tiny arrow-external-link"><path d="M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z"></path></svg></a><span> </span>in an electrochemical reactor has shown that clean and abundant wind energy can be applied in green ammonia production that significantly lower the environmental impacts. The ammonia-based car can suppress the <span>GHGs to 0.1 kg/km compared to gasoline-based cars (0.27 kg/km). This lowers total GHG emissions in cities. The <a href="https://www.sciencedirect.com/topics/engineering/combustion" title="Learn more about combustion process from ScienceDirect's AI-generated Topic Pages" class="topic-link">combustion process</a> is responsible for 97 % of the global warming potential in the natural gas power plant. It has been shown that replacing conventional fuels with green ammonia, the significant effect of power generation and city transportation, could be extremely mitigated </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1445" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1445"><span class="anchor-text">[289]</span></a><span>. The carbon footprint of a hybrid energy production system consists of wind energy and ammonia <a href="https://www.sciencedirect.com/topics/engineering/energy-storage-system" title="Learn more about energy storage system from ScienceDirect's AI-generated Topic Pages" class="topic-link">energy storage system</a> Power-to-Ammonia-to-Power (P2A2P) compared to coal-based, and gas-based energy production, which is represented in </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0085" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0085"><span class="anchor-text">Fig. 17</span></a>. The CO<sub>2</sub>-footprint of the P2A2P is 0.03 kg/kWh, which is considerably lower than current technologies. Even without carbon capture storage (CCS), the P2A2P system is an economic competitor with traditional alternatives, and it is the most cost-effective option when CCS is introduced<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1390" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1390"><span class="anchor-text">[278]</span></a>.</p>
<figure class="figure text-xs" id="f0085"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr17.jpg" height="429" alt="" aria-describedby="cn0085"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr17_lrg.jpg" target="_blank" download="" title="Download high-res image (700KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (700KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr17.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0095"><span class="label">Fig. 17</span>.<span> </span>(a) The first-in-the-world P2A2P proto-type at the UMN WCROC, Morris, MN<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1475" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1475"><span class="anchor-text">[295]</span></a><span>, open access, (b) A schematic flow diagram for P2A2P where PSA. <a href="https://www.sciencedirect.com/topics/engineering/pressure-swing-adsorption" title="Learn more about Pressure Swing Adsorption from ScienceDirect's AI-generated Topic Pages" class="topic-link">Pressure Swing Adsorption</a>, HB. Haber-Bosch and an inset shows the carbon footprint and the <a href="https://www.sciencedirect.com/topics/engineering/levelized-cost-of-electricity" title="Learn more about levelized cost of electricity from ScienceDirect's AI-generated Topic Pages" class="topic-link">levelized cost of electricity</a> (LCOE) of P2A2P compared to coal and gas-based power with/without Carbon Capture, and heavy fuel </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1390" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1390"><span class="anchor-text">[278]</span></a>, open access (c) Reduction in CO<sub>2</sub><span> </span>owning to the use of green ammonia instead of ammonia<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1475" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1475"><span class="anchor-text">[295]</span></a>, open access. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)</p>
<span class="captions text-s"><span id="cn0085"></span></span></figure>
</div>
<p id="p0880">CO<sub>2</sub><span> </span>emissions are generated at different points of ammonia production and utilization, where they are emitted during energy implementation during production, transportation and on-land machinery work. It was recorded that half of the total CO<sub>2</sub><span> </span>emissions are owned to nitrogen-based fertilizer. However, increasing the concentration of these fertilizers doesn’t guarantee equivalent productivity and yields higher CO<sub>2</sub><span> </span>emissions rates. For N<sub>2</sub>O emissions, the majority of these emissions (48 %), which are strongly dependent on productivity, are attributable to the generated nitric acid. The latter is part of ammonium nitrate generation and is attributed to the nitrification/denitrification process<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1455" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1455"><span class="anchor-text">[291]</span></a>. However, the over-implementation of ammonia will cause a burden on the air quality since the CO<sub>2</sub><span> </span>emissions are discharged during ammonia production, and its usage as fertilizers will generate CO<sub>2</sub><span> </span>and nitrous oxide emissions. Further contributions to climate change by N<sub>2</sub>O “nitrous oxide” emissions are the production of nitric acid. Air pollution is associated with NH<sub>3</sub>, NOx emitted from soils, and pollutants emitted from production facilities.<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1350" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1350"><span class="anchor-text">[270]</span></a><span> </span>The production of green ammonia will eventually result in a significant decrease or minimization of the GHG emissions mentioned above.</p>
</section>
<section id="s0185">
<h3 id="st210" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.10.<span> </span>Impact of green ammonia on SDG15: Life on land</h3>
<p id="p0885">The utilization of land for agricultural purposes is decreased as the implementation of green ammonia increases. Because implementing green ammonia as green fertilizer will result in a higher yield of agricultural products per unit area and thus lowers the land consumed per ton of agricultural products<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1480" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1480"><span class="anchor-text">[296]</span></a><span>. Moreover, green ammonia will conserve the main nutrients and minerals such as nitrogen, potash, phosphate, etc. The impact of green ammonia on land is not limited to the arable area but also via eutrophication. The effect of green ammonia on aquatic eutrophication is challenging to evaluate since the impact starts with the manufacturing stage and application and ends with discharging. There are interconnected factors, such as water bodies and land proximity structures. Conventional ammonia is also responsible for <a href="https://www.sciencedirect.com/topics/engineering/terrestrial-ecotoxicity" title="Learn more about terrestrial ecotoxicity from ScienceDirect's AI-generated Topic Pages" class="topic-link">terrestrial ecotoxicity</a>, which is expressed in kg 1,4-dichlorobenzene (1,4-DCB) equivalent, where increasing the fertilizer quantity increases the ecotoxicity </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b0910" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0910"><span class="anchor-text">[182]</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1485" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1485"><span class="anchor-text">[297]</span></a>.</p>
<div>
<p id="p0890"><span>The ammonia production utilizing <a href="https://www.sciencedirect.com/topics/engineering/municipal-solid-waste" title="Learn more about municipal solid waste from ScienceDirect's AI-generated Topic Pages" class="topic-link">municipal solid waste</a> recorded the minimum global warming potential (0.34 kg CO</span><sub>2</sub>-eq/kg NH<sub>3</sub>) compared to other routes, such as the nuclear-based route (0.84 kg CO<sub>2</sub>-eq/kg NH<sub>3</sub>) and biomass-based approach (0.85 kg CO<sub>2</sub>-eq/kg NH<sub>3</sub>). The municipal solid waste also reported the minimum impact (160 g 1,4-DB-eq/kg NH<sub>3</sub>) on human health and toxicity, while nuclear high-temperature electrolysis-based ammonia (NHTEA) reported the maximum effect (950 g 1,4-DB-eq/kg NH<sub>3</sub><span>) owing to the large amounts of nuclear waste and hazardous gases discharged from the <a href="https://www.sciencedirect.com/topics/engineering/nuclear-power-plant" title="Learn more about nuclear plant from ScienceDirect's AI-generated Topic Pages" class="topic-link">nuclear plant</a>. The abiotic depletion reached its maximum value in the NHTEA route, followed by hydropower electrolysis-based ammonia (HEA) as illustrated in </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#f0090" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0090"><span class="anchor-text">Fig. 18</span></a>. This is owing to the main energy resource in the first route, which is the uranium, resulting in large consumption of the limited uranium per unit mass of ammonia developed<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1380" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1380"><span class="anchor-text">[276]</span></a>. Moreover, the crops will supply the soil with nitrogen. Since fertilizer improves yields, more widespread utilization could decrease the land required to produce the same crops and thereby help decrease the need to transform natural ecosystems into agricultural production. Meanwhile, improving fertilizer use can reduce environmental impacts from air pollution<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1350" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1350"><span class="anchor-text">[270]</span></a>. The production of green ammonia will result in a significant decrease or depreciation of the GHG emissions.</p>
<figure class="figure text-xs" id="f0090"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr18.jpg" height="555" alt="" aria-describedby="cn0090"></span>
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<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr18_lrg.jpg" target="_blank" download="" title="Download high-res image (326KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (326KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-gr18.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0100"><span class="label">Fig. 18</span>.<span> </span><span>(a) Green ammonia production via biomass in comparison to conventional Haber-Bosch process, (b) the corresponding greenhouse emissions, toxicity and <a href="https://www.sciencedirect.com/topics/engineering/abiotic-depletion-potential" title="Learn more about abiotic depletion potentials from ScienceDirect's AI-generated Topic Pages" class="topic-link">abiotic depletion potentials</a> of MWEA “municipal solid waste based electrolysis”, BEA “biomass electrolysis-based ammonia”, HEA “hydropower electrolysis-based ammonia”, <a href="https://www.sciencedirect.com/topics/engineering/high-temperature-electrolysis" title="Learn more about NHTEA from ScienceDirect's AI-generated Topic Pages" class="topic-link">NHTEA</a> “nuclear high-temperature electrolysis-based ammonia” </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1380" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1380"><span class="anchor-text">[276]</span></a><span> </span>reporoduced with permission No. 5444940362568, and (c) percentages of CO<sub>2</sub><span> </span>emissions in different industrial sectors<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#b1350" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b1350"><span class="anchor-text">[270]</span></a>, open access. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)</p>
<span class="captions text-s"><span id="cn0090"></span></span></figure>
</div>
</section>
<section id="s0190">
<h3 id="st215" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.11.<span> </span>Impact of green ammonia on SDG17: Partnership for achieving the goals</h3>
<p id="p0895">Strengthening the global partnership for the sustainable development of green ammonia will occur via finance and technology development related to sustainable green ammonia production. The nations can improve sustainability via national legislative laws, technology transfer, and integrated investment.</p>
</section>
<section id="s0195">
<h3 id="st220" class="u-h4 u-margin-m-top u-margin-xs-bottom">6.12.<span> </span>Contribution of green ammonia in SDGs targets</h3>
<div>
<p id="p0900">As illustrated above. Green ammonia is strongly contributing to eight of the 17 SDGs.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0196890422013723#t0050" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0050"><span class="anchor-text">Table 10</span></a><span> </span>illustrates the impact of green ammonia on SDGs targets.</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0050">
<p id="sp0150"><span class="label">Table 10</span>.<span> </span>Direct contribution of green ammonia into the SDGs and the related targets.</p>
<span class="captions text-s"><span id="cn0140"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left">SDGs</th>
<th scope="col" class="align-left">SDGs targets</th>
<th scope="col" class="align-left">Contribution of Green Ammonia</th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left" rowspan="3">SDG2<span> </span>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx1.jpg" height="101" alt=""></figure>
</td>
<td class="align-left">2.3</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0085">Promote the agricultural productivity</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">2.4</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0090">Sustainability of food production</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">2.5</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0095">Ensuring plants are cultivated and seeds diversity</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">SDG3<span> </span>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx2.jpg" height="106" alt=""></figure>
</td>
<td class="align-left">3.9</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0100">Lowering deaths and illnesses yields from air/water/soil pollution with hazardous chemicals</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">SDG6<span> </span>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx3.jpg" height="107" alt=""></figure>
</td>
<td class="align-left">6.4<br><br>6.6</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0105">Enhancement of hydropower-use efficiency in the production of green ammonia</p>
<p id="p0110">Protection of water-related ecosystems via responsible consumption of renewable energy from hydropower</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="3">SDG7<br>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx4.jpg" height="104" alt=""></figure>
</td>
<td class="align-left">7.1</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0115">Contribution of wind power and hydropower in the development of the production process energy services</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">7.2</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0120">By 2030, increase the contribution of renewable energy sources in the green ammonia industry</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">7.3</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0125">Enhancement of renewable energy efficiencies</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="4">SDG8<br>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx5.jpg" height="106" alt=""></figure>
</td>
<td class="align-left">8.1</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0130">Sustain economic growth per capita with a special focus on incomes of small-scale food production</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">8.2</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0135">Achievement of higher economic productivity via upgrading of production technologies</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">8.3</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0140">Supporting decarbonization policies that support creativity, innovation, and entrepreneurship and promote the formalization as well as the growth of enterprises at different scales</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">8.4</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0145">Improvement of resources efficiencies in consumption and production</p>
<p id="p0150">Compensation for economic decline resulting from environmental degradation,</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="5">SDG9<span> </span>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx6.jpg" height="106" alt=""></figure>
</td>
<td class="align-left">9.1</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0155">Development of sustainable industrial infrastructure to support economic development with a special focus on food, energy industries</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">9.2</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0160">Ensuring sustainable industrialization</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">9.3</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0165">Increment in industrial projects in developing countries owning to the implementation of their local renewable energies</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">9.4</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0170">Upgrading industrial infrastructure via coupling with renewable energies facilities, with an increment of the efficiencies of renewable energies resource-use</p>
<p id="p0175">Adoption of green and eco-friendly technologies in industrial processes</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">9.5</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0180">Enhance of innovated public and private research</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">SDG11<span> </span>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx7.jpg" height="105" alt=""></figure>
</td>
<td class="align-left">11.6</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0185">Reduction of environmental impact on cities, including to air quality and management of municipal and other waste</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="7">SDG12<span> </span>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx8.jpg" height="107" alt=""></figure>
</td>
<td class="align-left">12.1</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0190">Sustainable consumption /production via a reduction in fossil fuel consumption</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">12.2</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0195">Sustainable management of renewable energies</p>
<p id="p0200">Efficient use of natural resources</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">12.3</td>
<td class="align-left">Compensate food losses via enhanced productivity</td>
</tr>
<tr class="valign-top">
<td class="align-left">12.4</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0205">Significantly lowering the release of fossil fuel emissions into the air, subsequently minimising their negative impacts on the environment and human</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">12.5</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0210">Minimize waste generation via prevention or/and reduction of using fossil fuel</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">12.6</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0215">Promote companies to adopt new practices</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">12.7</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0220">Encourage public procurement practices that support policies</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="2">SDG13<span> </span>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx9.jpg" height="107" alt=""></figure>
</td>
<td class="align-left">13.1</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0225">Lowering GHGs -related hazards</p>
<p id="p0230">Improved air quality</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">13.2</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0235">Promote climate change-based national policies</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="3">SDG15<br>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx10.jpg" height="107" alt=""></figure>
</td>
<td class="align-left">15.5<br><br></td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0240">Minimizing the decline of natural habitats, promoting biodiversity</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left"></td>
<td class="align-left"></td>
</tr>
<tr class="valign-top">
<td class="align-left">15.9</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0245">Developing and establishing local and national planning through the introduction of biodiversity and ecosystem principled</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="12">SDG17<br>
<figure class="inline-figure"><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0196890422013723-fx11.jpg" height="117" alt=""></figure>
</td>
<td class="align-left">17.1</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0250">Supporting local resources mobilization</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.2</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0255">Technology transfer from developed countries to developing one</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.3</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0260">Widen the financial resources for developing countries</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.4</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0265">Production of green ammonia with the aid of integrated policies will reduce debt distress</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.5</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0270">Accelerate investment regimes for developed countries</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.6</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0275">Enhancement of international cooperation to share science and technology through a global science, and innovative technology facilitation mechanism</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.7</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0280">Green ammonia production will promote the dissemination, transfer, and development of eco-friendly technologies with a special focus on low-income countries.</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.11</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0285">Significantly increase the exports of developing countries, with a special focus on those own renewable energies such as wind and solar energies.</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.13</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0290">Supporting the macroeconomic stability worldwide.</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.14</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0295">Strengthen the policies for sustainable development</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.16</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0300">Transferring from conventional ammonia to green ammonia production will strengthen the global partnership for sustainable development through sharing the financial resources, expertise, knowledge, and technology</p>
</li>
</ul>
</td>
</tr>
<tr class="valign-top">
<td class="align-left">17.17</td>
<td class="align-left">
<ul class="list">
<li class="react-xocs-list-item"><span class="list-label">•</span>
<p id="p0305">Encourage effective public and public/private partnerships based on experience and resource exchanges.</p>
</li>
</ul>
</td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
</section>
</section>
<section id="s0200">
<h2 id="st225" class="u-h4 u-margin-l-top u-margin-xs-bottom">7.<span> </span>Conclusions</h2>
<p id="p0905"><span>Currently, large-scale green ammonia production through water electrolysis using the Haber process is commonly used. However, direct ammonia synthesis under mild conditions reveals many challenges, mainly due to their low <a href="https://www.sciencedirect.com/topics/engineering/faradic-efficiency" title="Learn more about faradic efficiency from ScienceDirect's AI-generated Topic Pages" class="topic-link">faradic efficiency</a> and the hydrogen evolution reaction (HER) competition. This review summarises the emerging methods for direct ammonia synthesis. The assessment of the different methods revealed that all the synthesis routes still have considerable challenges, such as low efficiencies, high cost, and negative environmental impacts. The direct processes for ammonia production show promising results, and further research and development will accelerate green ammonia synthesis to achieve sustainable development. Investment, legislative laws and international/national policies also play significant roles. Furthermore, 17 sustainable development goals (SDG) for green ammonia to achieve a better and more sustainable future for all are also covered. Green ammonia strongly contributes to eight SDGs (SDG2, SDG3, SDG6, SDG7, SDG8, SDG9, SDG12 and SDG13) of the main seventeen goals. Its significant contribution arises from zero-carbon emissions during its production or consumption. The progress in green ammonia is important for achieving SDG2 “Zero hunger” as nitrogen accounts for 50 % of the total demand for nitrogen-based fertilizer. Regarding SDG3 “healthy life and well-being” green ammonia will significantly safe the environment and thus protect the health from the 3.85, and 3.03 kg CO</span><sub>2</sub>-eq/kg NH<sub>3</sub><span> produced from the current <a href="https://www.sciencedirect.com/topics/engineering/steam-reforming" title="Learn more about steam reforming from ScienceDirect's AI-generated Topic Pages" class="topic-link">steam reforming</a> and <a href="https://www.sciencedirect.com/topics/engineering/coal-gasification" title="Learn more about coal gasification from ScienceDirect's AI-generated Topic Pages" class="topic-link">coal gasification</a> as well as achieving SDG13 “Climate action”. Ammonia can be easily stored as a liquid via pressurizing at 9 bar ambient temperature or cooling to −33°; therefore, green ammonia is considered the best green energy source in the near future, i.e., achieving SDG7 “green and affordable energy”. By</span> 2050, the forecast for green ammonia as a fuel in the marine sector is 99 %, which indicates the strong contribution of green ammonia in achieving SDG9 “Industry and Infrastructure”. Moreover, the progress in green ammonia production will save 35.2 GJ of natural gas currently used in ammonia production, thus achieving SDG12 “Responsible consumption/production”.</p>
</section>]]> </content:encoded>
</item>

<item>
<title>Managing nitrogen for sustainable development</title>
<link>https://sdgtalks.ai/managing-nitrogen-for-sustainable-development</link>
<guid>https://sdgtalks.ai/managing-nitrogen-for-sustainable-development</guid>
<description><![CDATA[ Improvements in nitrogen use efficiency in crop production are critical for addressing the triple challenges of food security, environmental degradation and climate change. Such improvements are conditional not only on technological innovation, but also on socio-economic factors that are at present poorly understood. Here we examine historical patterns of agricultural nitrogen-use efficiency and find a broad range of national approaches to agricultural development and related pollution. We analyse examples of nitrogen use and propose targets, by geographic region and crop type, to meet the 2050 global food demand projected by the Food and Agriculture Organization while also meeting the Sustainable Development Goals pertaining to agriculture recently adopted by the United Nations General Assembly. Furthermore, we discuss socio-economic policies and technological innovations that may help achieve them. ]]></description>
<enclosure url="https://www.genevaenvironmentnetwork.org/wp-content/uploads/2022/12/Nitrogen-cycle.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 23 Jan 2024 18:17:00 -0500</pubDate>
<dc:creator>njvahlberg</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<div class="main-content">
<section data-title="Main" data-gtm-vis-first-on-screen50443292_563="3783" data-gtm-vis-total-visible-time50443292_563="9100">
<div class="c-article-section" id="Sec1-section">
<h2 class="c-article-section__title js-section-title js-c-reading-companion-sections-item" id="Sec1">Main</h2>
<div class="c-article-section__content" id="Sec1-content">
<p>More than half the world’s people are nourished by crops grown with synthetic nitrogen (N) fertilizers, which were made possible in the early twentieth century by the invention of the Haber–Bosch process, which reduces atmospheric nitrogen gas (N<sub>2</sub>) to reactive forms of N (ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 1" title="Erisman, J. W., Sutton, M. A., Galloway, J., Klimont, Z. &amp; Winiwarter, W. How a century of ammonia synthesis changed the world. Nature Geosci. 1, 636–639 (2008)" href="https://www.nature.com/articles/nature15743#ref-CR1" id="ref-link-section-d27879965e599">1</a>). A reliable supply of N and other nutrients essential for plant growth has allowed farmers to increase crop production per unit land greatly over the past century, thus promoting economic development, allowing larger populations, and sparing forests that would probably otherwise have been converted to agriculture to meet food demand<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 2" title="Foley, J. A. et al. Solutions for a cultivated planet. Nature 478, 337–342 (2011)" href="https://www.nature.com/articles/nature15743#ref-CR2" id="ref-link-section-d27879965e603">2</a></sup>. Despite this progress, nearly one billion people remain undernourished<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 3" title="Alexandratos, N. &amp; Bruinsma, J. World Agriculture towards 2030/2050: the 2012 Revision. Agricultural Development Economics Division of the Economic and Social Development Department Working Paper No. 12-03, 
                  http://www.fao.org/docrep/016/ap106e/ap106e.pdf
                  
                 (Food and Agriculture Organization of the United Nations, 2012)" href="https://www.nature.com/articles/nature15743#ref-CR3" id="ref-link-section-d27879965e607">3</a></sup>. In addition, the global population will increase by two to three billion by 2050, implying that demands for N fertilizers and agricultural land are likely to grow substantially<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 2" title="Foley, J. A. et al. Solutions for a cultivated planet. Nature 478, 337–342 (2011)" href="https://www.nature.com/articles/nature15743#ref-CR2" id="ref-link-section-d27879965e611">2</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 4" title="Mueller, N. D. et al. Closing yield gaps through nutrient and water management. Nature 490, 254–257 (2012)" href="https://www.nature.com/articles/nature15743#ref-CR4" id="ref-link-section-d27879965e614">4</a></sup>. Although there are many causes of undernourishment and poverty, careful N management will be needed to nourish a growing population while minimizing adverse environmental and health impacts.</p>
<p>Unfortunately, unintended adverse environmental and human health impacts result from the escape of reactive N from agricultural soils, including groundwater contamination, eutrophication of freshwater and estuarine ecosystems, tropospheric pollution related to emissions of nitrogen oxides and ammonia gas, and accumulation of nitrous oxide, a potent greenhouse gas that depletes stratospheric ozone<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 5" title="Steffen, W. et al. Planetary boundaries: guiding human development on a changing planet. Science 347, 6223 (2015). This paper provides the most recent updates on the research under the planetary boundaries framework." href="https://www.nature.com/articles/nature15743#ref-CR5" id="ref-link-section-d27879965e621">5</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 6" title="Galloway, J. N. et al. The nitrogen cascade. Bioscience 53, 341–356 (2003). This is a classic paper on the many interacting environmental impacts of reactive forms of N as they move through the biosphere." href="https://www.nature.com/articles/nature15743#ref-CR6" id="ref-link-section-d27879965e624">6</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 7" title="Galloway, J. N. et al. Transformation of the nitrogen cycle: recent trends, questions, and potential solutions. Science 320, 889–892 (2008)" href="https://www.nature.com/articles/nature15743#ref-CR7" id="ref-link-section-d27879965e627">7</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 8" title="Reay, D. S. et al. Global agriculture and nitrous oxide emissions. Nature Clim. Change 2, 410–416 (2012)" href="https://www.nature.com/articles/nature15743#ref-CR8" id="ref-link-section-d27879965e630">8</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 9" title="Griffis, T. J. et al. Reconciling the differences between top-down and bottom-up estimates of nitrous oxide emissions for the U.S. corn belt. Glob. Biogeochem. Cycles 27, 746–754 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR9" id="ref-link-section-d27879965e633">9</a></sup><span> </span>(<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig1">Fig. 1</a>). Some of these environmental consequences, such as climate change and tropospheric ozone pollution, can also negatively affect crop yields<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 10" title="Avnery, S., Mauzerall, D. L., Liu, J. &amp; Horowitz, L. W. Global crop yield reductions due to surface ozone exposure: 1. Year 2000 crop production losses and economic damage. Atmos. Environ. 45, 2284–2296 (2011)" href="https://www.nature.com/articles/nature15743#ref-CR10" id="ref-link-section-d27879965e640">10</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 11" title="Robertson, G. P. et al. Nitrogen–climate interactions in US agriculture. Biogeochemistry 114, 41–70 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR11" id="ref-link-section-d27879965e643">11</a></sup><span> </span>and human health<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 12" title="Jerrett, M. et al. Long-term ozone exposure and mortality. N. Engl. J. Med. 360, 1085–1095 (2009)" href="https://www.nature.com/articles/nature15743#ref-CR12" id="ref-link-section-d27879965e647">12</a></sup>. Hence, too little N means lower crop productivity, poor human nutrition and soil degradation<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 13" title="Sanchez, P. A. &amp; Swaminathan, M. Hunger in Africa: the link between unhealthy people and unhealthy soils. Lancet 365, 442–444 (2005)" href="https://www.nature.com/articles/nature15743#ref-CR13" id="ref-link-section-d27879965e651">13</a></sup>, but too much N leads to environmental pollution and its concomitant threats to agricultural productivity, food security, ecosystem health, human health and economic prosperity.</p>
<div class="c-article-section__figure js-c-reading-companion-figures-item" data-test="figure" data-container-section="figure" id="figure-1" data-title="An illustration of the N budget in crop production and resulting N species released to the environment.">
<figure>
<figcaption><b id="Fig1" class="c-article-section__figure-caption" data-test="figure-caption-text">Figure 1: An illustration of the N budget in crop production and resulting N species released to the environment.</b></figcaption>
<div class="c-article-section__figure-content">
<div class="c-article-section__figure-item"><a class="c-article-section__figure-link" data-test="img-link" data-track="click" data-track-label="image" data-track-action="view figure" href="https://www.nature.com/articles/nature15743/figures/1" rel="nofollow"><picture><source type="image/webp" srcset="//media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig1_HTML.jpg?as=webp"><img aria-describedby="Fig1" src="https://media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig1_HTML.jpg" alt="figure 1" loading="lazy" width="685" height="785"></picture></a></div>
<div class="c-article-section__figure-description" data-test="bottom-caption" id="figure-1-desc">
<p>Inputs to agriculture are shown as blue arrows and harvest output as a green arrow. NUE is defined as the ratio of outputs (green) to inputs (blue) (i.e. NUE =<span> </span><i>N</i><sub>yield</sub>/<i>N</i><sub>input</sub>). The difference between inputs and outputs is defined as<span> </span><i>N</i><sub>sur</sub>, which is shown here as orange arrows for N losses to the environment and as N recycling within the soil (grey box) (that is,<span> </span><i>N</i><sub>sur</sub><span> </span>=<span> </span><i>N</i><sub>input</sub> − <i>N</i><sub>yield</sub>). Abbreviations: ammonia (NH<sub>3</sub>), nitrogen oxides (NO<sub><i>x</i></sub>), nitrous oxide (N<sub>2</sub>O), dinitrogen gas (N<sub>2</sub>), ammonium (NH<sub>4</sub><sup>+</sup>), nitrate (NO<sub>3</sub><sup>−</sup>), dissolved organic nitrogen (DON) and particulate organic nitrogen (PON).</p>
<p><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM41">PowerPoint slide</a></p>
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<p>Improving nitrogen-use efficiency (NUE)—that is, the fraction of N input harvested as product—is one of the most effective means of increasing crop productivity while decreasing environmental degradation<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 14" title="Cassman, K. G., Dobermann, A., Walters, D. T. &amp; Yang, H. Meeting cereal demand while protecting natural resources and improving environmental quality. Annu. Rev. Environ. Resour. 28, 315–358 (2003)" href="https://www.nature.com/articles/nature15743#ref-CR14" id="ref-link-section-d27879965e727">14</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 15" title="Davidson, E. A., Suddick, E. C., Rice, C. W. &amp; Prokopy, L. S. More food, low pollution (Mo Fo Lo Po): a grand challenge for the 21st century. J. Environ. Qual. 44, 305–311 (2015). This paper reports outcomes of an interdisciplinary conference on the technical, social, and economic impediments to improving NUE in crop and animal production systems, and it introduces a series of papers addressing this issue." href="https://www.nature.com/articles/nature15743#ref-CR15" id="ref-link-section-d27879965e730">15</a></sup>. Indeed, NUE has been proposed as an indicator for assessing progress in achieving the Sustainable Development Goals recently accepted by 193 countries of the United Nations General Assembly<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 16" title="Leadership Council of the Sustainable Development Solutions Network (SDSN). Indicators and a Monitoring Framework for Sustainable Development Goals—Revised Working Draft, 16 January 2015. 
                  http://unsdsn.org/resources
                  
                 (SDSN, 2015)" href="https://www.nature.com/articles/nature15743#ref-CR16" id="ref-link-section-d27879965e734">16</a></sup>. Fortunately, we have a large and growing knowledge base and technological capacity for managing N in agriculture<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 17" title="Newell Price, J. et al. An Inventory of Mitigation Methods and Guide to their Effects on Diffuse Water Pollution, Greenhouse Gas Emissions and Ammonia Emissions from Agriculture. 
                  http://www.avondtc.org.uk/Portals/0/Farmscoper/DEFRA%20user%20guide.pdf
                  
                 (Defra Project WQ0106, ADAS and Rothamsted Research North Wyke, 2011)" href="https://www.nature.com/articles/nature15743#ref-CR17" id="ref-link-section-d27879965e738">17</a></sup>, and awareness is growing among both agricultural and environmental stakeholder groups that N use is both essential and problematic<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 15" title="Davidson, E. A., Suddick, E. C., Rice, C. W. &amp; Prokopy, L. S. More food, low pollution (Mo Fo Lo Po): a grand challenge for the 21st century. J. Environ. Qual. 44, 305–311 (2015). This paper reports outcomes of an interdisciplinary conference on the technical, social, and economic impediments to improving NUE in crop and animal production systems, and it introduces a series of papers addressing this issue." href="https://www.nature.com/articles/nature15743#ref-CR15" id="ref-link-section-d27879965e742">15</a></sup>. This growing awareness, combined with ongoing advances in agricultural technology, is creating a possible turning point at which knowledge-based N management could advance substantially throughout the world. However, improving NUE requires more than technical knowledge. The cultural, social and economic incentives for and impediments to farmer adoption of NUE technologies and best management practices need to be better understood<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 15" title="Davidson, E. A., Suddick, E. C., Rice, C. W. &amp; Prokopy, L. S. More food, low pollution (Mo Fo Lo Po): a grand challenge for the 21st century. J. Environ. Qual. 44, 305–311 (2015). This paper reports outcomes of an interdisciplinary conference on the technical, social, and economic impediments to improving NUE in crop and animal production systems, and it introduces a series of papers addressing this issue." href="https://www.nature.com/articles/nature15743#ref-CR15" id="ref-link-section-d27879965e746">15</a></sup>.</p>
<p>Here we analyse historical patterns (1961–2011) of agricultural N use in 113 countries to demonstrate a broad range of pathways of socio-economic development and related N pollution. Our analysis suggests that many countries show a pattern similar to an environmental Kuznets curve (EKC), in which N pollution first increases and then decreases with economic growth<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 18" title="Dinda, S. Environmental Kuznets curve hypothesis: a survey. Ecol. Econ. 49, 431–455 (2004)" href="https://www.nature.com/articles/nature15743#ref-CR18" id="ref-link-section-d27879965e753">18</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 19" title="Grossman, G. M. &amp; Krueger, A. B. Economic growth and the environment. Q. J. Econ. 110, 353–377 (1995). This was among the first set of studies to provide empirical evidence for the EKC hypothesis." href="https://www.nature.com/articles/nature15743#ref-CR19" id="ref-link-section-d27879965e756">19</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 20" title="Arrow, K. et al. Economic growth, carrying capacity, and the environment. Ecol. Econ. 15, 91–95 (1995)" href="https://www.nature.com/articles/nature15743#ref-CR20" id="ref-link-section-d27879965e759">20</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 21" title="Panayotou, T. Empirical Tests and Policy Analysis of Environmental Degradation at Different Stages of Economic Development. Working Paper 238 (Technology and Employment Programme, International Labour Organization, 1993)" href="https://www.nature.com/articles/nature15743#ref-CR21" id="ref-link-section-d27879965e762">21</a></sup>. So far, most EKC analyses have focused on pollution from industrial and transportation sectors<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 19" title="Grossman, G. M. &amp; Krueger, A. B. Economic growth and the environment. Q. J. Econ. 110, 353–377 (1995). This was among the first set of studies to provide empirical evidence for the EKC hypothesis." href="https://www.nature.com/articles/nature15743#ref-CR19" id="ref-link-section-d27879965e766">19</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 22" title="Cole, M. A., Rayner, A. J. &amp; Bates, J. M. The environmental Kuznets curve: an empirical analysis. Environ. Dev. Econ. 2, 401–416 (1997)" href="https://www.nature.com/articles/nature15743#ref-CR22" id="ref-link-section-d27879965e769">22</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 23" title="Brock, W. A. &amp; Taylor, M. S. in Handbook of Economic Growth Vol. 1B (eds Aghion, P. &amp; Durlauf, S.) Ch. 28, 1749–1821 (Elsevier, 2005)" href="https://www.nature.com/articles/nature15743#ref-CR23" id="ref-link-section-d27879965e772">23</a></sup>; the present study is one of a few that consider agricultural N pollution in the EKC context<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 24" title="Li, F., Dong, S., Li, F. &amp; Yang, L. Is there an inverted U-shaped curve? Empirical analysis of the environmental Kuznets curve in agrochemicals. Front. Environ. Sci. Eng. 1–12 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR24" id="ref-link-section-d27879965e776">24</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 25" title="Singh, A. P. &amp; Narayanan, K. Impact of economic growth and population on agrochemical use: evidence from post-liberalization India. Environ. Dev. Sustain. 17, 1509–1525 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR25" id="ref-link-section-d27879965e779">25</a></sup>, and apply it globally. However, patterns of N pollution are neither automatic nor inevitable. Socio-economic circumstances and policies vary widely among countries, affecting factors such as fertilizer to crop price ratios and crop mixes, which, as our analysis shows, influence the turning points of the EKC. Although technological and socio-economic opportunities for NUE improvement vary regionally, our analysis shows that average global NUE in crop production needs to improve from ~0.4 to ~0.7 to meet the dual goals of food security and environmental stewardship in 2050.</p>
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<section data-title="Patterns of nitrogen pollution" data-gtm-vis-first-on-screen50443292_563="8738" data-gtm-vis-total-visible-time50443292_563="10000" data-gtm-vis-has-fired50443292_563="1">
<div class="c-article-section" id="Sec2-section">
<h2 class="c-article-section__title js-section-title js-c-reading-companion-sections-item" id="Sec2">Patterns of nitrogen pollution</h2>
<div class="c-article-section__content" id="Sec2-content">
<p>As a useful indicator of potential losses of N to the environment from agricultural soils<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 26" title="van Beek, C., Brouwer, L. &amp; Oenema, O. The use of farmgate balances and soil surface balances as estimator for nitrogen leaching to surface water. Nutr. Cycl. Agroecosyst. 67, 233–244 (2003)" href="https://www.nature.com/articles/nature15743#ref-CR26" id="ref-link-section-d27879965e791">26</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 27" title="Van Groenigen, J., Velthof, G., Oenema, O., Van Groenigen, K. &amp; Van Kessel, C. Towards an agronomic assessment of N2O emissions: a case study for arable crops. Eur. J. Soil Sci. 61, 903–913 (2010)" href="https://www.nature.com/articles/nature15743#ref-CR27" id="ref-link-section-d27879965e794">27</a></sup>, N surplus (<i>N</i><sub>sur</sub>; in units of kg N ha<sup>−1</sup><span> </span>yr<sup>−1</sup>) is defined as the sum of N inputs (fertilizer, manure, biologically fixed N, and N deposition) minus N outputs<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 28" title="Bouwman, L. et al. Exploring global changes in nitrogen and phosphorus cycles in agriculture induced by livestock production over the 1900–2050 period. Proc. Natl Acad. Sci. USA 110, 20882–20887 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR28" id="ref-link-section-d27879965e806">28</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 29" title="Liu, J. et al. A high-resolution assessment on global nitrogen flows in cropland. Proc. Natl Acad. Sci. USA 107, 8035–8040 (2010)" href="https://www.nature.com/articles/nature15743#ref-CR29" id="ref-link-section-d27879965e809">29</a></sup><span> </span>(the N removed within the harvested crop products,<span> </span><i>N</i><sub>yield</sub>;<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig1">Fig. 1</a>). Some of the<span> </span><i>N</i><sub>sur</sub><span> </span>recycles within the soil, but most<span> </span><i>N</i><sub>sur</sub><span> </span>is lost to the environment over the long term, because the difference between annual inputs and outputs is usually large relative to changes in soil N stocks. The related term of NUE, also called the output–input ratio of N, is mathematically defined as the dimensionless ratio of the sum of all N removed in harvest crop products (outputs or<span> </span><i>N</i><sub>yield</sub>) divided by the sum of all N inputs to a cropland<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 30" title="Lassaletta, L., Billen, G., Grizzetti, B., Anglade, J. &amp; Garnier, J. 50 year trends in nitrogen use efficiency of world cropping systems: the relationship between yield and nitrogen input to cropland. Environ. Res. Lett. 9, 105011 (2014).This paper presents the 50-year trend of NUE and the yield response to N input on a country scale." href="https://www.nature.com/articles/nature15743#ref-CR30" id="ref-link-section-d27879965e834">30</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 31" title="Conant, R. T., Berdanier, A. B. &amp; Grace, P. R. Patterns and trends in nitrogen use and nitrogen recovery efficiency in world agriculture. Glob. Biogeochem. Cycles 27, 558–566 (2013).This study creates a global N input database by country and several major crops and found no convergence in N use among countries." href="https://www.nature.com/articles/nature15743#ref-CR31" id="ref-link-section-d27879965e837">31</a></sup><span> </span>(<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig1">Fig. 1</a>). The<span> </span><i>N</i><sub>sur</sub>, NUE and<span> </span><i>N</i><sub>yield</sub><span> </span>terms can serve as environmental pollution, agricultural efficiency, and food security targets<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 32" title="Brouwer, F. Nitrogen balances at farm level as a tool to monitor effects of agri-environmental policy. Nutr. Cycl. Agroecosyst. 52, 303–308 (1998)" href="https://www.nature.com/articles/nature15743#ref-CR32" id="ref-link-section-d27879965e853">32</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 33" title="Zhang, X., Mauzerall, D. L., Davidson, E. A., Kanter, D. R. &amp; Cai, R. The economic and environmental consequences of implementing nitrogen-efficient technologies and management practices in agriculture. J. Environ. Qual. 44, 312–324 (2015).This paper develops a bioeconomic model to examine how technological and socioeconomic factors influence farming decisions and the resulting environmental impact." href="https://www.nature.com/articles/nature15743#ref-CR33" id="ref-link-section-d27879965e856">33</a></sup>, respectively, which are inherently interconnected through their mathematical definitions<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 33" title="Zhang, X., Mauzerall, D. L., Davidson, E. A., Kanter, D. R. &amp; Cai, R. The economic and environmental consequences of implementing nitrogen-efficient technologies and management practices in agriculture. J. Environ. Qual. 44, 312–324 (2015).This paper develops a bioeconomic model to examine how technological and socioeconomic factors influence farming decisions and the resulting environmental impact." href="https://www.nature.com/articles/nature15743#ref-CR33" id="ref-link-section-d27879965e860">33</a></sup><span> </span>(that is,<span> </span><img src="https://media.springernature.com/lw153/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_IEq1_HTML.gif" alt="">, see<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Information section 1</a><span> </span>for more information) and their real-world consequences (<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig1">Fig. 1</a>).</p>
<h3 class="c-article__sub-heading" id="Sec3">Variable turning points on the EKC</h3>
<p>As an indicator of the extent of environmental degradation,<span> </span><i>N</i><sub>sur</sub><span> </span>aggregated to a national average for all crops is closely related to income growth, mainly in two contrasting pathways as follows. On the one hand, increasing income enables demand for more food consumption<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 33" title="Zhang, X., Mauzerall, D. L., Davidson, E. A., Kanter, D. R. &amp; Cai, R. The economic and environmental consequences of implementing nitrogen-efficient technologies and management practices in agriculture. J. Environ. Qual. 44, 312–324 (2015).This paper develops a bioeconomic model to examine how technological and socioeconomic factors influence farming decisions and the resulting environmental impact." href="https://www.nature.com/articles/nature15743#ref-CR33" id="ref-link-section-d27879965e889">33</a></sup>, which can increase both the land area devoted to agriculture and the intensity of agricultural production and consequently results in more N lost to the environment. On the other hand, increasing income is often accompanied by a societal demand for improved environmental quality, such as clean water and clean air, and is also accompanied by access to advanced technology<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 18" title="Dinda, S. Environmental Kuznets curve hypothesis: a survey. Ecol. Econ. 49, 431–455 (2004)" href="https://www.nature.com/articles/nature15743#ref-CR18" id="ref-link-section-d27879965e893">18</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 19" title="Grossman, G. M. &amp; Krueger, A. B. Economic growth and the environment. Q. J. Econ. 110, 353–377 (1995). This was among the first set of studies to provide empirical evidence for the EKC hypothesis." href="https://www.nature.com/articles/nature15743#ref-CR19" id="ref-link-section-d27879965e896">19</a></sup>. Consequently, governments may impose regulatory policies or offer subsidies and incentives targeted at reducing local or regional N pollution, and farmers may adopt more efficient technologies.</p>
<p>Therefore, we hypothesize that<span> </span><i>N</i><sub>sur</sub><span> </span>follows a pattern similar to the EKC:<span> </span><i>N</i><sub>sur</sub><span> </span>increases with income growth and the quest for food security at early stages of national agricultural development (first phase), but then decreases with further income growth during a more affluent stage (second phase), eventually approaching an asymptote determined by the theoretical limit of the NUE of the crop system (third phase,<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig2">Fig. 2</a>). Sustainable intensification of agriculture has been advanced as the key to achieving the second phase of the EKC, including use of cultivars best adapted to the local soil and climate conditions, improved water management, balancing N application with other nutrient amendments, precision timing and placement of fertilizer and manure applications to meet crop demands, the use of enhanced-efficiency fertilizers, and support tools to calculate proper dosing<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 14" title="Cassman, K. G., Dobermann, A., Walters, D. T. &amp; Yang, H. Meeting cereal demand while protecting natural resources and improving environmental quality. Annu. Rev. Environ. Resour. 28, 315–358 (2003)" href="https://www.nature.com/articles/nature15743#ref-CR14" id="ref-link-section-d27879965e914">14</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 17" title="Newell Price, J. et al. An Inventory of Mitigation Methods and Guide to their Effects on Diffuse Water Pollution, Greenhouse Gas Emissions and Ammonia Emissions from Agriculture. 
                  http://www.avondtc.org.uk/Portals/0/Farmscoper/DEFRA%20user%20guide.pdf
                  
                 (Defra Project WQ0106, ADAS and Rothamsted Research North Wyke, 2011)" href="https://www.nature.com/articles/nature15743#ref-CR17" id="ref-link-section-d27879965e917">17</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 34" title="Snyder, C., Davidson, E., Smith, P. &amp; Venterea, R. Agriculture: sustainable crop and animal production to help mitigate nitrous oxide emissions. Curr. Opin. Environ. Sustain. 9–10, 46–54 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR34" id="ref-link-section-d27879965e920">34</a></sup>. While<span> </span><i>N</i><sub>sur</sub><span> </span>is the EKC environmental degradation indicator, the mathematical relationship between<span> </span><i>N</i><sub>sur</sub><span> </span>and NUE results in nearly mirror images in<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig2">Fig. 2</a><span> </span>(although see<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Information section 1</a><span> </span>for a discussion of situations in which<span> </span><i>N</i><sub>sur</sub><span> </span>and NUE can both increase simultaneously).</p>
<div class="c-article-section__figure js-c-reading-companion-figures-item" data-test="figure" data-container-section="figure" id="figure-2" data-title="An idealized EKC for Nsur and the related curve for NUE.">
<figure>
<figcaption><b id="Fig2" class="c-article-section__figure-caption" data-test="figure-caption-text">Figure 2: An idealized EKC for<span> </span><i>N</i><sub>sur</sub><span> </span>and the related curve for NUE.</b></figcaption>
<div class="c-article-section__figure-content">
<div class="c-article-section__figure-item"><a class="c-article-section__figure-link" data-test="img-link" data-track="click" data-track-label="image" data-track-action="view figure" href="https://www.nature.com/articles/nature15743/figures/2" rel="nofollow"><picture><source type="image/webp" srcset="//media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig2_HTML.jpg?as=webp"><img aria-describedby="Fig2" src="https://media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig2_HTML.jpg" alt="figure 2" loading="lazy" width="685" height="1074"></picture></a></div>
<div class="c-article-section__figure-description" data-test="bottom-caption" id="figure-2-desc">
<p><b>a</b>, The EKC for<span> </span><i>N</i><sub>sur</sub>.<span> </span><b>b</b>, The curve for NUE, which is related to the EKC for<span> </span><i>N</i><sub>sur</sub>. The theoretical limit for NUE (assuming no soil mining of nutrients) is unknown, but no biological system is 100% efficient, so the hypothetical NUE limit is shown as close to but less than unity.</p>
<p><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM42">PowerPoint slide</a></p>
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<p>Of the three phases of the<span> </span><i>N</i><sub>sur</sub><span> </span>trend, it is the second phase of sustainable intensification with increasing affluence that is of greatest contemporary interest. The first phase of agricultural expansion is well documented<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 30" title="Lassaletta, L., Billen, G., Grizzetti, B., Anglade, J. &amp; Garnier, J. 50 year trends in nitrogen use efficiency of world cropping systems: the relationship between yield and nitrogen input to cropland. Environ. Res. Lett. 9, 105011 (2014).This paper presents the 50-year trend of NUE and the yield response to N input on a country scale." href="https://www.nature.com/articles/nature15743#ref-CR30" id="ref-link-section-d27879965e995">30</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 31" title="Conant, R. T., Berdanier, A. B. &amp; Grace, P. R. Patterns and trends in nitrogen use and nitrogen recovery efficiency in world agriculture. Glob. Biogeochem. Cycles 27, 558–566 (2013).This study creates a global N input database by country and several major crops and found no convergence in N use among countries." href="https://www.nature.com/articles/nature15743#ref-CR31" id="ref-link-section-d27879965e998">31</a></sup>, and the third phase cannot yet be evaluated. So far, no country has yet approached the third phase, nor do we know how close to 100% efficiency the use of N inputs could become. For the first phase, as incomes rise, virtually all countries initially increase fertilizer use,<span> </span><i>N</i><sub>yield</sub>, and<span> </span><i>N</i><sub>sur</sub><span> </span>while NUE decreases<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 30" title="Lassaletta, L., Billen, G., Grizzetti, B., Anglade, J. &amp; Garnier, J. 50 year trends in nitrogen use efficiency of world cropping systems: the relationship between yield and nitrogen input to cropland. Environ. Res. Lett. 9, 105011 (2014).This paper presents the 50-year trend of NUE and the yield response to N input on a country scale." href="https://www.nature.com/articles/nature15743#ref-CR30" id="ref-link-section-d27879965e1011">30</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 31" title="Conant, R. T., Berdanier, A. B. &amp; Grace, P. R. Patterns and trends in nitrogen use and nitrogen recovery efficiency in world agriculture. Glob. Biogeochem. Cycles 27, 558–566 (2013).This study creates a global N input database by country and several major crops and found no convergence in N use among countries." href="https://www.nature.com/articles/nature15743#ref-CR31" id="ref-link-section-d27879965e1014">31</a></sup>. To test the existence of the second phase, we examine whether the relationship between gross domestic product (GDP) per capita and<span> </span><i>N</i><sub>sur</sub><span> </span>breaks away from the linearly (or exponentially) increasing trend and follows more of a bell-shaped pattern over the long term.</p>
<p>We tested the existence of a sustainable intensification phase (or an EKC pattern) with a five-decade record (1961–2011) of<span> </span><i>N</i><sub>sur</sub><span> </span>and GDP per capita<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 28" title="Bouwman, L. et al. Exploring global changes in nitrogen and phosphorus cycles in agriculture induced by livestock production over the 1900–2050 period. Proc. Natl Acad. Sci. USA 110, 20882–20887 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR28" id="ref-link-section-d27879965e1029">28</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 35" title="Food and Agriculture Organization of the United Nations. FAOSTAT Online Database
                  http://faostat.fao.org/
                  
                 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR35" id="ref-link-section-d27879965e1032">35</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 36" title="World Bank Group. World Development Indicators 2012
                  http://data.worldbank.org/sites/default/files/wdi-2012-ebook.pdf
                  
                 (World Bank Publications, 2012)" href="https://www.nature.com/articles/nature15743#ref-CR36" id="ref-link-section-d27879965e1035">36</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 37" title="Lassaletta, L. et al. Food and feed trade as a driver in the global nitrogen cycle: 50-year trends. Biogeochemistry 118, 225–241 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR37" id="ref-link-section-d27879965e1038">37</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 38" title="Heffer, P. Assessment of Fertilizer Use by Crop at the Global Level 2007–2007/08 (International Fertilizer Industry Association, 2009)" href="https://www.nature.com/articles/nature15743#ref-CR38" id="ref-link-section-d27879965e1041">38</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 39" title="Monfreda, C., Ramankutty, N. &amp; Foley, J. A. Farming the planet: 2. Geographic distribution of crop areas, yields, physiological types, and net primary production in the year 2000. Glob. Biogeochem. Cycles 22, 1–19 (2008)" href="https://www.nature.com/articles/nature15743#ref-CR39" id="ref-link-section-d27879965e1044">39</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 40" title="Herridge, D. F., Peoples, M. B. &amp; Boddey, R. M. Global inputs of biological nitrogen fixation in agricultural systems. Plant Soil 311, 1–18 (2008)" href="https://www.nature.com/articles/nature15743#ref-CR40" id="ref-link-section-d27879965e1048">40</a></sup><span> </span>with a fixed effects model<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 41" title="Jayanthakumaran, K., Verma, R. &amp; Liu, Y. CO2 emissions, energy consumption, trade and income: a comparative analysis of China and India. Energy Policy 42, 450–460 (2012)" href="https://www.nature.com/articles/nature15743#ref-CR41" id="ref-link-section-d27879965e1052">41</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 42" title="He, J. &amp; Wang, H. Economic structure, development policy and environmental quality: An empirical analysis of environmental Kuznets curves with Chinese municipal data. Ecol. Econ. 76, 49–59 (2012)" href="https://www.nature.com/articles/nature15743#ref-CR42" id="ref-link-section-d27879965e1055">42</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 43" title="Al-Mulali, U., Saboori, B. &amp; Ozturk, I. Investigating the environmental Kuznets curve hypothesis in Vietnam. Energy Policy 76, 123–131 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR43" id="ref-link-section-d27879965e1058">43</a></sup><span> </span>across 113 countries for which sufficient data were available and a regression model for each individual country<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 18" title="Dinda, S. Environmental Kuznets curve hypothesis: a survey. Ecol. Econ. 49, 431–455 (2004)" href="https://www.nature.com/articles/nature15743#ref-CR18" id="ref-link-section-d27879965e1062">18</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 44" title="Alam, M. S. &amp; Kabir, N. Economic growth and environmental sustainability: empirical evidence from East and South-East Asia. Int. J. Econ. Finance 5, 86–97 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR44" id="ref-link-section-d27879965e1065">44</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 45" title="Diao, X., Zeng, S., Tam, C. M. &amp; Tam, V. W. EKC analysis for studying economic growth and environmental quality: a case study in China. J. Clean. Prod. 17, 541–548 (2009)" href="https://www.nature.com/articles/nature15743#ref-CR45" id="ref-link-section-d27879965e1068">45</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 46" title="Song, M.-L., Zhang, W. &amp; Wang, S.-H. Inflection point of environmental Kuznets curve in mainland China. Energy Policy 57, 14–20 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR46" id="ref-link-section-d27879965e1071">46</a></sup><span> </span>(see sections 1 and 2 in the<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Information</a>). The fixed effects model shows a significant quadratic relationship between GDP per capita and<span> </span><i>N</i><sub>sur</sub><span> </span>(<i>P </i>&lt; 0.001,<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Table 9</a>). Regressions between GDP per capita and<span> </span><i>N</i><sub>sur</sub><span> </span>for each individual country fall into five response types (examples of each group are shown in<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig3">Fig. 3</a>). Of the 113 countries, 56 countries (group 1) show bell-shaped relationships between<span> </span><i>N</i><sub>sur</sub><span> </span>and GDP per capita, indicating that<span> </span><i>N</i><sub>sur</sub><span> </span>increased and then levelled off or decreased as economic development proceeded, as expected for an EKC (two examples are illustrated in<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig3">Fig. 3a</a>). Those 56 countries account for about 87% of N fertilizer consumption and about 70% of harvested area of all 113 countries. These data provide support for an EKC pattern for N pollution from agriculture, although as we show below, the potential causes of EKC shapes and turning points are complex. Furthermore, for 28 of the 56 countries, by 2011 the rate of increase in<span> </span><i>N</i><sub>sur</sub><span> </span>had only slowed or levelled off and had not yet actually decreased, indicating likely but still uncertain conformance with an EKC (<a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Tables 5 and 6</a>).</p>
<div class="c-article-section__figure js-c-reading-companion-figures-item" data-test="figure" data-container-section="figure" id="figure-3" data-title="Examples of historical trends of the relationship between GDP per capita and Nsur.">
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<figcaption><b id="Fig3" class="c-article-section__figure-caption" data-test="figure-caption-text">Figure 3: Examples of historical trends of the relationship between GDP per capita and<span> </span><i>N</i><sub>sur</sub>.</b></figcaption>
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<div class="c-article-section__figure-item"><a class="c-article-section__figure-link" data-test="img-link" data-track="click" data-track-label="image" data-track-action="view figure" href="https://www.nature.com/articles/nature15743/figures/3" rel="nofollow"><picture><source type="image/webp" srcset="//media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig3_HTML.jpg?as=webp"><img aria-describedby="Fig3" src="https://media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig3_HTML.jpg" alt="figure 3" loading="lazy" width="685" height="1034"></picture></a></div>
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<p>The observations are the record of annual<span> </span><i>N</i><sub>sur</sub><span> </span>smoothed using a ten-year window for each country; the model results are the outcome of the regression using the following model:<span> </span><i>Y </i>= <i>a </i>+ <i>bX</i> + <i>cX</i><sup>2</sup>, where the dependent variable<span> </span><i>Y</i><span> </span>is the country’s<span> </span><i>N</i><sub>sur</sub><span> </span>and the independent variable<span> </span><i>X</i><span> </span>is the country’s GDP per capita. We categorized the 113 countries into five groups, based on the significance (that is,<span> </span><i>P</i><span> </span>value) and sign of the regression coefficients<span> </span><i>b</i><span> </span>and<span> </span><i>c</i><span> </span>(see<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Information sections 2.1 and 3.1</a>).<span> </span><b>a</b>, France and USA are examples of group 1, which have significantly negative<span> </span><i>c</i><span> </span>(<i>P</i><sub><i>c</i></sub> &lt; 0.05 and<span> </span><i>c</i> &lt; 0), thus indicating that<span> </span><i>N</i><sub>sur</sub><span> </span>has started to level off or has declined;<span> </span><b>b</b>, Brazil, Thailand, Malawi and Algeria are examples of groups 2–5, which increase nonlinearly, increase linearly, have no significant correlation (<i>P</i><sub><i>b </i></sub>&gt; 0.05 and<span> </span><i>P</i><sub><i>c </i></sub>&gt; 0.05), or have a negative surplus in 2007–2011, respectively (see<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Tables 5 and 6</a>). The results for all countries can be found in the figures in the<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Information</a>.</p>
<p><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM43">PowerPoint slide</a></p>
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<p>Countries with a linear or accelerating increase in<span> </span><i>N</i><sub>sur</sub><span> </span>(group 3 and most countries in group 2) as GDP per capita grew have not yet approached an EKC turning point (for example,<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig3">Fig. 3b</a>), but could still follow an EKC in the future as their N input growth slows and NUE increases. Most countries showing an insignificant (<i>P </i>&gt; 0.05) relationship between<span> </span><i>N</i><sub>sur</sub><span> </span>and GDP per capita (group 4) or with a negative<span> </span><i>N</i><sub>sur</sub><span> </span>(group 5) have had such little income growth and use so little N that the EKC concept cannot be evaluated yet owing to limited change in the country’s GDP per capita (for example,<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig3">Fig. 3b</a>).</p>
<p>Classic empirical studies on EKC, such as Grossman and Krueger (ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 19" title="Grossman, G. M. &amp; Krueger, A. B. Economic growth and the environment. Q. J. Econ. 110, 353–377 (1995). This was among the first set of studies to provide empirical evidence for the EKC hypothesis." href="https://www.nature.com/articles/nature15743#ref-CR19" id="ref-link-section-d27879965e1258">19</a>), have been criticized because of concerns regarding statistical analyses of time series data that may be non-stationary<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 47" title="Wagner, M. The carbon Kuznets curve: a cloudy picture emitted by bad econometrics? Resour. Energy Econ. 30, 388–408 (2008)" href="https://www.nature.com/articles/nature15743#ref-CR47" id="ref-link-section-d27879965e1262">47</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 48" title="Müller-Fürstenberger, G. &amp; Wagner, M. Exploring the environmental Kuznets hypothesis: theoretical and econometric problems. Ecol. Econ. 62, 648–660 (2007)" href="https://www.nature.com/articles/nature15743#ref-CR48" id="ref-link-section-d27879965e1265">48</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 49" title="Chow, G. C. &amp; Li, J. Environmental Kuznets curve: conclusive econometric evidence for CO2 . Pac. Econ. Rev. 19, 1–7 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR49" id="ref-link-section-d27879965e1268">49</a></sup>. Therefore, we examined the stationarity of our data (<a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Table 7</a>) and used the Autoregressive Distributed Lag modelling approach (ARDL)<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 50" title="Pesaran, M. H., Shin, Y. &amp; Smith, R. J. Bounds testing approaches to the analysis of level relationships. J. Appl. Econ. 16, 289–326 (2001)" href="https://www.nature.com/articles/nature15743#ref-CR50" id="ref-link-section-d27879965e1275">50</a></sup>, which is the most frequently used method for the co-integration test in EKC empirical studies published in the last decade<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 43" title="Al-Mulali, U., Saboori, B. &amp; Ozturk, I. Investigating the environmental Kuznets curve hypothesis in Vietnam. Energy Policy 76, 123–131 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR43" id="ref-link-section-d27879965e1279">43</a></sup>, to test co-integration on a subset of the data. The ARDL regression models showed the same long-term relationships between<span> </span><i>N</i><sub>sur</sub><span> </span>and GDP per capita as presented above for all tested countries (<a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Table 8</a>). The application of the ARDL method in EKC studies has also been criticized recently for including the quadratic term in the co-integration test, and some new methods have been proposed<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 51" title="Wagner, M. The environmental Kuznets curve, cointegration and nonlinearity. J. Appl. Econ. 30, 948–967 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR51" id="ref-link-section-d27879965e1291">51</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 52" title="Wagner, M. &amp; Hong, S. H. Cointegrating polynomial regressions: fully modified OLS estimation and inference. Econom. Theory, 
                  http://dx.doi.org/10.1017/S0266466615000213
                  
                 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR52" id="ref-link-section-d27879965e1294">52</a></sup>. Further evaluation is needed on the limitations and performance of the ARDL and newly proposed methods for EKC analyses.</p>
<p>Another common criticism of the EKC concept is that the turning point for transitioning to declining environmental degradation is highly variable among pollutants and among countries<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 18" title="Dinda, S. Environmental Kuznets curve hypothesis: a survey. Ecol. Econ. 49, 431–455 (2004)" href="https://www.nature.com/articles/nature15743#ref-CR18" id="ref-link-section-d27879965e1301">18</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 53" title="Stern, D. I. The rise and fall of the environmental Kuznets curve. World Dev. 32, 1419–1439 (2004)" href="https://www.nature.com/articles/nature15743#ref-CR53" id="ref-link-section-d27879965e1304">53</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 54" title="Cavlovic, T. A., Baker, K. H., Berrens, R. P. &amp; Gawande, K. A meta-analysis of environmental Kuznets curve studies. Agric. Res. Econ. Rev. 29, 32–42 (2000)" href="https://www.nature.com/articles/nature15743#ref-CR54" id="ref-link-section-d27879965e1307">54</a></sup>. Consistent with those observations, no specific value of GDP per capita was a good predictor of turning points for<span> </span><i>N</i><sub>sur</sub><span> </span>on the EKC among countries in the present study. For example,<span> </span><i>N</i><sub>sur</sub><span> </span>in Germany and France started to decline when GDP per capita reached about US$25,000 in the 1980s, while<span> </span><i>N</i><sub>sur</sub><span> </span>in the USA levelled off and started to decline more recently when GDP per capita reached about US$40,000. Our analysis also shows that countries have widely differing values of NUE and<span> </span><i>N</i><sub>sur</sub><span> </span>even when yields are similar. Some of this variation is probably due to underlying biophysical conditions, such as rainfall variability and soil quality, which influence crop choices, yield responses, and NUE. However, cultural, social, technological, economic and policy factors also probably affect the turning points on the EKC trajectory of each country.</p>
<p>The turning point in European Union (EU) countries appears to have been reached at least in part owing to policies<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 55" title="Sutton, M. A. et al. (eds) The European Nitrogen Assessment: Sources, Effects and Policy Perspectives (Cambridge Univ. Press, 2011)" href="https://www.nature.com/articles/nature15743#ref-CR55" id="ref-link-section-d27879965e1331">55</a></sup>. Beginning in the late 1980s and through the early 2000s, increases in NUE and decreases in<span> </span><i>N</i><sub>sur</sub><span> </span>in several EU countries coincided with changes in the EU Common Agricultural Policy, which reduced crop subsidies, and adoption of the EU Nitrates Directive, which limited manure application rates on cropland<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 56" title="van Grinsven, H. et al. Management, regulation and environmental impacts of nitrogen fertilization in northwestern Europe under the Nitrates Directive: a benchmark study. Biogeosciences 9, 5143–5160 (2012)" href="https://www.nature.com/articles/nature15743#ref-CR56" id="ref-link-section-d27879965e1339">56</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 57" title="van Grinsven, H. J. et al. Losses of ammonia and nitrate from agriculture and their effect on nitrogen recovery in the European Union and the United States between 1900 and 2050. J. Environ. Qual. 44, 356–367 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR57" id="ref-link-section-d27879965e1342">57</a></sup>. Relying mostly on volunteer approaches in the USA, the levelling off and modest decrease in<span> </span><i>N</i><sub>sur</sub><span> </span>since the 1990s is largely the result of increasing crop yields while holding N inputs steady (<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig4">Fig. 4a</a>), which has resulted from improved crop varieties, increased irrigation and other technological improvements<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 57" title="van Grinsven, H. J. et al. Losses of ammonia and nitrate from agriculture and their effect on nitrogen recovery in the European Union and the United States between 1900 and 2050. J. Environ. Qual. 44, 356–367 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR57" id="ref-link-section-d27879965e1354">57</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 58" title="Ferguson, R. B. Groundwater quality and nitrogen use efficiency in Nebraska’s Central Platte River valley. J. Environ. Qual. 44, 449–459 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR58" id="ref-link-section-d27879965e1357">58</a></sup>. A few state regulatory programmes have required nutrient management plans, placed limitations on fertilizer application dates and amounts, and required soil and plant testing, with varying degrees of success<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 58" title="Ferguson, R. B. Groundwater quality and nitrogen use efficiency in Nebraska’s Central Platte River valley. J. Environ. Qual. 44, 449–459 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR58" id="ref-link-section-d27879965e1361">58</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 59" title="Osmond, D. L., Hoag, D. L., Luloff, A. E., Meals, D. W. &amp; Neas, K. Farmers’ use of nutrient management: lessons from watershed case studies. J. Environ. Qual. 44, 382–390 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR59" id="ref-link-section-d27879965e1364">59</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 60" title="Perez, M. R. Regulating farmer nutrient management: a three-state case study on the Delmarva Peninsula. J. Environ. Qual. 44, 402–414 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR60" id="ref-link-section-d27879965e1367">60</a></sup>. Concerns about water and air quality, estuarine hypoxic zones, stratospheric ozone depletion, and climate change have also stimulated many outreach efforts by governments, fertilizer industry groups, retailers, and environmental organizations to provide farmers with information, training and innovative financial incentives to improve NUE voluntarily<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 15" title="Davidson, E. A., Suddick, E. C., Rice, C. W. &amp; Prokopy, L. S. More food, low pollution (Mo Fo Lo Po): a grand challenge for the 21st century. J. Environ. Qual. 44, 305–311 (2015). This paper reports outcomes of an interdisciplinary conference on the technical, social, and economic impediments to improving NUE in crop and animal production systems, and it introduces a series of papers addressing this issue." href="https://www.nature.com/articles/nature15743#ref-CR15" id="ref-link-section-d27879965e1371">15</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 59" title="Osmond, D. L., Hoag, D. L., Luloff, A. E., Meals, D. W. &amp; Neas, K. Farmers’ use of nutrient management: lessons from watershed case studies. J. Environ. Qual. 44, 382–390 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR59" id="ref-link-section-d27879965e1374">59</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 61" title="International Fertilizer Industry Association (IFA). The Global ‘4R’ Nutrient Stewardship Framework. Developing Fertilizer Best Management Practices for Delivering Economic, Social, and Environmental Benefits. AgCom/09/44, 
                  https://www.ipni.net/ipniweb/portal/4r.nsf/article/global-4r-framework
                  
                 (IFA Task Force on Fertilizer Best Management Practices, IFA, 2009)" href="https://www.nature.com/articles/nature15743#ref-CR61" id="ref-link-section-d27879965e1377">61</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 62" title="Davidson, E., Galloway, J., Millar, N. &amp; Leach, A. N-related greenhouse gases in North America: innovations for a sustainable future. Curr. Opin. Environ. Sust. 9–10, 1–8 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR62" id="ref-link-section-d27879965e1380">62</a></sup>.</p>
<div class="c-article-section__figure js-c-reading-companion-figures-item" data-test="figure" data-container-section="figure" id="figure-4" data-title="A comparison of historical trends.">
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<figcaption><b id="Fig4" class="c-article-section__figure-caption" data-test="figure-caption-text">Figure 4: A comparison of historical trends.</b></figcaption>
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<div class="c-article-section__figure-item"><a class="c-article-section__figure-link" data-test="img-link" data-track="click" data-track-label="image" data-track-action="view figure" href="https://www.nature.com/articles/nature15743/figures/4" rel="nofollow"><picture><source type="image/webp" srcset="//media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig4_HTML.jpg?as=webp"><img aria-describedby="Fig4" src="https://media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig4_HTML.jpg" alt="figure 4" loading="lazy" width="685" height="1587"></picture></a></div>
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<p><b>a</b>, Nationally averaged annual fertilization rates and yields of maize in China and the USA.<span> </span><b>b</b>, NUE averaged across crops in China and the USA.<span> </span><b>c</b>, Fertilizer to crop price ratios for China, India, USA and France. The dashed blue line in<span> </span><b>a</b><span> </span>shows a typical yield response function for maize based on fertilizer response trials<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 33" title="Zhang, X., Mauzerall, D. L., Davidson, E. A., Kanter, D. R. &amp; Cai, R. The economic and environmental consequences of implementing nitrogen-efficient technologies and management practices in agriculture. J. Environ. Qual. 44, 312–324 (2015).This paper develops a bioeconomic model to examine how technological and socioeconomic factors influence farming decisions and the resulting environmental impact." href="https://www.nature.com/articles/nature15743#ref-CR33" id="ref-link-section-d27879965e1407">33</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 63" title="Sawyer, J. E. et al. Concepts and Rationale for Regional Nitrogen Rate Guidelines for Corn. 
                  http://www.extension.iastate.edu/publications/pm2015.pdf
                  
                 (Iowa State University Extension, 2006)" href="https://www.nature.com/articles/nature15743#ref-CR63" id="ref-link-section-d27879965e1410">63</a></sup>, which demonstrates diminishing return in yield as N inputs increase. Note that the historical trend for China follows a pattern similar to a typical yield response function, indicating that further increases in N application rates will result in diminishing yield returns in China. In contrast, maize yield has increased in the USA since 2001 without increasing nationally averaged N input rates, suggesting that the yield improvement has been achieved by adopting more efficient technologies or management practices that shift the yield response curve upwards<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 33" title="Zhang, X., Mauzerall, D. L., Davidson, E. A., Kanter, D. R. &amp; Cai, R. The economic and environmental consequences of implementing nitrogen-efficient technologies and management practices in agriculture. J. Environ. Qual. 44, 312–324 (2015).This paper develops a bioeconomic model to examine how technological and socioeconomic factors influence farming decisions and the resulting environmental impact." href="https://www.nature.com/articles/nature15743#ref-CR33" id="ref-link-section-d27879965e1414">33</a></sup>. The dashed pink line in<span> </span><b>b</b><span> </span>shows what the NUE in China would be if it achieved NUE values realized in the USA for all crops, but with the crop mix of China. The gap between the dashed pink line and the black line (USA record) is the difference in NUE between countries that is attributable to the differences in crop mixes. The fertilizer to crop price ratio shown in<span> </span><b>c</b><span> </span>is determined by the N price of urea divided by the N price of maize product (see section 1.6 in<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Information</a><span> </span>for data sources and methodologies). The data are smoothed using a ten-year window.</p>
<p><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM44">PowerPoint slide</a></p>
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<div class="u-text-right u-hide-print"><a class="c-article__pill-button" data-test="article-link" data-track="click" data-track-label="button" data-track-action="view figure" href="https://www.nature.com/articles/nature15743/figures/4" data-track-dest="link:Figure4 Full size image" aria-label="Full size image figure 4" rel="nofollow"><span>Full size image</span><svg width="16" height="16" focusable="false" role="img" aria-hidden="true" class="u-icon"><use xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="#icon-eds-i-chevron-right-small"></use></svg></a></div>
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<h3 class="c-article__sub-heading" id="Sec4">Fertilizer to crop price ratios</h3>
<p>Policy can affect NUE not only through regulation and outreach, but also by affecting prices at the farm gate. The ratio of fertilizer to crop prices,<span> </span><i>R</i><sub>fc</sub>, has been widely used in combination with data on yield responses to fertilizer application to advise farmers on fertilizer application rates that yield optimal economic returns<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 63" title="Sawyer, J. E. et al. Concepts and Rationale for Regional Nitrogen Rate Guidelines for Corn. 
                  http://www.extension.iastate.edu/publications/pm2015.pdf
                  
                 (Iowa State University Extension, 2006)" href="https://www.nature.com/articles/nature15743#ref-CR63" id="ref-link-section-d27879965e1454">63</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 64" title="Robertson, G. P. &amp; Vitousek, P. M. Nitrogen in agriculture: balancing the cost of an essential resource. Annu. Rev. Environ. Resour. 34, 97–125 (2009)" href="https://www.nature.com/articles/nature15743#ref-CR64" id="ref-link-section-d27879965e1457">64</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 65" title="Setiyono, T. D. et al. Maize-N: a decision tool for nitrogen management in maize. Agron. J. 103, 1276–1283 (2011)" href="https://www.nature.com/articles/nature15743#ref-CR65" id="ref-link-section-d27879965e1460">65</a></sup>. In addition to influencing fertilizer application rates,<span> </span><i>R</i><sub>fc</sub><span> </span>also affects farmer decisions regarding their choice of technologies and practices for nutrient management, all of which affect NUE and<span> </span><i>N</i><sub>sur</sub><span> </span>(ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 33" title="Zhang, X., Mauzerall, D. L., Davidson, E. A., Kanter, D. R. &amp; Cai, R. The economic and environmental consequences of implementing nitrogen-efficient technologies and management practices in agriculture. J. Environ. Qual. 44, 312–324 (2015).This paper develops a bioeconomic model to examine how technological and socioeconomic factors influence farming decisions and the resulting environmental impact." href="https://www.nature.com/articles/nature15743#ref-CR33" id="ref-link-section-d27879965e1472">33</a>). We tested whether the influence of<span> </span><i>R</i><sub>fc</sub><span> </span>appears at the national level using two methods: one examines the correlation coefficient of<span> </span><i>R</i><sub>fc</sub><span> </span>and NUE for individual countries, and the other applies a fixed effects model to all data to test the correlation between<span> </span><i>R</i><sub>fc</sub><span> </span>and NUE with and without including GDP per capita and crop mix (see section 2.3 in<span> </span><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Information</a>). Because both the fertilizer and crop prices are ‘at the farm gate’, they include the effects of government subsidies<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 35" title="Food and Agriculture Organization of the United Nations. FAOSTAT Online Database
                  http://faostat.fao.org/
                  
                 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR35" id="ref-link-section-d27879965e1492">35</a></sup>. The results for maize, for which the most data are available, indicate that the fertilizer to maize price ratio is positively correlated with NUE using both statistical approaches (<a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Table 12</a>). We also found that maize prices are linearly correlated with the prices of most major crops, so we infer that the fertilizer to maize price ratio is likely to be a good index for the long-term trend of<span> </span><i>R</i><sub>fc</sub><span> </span>for all crops. Indeed, we found a statistically significant (<i>P </i>&lt; 0.001) positive correlation between historical values of<span> </span><i>R</i><sub>fc</sub><span> </span>for maize and the NUE aggregated for all other crops. Moreover, this correlation is still statistically significant (<i>P</i> &lt; 0.001) after adjusting for the effect of GDP per capita and crop mix (<a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Table 11</a>).</p>
<p>Increases in<span> </span><i>R</i><sub>fc</sub><span> </span>since the 1990s, in both France and the USA (<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig4">Fig. 4c</a>), coincided with increases in NUE (ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 57" title="van Grinsven, H. J. et al. Losses of ammonia and nitrate from agriculture and their effect on nitrogen recovery in the European Union and the United States between 1900 and 2050. J. Environ. Qual. 44, 356–367 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR57" id="ref-link-section-d27879965e1526">57</a>) and may have affected the EKC turning point. At the other extreme, both China and India have had declining values of<span> </span><i>R</i><sub>fc</sub><span> </span>(<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig4">Fig. 4c</a>), owing to heavily subsidized fertilizer prices<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 25" title="Singh, A. P. &amp; Narayanan, K. Impact of economic growth and population on agrochemical use: evidence from post-liberalization India. Environ. Dev. Sustain. 17, 1509–1525 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR25" id="ref-link-section-d27879965e1538">25</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 66" title="Li, Y. et al. An analysis of China’s fertilizer policies: impacts on the industry, food security, and the environment. J. Environ. Qual. 42, 972–981 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR66" id="ref-link-section-d27879965e1541">66</a></sup>. Fertilizer subsidies reached US$18 billion in China in 2010 (ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 66" title="Li, Y. et al. An analysis of China’s fertilizer policies: impacts on the industry, food security, and the environment. J. Environ. Qual. 42, 972–981 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR66" id="ref-link-section-d27879965e1544">66</a>). Rates of N inputs have now reached levels of diminishing returns for crop yield in China (<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig4">Fig. 4a</a>), and China has the largest<span> </span><i>N</i><sub>sur</sub><span> </span>and one of the lowest nationally averaged NUE values in the world (<a data-track="click" data-track-label="link" data-track-action="table anchor" href="https://www.nature.com/articles/nature15743#Tab1">Table 1</a>). The very low<span> </span><i>R</i><sub>fc</sub><span> </span>in China incentivizes farmers to attempt to increase crop yield by simply adding more N or by choosing more N-demanding cropping systems (for example, change from cereal production to greenhouse vegetable production<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 67" title="Ju, X., Kou, C., Christie, P., Dou, Z. &amp; Zhang, F. Changes in the soil environment from excessive application of fertilizers and manures to two contrasting intensive cropping systems on the North China Plain. Environ. Pollut. 145, 497–506 (2007)" href="https://www.nature.com/articles/nature15743#ref-CR67" id="ref-link-section-d27879965e1563">67</a></sup>) instead of adopting more N-efficient technologies and management practices.</p>
<div class="c-article-table" data-test="inline-table" data-container-section="table" id="table-1">
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<figcaption class="c-article-table__figcaption"><b id="Tab1" data-test="table-caption">Table 1 N budget and NUE in crop production by region and crop in 2010 and projected for 2050</b></figcaption>
<div class="u-text-right u-hide-print"><a class="c-article__pill-button" data-test="table-link" data-track="click" data-track-action="view table" data-track-label="button" rel="nofollow" href="https://www.nature.com/articles/nature15743/tables/1" aria-label="Full size table 1"><span>Full size table</span><svg width="16" height="16" focusable="false" role="img" aria-hidden="true" class="u-icon"><use xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="#icon-eds-i-chevron-right-small"></use></svg></a></div>
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<p>Not all fertilizer subsidies are inappropriate. Where infrastructure for producing and transporting fertilizers is poor, as is the case for most of Africa, the cost can be so high that fertilizer use is prohibitively expensive for smallholder farmers, resulting in low yield and small, even negative<span> </span><i>N</i><sub>sur</sub><span> </span>(soil mining). In these cases, there is room for fertilizer subsidies to increase N inputs, because significant increases in N inputs could be absorbed and greatly increase crop yields without much immediate risk of N pollution<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 68" title="Hickman, J. E., Tully, K. L., Groffman, P. M., Diru, W. &amp; Palm, C. A. A potential tipping point in tropical agriculture: avoiding rapid increases in nitrous oxide fluxes from agricultural intensification in Kenya. J. Geophys. Res. Biogeosci. 120, 938–951 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR68" id="ref-link-section-d27879965e2944">68</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 69" title="Hickman, J. E., Havlikova, M., Kroeze, C. &amp; Palm, C. A. Current and future nitrous oxide emissions from African agriculture. Curr. Opin. Environ. Sust. 3, 370–378 (2011)" href="https://www.nature.com/articles/nature15743#ref-CR69" id="ref-link-section-d27879965e2947">69</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 70" title="Zhou, M. et al. Regional nitrogen budget of the Lake Victoria Basin, East Africa: syntheses, uncertainties and perspectives. Environ. Res. Lett. 9, 105009 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR70" id="ref-link-section-d27879965e2950">70</a></sup>. When properly designed, temporary fertilizer subsidies structured to build up the private delivery network and with a built-in exit strategy can be an appropriate step<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 71" title="Jayne, T. S. &amp; Rashid, S. Input subsidy programs in sub-Saharan Africa: a synthesis of recent evidence. Agric. Econ. 44, 547–562 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR71" id="ref-link-section-d27879965e2954">71</a></sup>. The longer-term question for these countries will be whether they can ‘tunnel through’ the EKC by shifting crop production directly from a low-yield, high-NUE status to a high-yield, high-NUE status. This shift will require leapfrogging over the historical evolution of agricultural management practices by employing technologies and management practices that promote high NUE before<span> </span><i>N</i><sub>sur</sub><span> </span>grows to environmentally degrading levels. Acquiring and deploying such technologies, such as improved seed, balanced nutrient amendments, and water management, will require investments in technology transfer and capacity building.</p>
<h3 class="c-article__sub-heading" id="Sec5">Importance of crop mix</h3>
<p>Another factor that may confound EKC trajectories is the mix of crops countries grow over time, which is affected by both demand and trade policies<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 72" title="Billen, G., Lassaletta, L. &amp; Garnier, J. A vast range of opportunities for feeding the world in 2050: trade-off between diet, N contamination and international trade. Environ. Res. Lett. 10, 025001 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR72" id="ref-link-section-d27879965e2970">72</a></sup>. For example, changing patterns of crop mixes help to explain some of the differences between China and the USA. Since the 1990s an increasing percentage of agricultural land in China has been devoted to fruit and vegetable production, and N application to fruits and vegetables now accounts for about 30% of total fertilizer consumption<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 38" title="Heffer, P. Assessment of Fertilizer Use by Crop at the Global Level 2007–2007/08 (International Fertilizer Industry Association, 2009)" href="https://www.nature.com/articles/nature15743#ref-CR38" id="ref-link-section-d27879965e2974">38</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 73" title="Heffer, P. Assessment of Fertilizer Use by Crop at the Global Level 2010–2010/11. 
                  http://www.fertilizer.org/En/Statistics/Agriculture_Committee_Databases.aspx
                  
                 (International Fertilizer Industry Association, 2013)" href="https://www.nature.com/articles/nature15743#ref-CR73" id="ref-link-section-d27879965e2977">73</a></sup>, with an average NUE of only about 0.10 (which is below the globally averaged NUE for fruits and vegetables of 0.14, and well below the global averages for other major crops;<span> </span><a data-track="click" data-track-label="link" data-track-action="table anchor" href="https://www.nature.com/articles/nature15743#Tab1">Table 1</a>)<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 74" title="Shi, W.-M., Yao, J. &amp; Yan, F. Vegetable cultivation under greenhouse conditions leads to rapid accumulation of nutrients, acidification and salinity of soils and groundwater contamination in South-Eastern China. Nutr. Cycl. Agroecosyst. 83, 73–84 (2009)" href="https://www.nature.com/articles/nature15743#ref-CR74" id="ref-link-section-d27879965e2984">74</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 75" title="Ju, X.-T. et al. Reducing environmental risk by improving N management in intensive Chinese agricultural systems. Proc. Natl Acad. Sci. USA 106, 3041–3046 (2009)" href="https://www.nature.com/articles/nature15743#ref-CR75" id="ref-link-section-d27879965e2987">75</a></sup>. At the same time, China has been increasingly relying on imported soybeans, an N-fixing crop that has very low<span> </span><i>N</i><sub>sur</sub><span> </span>(<a data-track="click" data-track-label="link" data-track-action="table anchor" href="https://www.nature.com/articles/nature15743#Tab1">Table 1</a>)<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 76" title="Drinkwater, L. E., Wagoner, P. &amp; Sarrantonio, M. Legume-based cropping systems have reduced carbon and nitrogen losses. Nature 396, 262–265 (1998)" href="https://www.nature.com/articles/nature15743#ref-CR76" id="ref-link-section-d27879965e2999">76</a></sup>. In contrast, US soybean production has been growing and now accounts for about 30% of the harvested area for crop production (excluding land devoted to production of grasses or crops for feeding livestock) in the USA. While fertilizer subsidies in China probably account for much of the low NUE there, our analysis shows that the difference in crop mix also accounts for nearly half of the NUE difference between China and USA (<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig4">Fig. 4b</a>).</p>
<p>To address this issue globally, we tested the relationship between NUE and the fraction of harvested area for fruits and vegetables with a fixed effects model for the 113 countries (<a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM46">Supplementary Table 11</a>). The fraction of harvested area for fruit and vegetable production negatively correlates with NUE, and that relationship is still significant (<i>P </i>&lt; 0.001) even after adjusting for the effect of GDP per capita.</p>
</div>
</div>
</section>
<section data-title="Meeting the growing challenge" data-gtm-vis-first-on-screen50443292_563="16319" data-gtm-vis-total-visible-time50443292_563="9100" data-gtm-vis-polling-id50443292_563="5206" data-gtm-vis-recent-on-screen50443292_563="71846">
<div class="c-article-section" id="Sec6-section">
<h2 class="c-article-section__title js-section-title js-c-reading-companion-sections-item" id="Sec6">Meeting the growing challenge</h2>
<div class="c-article-section__content" id="Sec6-content">
<p>Agriculture is currently facing unprecedented challenges globally. On one hand, crop production needs to increase by about 60%–100% from 2007 to 2050 to meet global food demand<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 3" title="Alexandratos, N. &amp; Bruinsma, J. World Agriculture towards 2030/2050: the 2012 Revision. Agricultural Development Economics Division of the Economic and Social Development Department Working Paper No. 12-03, 
                  http://www.fao.org/docrep/016/ap106e/ap106e.pdf
                  
                 (Food and Agriculture Organization of the United Nations, 2012)" href="https://www.nature.com/articles/nature15743#ref-CR3" id="ref-link-section-d27879965e3024">3</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 77" title="Searchinger, T. et al. Creating a Sustainable Food Future: a Menu of Solutions to Sustainably Feed more than 9 billion people by 2050. World Resources Report 2013-14, Interim Findings (World Resources Institute, 2013)" href="https://www.nature.com/articles/nature15743#ref-CR77" id="ref-link-section-d27879965e3027">77</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 78" title="Bodirsky, B. L. et al. Reactive nitrogen requirements to feed the world in 2050 and potential to mitigate nitrogen pollution. Nature Commun. 5, 3858 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR78" id="ref-link-section-d27879965e3030">78</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 79" title="Tilman, D., Balzer, C., Hill, J. &amp; Befort, B. L. Global food demand and the sustainable intensification of agriculture. Proc. Natl Acad. Sci. USA 108, 20260–20264 (2011)" href="https://www.nature.com/articles/nature15743#ref-CR79" id="ref-link-section-d27879965e3033">79</a></sup>. On the other hand, anthropogenic reactive N input to the biosphere has already exceeded a proposed planetary boundary<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 5" title="Steffen, W. et al. Planetary boundaries: guiding human development on a changing planet. Science 347, 6223 (2015). This paper provides the most recent updates on the research under the planetary boundaries framework." href="https://www.nature.com/articles/nature15743#ref-CR5" id="ref-link-section-d27879965e3037">5</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 80" title="de Vries, W., Kros, J., Kroeze, C. &amp; Seitzinger, S. P. Assessing planetary and regional nitrogen boundaries related to food security and adverse environmental impacts. Curr. Opin. Environ. Sustain. 5, 392–402 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR80" id="ref-link-section-d27879965e3040">80</a></sup>, and the increasing demand for food and biofuel is likely to drive up N inputs even further. Therefore, it is critical to establish global and national goals for N use in crop production and to use those goals as reference points to evaluate progress made and guide NUE improvement.</p>
<h3 class="c-article__sub-heading" id="Sec7">Global and national goals</h3>
<p>The planetary boundary for human use of reactive N that can be tolerated without causing unsustainable air and water pollution has been defined in mainly two ways: (1) as the maximum allowable amount of anthropogenic newly fixed N in agriculture that can be introduced into the earth system (62–82 Tg N yr<sup>−1</sup>)<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 5" title="Steffen, W. et al. Planetary boundaries: guiding human development on a changing planet. Science 347, 6223 (2015). This paper provides the most recent updates on the research under the planetary boundaries framework." href="https://www.nature.com/articles/nature15743#ref-CR5" id="ref-link-section-d27879965e3053">5</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 80" title="de Vries, W., Kros, J., Kroeze, C. &amp; Seitzinger, S. P. Assessing planetary and regional nitrogen boundaries related to food security and adverse environmental impacts. Curr. Opin. Environ. Sustain. 5, 392–402 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR80" id="ref-link-section-d27879965e3056">80</a></sup>, and (2) as the maximum allowable<span> </span><i>N</i><sub>sur</sub><span> </span>released from agricultural production to the environment.</p>
<p>Calculations of planetary boundaries according to the first definition require assumptions about nutrient-use efficiency in agriculture. As NUE increases, more N inputs would be manageable while still remaining within air and water pollution limits because more applied N would be taken up by harvested crops. Therefore, rather than focusing on a planetary boundary of allowable newly fixed N, which varies depending on the NUE assumption, we follow the second approach, by estimating what NUE would be needed to produce the food demand projected for 2050 (ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 3" title="Alexandratos, N. &amp; Bruinsma, J. World Agriculture towards 2030/2050: the 2012 Revision. Agricultural Development Economics Division of the Economic and Social Development Department Working Paper No. 12-03, 
                  http://www.fao.org/docrep/016/ap106e/ap106e.pdf
                  
                 (Food and Agriculture Organization of the United Nations, 2012)" href="https://www.nature.com/articles/nature15743#ref-CR3" id="ref-link-section-d27879965e3066">3</a>;<span> </span><a data-track="click" data-track-label="link" data-track-action="table anchor" href="https://www.nature.com/articles/nature15743#Tab1">Table 1</a>) while keeping<span> </span><i>N</i><sub>sur</sub><span> </span>within the bounds estimated for acceptable air and water quality. Over 60% of N pollution is estimated to originate from crop production<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 78" title="Bodirsky, B. L. et al. Reactive nitrogen requirements to feed the world in 2050 and potential to mitigate nitrogen pollution. Nature Commun. 5, 3858 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR78" id="ref-link-section-d27879965e3077">78</a></sup>, so this is the primary sector that must be addressed to reduce N pollution. From an analysis of the implications of N cycling in several “shared socio-economic pathways”<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 81" title="Nakicenovic, N. &amp; Swart, R. (eds) IPCC Special Report on Emissions Scenarios (Cambridge Univ. Press, 2000)" href="https://www.nature.com/articles/nature15743#ref-CR81" id="ref-link-section-d27879965e3081">81</a></sup>, Bodirsky<span> </span><i>et al</i>. (ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 78" title="Bodirsky, B. L. et al. Reactive nitrogen requirements to feed the world in 2050 and potential to mitigate nitrogen pollution. Nature Commun. 5, 3858 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR78" id="ref-link-section-d27879965e3088">78</a>) calculated that global agricultural<span> </span><i>N</i><sub>sur</sub><span> </span>should not exceed about 50–100 Tg N yr<sup>−1</sup>. Therefore, we use 50 Tg N yr<sup>−1</sup><span> </span>as an estimate of the global limit of<span> </span><i>N</i><sub>sur</sub><span> </span>from crop production.</p>
<p>Meeting the 2050 food demand of 107 Tg N yr<sup>−1</sup><span> </span>projected by the Food and Agriculture Organization (FAO, ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 3" title="Alexandratos, N. &amp; Bruinsma, J. World Agriculture towards 2030/2050: the 2012 Revision. Agricultural Development Economics Division of the Economic and Social Development Department Working Paper No. 12-03, 
                  http://www.fao.org/docrep/016/ap106e/ap106e.pdf
                  
                 (Food and Agriculture Organization of the United Nations, 2012)" href="https://www.nature.com/articles/nature15743#ref-CR3" id="ref-link-section-d27879965e3109">3</a>) while reducing<span> </span><i>N</i><sub>sur</sub><span> </span>from the current 100 Tg N yr<sup>−1</sup><span> </span>to a global limit of 50 Tg N yr<sup>−1</sup><span> </span>(ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 78" title="Bodirsky, B. L. et al. Reactive nitrogen requirements to feed the world in 2050 and potential to mitigate nitrogen pollution. Nature Commun. 5, 3858 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR78" id="ref-link-section-d27879965e3121">78</a>) requires very large across-the-board increases in NUE. Globally, NUE would increase from ~0.4 to ~0.7, while the crop yield would increase from 74 Tg N yr<sup>−1</sup><span> </span>to 107 Tg N yr<sup>−1</sup><span> </span>(<a data-track="click" data-track-label="link" data-track-action="table anchor" href="https://www.nature.com/articles/nature15743#Tab1">Table 1</a>). Recognizing regional differences in crop production and development stage, this average could be achieved if average NUE rose to 0.75 in the EU and USA, to 0.60 in China and the rest of Asia (assuming they continue to have a high proportion of fruits and vegetables in their crop mix), and to 0.70 in other countries, including not dropping below 0.70 in sub-Saharan Africa as it develops (<a data-track="click" data-track-label="link" data-track-action="table anchor" href="https://www.nature.com/articles/nature15743#Tab1">Table 1</a>). Similarly, NUE targets could be established for individual crops, such as improving the global average from 0.14 to 0.40 for fruits and vegetables, and increasing the global average NUE for maize from 0.50 to 0.70 (<a data-track="click" data-track-label="link" data-track-action="table anchor" href="https://www.nature.com/articles/nature15743#Tab1">Table 1</a>).</p>
<p>The challenges in achieving these ambitious goals differ among countries.<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig5">Figure 5</a><span> </span>shows the trajectories of major crop producing countries on the yield–NUE map for the last five decades. The<span> </span><i>x</i><span> </span>and<span> </span><i>y</i><span> </span>axes show the two efficiency terms in crop production, NUE and<span> </span><i>N</i><sub>yield</sub>, while the greyscale displays<span> </span><i>N</i><sub>sur</sub>. To compare the nationally averaged field-scale (in units of kg N ha<sup>−1</sup><span> </span>yr<sup>−1</sup>)<span> </span><i>N</i><sub>sur</sub><span> </span>in<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig5">Fig. 5</a><span> </span>to a global limit of 50–100 Tg N yr<sup>−1</sup>, the global average<span> </span><i>N</i><sub>sur</sub><span> </span>target would need to be 39–78 kg N ha<sup>−1</sup><span> </span>yr<sup>−1</sup><span> </span>across the 2010 harvested area of 1.3 billion hectares. For the examples shown, the USA, France, and Brazil appear to be on this trajectory, although further progress is still needed. In contrast, China and India not only have not yet found an EKC turning point, but also have much ground to make up to reduce their<span> </span><i>N</i><sub>sur</sub><span> </span>once they turn the corner on their EKC. Although a great challenge, this could also be seen as an opportunity to reduce fertilizer expenditures while increasing agricultural productivity. Malawi, like many sub-Saharan African countries and other least developed countries, has been on a classic downward trajectory of decreasing NUE as it has started to increase N inputs, although evidence from recent years suggests that this decline may have reversed, which would be a necessary first step to tunnelling through the EKC (<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig5">Fig. 5</a>).</p>
<div class="c-article-section__figure js-c-reading-companion-figures-item" data-test="figure" data-container-section="figure" id="figure-5" data-title="Historical trends of Nyield, NUE and Nsur, for a sample of countries examined in this study.">
<figure>
<figcaption><b id="Fig5" class="c-article-section__figure-caption" data-test="figure-caption-text">Figure 5: Historical trends of<span> </span><i>N</i><sub>yield</sub>, NUE and<span> </span><i>N</i><sub>sur</sub>, for a sample of countries examined in this study.</b></figcaption>
<div class="c-article-section__figure-content">
<div class="c-article-section__figure-item"><a class="c-article-section__figure-link" data-test="img-link" data-track="click" data-track-label="image" data-track-action="view figure" href="https://www.nature.com/articles/nature15743/figures/5" rel="nofollow"><picture><source type="image/webp" srcset="//media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig5_HTML.jpg?as=webp"><img aria-describedby="Fig5" src="https://media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fnature15743/MediaObjects/41586_2015_Article_BFnature15743_Fig5_HTML.jpg" alt="figure 5" loading="lazy" width="685" height="547"></picture></a></div>
<div class="c-article-section__figure-description" data-test="bottom-caption" id="figure-5-desc">
<p>The greyscale shows the level of<span> </span><i>N</i><sub>sur</sub>. The area covered in red indicates negative<span> </span><i>N</i><sub>sur</sub>, where the crop production is mining soil N. The data have been smoothed by ten years to limit the impact of year-to-year variation in weather conditions. Curves moving towards the lower right indicate that those countries are achieving yield increases by sacrificing NUE and increasing<span> </span><i>N</i><sub>sur</sub>, whereas curves moving towards the upper right indicate countries achieving yield increases by increasing NUE and resulting in steady or decreasing<span> </span><i>N</i><sub>sur</sub>.</p>
<p><a data-track="click" data-track-label="link" data-track-action="supplementary material anchor" href="https://www.nature.com/articles/nature15743#MOESM45">PowerPoint slide</a></p>
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<h3 class="c-article__sub-heading" id="Sec8">Achieving NUE targets</h3>
<p>Achieving ambitious NUE targets while also increasing yields to meet future food demands requires implementation of technologies and management practices at the farm scale, which has been described widely and in considerable detail in the agricultural, environmental, and development literature<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 17" title="Newell Price, J. et al. An Inventory of Mitigation Methods and Guide to their Effects on Diffuse Water Pollution, Greenhouse Gas Emissions and Ammonia Emissions from Agriculture. 
                  http://www.avondtc.org.uk/Portals/0/Farmscoper/DEFRA%20user%20guide.pdf
                  
                 (Defra Project WQ0106, ADAS and Rothamsted Research North Wyke, 2011)" href="https://www.nature.com/articles/nature15743#ref-CR17" id="ref-link-section-d27879965e3249">17</a></sup>. Some common principles include the ‘4Rs’ approach of applying the right source, at the right rate, at the right time, in the right place<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 34" title="Snyder, C., Davidson, E., Smith, P. &amp; Venterea, R. Agriculture: sustainable crop and animal production to help mitigate nitrous oxide emissions. Curr. Opin. Environ. Sustain. 9–10, 46–54 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR34" id="ref-link-section-d27879965e3253">34</a></sup>. However, the technologies and management practices needed to achieve the 4Rs vary regionally depending on the local cropping systems, soil types, climate and socio-economic situations. Where improvements in plant breeding, irrigation, and application of available 4R technologies have already made large gains, new technological developments may be needed to achieve further gains, such as more affordable slow-release fertilizers, nitrification and urease inhibitors, fertigation (that is, applying fertilizer via irrigation water), and high-tech approaches to precision agriculture<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 58" title="Ferguson, R. B. Groundwater quality and nitrogen use efficiency in Nebraska’s Central Platte River valley. J. Environ. Qual. 44, 449–459 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR58" id="ref-link-section-d27879965e3257">58</a></sup>.</p>
<p>It is promising that the development and the combination of information technology, remote sensing, and ground measurements will make information about precision farming more readily available, accessible, affordable and site-specific<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 82" title="Mulla, D. J. Twenty five years of remote sensing in precision agriculture: key advances and remaining knowledge gaps. Biosystems Eng. 114, 358–371 (2013)" href="https://www.nature.com/articles/nature15743#ref-CR82" id="ref-link-section-d27879965e3264">82</a></sup>. In many cases, large gains could still be made with more widespread adoption of existing technologies, but a myriad of social and economic factors affecting farmer decision-making regarding nutrient management have only recently begun to receive attention and are critical in improving NUE (ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 15" title="Davidson, E. A., Suddick, E. C., Rice, C. W. &amp; Prokopy, L. S. More food, low pollution (Mo Fo Lo Po): a grand challenge for the 21st century. J. Environ. Qual. 44, 305–311 (2015). This paper reports outcomes of an interdisciplinary conference on the technical, social, and economic impediments to improving NUE in crop and animal production systems, and it introduces a series of papers addressing this issue." href="https://www.nature.com/articles/nature15743#ref-CR15" id="ref-link-section-d27879965e3267">15</a>). Socio-economic impediments, often related to cost and perceived risk, as well as lack of trust in recommendations by agricultural extension agents, often discourage farmers from adopting improved nutrient management practices<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 59" title="Osmond, D. L., Hoag, D. L., Luloff, A. E., Meals, D. W. &amp; Neas, K. Farmers’ use of nutrient management: lessons from watershed case studies. J. Environ. Qual. 44, 382–390 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR59" id="ref-link-section-d27879965e3271">59</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 60" title="Perez, M. R. Regulating farmer nutrient management: a three-state case study on the Delmarva Peninsula. J. Environ. Qual. 44, 402–414 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR60" id="ref-link-section-d27879965e3274">60</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 83" title="David, M. B. et al. Navigating the socio-bio-geo-chemistry and engineering of nitrogen management in two Illinois tile-drained watersheds. J. Environ. Qual. 44, 368–381 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR83" id="ref-link-section-d27879965e3277">83</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 84" title="Weber, C. &amp; McCann, L. Adoption of nitrogen-efficient technologies by US corn farmers. J. Environ. Qual. 44, 391–410 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR84" id="ref-link-section-d27879965e3280">84</a></sup>. Experience has shown that tailoring regulations, incentives, and outreach to local conditions, administered and enforced by local entities, and supported by trust established among local stakeholders improve the success of efforts designed to increase NUE (ref.<span> </span><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 15" title="Davidson, E. A., Suddick, E. C., Rice, C. W. &amp; Prokopy, L. S. More food, low pollution (Mo Fo Lo Po): a grand challenge for the 21st century. J. Environ. Qual. 44, 305–311 (2015). This paper reports outcomes of an interdisciplinary conference on the technical, social, and economic impediments to improving NUE in crop and animal production systems, and it introduces a series of papers addressing this issue." href="https://www.nature.com/articles/nature15743#ref-CR15" id="ref-link-section-d27879965e3283">15</a>).</p>
<p>Although much of the work must be done at the farm scale, there are important policies that should be implemented on national and multi-national scales. First, improving NUE should be adopted as one of the indicators of the Sustainable Development Goals<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 16" title="Leadership Council of the Sustainable Development Solutions Network (SDSN). Indicators and a Monitoring Framework for Sustainable Development Goals—Revised Working Draft, 16 January 2015. 
                  http://unsdsn.org/resources
                  
                 (SDSN, 2015)" href="https://www.nature.com/articles/nature15743#ref-CR16" id="ref-link-section-d27879965e3290">16</a></sup><span> </span>and should be used in conjunction with crop yield and perhaps other soil health parameters to measure the sustainability of agricultural development. To report reliably on a NUE indicator, countries should be strongly encouraged to collect data routinely on their N management in crop and livestock production. These data should be used to trace trajectories of the three indices of agricultural N pollution, agricultural efficiency and food security targets (that is,<span> </span><i>N</i><sub>sur</sub>, NUE and<span> </span><i>N</i><sub>yield</sub>), as we have done here (<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig5">Fig. 5</a>) to demonstrate where progress is being made and where stronger local efforts are needed. The data used to construct<span> </span><a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig5">Fig. 5</a><span> </span>have served to demonstrate trends, but both improved data quality and international harmonization of data standards are needed. Regular attention should be given to these trends to establish national and local targets and policies. Just as protocols established by the Intergovernmental Panel on Climate Change permit nations to gauge their progress and commitment for reducing greenhouse gas emissions, protocols for measuring and reporting on a Sustainable Development Goal pertaining to NUE could enable governments to assess their progress in achieving food security goals while maintaining environmental quality.</p>
<p>Second, nutrient management in livestock operations and human dietary choices needs more attention. Here we have focused entirely on crop production, largely because of availability of data, but the<span> </span><i>N</i><sub>sur</sub>, NUE and<span> </span><i>N</i><sub>yield</sub><span> </span>indices are equally important in livestock management<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 85" title="Powell, J., Gourley, C., Rotz, C. &amp; Weaver, D. Nitrogen use efficiency: a potential performance indicator and policy tool for dairy farms. Environ. Sci. Policy 13, 217–228 (2010)" href="https://www.nature.com/articles/nature15743#ref-CR85" id="ref-link-section-d27879965e3320">85</a></sup>. Indeed, soybeans and some cereals have high NUE as crops, but when fed to livestock, efficient recycling of the N in manure is challenging, resulting in lower integrated NUE for the crop–livestock production system<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 86" title="Powell, J. &amp; Rotz, C. Measures of nitrogen use efficiency and nitrogen loss from dairy production systems. J. Environ. Qual. 44, 336–344 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR86" id="ref-link-section-d27879965e3324">86</a></sup>. The crop production scenario used here for 2050 (<a data-track="click" data-track-label="link" data-track-action="table anchor" href="https://www.nature.com/articles/nature15743#Tab1">Table 1</a>) makes assumptions about future dietary choices<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 3" title="Alexandratos, N. &amp; Bruinsma, J. World Agriculture towards 2030/2050: the 2012 Revision. Agricultural Development Economics Division of the Economic and Social Development Department Working Paper No. 12-03, 
                  http://www.fao.org/docrep/016/ap106e/ap106e.pdf
                  
                 (Food and Agriculture Organization of the United Nations, 2012)" href="https://www.nature.com/articles/nature15743#ref-CR3" id="ref-link-section-d27879965e3332">3</a></sup>, which are beyond the scope of this study, but we note that future trends in diet will affect the demand for crop and livestock products, the crop mixes grown, and hence the NUE and<span> </span><i>N</i><sub>sur</sub><span> </span>of future agricultural systems<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 72" title="Billen, G., Lassaletta, L. &amp; Garnier, J. A vast range of opportunities for feeding the world in 2050: trade-off between diet, N contamination and international trade. Environ. Res. Lett. 10, 025001 (2015)" href="https://www.nature.com/articles/nature15743#ref-CR72" id="ref-link-section-d27879965e3340">72</a></sup>.</p>
<p>Third, a similar approach to efficiency analysis would also be valuable for phosphorus (P) fertilizer management, interactions of N and P management, and reducing both N and P loading into aquatic ecosystems<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 87" title="MacDonald, G. K., Bennett, E. M., Potter, P. A. &amp; Ramankutty, N. Agronomic phosphorus imbalances across the world’s croplands. Proc. Natl Acad. Sci. USA 108, 3086–3091 (2011)" href="https://www.nature.com/articles/nature15743#ref-CR87" id="ref-link-section-d27879965e3348">87</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 88" title="MacDonald, G. K., Bennett, E. M. &amp; Taranu, Z. E. The influence of time, soil characteristics, and land-use history on soil phosphorus legacies: a global meta-analysis. Glob. Change Biol. 18, 1904–1917 (2012)" href="https://www.nature.com/articles/nature15743#ref-CR88" id="ref-link-section-d27879965e3351">88</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 89" title="Cordell, D., Drangert, J.-O. &amp; White, S. The story of phosphorus: global food security and food for thought. Glob. Environ. Change 19, 292–305 (2009)" href="https://www.nature.com/articles/nature15743#ref-CR89" id="ref-link-section-d27879965e3354">89</a>,<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 90" title="Schoumans, O. et al. Mitigation options to reduce phosphorus losses from the agricultural sector and improve surface water quality: a review. Sci. Total Environ. 468–469, 1255–1266 (2014)" href="https://www.nature.com/articles/nature15743#ref-CR90" id="ref-link-section-d27879965e3357">90</a></sup>.</p>
<p>Fourth, national and international communities should facilitate technology transfer and promote agricultural innovation. Stronger international collaborations and investments in research, extension and human resources are urgently needed so that knowledge and experience can be shared, creating political and market environments that help to incentivize the development and implementation of more efficient technologies. Technology transfer and capacity building will be needed to enable sub-Saharan African countries to tunnel through the EKC (<a data-track="click" data-track-label="link" data-track-action="figure anchor" href="https://www.nature.com/articles/nature15743#Fig5">Fig. 5</a>).</p>
<p>These solutions to improving NUE will require cross-disciplinary and cross-sectorial partnerships, such as: (1) integrating research and development of innovative agricultural technology and management systems with socio-economic research and the outreach needed for such innovations to be socially and economically viable and readily adopted by farmers; (2) analysing the nexus of food, water, nutrients and energy management to avoid pollution swapping (a measure designed to address one pollution problem leads to another; for example, retaining crop residues can reduce nitrogen runoff, but may lead to higher N<sub>2</sub>O emission<sup><a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 91" title="Stevens, C. J. &amp; Quinton, J. N. Diffuse pollution swapping in arable agricultural systems. Crit. Rev. Environ. Sci. Technol. 39, 478–520 (2009)" href="https://www.nature.com/articles/nature15743#ref-CR91" id="ref-link-section-d27879965e3372">91</a></sup>) and to optimize the net benefits to farmers, the environment and society; (3) promoting knowledge and data sharing among private and public sectors to advance science-based nutrient management; and (4) training the next generation of interdisciplinary agronomic and environmental scientists equipped with broad perspectives and skills pertaining to food, water, energy and environment issues.</p>
<p>The EKC has often been described as an optimist’s view of a world with declining environmental degradation. Here we have shown that there is evidence—indeed, there is hope—for the EKC pattern of declining N pollution with improving efficiencies in agriculture. However, we have also shown that continuation of the progress made so far is neither inevitable nor is it sufficient to achieve the projected 2050 goals of both food security and environmental stewardship. Turning points and trajectories of national agricultural EKCs will depend largely on agricultural, economic, environmental, educational and trade policies, and these will largely dictate the food and pollution outputs of future agriculture.</p>
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<title>Recent advances and sustainable development of biofuels production from lignocellulosic biomass</title>
<link>https://sdgtalks.ai/recent-advances-and-sustainable-development-of-biofuels-production-from-lignocellulosic-biomass</link>
<guid>https://sdgtalks.ai/recent-advances-and-sustainable-development-of-biofuels-production-from-lignocellulosic-biomass</guid>
<description><![CDATA[ The advances in the biofuel generation using lignocellulosic biomass is discussed in detail. ]]></description>
<enclosure url="https://encrypted-tbn0.gstatic.com/images" length="49398" type="image/jpeg"/>
<pubDate>Tue, 23 Jan 2024 18:14:13 -0500</pubDate>
<dc:creator>njvahlberg</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<div class="abstract author" id="ab015" lang="en">
<h2 class="section-title u-h4 u-margin-l-top u-margin-xs-bottom">Abstract</h2>
<div id="as015">
<p id="sp0015">Many countries in the world are facing the demand for non-renewable fossil fuels because of overpopulation and economic boom. To reduce environmental pollution and zero carbon emission, the conversion of biomass into biofuels has paid better attention and is considered to be an innovative approach. A diverse raw material has been utilized as feedstock for the production of biofuel, depending on the availability of biomass, cost-effectiveness, and their geographic location. Among the different raw materials, lignocellulosic biomass has fascinated many researchers around the world. The current review discovers the potential application of lignocellulosic biomass for the production of biofuels. Various pretreatment methods have been widely used to increase the hydrolysis rate and accessibility of biomass. This review highlights recent advances in pretreatment methodologies for the enhanced production of biofuels. Detailed descriptions of the mechanism of biomass processing pathway, optimization, and modeling study have been discussed.</p>
</div>
</div>
<div class="abstract graphical" id="ab005" lang="en">
<h2 class="section-title u-h4 u-margin-l-top u-margin-xs-bottom">Graphical abstract</h2>
<div id="as005">
<p id="sp0005"><span class="display"></span></p>
<figure class="figure text-xs" id="f0015"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0960852421015455-ga1.jpg" height="244" alt=""></span></figure>
<p><span></span></p>
<section id="s0005">
<h2 id="st025" class="u-h4 u-margin-l-top u-margin-xs-bottom">1.<span> </span>Introduction</h2>
<p id="p0025"><span>Biomass is one of the most ample and sustainable carbon sources on the planet. Agricultural <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/crop-residue" title="Learn more about crop residues from ScienceDirect's AI-generated Topic Pages" class="topic-link">crop residues</a>, algae, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/forestry" title="Learn more about forestry from ScienceDirect's AI-generated Topic Pages" class="topic-link">forestry</a> residues, wood <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/processing-residues" title="Learn more about processing residues from ScienceDirect's AI-generated Topic Pages" class="topic-link">processing residues</a> are the major biomass sources for the production of bio-energy. In terms of application-oriented <a href="https://www.sciencedirect.com/topics/engineering/downstream-processing" title="Learn more about downstream processing from ScienceDirect's AI-generated Topic Pages" class="topic-link">downstream processing</a> of biomass products, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/lignocellulose" title="Learn more about lignocellulose from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignocellulose</a> has shown to be a preferable option. Lignocellulose is a <a href="https://www.sciencedirect.com/topics/engineering/complex-matrix" title="Learn more about complex matrix from ScienceDirect's AI-generated Topic Pages" class="topic-link">complex matrix</a> made up of a thick lignin and <a href="https://www.sciencedirect.com/topics/engineering/hemicellulose" title="Learn more about hemicellulose from ScienceDirect's AI-generated Topic Pages" class="topic-link">hemicellulose</a> structure that wraps around the <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/cellulose" title="Learn more about cellulose from ScienceDirect's AI-generated Topic Pages" class="topic-link">cellulose</a> molecules (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0385" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0385"><span class="anchor-text">Ma et al., 2019</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0240" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0240"><span class="anchor-text">Isikgor and Becer, 2015</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0170" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0170"><span class="anchor-text">Fan et al., 2021</span></a><span>). The residual portion of lignocellulosic biomass is made up of <a href="https://www.sciencedirect.com/topics/engineering/extractives" title="Learn more about extractives from ScienceDirect's AI-generated Topic Pages" class="topic-link">extractives</a> such as oil, ash and proteins. <a href="https://www.sciencedirect.com/topics/engineering/lignocellulosics" title="Learn more about Lignocellulosics from ScienceDirect's AI-generated Topic Pages" class="topic-link">Lignocellulosics</a> are a biotechnologically valuable substrate due to the chemical attributes of its constituents. These lignocellulose materials are high in energy compounds and may be utilised as raw materials in a variety of industries. <a href="https://www.sciencedirect.com/topics/engineering/bioconversion" title="Learn more about Bioconversion from ScienceDirect's AI-generated Topic Pages" class="topic-link">Bioconversion</a> of specific constituents from lignocellulosic wastes has been used in bio refining to produce a variety of bio-products. Lignocellulosic bio-refinery consists of two different types of conversions (i) sugar (Fermentation of sugars obtained from the biomass) and (ii) syngas/thermochemical conversion (gasification of biomass to produce syngas) (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0365" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0365"><span class="anchor-text">Liu et al., 2020</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0670" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0670"><span class="anchor-text">Zhang et al., 2020a</span></a><span>). In sugar fermentation, lignocellulosic components are transformed into biofuels and <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/bioproducts" title="Learn more about bioproducts from ScienceDirect's AI-generated Topic Pages" class="topic-link">bioproducts</a>. On the other hand, <a href="https://www.sciencedirect.com/topics/engineering/syngas" title="Learn more about syngas from ScienceDirect's AI-generated Topic Pages" class="topic-link">syngas</a> or <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/thermochemical" title="Learn more about thermochemical from ScienceDirect's AI-generated Topic Pages" class="topic-link">thermochemical</a> conversion, converts biomass into useful substrates for downstream fermentation. Organic acids, <a href="https://www.sciencedirect.com/topics/engineering/biopolymer" title="Learn more about biopolymers from ScienceDirect's AI-generated Topic Pages" class="topic-link">biopolymers</a>, proteins, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/biofertilizer" title="Learn more about biofertilizers from ScienceDirect's AI-generated Topic Pages" class="topic-link">biofertilizers</a>, composites, industrial <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/lysozyme" title="Learn more about enzymes from ScienceDirect's AI-generated Topic Pages" class="topic-link">enzymes</a> and biofuels are among the products of lignocellulose bioconversion (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0160" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0160"><span class="anchor-text">Dietrich et al., 2018</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0030" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0030"><span class="anchor-text">Arevalo-Gallegos et al., 2017</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0300" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0300"><span class="anchor-text">Kumar et al., 2015</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0145" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0145"><span class="anchor-text">Laure et al., 2021</span></a>).</p>
<p id="p0030"><span>In recent years, global economic development has raised energy demand more than consumption. Excessive use of fossil fuels has resulted in price hikes and <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/greenhouse-gas-emission" title="Learn more about greenhouse gas emissions from ScienceDirect's AI-generated Topic Pages" class="topic-link">greenhouse gas emissions</a> that were not anticipated. All of these flaws in fossil fuels, together with their rapid depletion, have promoted the concept of alternate, inexpensive and <a href="https://www.sciencedirect.com/topics/engineering/renewable-energy-source" title="Learn more about renewable energy sources from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable energy sources</a> like biofuels (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0305" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0305"><span class="anchor-text">Kumar et al., 2020</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0310" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0310"><span class="anchor-text">Kumari and Singh, 2018</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0445" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0445"><span class="anchor-text">Moshood et al., 2021</span></a><span>). From a strategic view point, biofuels are one of the most significant <a href="https://www.sciencedirect.com/topics/engineering/renewable-fuel" title="Learn more about renewable fuel from ScienceDirect's AI-generated Topic Pages" class="topic-link">renewable fuel</a> sources. Biochar, fuelwood, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/biodiesel" title="Learn more about biodiesel from ScienceDirect's AI-generated Topic Pages" class="topic-link">biodiesel</a>, alcohols – methanol, ethanol, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/butanol" title="Learn more about butanol from ScienceDirect's AI-generated Topic Pages" class="topic-link">butanol</a>, <a href="https://www.sciencedirect.com/topics/engineering/biomethane" title="Learn more about biomethane from ScienceDirect's AI-generated Topic Pages" class="topic-link">biomethane</a> and <a href="https://www.sciencedirect.com/topics/engineering/biohydrogen" title="Learn more about biohydrogen from ScienceDirect's AI-generated Topic Pages" class="topic-link">biohydrogen</a> are just a few of the solid, gaseous, and <a href="https://www.sciencedirect.com/topics/engineering/liquid-biofuels" title="Learn more about liquid biofuels from ScienceDirect's AI-generated Topic Pages" class="topic-link">liquid biofuels</a> produced from bio-sourced <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/feedstock" title="Learn more about feedstocks from ScienceDirect's AI-generated Topic Pages" class="topic-link">feedstocks</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0280" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0280"><span class="anchor-text">Ko et al., 2020</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0590" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0590"><span class="anchor-text">Soltanian et al., 2020</span></a><span>). <a href="https://www.sciencedirect.com/topics/engineering/second-generation-biofuels" title="Learn more about Second generation biofuels from ScienceDirect's AI-generated Topic Pages" class="topic-link">Second generation biofuels</a> made from lignocellulose biomass are the most favourable of the four generations owing to their relative abundance, eco-friendliness, economic sustainability and zero <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/carbon-dioxide-emission" title="Learn more about carbon emissions from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbon emissions</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0350" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0350"><span class="anchor-text">Lin and Lu, 2021</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0360" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0360"><span class="anchor-text">Liu and Qu, 2018</span></a>).</p>
<p id="p0035"><span>Complex lignocellulose structures possess recalcitrant character inhibiting their breakdown for generating useful products. Lignin, in particular, is a major physical barrier that obstructs the enzymatic breakdown process. As a result, an appropriate pretreatment approach is required to maximise the <a href="https://www.sciencedirect.com/topics/engineering/deconstruction" title="Learn more about deconstruction from ScienceDirect's AI-generated Topic Pages" class="topic-link">deconstruction</a> of complicated structures (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0500" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0500"><span class="anchor-text">Prasad et al., 2019</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0475" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0475"><span class="anchor-text">Oliveira et al., 2019a</span></a><span>). Pretreatment procedures modify the chemical content and macromolecular structure of the material, making it more vulnerable to subsequent degradation or <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/enzymatic-hydrolysis" title="Learn more about hydrolysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrolysis</a>. Pretreatment is the major unit operation in lignocellulose <a href="https://www.sciencedirect.com/topics/engineering/biorefineries" title="Learn more about biorefinery from ScienceDirect's AI-generated Topic Pages" class="topic-link">biorefinery</a> and accounts for about 20% of total capital investment. In the industrial scale, pretreatment is quite expensive among the several processes involved in biorefinery process. Physical, chemical, physicochemical, and <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/biological-phenomena-and-functions-concerning-the-entire-organism" title="Learn more about biological processes from ScienceDirect's AI-generated Topic Pages" class="topic-link">biological processes</a> are among the pretreatment strategies now in practice. Each pretreatment process has its own set of benefits and drawbacks (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0020" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0020"><span class="anchor-text">Amin et al., 2017</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0540" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0540"><span class="anchor-text">Roy et al., 2020</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0625" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0625"><span class="anchor-text">Veluchamy et al., 2018</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0455" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0455"><span class="anchor-text">Mulyaningtyas and Sediawan, 2019</span></a>).</p>
<p id="p0040"><span><a href="https://www.sciencedirect.com/topics/engineering/metabolic-engineering" title="Learn more about Metabolic engineering from ScienceDirect's AI-generated Topic Pages" class="topic-link">Metabolic engineering</a> and genetic engineering has recognized as important tools to improvement in the hydrolysis and fermentation process, and wide range of substrate utilization. (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0195" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0195"><span class="anchor-text">Ghag et al., 2019</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0700" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0700"><span class="anchor-text">Zhou et al., 2021</span></a><span>). <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/micro-organism" title="Learn more about Microorganisms from ScienceDirect's AI-generated Topic Pages" class="topic-link">Microorganisms</a> may now alter <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/anabolism" title="Learn more about biosynthetic pathways from ScienceDirect's AI-generated Topic Pages" class="topic-link">biosynthetic pathways</a> to produce more enzymes because of advances in molecular and <a href="https://www.sciencedirect.com/topics/engineering/synthetic-biology" title="Learn more about synthetic biology from ScienceDirect's AI-generated Topic Pages" class="topic-link">synthetic biology</a>. Manipulations like as <a href="https://www.sciencedirect.com/topics/engineering/overexpression" title="Learn more about overexpression from ScienceDirect's AI-generated Topic Pages" class="topic-link">overexpression</a> of genes, <a href="https://www.sciencedirect.com/topics/engineering/enzyme-engineering" title="Learn more about enzyme engineering from ScienceDirect's AI-generated Topic Pages" class="topic-link">enzyme engineering</a>, <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/gene-knockout" title="Learn more about gene knockout from ScienceDirect's AI-generated Topic Pages" class="topic-link">gene knockout</a>, and gene insertion targeting are successful in regulating pathways of interest in the metabolic engineering method. Through this, microbes would acquire intracellular and intercellular signal processing capabilities with pathway expression control, allowing gene regulation and expression to be coordinated for maximum output (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0085" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0085"><span class="anchor-text">Brar et al., 2021</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0250" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0250"><span class="anchor-text">Jin and Cate, 2017</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0655" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0655"><span class="anchor-text">Yao and Shimizu, 2013</span></a><span>). By providing relevant information that can be utilised for analysis, design, and operation of any fermentation process, the model may effectively represent the interaction among the numerous state variables and quantitatively explain the behaviour of fermentation. For determining the behaviour of <a href="https://www.sciencedirect.com/topics/engineering/generation-biofuels" title="Learn more about biofuel generation from ScienceDirect's AI-generated Topic Pages" class="topic-link">biofuel generation</a> from lignocellulose, some models use only two to three factors, while others consider a variety of structural and compositional characteristics (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0440" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0440"><span class="anchor-text">Monlau et al., 2012</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0450" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0450"><span class="anchor-text">Mullai et al., 2013</span></a>).</p>
<p id="p0045">The aim of this study is to review the current advances in lignocellulose-based biofuel production. This review provides an overview of the following: (i) variables that contribute to the bioconversion process, including recalcitrant (ii) biorefinery properties of lignocellulose biomass and (iii) different pretreatment methods and (iv) conversion mechanism. This review critically describes different pretreatment processes used for lignocellulosic pretraetment and their effects on biofuel generation. This review gives an overview of the recent advances on the bioconversion mechanism of lignocellulose into biofuel. For future advances, each technique – genetic engineering and metabolic approach – has been discussed in depth. Modeling associated to biofuel production considerations is also referred to in order to fully comprehend the biofuel production process.</p>
</section>
<section id="s0010">
<h2 id="st030" class="u-h4 u-margin-l-top u-margin-xs-bottom">2.<span> </span>Biomass recalcitrance: Overview</h2>
<p id="p0050"><span>In the context of biofuel production from <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/lignocellulose" title="Learn more about lignocelluloses from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignocelluloses</a>, <a href="https://www.sciencedirect.com/topics/engineering/deconstruction" title="Learn more about deconstruction from ScienceDirect's AI-generated Topic Pages" class="topic-link">deconstruction</a> of the plant cell wall is one of the tedious processes. Biomass recalcitrance is a multi-parametric, intrinsic property conferred by lignocellulose attributes that defend <a href="https://www.sciencedirect.com/topics/food-science/carbohydrate" title="Learn more about carbohydrates from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbohydrates</a> against chemical or <a href="https://www.sciencedirect.com/topics/engineering/biological-degradation" title="Learn more about biological degradation from ScienceDirect's AI-generated Topic Pages" class="topic-link">biological degradation</a>. Lignocellulosic biomass made up mostly of lignin, <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/cellulose" title="Learn more about cellulose from ScienceDirect's AI-generated Topic Pages" class="topic-link">cellulose</a> and <a href="https://www.sciencedirect.com/topics/engineering/hemicellulose" title="Learn more about hemicelluloses from ScienceDirect's AI-generated Topic Pages" class="topic-link">hemicelluloses</a> has a recalcitrant property that is directly connected to its structural form, arising from interactions between these primary component molecules (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0380" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0380"><span class="anchor-text">Lu et al., 2019</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0185" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0185"><span class="anchor-text">Gao et al., 2021</span></a>). To segregate these key compounds, notable chemical, biological and mechanical forces are necessary.</p>
<div>
<p id="p0055"><span>The chemical composition of lignocellulose is an important element in its recalcitrance. Classification of different <a href="https://www.sciencedirect.com/topics/engineering/lignocellulosics" title="Learn more about lignocellulosic from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignocellulosic</a> biomasses and their compositions were presented in </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#t0005" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0005"><span class="anchor-text">Table 1</span></a><span>. Cellulose, which is made up of linearly organised <a href="https://www.sciencedirect.com/topics/engineering/glucose-molecule" title="Learn more about glucose molecules from ScienceDirect's AI-generated Topic Pages" class="topic-link">glucose molecules</a>, is the most prevalent polymer component (45–60%) of lignocellulose biomass. Hemicelluloses are heterogeneous <a href="https://www.sciencedirect.com/topics/engineering/polysaccharide" title="Learn more about polysaccharides from ScienceDirect's AI-generated Topic Pages" class="topic-link">polysaccharides</a> made up of glucose, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/mannose" title="Learn more about mannose from ScienceDirect's AI-generated Topic Pages" class="topic-link">mannose</a>, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/arabinose" title="Learn more about arabinose from ScienceDirect's AI-generated Topic Pages" class="topic-link">arabinose</a>, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/rhamnose" title="Learn more about rhamnose from ScienceDirect's AI-generated Topic Pages" class="topic-link">rhamnose</a>, and other sugars that make up 20–30% of the weight of biomass (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0460" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0460"><span class="anchor-text">Nagarajan et al., 2017</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0480" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0480"><span class="anchor-text">Oliveira et al., 2019b</span></a><span>). Hemicellulose interacts well with cellulose due to its structure and nature, giving the lignocellulosic <a href="https://www.sciencedirect.com/topics/engineering/flexibility-matrix" title="Learn more about matrix flexibility from ScienceDirect's AI-generated Topic Pages" class="topic-link">matrix flexibility</a> and stability. As the removal of hemicelluloses is often assisted by lignin separation, the effect of hemicelluloses on lignocellulose biomass recalcitrance is still unclear. Lignin, a hydrophobic polymer, is another primary component of lignocellulosic biomass cell walls, constituting about 20–30% in total. It is responsible for the binding of cellulose and hemicelluloses, and for providing structural rigidity (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0080" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0080"><span class="anchor-text">Brandt et al., 2013</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0220" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0220"><span class="anchor-text">Haghdan et al., 2016</span></a>).</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0005">
<p id="sp0030"><span class="label">Table 1</span>.<span> </span>Classification and composition of lignocellulosic biomass materials.</p>
<span class="captions text-s"><span id="cn0015"></span></span>
<div class="groups">
<table>
<thead>
<tr class="valign-top">
<th scope="col" class="align-left" colspan="3"><strong>Raw material</strong></th>
<th scope="col" class="align-left" colspan="3"><strong>Composition (%)</strong></th>
<th scope="col" class="align-left" rowspan="2"><strong>References</strong></th>
</tr>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left"><strong>Class</strong></th>
<th scope="col" class="align-left"><strong>Type</strong></th>
<th scope="col" class="align-left"><strong>Biomass</strong></th>
<th scope="col" class="align-left"><strong>Hemicellulose</strong></th>
<th scope="col" class="align-left"><strong>Cellulose</strong></th>
<th scope="col" class="align-left"><strong>Lignin</strong></th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left" rowspan="15">Agricultural residue</td>
<td class="align-left">Food</td>
<td class="align-left">Sugarcane bagasse</td>
<td class="align-left">25</td>
<td class="align-left">50</td>
<td class="align-left">25</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0595" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0595"><span class="anchor-text">Su et al., 2015</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Corn cob</td>
<td class="align-left">38.78</td>
<td class="align-left">27.71</td>
<td class="align-left">9.4</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0575" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0575"><span class="anchor-text">Shinners et al., 2007</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Rice straw</td>
<td class="align-left">28</td>
<td class="align-left">32.15</td>
<td class="align-left">19.64</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0560" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0560"><span class="anchor-text">Shawky et al., 2011</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Wheat straw</td>
<td class="align-left">9.3</td>
<td class="align-left">35.1</td>
<td class="align-left">26.1</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0650" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0650"><span class="anchor-text">Yang et al., 2016</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Corn stover</td>
<td class="align-left">31.10</td>
<td class="align-left">40.67</td>
<td class="align-left">11.70</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0415" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0415"><span class="anchor-text">Mensah et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Barley straw</td>
<td class="align-left">34.9</td>
<td class="align-left">37.6</td>
<td class="align-left">15.8</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0605" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0605"><span class="anchor-text">Sun et al., 2005</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Sorghum bagasse</td>
<td class="align-left">31.28</td>
<td class="align-left">34.80</td>
<td class="align-left">24.77</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0095" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0095"><span class="anchor-text">Camargo et al., 2019</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Non-food</td>
<td class="align-left">Coconut husk</td>
<td class="align-left">17.33</td>
<td class="align-left">21.26</td>
<td class="align-left">46.36</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0200" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0200"><span class="anchor-text">Gonçalves et al., 2019</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Non-food</td>
<td class="align-left">Cotton stalk</td>
<td class="align-left">38.62</td>
<td class="align-left">34.70</td>
<td class="align-left">20.99</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0270" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0270"><span class="anchor-text">Kang et al., 2012</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Soybean straw</td>
<td class="align-left">16.9</td>
<td class="align-left">35.3</td>
<td class="align-left">21.8</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0090" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0090"><span class="anchor-text">Cabrera et al., 2015</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Maize</td>
<td class="align-left">35</td>
<td class="align-left">18</td>
<td class="align-left">6</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0190" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0190"><span class="anchor-text">Gáspár et al., 2007</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Sorghum straw</td>
<td class="align-left">26.04</td>
<td class="align-left">35.87</td>
<td class="align-left">7.52</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0100" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0100"><span class="anchor-text">Cardoso et al., 2013</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Rice husk</td>
<td class="align-left">26</td>
<td class="align-left">33</td>
<td class="align-left">7</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0255" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0255"><span class="anchor-text">Johar et al., 2012</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food</td>
<td class="align-left">Oak sawdust</td>
<td class="align-left">6.3</td>
<td class="align-left">41.9</td>
<td class="align-left">26.2</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0040" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0040"><span class="anchor-text">Atila 2019</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Non-food</td>
<td class="align-left">Flax shives</td>
<td class="align-left">24</td>
<td class="align-left">52</td>
<td class="align-left">24</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0535" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0535"><span class="anchor-text">Ross and Mazza 2010</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="9">Forest residue</td>
<td class="align-left">Hardwood</td>
<td class="align-left">Olive tree pruning</td>
<td class="align-left">25.70</td>
<td class="align-left">41</td>
<td class="align-left">21.80</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0545" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0545"><span class="anchor-text">Sanchez-Gutierrez et al., 2020</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Hardwood</td>
<td class="align-left">Sawmill</td>
<td class="align-left">30</td>
<td class="align-left">45</td>
<td class="align-left">25</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0140" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0140"><span class="anchor-text">Choudhury and Khan 2014</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Hardwood</td>
<td class="align-left">Beech wood</td>
<td class="align-left">34.30</td>
<td class="align-left">42.50</td>
<td class="align-left">22.20</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0155" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0155"><span class="anchor-text">Demirbas, 2005</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Softwood</td>
<td class="align-left">Spruce wood</td>
<td class="align-left">30.6</td>
<td class="align-left">39.5</td>
<td class="align-left">27.5</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0660" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0660"><span class="anchor-text">Zadeh et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Softwood</td>
<td class="align-left">Pine wood</td>
<td class="align-left">23</td>
<td class="align-left">42</td>
<td class="align-left">24</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0570" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0570"><span class="anchor-text">Shemfe et al., 2015</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Hardwood</td>
<td class="align-left">Rubber wood</td>
<td class="align-left">30</td>
<td class="align-left">40</td>
<td class="align-left">26</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0435" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0435"><span class="anchor-text">Mohtar et al., 2014</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Hardwood</td>
<td class="align-left">Birch wood</td>
<td class="align-left">28.9</td>
<td class="align-left">43.9</td>
<td class="align-left">20.2</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0315" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0315"><span class="anchor-text">Lachowicz et al., 2019</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Hardwood</td>
<td class="align-left">Red maple</td>
<td class="align-left">36</td>
<td class="align-left">42</td>
<td class="align-left">22</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0515" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0515"><span class="anchor-text">Radivojevic and Cooper, 2010</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Hardwood</td>
<td class="align-left">Aspen wood</td>
<td class="align-left">24.5</td>
<td class="align-left">46</td>
<td class="align-left">20</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0110" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0110"><span class="anchor-text">Chen et al., 2015</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="6">Waste materials</td>
<td class="align-left">Food waste</td>
<td class="align-left">Banana peel</td>
<td class="align-left">25.52</td>
<td class="align-left">11.45</td>
<td class="align-left">9.82</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0485" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0485"><span class="anchor-text">Orozco et al., 2014</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food waste</td>
<td class="align-left">Orange peel</td>
<td class="align-left">10.9</td>
<td class="align-left">14.4</td>
<td class="align-left">1.33</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0070" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0070"><span class="anchor-text">Bicu and Mustata, 2011</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food waste</td>
<td class="align-left">Cassava peel</td>
<td class="align-left">32.36</td>
<td class="align-left">9.71</td>
<td class="align-left">16.89</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0465" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0465"><span class="anchor-text">Nanssou et al., 2016</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food waste</td>
<td class="align-left">Groundnut shell</td>
<td class="align-left">27.62</td>
<td class="align-left">38.31</td>
<td class="align-left">21.10</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0045" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0045"><span class="anchor-text">Bano and Negi, 2017</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food waste</td>
<td class="align-left">Cashewnut shell</td>
<td class="align-left">7.35</td>
<td class="align-left">11.50</td>
<td class="align-left">7.45</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0470" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0470"><span class="anchor-text">Nuithitikul et al., 2020</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Food waste</td>
<td class="align-left">Sweet lime peel</td>
<td class="align-left">9.4</td>
<td class="align-left">25.4</td>
<td class="align-left">23.6</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0260" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0260"><span class="anchor-text">John et al., 2017</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
<p id="p0060"><span>Physical factors such as <a href="https://www.sciencedirect.com/topics/engineering/crystallinity" title="Learn more about crystallinity from ScienceDirect's AI-generated Topic Pages" class="topic-link">crystallinity</a>, particle size, assessable volume and surface area are the indirect factors that have a significant impact on lignocellulose recalcitrance. The size of the particles has been shown to be an important factor in cellulose <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/enzymatic-hydrolysis" title="Learn more about hydrolysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrolysis</a> potential (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0050" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0050"><span class="anchor-text">Barakat et al., 2014</span></a>). Techniques for size reduction might impact on cellulose-enzyme affinity, thus deconstructing the compact structure of lignocellulose and facilitating the hydrolysis process. An increase in accessible surface area is accompanied by an enhancement in pore size and particle size decline. The above physical characteristics were more crucial contributing to biomass recalcitrance in relative to crystallinity. For biomass recalcitrance, the S/G ratio of lignin structure is especially essential. The impact of the S/G ratio is not the same in all parts of the plant cell. The higher S/G ratio had a negative association with p-hydroxybenzoate and links in selected<span> </span><span><em><a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/populus-trichocarpa" title="Learn more about Populus trichocarpa from ScienceDirect's AI-generated Topic Pages" class="topic-link">Populus trichocarpa</a></em></span><span>, but a positive correlation with β-O-4 linkages and <a href="https://www.sciencedirect.com/topics/engineering/ethanol-production" title="Learn more about ethanol production from ScienceDirect's AI-generated Topic Pages" class="topic-link">ethanol production</a>. Furthermore, lignocellulose source and pretreatment techniques have a role in combating stiffness and hardness.</span></p>
</section>
<section id="s0015">
<h2 id="st035" class="u-h4 u-margin-l-top u-margin-xs-bottom">3.<span> </span>Biorefinery</h2>
<p id="p0065"><span>An efficient biorefinery process utilises a succession of steps and processing to achieve <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/zero-wastes" title="Learn more about zero waste from ScienceDirect's AI-generated Topic Pages" class="topic-link">zero waste</a>. There are three phases in biorefinery concept. Phase I is concerned with a single feed source, product, and process. Phase II biorefineries deal with a single input substrate but a variety of processes and products. Phase III of the biorefinery is linked to a variety of feeds, processes, and products. High crystalline structure of cellulose which is embedded in a matrix of polymers-lignin and hemicellulose are the main obstacle of biomass recalcitrance during the separation process. A single product is produced from <a href="https://www.sciencedirect.com/topics/engineering/substrate-complex" title="Learn more about complex substrates from ScienceDirect's AI-generated Topic Pages" class="topic-link">complex substrates</a> in the traditional biorefinery paradigm (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0410" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0410"><span class="anchor-text">Menon and Rao, 2012</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0495" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0495"><span class="anchor-text">Pinales-Márquez et al., 2021</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0295" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0295"><span class="anchor-text">Kumar and Verma, 2021</span></a><span>). Recent bio refineries, on the other hand, have focused on utilising lignocellulose biomass as a substrate for the production of different biofuels. In the lignocellulose biorefinery process, there are several stages. To overcome the recalcitrance of lignocellulose biomass, the first step is to pre-treat it with physical, chemical, biological, and physico-chemical techniques. The resulting biomass is utilised for additional hydrolysis or fermentation, which results in the production of the required products. Suitable <a href="https://www.sciencedirect.com/topics/engineering/downstream-processing" title="Learn more about downstream processing from ScienceDirect's AI-generated Topic Pages" class="topic-link">downstream processing</a> procedures recover the generated biofuels from the fermented systems. The advancement of separation technology to separate the essential components of lignocellulosic biomass such as lignin, cellulose and hemicellulose is primarily required. So lignocellulose <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/feedstock" title="Learn more about feed stock from ScienceDirect's AI-generated Topic Pages" class="topic-link">feed stock</a> is refined for better homogeneity of <a href="https://www.sciencedirect.com/topics/engineering/raw-biomass" title="Learn more about raw biomass from ScienceDirect's AI-generated Topic Pages" class="topic-link">raw biomass</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0105" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0105"><span class="anchor-text">Chandel et al., 2018</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0490" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0490"><span class="anchor-text">Patel and Shah, 2021</span></a>).</p>
</section>
<section id="s0020">
<h2 id="st040" class="u-h4 u-margin-l-top u-margin-xs-bottom">4.<span> </span>Pretreatment methods</h2>
<div>
<p id="p0070"><span>Pretreatment improves the <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/digestibility" title="Learn more about digestibility from ScienceDirect's AI-generated Topic Pages" class="topic-link">digestibility</a> of lignocellulosic biomass by allowing the major components of biomass, such as cellulose, hemicellulose, and lignin, to be solubilized or separated. Physical, chemical, biological and physico-chemical methods are few pretreatment techniques employed for lignocellulose biomass (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0540" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0540"><span class="anchor-text">Roy et al., 2020</span></a><span>). Pretreatment processes are aimed at altering the structural form, assisting the deconstruction of polymers and increasing the biomass surface area for subsequent <a href="https://www.sciencedirect.com/topics/engineering/saccharification" title="Learn more about saccharification from ScienceDirect's AI-generated Topic Pages" class="topic-link">saccharification</a> of lignocellulose into biofuel. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#t0010" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0010"><span class="anchor-text">Table 2</span></a><span> </span>summarizes different pretreatment methods utilized for the production of various bio-products from the lignocellulosic biomass and their percentage yields. The best pretreatment method relies on feedstocks, as well as their environmental and economic implications.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#f0005" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0005"><span class="anchor-text">Fig. 1</span></a><span> </span>shows that different pre-treatment methods for conversion of lignocellulosic biomass to biofuel. The various pretreatment methods of lignocellulosic biomasses were compared and their pros and cons were provided in<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#t0015" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="t0015"><span class="anchor-text">Table 3</span></a>.</p>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0010">
<p id="sp0035"><span class="label">Table 2</span>.<span> </span>Different pretreatment methods utilized for the production various bio-products from the lignocellulosic biomass.</p>
<span class="captions text-s"><span id="cn0020"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left"><strong>Conventional type</strong></th>
<th scope="col" class="align-left"><strong>Pretreatment methods</strong></th>
<th scope="col" class="align-left"><strong>Substrate</strong></th>
<th scope="col" class="align-left"><strong>Process conditions</strong></th>
<th scope="col" class="align-left"><strong>Product</strong></th>
<th scope="col" class="align-left"><strong>Yield</strong></th>
<th scope="col" class="align-left"><strong>References</strong></th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left">Combined</td>
<td class="align-left">Thermo-alkaline</td>
<td class="align-left">Buckwheat hull</td>
<td class="align-left">Anaerobic digestion</td>
<td class="align-left">Biomethane</td>
<td class="align-left">+122%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0425" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0425"><span class="anchor-text">Mirko et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">H<sub>2</sub>O<sub>2</sub></td>
<td class="align-left">Sweet sorghum stalk</td>
<td class="align-left">Temperature: 280 °C</td>
<td class="align-left">Bio-oil</td>
<td class="align-left">44 wt%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0345" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0345"><span class="anchor-text">Li et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Combined</td>
<td class="align-left">Steam explosion &amp; green-liquor</td>
<td class="align-left">Bamboo</td>
<td class="align-left">Saccharification</td>
<td class="align-left">Bioethanol</td>
<td class="align-left">23%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0185" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0185"><span class="anchor-text">Gao et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">Na<sub>2</sub>CO<sub>3</sub>-O<sub>2</sub></td>
<td class="align-left">Waste wheat straw</td>
<td class="align-left">Enzymatic hydrolysis(Temperature: 110 °C)</td>
<td class="align-left">Sugar recovery</td>
<td class="align-left">66.1%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0120" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0120"><span class="anchor-text">Chen et al., 2021a</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">Acidic ionic liquid (1-(carboxymethyl) pyridinium chloride)</td>
<td class="align-left">Rice straw</td>
<td class="align-left">Enzymatic hydrolysis</td>
<td class="align-left">Bioethanol</td>
<td class="align-left">62.2%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0005" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0005"><span class="anchor-text">Abdolmaleki et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Physicochemical</td>
<td class="align-left">Autohydrolysis</td>
<td class="align-left">Bamboo</td>
<td class="align-left">Torrefaction (Temperature: 160 °C)</td>
<td class="align-left">Hemicellulose</td>
<td class="align-left">80.24%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0685" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0685"><span class="anchor-text">Zheng et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">Aqueous ammonia</td>
<td class="align-left">Corn cob powder</td>
<td class="align-left">Enzymatic hydrolysis</td>
<td class="align-left">Cellulose</td>
<td class="align-left">97.1%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0665" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0665"><span class="anchor-text">Zhang &amp; Wu 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Combined</td>
<td class="align-left">Microwave thermochemical</td>
<td class="align-left">Maize stem</td>
<td class="align-left">Fractionation</td>
<td class="align-left">Sugar</td>
<td class="align-left">1.25 µmol/mg biomass</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0705" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0705"><span class="anchor-text">Zhu et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">NaOH</td>
<td class="align-left">Rice straw</td>
<td class="align-left">Enzymatic hydrolysis and fermentation (72 h)</td>
<td class="align-left">Biobutanol</td>
<td class="align-left">10.1 g/L</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0615" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0615"><span class="anchor-text">Valles et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">Ethylene glycol/H<sub>2</sub>O-HCl</td>
<td class="align-left">Bagasse</td>
<td class="align-left">Enzymatic saccharification</td>
<td class="align-left">Glucose</td>
<td class="align-left">94.3%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0640" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0640"><span class="anchor-text">Wei et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Physicochemical</td>
<td class="align-left">Subcritical water</td>
<td class="align-left">Wheat straw</td>
<td class="align-left">Separate hydrolysis and fermentation</td>
<td class="align-left">Ethanol</td>
<td class="align-left">37.00 g/L</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0125" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0125"><span class="anchor-text">Chen et al., 2021b</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">Phosphoric acid</td>
<td class="align-left">Sugarcane bagasse</td>
<td class="align-left">Hydrolysis</td>
<td class="align-left">Sugar</td>
<td class="align-left">98%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b9000" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b9000"><span class="anchor-text">Junior et al., 2020</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Physicochemical</td>
<td class="align-left">Compressed hot water</td>
<td class="align-left">Corn stalk</td>
<td class="align-left">Fermentation</td>
<td class="align-left">Bioethanol</td>
<td class="align-left">31.06 g/L</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0010" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0010"><span class="anchor-text">Adekunle et al., 2020</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">Combined sodium percarbonate &amp; glycerol</td>
<td class="align-left">Sugarcane bagasse</td>
<td class="align-left">Enzymatic hydrolysis</td>
<td class="align-left">Reducing sugar</td>
<td class="align-left">16.67 g/L</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0205" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0205"><span class="anchor-text">Gong et al., 2020</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">Modified alkaline peroxide</td>
<td class="align-left">Bamboo</td>
<td class="align-left">Saccharification and fermentation</td>
<td class="align-left">Bioethanol</td>
<td class="align-left">75%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0235" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0235"><span class="anchor-text">Huang et al., 2020</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">Alkali (NaOH and Na<sub>2</sub>CO<sub>3</sub>)</td>
<td class="align-left">Softwood pine</td>
<td class="align-left">Enzymatic hydrolysis</td>
<td class="align-left">Glucose</td>
<td class="align-left">46.5%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0055" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0055"><span class="anchor-text">Bay et al., 2020</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">NaOH catalytic ethanol</td>
<td class="align-left">Sugarcane bagasse</td>
<td class="align-left">Hydrolysis</td>
<td class="align-left">Glucose</td>
<td class="align-left">91.6%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0680" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0680"><span class="anchor-text">Zhang et al., 2021</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Chemical</td>
<td class="align-left">NaOH-catalyzed organosolv</td>
<td class="align-left">Sugarcane bagasse</td>
<td class="align-left">Hydrolysis</td>
<td class="align-left">Glucose</td>
<td class="align-left">95.1%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0675" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0675"><span class="anchor-text">Zhang et al., 2020b</span></a></td>
</tr>
<tr class="valign-top">
<td class="align-left">Physicochemical</td>
<td class="align-left">Glycerol thermal</td>
<td class="align-left">Paddy straw</td>
<td class="align-left">Hydrolysis</td>
<td class="align-left">Reducing sugar</td>
<td class="align-left">71.52%</td>
<td class="align-left"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0180" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0180"><span class="anchor-text">Gabhane et al., 2020</span></a></td>
</tr>
</tbody>
</table>
</div>
</div>
<figure class="figure text-xs" id="f0005"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0960852421015455-gr1.jpg" height="447" alt="" aria-describedby="cn0005"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0960852421015455-gr1_lrg.jpg" target="_blank" download="" title="Download high-res image (122KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (122KB)</span></span></a></li>
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</ol>
<p id="sp0020"><span class="label">Fig. 1</span>.<span> </span><span>Different <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/pretreatment" title="Learn more about pretreatment from ScienceDirect's AI-generated Topic Pages" class="topic-link">pretreatment</a> methods for the conversion of </span><a href="https://www.sciencedirect.com/topics/engineering/lignocellulosic-biomass" title="Learn more about lignocellulosic biomass from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignocellulosic biomass</a><span> </span>to biofuel.</p>
<span class="captions text-s"><span id="cn0005"></span></span></figure>
<div class="tables frame-topbot rowsep-0 colsep-0" id="t0015">
<p id="sp0040"><span class="label">Table 3</span>.<span> </span>Comparative analysis of pros and cons of different lignocellulosic biomass pretreatment methods.</p>
<span class="captions text-s"><span id="cn0025"></span></span>
<div class="groups">
<table>
<thead>
<tr class="rowsep-1 valign-top">
<th scope="col" class="align-left"><strong>S.No</strong></th>
<th scope="col" class="align-left"><strong>Conventional type</strong></th>
<th scope="col" class="align-left"><strong>Pretreatment methods</strong></th>
<th scope="col" class="align-left"><strong>Pros</strong></th>
<th scope="col" class="align-left"><strong>Cons</strong></th>
</tr>
</thead>
<tbody>
<tr class="valign-top">
<td class="align-left" rowspan="5">1</td>
<td class="align-left" rowspan="5">Physical</td>
<td class="align-left">Mechanical</td>
<td class="align-left">Increasing crystallinity of biomassEasy operation control</td>
<td class="align-left">High energy consumption</td>
</tr>
<tr class="valign-top">
<td class="align-left">Microwave</td>
<td class="align-left">Increasing porosity and surface areaLess energy consumption</td>
<td class="align-left">Not environmental compatibleGeneration of waste materialsHigh cost</td>
</tr>
<tr class="valign-top">
<td class="align-left">Ball milling</td>
<td class="align-left">High efficiency when combined with other pretreatment processNo release of toxic compounds</td>
<td class="align-left">Less product efficiencyGeneration of waste materials</td>
</tr>
<tr class="valign-top">
<td class="align-left">Ultrasound</td>
<td class="align-left">Increasing porosity and surface areaHigher efficiency</td>
<td class="align-left">High costHigh temperature and high pressure</td>
</tr>
<tr class="valign-top">
<td class="align-left">Electrokinetic</td>
<td class="align-left">Easy and simple operationForming the electric potential across the cell wall of biomass</td>
<td class="align-left">Not suitable for dry biomass</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="4">2</td>
<td class="align-left" rowspan="4">Chemical</td>
<td class="align-left">Acid</td>
<td class="align-left">Less reaction timeCost effectiveHigher efficiency</td>
<td class="align-left">Degradation of yieldBioreactor corrosion might occurRelease of toxic chemicalsCausing environmental pollutionHigh water consumption</td>
</tr>
<tr class="valign-top">
<td class="align-left">Alkali</td>
<td class="align-left">Higher efficiency in lignin removalEnriched glucose yield from biomass</td>
<td class="align-left">Recovery of biomass is lessRelease of toxic chemicalsNot environmental compatibleHigh water consumption (washing)</td>
</tr>
<tr class="valign-top">
<td class="align-left">Ionic liquid</td>
<td class="align-left">Recycling and reuseWaste generation</td>
<td class="align-left">High energy demandHigh costWaste generation</td>
</tr>
<tr class="valign-top">
<td class="align-left">Organic solvent</td>
<td class="align-left">Higher fractionation and conversionWaste generationHigh purity product</td>
<td class="align-left">High cost (Solvent)</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="3">3</td>
<td class="align-left" rowspan="3">Physicochemical</td>
<td class="align-left">Steam explosion</td>
<td class="align-left">Higher efficiency (Lignin removal, hemicellulose solubilization)Porosity of biomass increases by rupturing</td>
<td class="align-left">High temperature and high pressureHigh process cost</td>
</tr>
<tr class="valign-top">
<td class="align-left">Autohydrolysis</td>
<td class="align-left">Higher efficiencyHigher hydrolysis rate</td>
<td class="align-left">High water consumptionHigh energy demand</td>
</tr>
<tr class="valign-top">
<td class="align-left">Hydrothermal</td>
<td class="align-left">Increasing the cellulose digestibilityLess energy consumptionEnvironmental compatible</td>
<td class="align-left">High energy demandNot suitable for softwood biomass</td>
</tr>
<tr class="valign-top">
<td class="align-left" rowspan="3">4</td>
<td class="align-left" rowspan="3">Biological</td>
<td class="align-left">Bacterial</td>
<td class="align-left">Environmental compatibleCost effectiveHigher hydrolysis rate</td>
<td class="align-left">Long duration process</td>
</tr>
<tr class="valign-top">
<td class="align-left">Fungal</td>
<td class="align-left">Environmental compatibleCost effectiveLess energy consumptionHigher hydrolysis rateEasy operation</td>
<td class="align-left">Hydrolysis rate is very slowLong duration processGeneration of waste materials</td>
</tr>
<tr class="valign-top">
<td class="align-left">Enzymatic</td>
<td class="align-left">Environmental compatibleLess energy consumptionImmobilized enzymes – RecyclingDelignification</td>
<td class="align-left">High cost (Enzyme purification &amp; production)High maintenance cost</td>
</tr>
</tbody>
</table>
</div>
</div>
</div>
<section id="s0025">
<h3 id="st045" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.1.<span> </span>Physical method</h3>
<p id="p0075"><span>Physical pre-treatment energy needs are determined by the ultimate particle size and <a href="https://www.sciencedirect.com/topics/engineering/crystallinity" title="Learn more about crystallinity from ScienceDirect's AI-generated Topic Pages" class="topic-link">crystallinity</a> reduction of the lignocellulose biomass. Mechanical extrusion, drying, microwave, ultrasound, and <a href="https://www.sciencedirect.com/topics/engineering/pyrolysis" title="Learn more about pyrolysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">pyrolysis</a> are all common physical preparation methods. <a href="https://www.sciencedirect.com/topics/engineering/grinding-machining" title="Learn more about Grinding from ScienceDirect's AI-generated Topic Pages" class="topic-link">Grinding</a>, compression and crushing methods comes under this technique. The microstructure of lignocellulosic feedstock can be decreased using the mechanical splintered technique to increase the material's contact surface for further acid or enzyme treatment. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0225" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0225"><span class="anchor-text">Heredia-Olea et al. (2015)</span></a><span> investigated the influence of extrusion pretreatment on <a href="https://www.sciencedirect.com/topics/engineering/bioconversion" title="Learn more about bioconversion from ScienceDirect's AI-generated Topic Pages" class="topic-link">bioconversion</a> of <a href="https://www.sciencedirect.com/topics/engineering/sweet-sorghum" title="Learn more about sweet sorghum from ScienceDirect's AI-generated Topic Pages" class="topic-link">sweet sorghum</a> biomass into bio-ethanol. Extrusion treatment of sweet sorghum prior to saccharification process yielded around 70% of sugars producing 200 mL of ethanol/kg biomass (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0225" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0225"><span class="anchor-text">Heredia-Olea et al., 2015</span></a>). A study conducted on testing the impact of ultrasound treatment on sugarcane bagasse’s fermentation and saccharification to produce ethanol using<span> </span><span><em><a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/trichoderma-reesei" title="Learn more about Trichoderma reesei from ScienceDirect's AI-generated Topic Pages" class="topic-link">Trichoderma reesei</a></em></span><span>. 90% <a href="https://www.sciencedirect.com/topics/engineering/ethanol-production" title="Learn more about ethanol production from ScienceDirect's AI-generated Topic Pages" class="topic-link">ethanol production</a> was attained with ultrasound pretreatment of <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/sugarcane-bagasse" title="Learn more about sugarcane bagasse from ScienceDirect's AI-generated Topic Pages" class="topic-link">sugarcane bagasse</a> biomass (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0620" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0620"><span class="anchor-text">Velmurugan and Incharoensakdi, 2016</span></a>).</p>
<p id="p0080">Thermal pre-treatment is one of the most effective physical pretreatment techniques, where the complex compounds are broke down into sugars, which in turn enhanced the fermentation process and product generation. Thermal pretreatment technique could develop the methanogenic and acidogenic digestibility process of lignocellulosic biomass for the production of biofuels from lignocellulosic biomass (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0555" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0555"><span class="anchor-text">Sarip et al., 2016</span></a>). In thermal pretreatment, the compounds have been heated above the temperature of 260 °C and pressure 4.5 MPa. Thermal pretreatment progresses the enzyme digestibility of the lignocellulosic biomass and converting the perverse cellulose fraction into glucose for fermentation. Further, the porosity of cellulose rich residue could be increased for greater access of cellulose enzymes. Lignin phase has significant impact on cellulose accessibility which has been disrupted under the thermal pretreatment technique. A research performed by<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0285" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0285"><span class="anchor-text">Kong et al. (2018)</span></a><span> concluded that there was a slight increase of 12.6% in <a href="https://www.sciencedirect.com/topics/chemical-engineering/dextrose" title="Learn more about dextrose from ScienceDirect's AI-generated Topic Pages" class="topic-link">dextrose</a> sugar production after thermal pre-treatment method which could be further employed for biofuel production (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0285" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0285"><span class="anchor-text">Kong et al., 2018</span></a><span>). Microwave pretreatment includes thermal and non-thermal effects and this heating process can significantly reduce pretreatment time and efficiency. In some cases, microwave assisted combined <a href="https://www.sciencedirect.com/topics/engineering/ball-milling" title="Learn more about ball milling from ScienceDirect's AI-generated Topic Pages" class="topic-link">ball milling</a> technique are used. Microwave assisted ball milling technique was effective in reducing the crystallinity index, improving the enzymatic hydrolysis, swelling and fragmentation which enhances the accessibility of the catalysts and substrates and leads the degradation of hemicellulose and lignin in the biomass. In a study involving <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/gluconeogenesis" title="Learn more about glucose production from ScienceDirect's AI-generated Topic Pages" class="topic-link">glucose production</a> using microwave assisted combined ball milling (ball milling for 1 h and microwave for 20 min) could yield higher glucose production compared with ball milling technique at the time period of 6 h (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0505" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0505"><span class="anchor-text">Puligundla et al., 2016</span></a><span>). Similarly for <a href="https://www.sciencedirect.com/topics/engineering/biobutanol-production" title="Learn more about biobutanol production from ScienceDirect's AI-generated Topic Pages" class="topic-link">biobutanol production</a> from brewer’s spent <a href="https://www.sciencedirect.com/topics/food-science/cereal" title="Learn more about grain from ScienceDirect's AI-generated Topic Pages" class="topic-link">grain</a>, microwave assisted alkaline pretreatment was carried out. Around 28 kg of <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/butanol" title="Learn more about butanol from ScienceDirect's AI-generated Topic Pages" class="topic-link">butanol</a> per tonne of spent grains was attained with hydrolysis and fermentation by <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/clostridium" title="Learn more about Clostridium from ScienceDirect's AI-generated Topic Pages" class="topic-link">Clostridium</a> sp. following microwave assisted pre-treated samples (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0375" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0375"><span class="anchor-text">Lopez-Linares et al., 2020</span></a>). Biomass pyrolysis is the most common pre-treatment process employed in most of the researches. It involves the thermal breakdown of organic biomass at a particular range of temperature (300–600 °C) in the absence of free oxygen.</p>
</section>
<section id="s0030">
<h3 id="st050" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.2.<span> </span>Chemical method</h3>
<p id="p0085"><span>Chemical pre-treatments have mostly been used to increase cellulose <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/biodegradability" title="Learn more about biodegradability from ScienceDirect's AI-generated Topic Pages" class="topic-link">biodegradability</a> by removing lignin and/or hemicellulose, as well as to reduce the <a href="https://www.sciencedirect.com/topics/engineering/degree-of-polymerization" title="Learn more about degree of polymerization from ScienceDirect's AI-generated Topic Pages" class="topic-link">degree of polymerization</a> (DP) and cellulose crystallinity to a limited extent. Acid, alkali, <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/ionic-liquid" title="Learn more about ionic liquid from ScienceDirect's AI-generated Topic Pages" class="topic-link">ionic liquid</a> and oxidative are the most frequently applied chemical treatment techniques. Acid pre-treatment includes breaking of <a href="https://www.sciencedirect.com/topics/engineering/lignocellulosic-material" title="Learn more about lignocellulosic material's from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignocellulosic material's</a> hard structure with diluted and concentrated acids. The acid pretreatment using concentrated acid suitable for hydrolysis of lignocellulose biomass which cleaves the <a href="https://www.sciencedirect.com/topics/engineering/glycosidic-bond" title="Learn more about glycosidic bond from ScienceDirect's AI-generated Topic Pages" class="topic-link">glycosidic bond</a> in the cellulose structure and the acid stable hemicellulose can decomposes to <a href="https://www.sciencedirect.com/topics/engineering/glucomannan" title="Learn more about glucomannan from ScienceDirect's AI-generated Topic Pages" class="topic-link">glucomannan</a> or xylon. It improves the lignocellulose digestibility by <a href="https://www.sciencedirect.com/topics/engineering/solubilization" title="Learn more about solubilisation from ScienceDirect's AI-generated Topic Pages" class="topic-link">solubilisation</a> of lignocellulose, lignin precipitation and rendering better availability of cellulose for further processes. The most significant parameters that affect acid treatment processes are solid to liquid ratio, size of the lignocellulose particle, concentration of the acid, pre-treatment temperatures and duration. Though both dilute and concentrated acids have been used in lignocellulose chemical pretreatment processes, usage of concentrated acid is less appealing due to its eroding, noxious and expensive nature. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0210" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0210"><span class="anchor-text">Gonzales et al. (2017)</span></a><span> used dilute acid pre-treatment of <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/pinus" title="Learn more about pine from ScienceDirect's AI-generated Topic Pages" class="topic-link">pine</a> tree <a href="https://www.sciencedirect.com/topics/engineering/wood-pellet" title="Learn more about wood pellet from ScienceDirect's AI-generated Topic Pages" class="topic-link">wood pellet</a> – lignocellulosic biomass for the enhanced <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-production" title="Learn more about hydrogen production from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen production</a>. Maximal hydrogen production of 1824 mL H</span><sub>2</sub><span>/L.d was observed following the dilute <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/sulfuric-acid" title="Learn more about sulfuric acid from ScienceDirect's AI-generated Topic Pages" class="topic-link">sulfuric acid</a> treatment procedure. Few researchers conducted a similar study in which they assessed the dilute acid treatment using the <a href="https://www.sciencedirect.com/topics/engineering/combined-severity-factor" title="Learn more about combined severity factor from ScienceDirect's AI-generated Topic Pages" class="topic-link">combined severity factor</a> (CSF) that considers reaction pH, temperature and time of a certain hydrolysis process. Optimum CSF values were required to attain maximal sugar generation for <a href="https://www.sciencedirect.com/topics/engineering/biohydrogen-production" title="Learn more about biohydrogen production from ScienceDirect's AI-generated Topic Pages" class="topic-link">biohydrogen production</a>. For <a href="https://www.sciencedirect.com/topics/engineering/severity-factor" title="Learn more about severity factors from ScienceDirect's AI-generated Topic Pages" class="topic-link">severity factors</a> of 1.86 and 1.95 optimum rate of H</span><sub>2</sub><span> </span>production of 3340 and 2640 mL H<sub>2</sub><span>/L.d were reported for <a href="https://www.sciencedirect.com/topics/engineering/rice-husk" title="Learn more about rice husk from ScienceDirect's AI-generated Topic Pages" class="topic-link">rice husk</a> and empty palm fruit bunch respectively (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0215" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0215"><span class="anchor-text">Gonzales et al., 2016</span></a>).</p>
<p id="p0090"><span>Pretreatment of lignocellulosic biomass using bases such as <a href="https://www.sciencedirect.com/topics/food-science/sodium" title="Learn more about sodium from ScienceDirect's AI-generated Topic Pages" class="topic-link">sodium</a>, <a href="https://www.sciencedirect.com/topics/engineering/potassium" title="Learn more about potassium from ScienceDirect's AI-generated Topic Pages" class="topic-link">potassium</a>, calcium, and ammonium hydroxide is known as alkaline pretreatment. The application of an alkali causes ester and glycosidic side chains to degrade, leading to lignin structural changes, partial hemicellulose <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/solvation" title="Learn more about solvation from ScienceDirect's AI-generated Topic Pages" class="topic-link">solvation</a> with crystallization and cellulose dilatation (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0065" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0065"><span class="anchor-text">Bhatia et al., 2020</span></a><span>). Mostly, potassium hydroxide (KOH), sodium hydroxide (NaOH) and <a href="https://www.sciencedirect.com/topics/chemical-engineering/hydrated-lime" title="Learn more about calcium hydroxide from ScienceDirect's AI-generated Topic Pages" class="topic-link">calcium hydroxide</a> Ca(OH)</span><sub>2</sub><span> are used in this pre-treatment procedure which separates lignin, cellulose and hemicellulose. <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/saponification" title="Learn more about Saponification from ScienceDirect's AI-generated Topic Pages" class="topic-link">Saponification</a> process majorly helps for hydrolysis process which breaks and modifies the amorphous and crystalline structure of cellulose and cleaves the lignin-carbohydrate linkages. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0245" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0245"><span class="anchor-text">Jiang et al. (2020)</span></a><span> </span>examined the effect of NaOH and Ca(OH)<sub>2</sub><span> pretreatment of Giant reed for photofermentative hydrogen production. This cleavage indirectly affects the hydrogen production by a negative impaction on sugar yield from lignocellulose. NaOH pretreatment of giant reed was found to be more suitable for biofuel production than <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/limes" title="Learn more about lime from ScienceDirect's AI-generated Topic Pages" class="topic-link">lime</a> treatment (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0245" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0245"><span class="anchor-text">Jiang et al., 2020</span></a><span>). In relative to acid treatment, alkaline pretreatment typically results in less degradation of lignocellulose. Furthermore, this technique demonstrates better efficacy on <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/agricultural-science" title="Learn more about agriculture from ScienceDirect's AI-generated Topic Pages" class="topic-link">agriculture</a> based lignocellulose materials (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0525" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0525"><span class="anchor-text">Reilly et al., 2015</span></a>).</p>
<p id="p0095"><span><a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/alpha-oxidation" title="Learn more about Oxidation from ScienceDirect's AI-generated Topic Pages" class="topic-link">Oxidation</a> treatment method includes the usage of oxidant which aids in the degradation of lignocellulose. Oxidants such as peroxide dissolve the lignocellulose content where only cellulose (crystalline form) remains undissolved and hemicellulose separation from cellulose occur. <a href="https://www.sciencedirect.com/topics/engineering/photocatalysis" title="Learn more about Photocatalysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">Photocatalysis</a>, <a href="https://www.sciencedirect.com/topics/engineering/ozonolysis" title="Learn more about ozonolysis from ScienceDirect's AI-generated Topic Pages" class="topic-link">ozonolysis</a> and wet oxidation are some of the prevailing processes in oxidative pre-treatment. Wet oxidation is directly affects the three components of lignocellulosic biomass, lignin is comprehensively undergoes oxidation and cleavage, hemicellulose is broke into sugars and cellulose is degraded into organic acids. Furthermore, wet oxidation improves the cellulose accessibility via the removal of hemicellulose and lignin. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0550" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0550"><span class="anchor-text">dos Santos et al. (2018)</span></a><span> analysed the <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/biogas" title="Learn more about biogas from ScienceDirect's AI-generated Topic Pages" class="topic-link">biogas</a> production using oxidative pretreated <a href="https://www.sciencedirect.com/topics/engineering/coffee-husk" title="Learn more about coffee husks from ScienceDirect's AI-generated Topic Pages" class="topic-link">coffee husks</a>. They determined that the <a href="https://www.sciencedirect.com/topics/engineering/ozonation" title="Learn more about ozonation from ScienceDirect's AI-generated Topic Pages" class="topic-link">ozonation</a> conditions resulted in better dissolution of hemicellulose, lignin and cellulose. Large quantities of <a href="https://www.sciencedirect.com/topics/engineering/hydroxyl-ion" title="Learn more about hydroxyl ions from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydroxyl ions</a> might induce ozone molecule to breakdown releasing <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/hydroxyl-radical" title="Learn more about hydroxyl radicals from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydroxyl radicals</a>. Consequently superoxide radicals are generated which act as a potential oxidant for efficient lignocellulose degradation (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0550" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0550"><span class="anchor-text">dos Santos et al., 2018</span></a><span>). A study based on improving methane yield from palm fruit bunches by wet oxidation method using hydrogen peroxide resulted in better methane production. Here, following the peroxide treatment, lignocellulose's <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/superlattice" title="Learn more about superstructure from ScienceDirect's AI-generated Topic Pages" class="topic-link">superstructure</a> is broken apart rather than solubilized, making it easier for enzymes like <a href="https://www.sciencedirect.com/topics/engineering/cellulase" title="Learn more about cellulases from ScienceDirect's AI-generated Topic Pages" class="topic-link">cellulases</a> to access to lignocellulose materials (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0325" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0325"><span class="anchor-text">Lee et al., 2020</span></a><span>). Some of the solvents used in this technique include thiourea/NaOH solutions, N-methyl morpholine N-oxide, tetrafluoroborate, molten <a href="https://www.sciencedirect.com/topics/engineering/salt-hydrate" title="Learn more about salt hydrates from ScienceDirect's AI-generated Topic Pages" class="topic-link">salt hydrates</a> (inorganic) and metal complex solutions. The method, also known as cellulose-based treatment, has the ability to dissolve lignocellulosic components such as hemicellulose, cellulose, and lignin selectively. Anti-solvent system is used for the cellulose precipitation when both lignin and cellulose are dispersed in the ionic liquid system (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0420" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0420"><span class="anchor-text">Millati et al., 2020</span></a>). In a research performed by<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0430" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0430"><span class="anchor-text">Mohammadi et al. (2019)</span></a>, 1-H-3-methylmorpholinium chloride was employed as an ionic liquid for the pretreatment of rice straw for enhanced ethanol production. After processing, the rice straws ordered and impenetrable structure was transformed to an accessible structure with the absence of outer covering. Also the particle size and porosity was enhanced resulting in improved ethanol production (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0430" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0430"><span class="anchor-text">Mohammadi et al., 2019</span></a>).</p>
</section>
<section id="s0035">
<h3 id="st055" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.3.<span> </span>Physico-chemical method</h3>
<p id="p0100"><span>Physico-chemical pre-treatment techniques include steam explosion, <a href="https://www.sciencedirect.com/topics/engineering/torrefaction" title="Learn more about torrefaction from ScienceDirect's AI-generated Topic Pages" class="topic-link">torrefaction</a> and ammonium fibre explosion. By altering the working conditions (pressure and temperature) in the presence or absence of a chemical, lignin and hemicellulose are eliminated and cellulose is degraded in physico-chemical pretreatment. The torrefaction process us carried out in an <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/inert-atmosphere" title="Learn more about inert atmosphere from ScienceDirect's AI-generated Topic Pages" class="topic-link">inert atmosphere</a> at high temperatures (200 to 300 °C). Torrefied biomass has less <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/moisture" title="Learn more about moisture content from ScienceDirect's AI-generated Topic Pages" class="topic-link">moisture content</a>, fibrous nature and larger <a href="https://www.sciencedirect.com/topics/engineering/calorific-value" title="Learn more about calorific value from ScienceDirect's AI-generated Topic Pages" class="topic-link">calorific value</a> relative to <a href="https://www.sciencedirect.com/topics/engineering/raw-biomass" title="Learn more about raw biomass from ScienceDirect's AI-generated Topic Pages" class="topic-link">raw biomass</a> which results partial <a href="https://www.sciencedirect.com/topics/engineering/depolymerisation" title="Learn more about depolymerisation from ScienceDirect's AI-generated Topic Pages" class="topic-link">depolymerisation</a> of cellulose and lignin and decomposition of hemicellulose. In the course of devolatization and dehydration processes, hydroxyl groups are eliminated from raw lignocellulose biomass making it hydrophobic. Effective breakage of aryl–ether linkages is a vital technique for producing fuels from lignin. A research employing pre-treated rice straw and the torrefaction procedure for ethanol production verified the breakdown of cellulose micro fibrils. It decreased the cellulose crystallinity and improved its availability for further hydrolysis (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0565" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0565"><span class="anchor-text">Sheikh et al., 2013</span></a>).<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0335" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0335"><span class="anchor-text">Li et al. (2014)</span></a><span> pretreated the rice straw using torrefaction process and observed better bio-oil yield of around 55%. However at higher torrefaction temperature, there was low conversion of <a href="https://www.sciencedirect.com/topics/food-science/carbohydrate" title="Learn more about carbohydrate from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbohydrate</a> and partial lignocellulose decomposition. Hence the optimum torrefaction temperature should be maintained for better <a href="https://www.sciencedirect.com/topics/engineering/generation-biofuels" title="Learn more about biofuel generation from ScienceDirect's AI-generated Topic Pages" class="topic-link">biofuel generation</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0335" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0335"><span class="anchor-text">Li et al., 2014</span></a>).</p>
<p id="p0105"><span>In steam explosion pretreatment, the lignocellulosic biomass is primary treated with immersed steam for a specific measure of time. The steam accessibility into the internal structures of biomass is high because of great fume stage dissemination. By doing the <a href="https://www.sciencedirect.com/topics/engineering/steam-condensation" title="Learn more about condensation steam from ScienceDirect's AI-generated Topic Pages" class="topic-link">condensation steam</a>, the microporous structure of biomass is soaked with hot liquid water which causes release the acids from the hemicellulose and reducing the pH (3.0 to 4.0). The moderate acidic conditions can particularly cleave the lignin ether bonds and hydrolyze the hemicellulose. This separation of lignocellulose structure and the expulsion of hemicellulose enhance the enzymatic digestibility. Steam explosion approach entails the molecular decomposition through shearing and steam caused by the rapid <a href="https://www.sciencedirect.com/topics/engineering/depressurization" title="Learn more about depressurization from ScienceDirect's AI-generated Topic Pages" class="topic-link">depressurization</a> system. This technique is divided into two phases. For a few seconds, lignocelluloses are subjected to pressurised steam. They are then abruptly depressurised to reach air pressure. It is quite inexpensive in most situations and degrades hemicellulose and lignin compounds. In certain circumstances, severe process conditions resulted in low <a href="https://www.sciencedirect.com/topics/engineering/glucose-concentration" title="Learn more about glucose concentration from ScienceDirect's AI-generated Topic Pages" class="topic-link">glucose concentration</a> in wheat straw for ethanol production owing to early cellulose breakdown and glucose loss as residue (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0060" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0060"><span class="anchor-text">Bera et al., 2021</span></a><span>). Transformation of lignin with cellulose removal is the principal physico-chemical modifications attributed due to steam explosion pre-treatment technique which aid in improving biomass digestibility to enzymes. The following variables influence steam explosion measurement: moisture levels, temperature, chip size and retention time. Another approach for pretreatment of lignocelluloses is wet oxidation (WO). It has the capacity to fractionate woody materials cellulose rich fraction while forming few inhibitors. Following the WO process, lignocellulose material gets solubilized and decomposition of lignin to <a href="https://www.sciencedirect.com/topics/chemical-engineering/carbon-dioxide" title="Learn more about carbon dioxide from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbon dioxide</a> and water occurs. However, optimizing the treatment conditions could increase up the cost of the pre-treatment process. Other treatments like explosion using ammonium fibre and carbon dioxide are rarely used for lignocellulose due to its less efficiency (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0580" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0580"><span class="anchor-text">Shirkavand et al., 2016</span></a>).</p>
</section>
<section id="s0040">
<h3 id="st060" class="u-h4 u-margin-m-top u-margin-xs-bottom">4.4.<span> </span>Biological method</h3>
<p id="p0110"><span>The biological pre-treatment approach uses <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/micro-organism" title="Learn more about microorganisms from ScienceDirect's AI-generated Topic Pages" class="topic-link">microorganisms</a> such as bacteria and fungi to modify the lignocellulosic biomass, making it more susceptible to enzymatic digestion. In enzymatic pretreatment, pure enzymes can be used to accelerate the degradation of lignocellulose. Generally, enzymes help to release the <a href="https://www.sciencedirect.com/topics/engineering/fermentable-sugar" title="Learn more about fermentable sugars from ScienceDirect's AI-generated Topic Pages" class="topic-link">fermentable sugars</a> from hemicellulose and cellulose and reduce the recalcitrance of lignocellulose to enhance the biogas generation from the biomass. Enzymatic pretreatment has major impact on the characteristics of recalcitrance for example decreasing crystallinity and polymerization; improving accessible surface area and eliminating lignin content. Removal of lignin and hemicellulose result in improved digestibility of cellulose which is mostly preferred for fermentation process. Most of these bacteria generate lignin degrading enzymes, which results in biomass alteration. Brown rot and white <a href="https://www.sciencedirect.com/topics/engineering/rot-fungus" title="Learn more about rot fungi from ScienceDirect's AI-generated Topic Pages" class="topic-link">rot fungi</a> are the most commonly studied for this process. The lignolytic enzymes generated by white rot fungus are highly beneficial for biofuel generation by lignin degradation due to their high <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/substrate-specificity" title="Learn more about substrate specificity from ScienceDirect's AI-generated Topic Pages" class="topic-link">substrate specificity</a> and high oxidation efficiency. </span><span><em><a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/irpex-lacteus" title="Learn more about Irpex lacteus from ScienceDirect's AI-generated Topic Pages" class="topic-link">Irpex lacteus</a></em></span><span> </span>(<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0510" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0510"><span class="anchor-text">Qin et al., 2018</span></a>),<span> </span><span><em><a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/polyporus" title="Learn more about Polyporus from ScienceDirect's AI-generated Topic Pages" class="topic-link">Polyporus</a></em><em> brumalis</em></span><span> </span>(<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0695" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0695"><span class="anchor-text">Zhou et al., 2017</span></a>), and<span> </span><span><em><a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/myrothecium-verrucaria" title="Learn more about Myrothecium verrucaria from ScienceDirect's AI-generated Topic Pages" class="topic-link">Myrothecium verrucaria</a></em></span><span> </span>(<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0600" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0600"><span class="anchor-text">Su et al., 2018</span></a><span>) were among the fungi used in the pretreatment research. Free radical chain based reaction mechanism occurs in this pretreatment. Initially, formation of high reactive radical species occurs which results in fragments owing to bond breaking during lignin depolymerisation. The <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/earth-surface-processes" title="Learn more about surface process from ScienceDirect's AI-generated Topic Pages" class="topic-link">surface process</a> is linked to lignin breakdown by white rot fungus. Cellulase enzymes produced by this type of fungi dissolves the waxy <a href="https://www.sciencedirect.com/topics/engineering/coating-surface" title="Learn more about coating surface from ScienceDirect's AI-generated Topic Pages" class="topic-link">coating surface</a> of <a href="https://www.sciencedirect.com/topics/engineering/lignocellulosic-substrate" title="Learn more about lignocellulosic substrates from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignocellulosic substrates</a> paving the way for the fungal hyphae to penetrate into it. Following that, a cascade of enzymes such as <a href="https://www.sciencedirect.com/topics/engineering/hemicellulases" title="Learn more about hemicellulases from ScienceDirect's AI-generated Topic Pages" class="topic-link">hemicellulases</a>, <a href="https://www.sciencedirect.com/topics/engineering/exoglucanase" title="Learn more about exoglucanases from ScienceDirect's AI-generated Topic Pages" class="topic-link">exoglucanases</a>, <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/peroxidase" title="Learn more about peroxidases from ScienceDirect's AI-generated Topic Pages" class="topic-link">peroxidases</a>, and endoglycanases are generated, resulting in a more efficient breakdown process. Brown rot fungi are suitable for the pectin decomposition. Fenton’s reaction occurs in brown rot fungi based treatment process and is primarily used for low weight breakdown compounds. The biological pretreatment of wheat straw was investigated using white rot fungi and found that 35% of wheat straw was converted into reducing sugars (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0610" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0610"><span class="anchor-text">Talebnia et al., 2010</span></a>). However, one drawback of utilising this white rot fungus is the mild alteration of lignin rather than breakdown (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0115" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0115"><span class="anchor-text">Chen et al., 2017</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0585" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0585"><span class="anchor-text">Sindhu et al., 2016</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0645" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0645"><span class="anchor-text">Yadav et al., 2019</span></a><span>). Biological pretreatment looks to be a viable <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/science-and-technology" title="Learn more about technology from ScienceDirect's AI-generated Topic Pages" class="topic-link">technology</a> with several advantages, including <a href="https://www.sciencedirect.com/topics/engineering/low-energy-input" title="Learn more about low input energy from ScienceDirect's AI-generated Topic Pages" class="topic-link">low input energy</a>, gentle ambient conditions, an ecologically acceptable operating method and minimal chemical demand. However, its downsides are as obvious as its advantages since biological pretreatment is slow and requires careful management of growing conditions as well as a considerable quantity of area to be performed. Furthermore, most lignolytic organisms solubilize and consume lignin, hemicellulose, and cellulose. As a result, biological pretreatment confronts technological and economic hurdles, making it less appealing commercially.</span></p>
</section>
</section>
<section id="s0045">
<h2 id="st065" class="u-h4 u-margin-l-top u-margin-xs-bottom">5.<span> </span>Conversion mechanism of lignocellulosic biomass to biofuel</h2>
<div>
<p id="p0115"><span>Steps involved in the conversion of lignocellulosic biomass into valuable <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/bioproducts" title="Learn more about bioproduct from ScienceDirect's AI-generated Topic Pages" class="topic-link">bioproduct</a> including biofuels were listed in </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#f0010" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="f0010"><span class="anchor-text">Fig. 2</span></a>.</p>
<figure class="figure text-xs" id="f0010"><span><img src="https://ars.els-cdn.com/content/image/1-s2.0-S0960852421015455-gr2.jpg" height="340" alt="" aria-describedby="cn0010"></span>
<ol class="u-margin-s-bottom">
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0960852421015455-gr2_lrg.jpg" target="_blank" download="" title="Download high-res image (111KB)" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download high-res image (111KB)</span></span></a></li>
<li><a class="anchor download-link u-font-sans u-display-inline anchor-default" href="https://ars.els-cdn.com/content/image/1-s2.0-S0960852421015455-gr2.jpg" target="_blank" download="" title="Download full-size image" rel="noopener"><span class="anchor-text">Download :<span> </span><span class="download-link-title">Download full-size image</span></span></a></li>
</ol>
<p id="sp0025"><span class="label">Fig. 2</span>.<span> </span>Steps involved in conversion of<span> </span><a href="https://www.sciencedirect.com/topics/engineering/lignocellulosic-biomass" title="Learn more about lignocellulosic biomass from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignocellulosic biomass</a><span> </span>into biofuel.</p>
<span class="captions text-s"><span id="cn0010"></span></span></figure>
</div>
<section id="s0050">
<h3 id="st070" class="u-h4 u-margin-m-top u-margin-xs-bottom">5.1.<span> </span>Genetic engineering approach</h3>
<p id="p0120"><span>For the efficient conversion of lignocellulose substrate to fuels, both microorganisms and substrate are crucial. There may be less biomass accessibility with native or altered microorganisms. Several genetic engineering techniques have been developed to convert lignocellulose to biofuel. Genetic engineering of lignocellulose biomass is the primary source for enhancing biofuel output. This process was aided by the formation of a molecular matrix between hemicellulose molecules and the resulting complexing with neighbouring cellulose fibrils. Lignin composition varies as a result of <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/dna-modification" title="Learn more about genetic modification from ScienceDirect's AI-generated Topic Pages" class="topic-link">genetic modification</a> which improves the digestion of the cell wall <a href="https://www.sciencedirect.com/topics/engineering/polysaccharide" title="Learn more about polysaccharides from ScienceDirect's AI-generated Topic Pages" class="topic-link">polysaccharides</a> (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0630" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0630"><span class="anchor-text">Wang et al., 2015</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0390" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0390"><span class="anchor-text">Madadi et al., 2017</span></a><span>). Silencing the gene responsible for lignin production also improves the biomass <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/digestibility" title="Learn more about digestibility from ScienceDirect's AI-generated Topic Pages" class="topic-link">digestibility</a>. The functional characterization of genes provides potential targets for enlightening <a href="https://www.sciencedirect.com/topics/engineering/saccharification" title="Learn more about saccharification from ScienceDirect's AI-generated Topic Pages" class="topic-link">saccharification</a> and modifies the lignin content and composition. Genetically engineered approach modifies the lignin pathway which generates <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/transgenics" title="Learn more about transgenic from ScienceDirect's AI-generated Topic Pages" class="topic-link">transgenic</a> lines with improving enzymatic sugar release proportional to the extent of lignin <a href="https://www.sciencedirect.com/topics/engineering/downregulation" title="Learn more about down regulation from ScienceDirect's AI-generated Topic Pages" class="topic-link">down regulation</a>. These transgenic approaches used to increase the cell wall traits and characterize the <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/anabolism" title="Learn more about biosynthetic pathway from ScienceDirect's AI-generated Topic Pages" class="topic-link">biosynthetic pathway</a> of lignin, reduce the lignin content. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0400" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0400"><span class="anchor-text">Mazarei et al. (2020)</span></a><span> studied the improvement in biofuel production from <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/panicum-virgatum" title="Learn more about switch grass from ScienceDirect's AI-generated Topic Pages" class="topic-link">switch grass</a> by silencing Folypolyglutamate synthetase gene. Partial downregulation of this gene slightly altered the lignin composition and increased the ethanol productivity by 18% (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0400" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0400"><span class="anchor-text">Mazarei et al., 2020</span></a>). Similarly,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0320" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0320"><span class="anchor-text">Lee et al. (2021)</span></a><span> investigated lignin modification utilising CRISPR/CAS systems for improved biofuel production using barley. A <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/transgenic-plant" title="Learn more about transgenic plant from ScienceDirect's AI-generated Topic Pages" class="topic-link">transgenic plant</a> with a mutant <a href="https://www.sciencedirect.com/topics/engineering/caffeic" title="Learn more about caffeic from ScienceDirect's AI-generated Topic Pages" class="topic-link">caffeic</a> acid O-methyl transferase 1 mutant was grown and tested for <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/bioethanol" title="Learn more about bioethanol from ScienceDirect's AI-generated Topic Pages" class="topic-link">bioethanol</a> production in this work. The mutant barley plant had a 34% greater <a href="https://www.sciencedirect.com/topics/engineering/ethanol-concentration" title="Learn more about ethanol concentration from ScienceDirect's AI-generated Topic Pages" class="topic-link">ethanol concentration</a> and a 14% reduced lignin content (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0320" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0320"><span class="anchor-text">Lee et al., 2021</span></a>). Lignin biosynthetic genes have also been engineered for easy digestibility of the biomass.</p>
<p id="p0125"><span>The alteration of strains engaged in the bioconversion process is another option. With the aid of genetic engineering, microbial transformation into requisite cell factories occurs. Genetic modification of organisms offers a greater potential for biomass <a href="https://www.sciencedirect.com/topics/engineering/depolymerisation" title="Learn more about depolymerisation from ScienceDirect's AI-generated Topic Pages" class="topic-link">depolymerisation</a> and conversion of fermented sugar <a href="https://www.sciencedirect.com/topics/engineering/hydrolyzate" title="Learn more about hydrolyzate from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrolyzate</a> into <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/free-fatty-acids" title="Learn more about free fatty acids from ScienceDirect's AI-generated Topic Pages" class="topic-link">free fatty acids</a> in <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/biodiesel" title="Learn more about biodiesel from ScienceDirect's AI-generated Topic Pages" class="topic-link">biodiesel</a> synthesis from lignocellulose. In this situation, genetic engineering can be used in one of two ways. First will be engineering of native cellulolytic microbes for improving the product related aspects. Second, non-cellulolytic organisms will be engineered to generate <a href="https://www.sciencedirect.com/topics/engineering/cellulase" title="Learn more about cellulase from ScienceDirect's AI-generated Topic Pages" class="topic-link">cellulase</a> enzymes. Few studies have focused on using export-related <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/fusion-protein" title="Learn more about protein fusions from ScienceDirect's AI-generated Topic Pages" class="topic-link">protein fusions</a> in </span><span><em><a href="https://www.sciencedirect.com/topics/food-science/escherichia-coli" title="Learn more about E. coli from ScienceDirect's AI-generated Topic Pages" class="topic-link">E. coli</a></em></span><span> to extracellularly produce enzymes such <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/xylanase" title="Learn more about xylanases from ScienceDirect's AI-generated Topic Pages" class="topic-link">xylanases</a>, cellulases, cellobiase, xylobiosidase, and <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/glucosidase" title="Learn more about glucosidases from ScienceDirect's AI-generated Topic Pages" class="topic-link">glucosidases</a>. With <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/ionic-liquid" title="Learn more about ionic liquid from ScienceDirect's AI-generated Topic Pages" class="topic-link">ionic liquid</a> pre-treated switch grass, this modified strain grew well and enhanced biomass hydrolysis (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0355" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0355"><span class="anchor-text">Lin et al., 2013</span></a>). In the production of biofuels, high product concentration can sometimes be a hindrance. Butanol, for example, can create a partition in the cytoplasmic membrane, altering its shape. As a result, strains must be modified to improve product tolerance in biofuel-producing microbes. Strains can also be engineered to grow on complicated lignocellulose substrates, increasing biofuel production rate.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0370" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0370"><span class="anchor-text">Lopez-Hidalgo et al. (2021)</span></a><span> investigated the effect of a genetically modified E.coli strain on ethanol and hydrogen coproduction from <a href="https://www.sciencedirect.com/topics/food-science/maize" title="Learn more about corn from ScienceDirect's AI-generated Topic Pages" class="topic-link">corn</a> stover and wheat straw. Different molecular methods were used to remove genes that produce <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/hydrogenase" title="Learn more about hydrogenases from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogenases</a> and <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/reductase" title="Learn more about reductases from ScienceDirect's AI-generated Topic Pages" class="topic-link">reductases</a> in order to improve coproduction in complicated substrates. Ethanol production of 20–30% was observed with this engineered strain (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0370" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0370"><span class="anchor-text">Lopez-Hidalgo et al., 2021</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0690" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0690"><span class="anchor-text">Zheng et al., 2015</span></a><span>). Yeast/fungi may also be developed to produce biofuels from lignocellulose substrate, such as ethanol, butanol, methane, and hydrogen. Extracellular enzymes responsible for lignin breakdown are secreted by them. For improved ethanol output, recombinant strains containing genes for intracellular expression of <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/xylitol" title="Learn more about xylitol from ScienceDirect's AI-generated Topic Pages" class="topic-link">xylitol</a> <a href="https://www.sciencedirect.com/topics/engineering/dehydrogenase" title="Learn more about dehydrogenase from ScienceDirect's AI-generated Topic Pages" class="topic-link">dehydrogenase</a>, reductase, kinase, and glucosidase from separate species such as </span><span><em><a href="https://www.sciencedirect.com/topics/engineering/pichia-stipitis" title="Learn more about Pichia stipitis from ScienceDirect's AI-generated Topic Pages" class="topic-link">Pichia stipitis</a></em></span>,<span> </span><span><em><a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/saccharomyces" title="Learn more about Saccharomyces from ScienceDirect's AI-generated Topic Pages" class="topic-link">Saccharomyces</a></em><em> cereviseae</em></span>, and<span> </span><span><em><a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/aspergillus" title="Learn more about Aspergillus from ScienceDirect's AI-generated Topic Pages" class="topic-link">Aspergillus</a></em><em> acleatus</em></span><span> </span>have been combined and used in a research (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0275" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0275"><span class="anchor-text">Katahira et al., 2006</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0025" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0025"><span class="anchor-text">Amores et al., 2015</span></a>). Developing genetically engineered constructs with modified lignolytic enzymes might improve the lignocellulose bioconversion into biofuel.</p>
</section>
<section id="s0055">
<h3 id="st075" class="u-h4 u-margin-m-top u-margin-xs-bottom">5.2.<span> </span>Metabolic engineering approach</h3>
<p id="p0130">Development in the generation of chemical by objective metabolic engineering is for the most part performed by<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#e0005" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="e0005"><span class="anchor-text">(1)</span></a><span> </span>upgrading the action of enzymes associated with the product biosynthesis<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#e0010" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="e0010"><span class="anchor-text">(2)</span></a><span> disturbing pathways that enter after carbon substrate or potentially electrons and additionally co-factors. Furthermore, microorganisms should be lenient to high grouping of the substance to permit large scale <a href="https://www.sciencedirect.com/topics/engineering/industrial-fermentation" title="Learn more about industrial fermentation from ScienceDirect's AI-generated Topic Pages" class="topic-link">industrial fermentation</a>. The <a href="https://www.sciencedirect.com/topics/engineering/biosynthetic-route" title="Learn more about biosynthetic route from ScienceDirect's AI-generated Topic Pages" class="topic-link">biosynthetic route</a> for lignocellulose fuel generation is a multi-step operation. The metabolism of microorganisms has thousands of processes that govern the energy process. Recent metabolic engineering approaches have contributed to increased flux for biofuel production. <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/enzyme-modification" title="Learn more about Enzyme modification from ScienceDirect's AI-generated Topic Pages" class="topic-link">Enzyme modification</a>, scaffold construction, codon optimization, and fermentation conditions are some of the most common tactics used in these engineering procedures. For improved carbon flow in product creation, two major methods have been developed. The first is the push–pull-block approach, in which specific metabolic pathways are inhibited and enzymes are overexpressed to enhance carbon flow. The second strategy is to reduce or block carbon flow in the creation of undesirable by-products, which increases <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/carbon-flux" title="Learn more about carbon flux from ScienceDirect's AI-generated Topic Pages" class="topic-link">carbon flux</a> in <a href="https://www.sciencedirect.com/topics/engineering/fuel-synthesis" title="Learn more about fuel synthesis from ScienceDirect's AI-generated Topic Pages" class="topic-link">fuel synthesis</a>. <a href="https://www.sciencedirect.com/topics/engineering/metabolic-engineering" title="Learn more about Metabolic engineering from ScienceDirect's AI-generated Topic Pages" class="topic-link">Metabolic engineering</a> may provide three main outcomes: high-yielding microorganisms, the capacity to endure harsh environmental conditions, and adaptation to a wide range of <a href="https://www.sciencedirect.com/topics/engineering/lignocellulosic-material" title="Learn more about lignocellulosic materials from ScienceDirect's AI-generated Topic Pages" class="topic-link">lignocellulosic materials</a>. Undesired product formation can also be inhibited by this approach (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0230" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0230"><span class="anchor-text">Hollinshead et al., 2014</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0395" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0395"><span class="anchor-text">Majidian et al., 2018</span></a>). In case of<span> </span><em>iso</em><span>-prenoid derived fuels, mevalonate and deoxy <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/xylulose" title="Learn more about xylulose from ScienceDirect's AI-generated Topic Pages" class="topic-link">xylulose</a> phosphate pathway can be overexpressed or deregulated by introducing or knocking out the gene in the desired organism to minimize the by-products formation (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0135" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0135"><span class="anchor-text">Choudhary et al., 2020</span></a>).</p>
<p id="p0135"><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0330" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0330"><span class="anchor-text">Li et al. (2019)</span></a><span> </span>investigated the butanol production from lignocellulose substrates using engineered<span> </span><span><em><a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/clostridium" title="Learn more about Clostridium from ScienceDirect's AI-generated Topic Pages" class="topic-link">Clostridium</a></em><em> tyrobutyricum</em></span><span> strain. This <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/bacterial-strain" title="Learn more about bacterial strain from ScienceDirect's AI-generated Topic Pages" class="topic-link">bacterial strain</a> with knocked out <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/acetate-kinase" title="Learn more about acetate kinase from ScienceDirect's AI-generated Topic Pages" class="topic-link">acetate kinase</a> (ack) gene was designed to overexpress adhE2 gene which encodes alcohol dehydrogenase gene involved in n-butanol synthesis. CtΔack-adhE2, a metabolically modified strain, provides a number of benefits, including absence of <a href="https://www.sciencedirect.com/topics/engineering/acetone" title="Learn more about acetone from ScienceDirect's AI-generated Topic Pages" class="topic-link">acetone</a> generation, increased butanol tolerance in the organism and its production. With this engineered strain, butanol synthesis of high yield 0.3 g/g and titre 15 g/L was achieved (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0330" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0330"><span class="anchor-text">Li et al., 2019</span></a>). For effective lignocellulose bioconversion,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0530" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0530"><span class="anchor-text">Romani et al. (2015)</span></a><span> modified the <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/xylose" title="Learn more about xylose from ScienceDirect's AI-generated Topic Pages" class="topic-link">xylose</a> metabolic pathway in </span><em>Saccharomyces cerevisiae</em><span> strains. Hydromycin resistance gene was used in place of <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/ura3" title="Learn more about URA3 from ScienceDirect's AI-generated Topic Pages" class="topic-link">URA3</a> marker gene to develop a superior xylose pathway. Deletion of the GRE gene was also done to improve biofuel production by enhancing the rate of xylose consumption in corn-cob hydrolyzates. Of the estimated theoretical yield, 92% was obtained with this practical study (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0530" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0530"><span class="anchor-text">Romani et al., 2015</span></a>).</p>
<p id="p0140"><span>The researchers have lately focused their research on the engineering of plant biosynthetic pathways for fuel synthesis. Lignocellulose substrates have been changed to allow for easy decomposition and the production of fuels with minimum pre-treatment. One of the primary recalcitrance factors, lignin, has been studied in order to decrease its impact on the enzymatic digestion of this biomass. Few researchers have demonstrated in a field study that biomass from <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/populus" title="Learn more about Poplar from ScienceDirect's AI-generated Topic Pages" class="topic-link">Poplar</a> plants with down regulated cinnamoyl-CoA reductase (CCR) gene has the greater potential for bioethanol production. CCR enzyme plays a crucial role in lignin biosynthetic pathway. Down regulation of this enzyme resulted in 161% increase in ethanol yield (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0075" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0075"><span class="anchor-text">Bilal et al., 2018</span></a>). Designing appropriate microorganisms that synthesis desired biofuels directly from lignin from biomass can increase lignin usage, but this requires a full understanding of engineering approach and lignin consumption mechanisms. Some strategies, such as genome scale modelling, systemic optimization and post translational enzyme modification, have resulted in significant lignocellulose conversion. Native organisms that consume lignocellulose and fuel overproducers can also be used to create hybrid strains for direct fuel synthesis from lignocellulose feedstock (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0130" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0130"><span class="anchor-text">Choi et al., 2020</span></a>).</p>
</section>
</section>
<section id="s0060">
<h2 id="st080" class="u-h4 u-margin-l-top u-margin-xs-bottom">6.<span> </span>Recent developments in modelling study</h2>
<p id="p0145"><span>Modelling study can be used to predict the fermentation process for biofuel generation in the following aspects (i) design the operating system (parameters: pH, temperature, alkalinity and substrate quantity) (ii) resource utilization efficiency (iii) lab scale to industrial scale operation (iv) time saving. A model is a depiction of the chemical, physical and <a href="https://www.sciencedirect.com/topics/biochemistry-genetics-and-molecular-biology/biological-phenomena-and-functions-concerning-the-entire-organism" title="Learn more about biological processes from ScienceDirect's AI-generated Topic Pages" class="topic-link">biological processes</a> that occur in a system. There are numeral methods of <a href="https://www.sciencedirect.com/topics/engineering/mathematical-description" title="Learn more about mathematical description from ScienceDirect's AI-generated Topic Pages" class="topic-link">mathematical description</a> of modelling have been approached for the bioconversion of lignocellulose to biofuels due to the diversity of feedstock and complexity of fermentation process. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0290" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0290"><span class="anchor-text">Kucharska et al. (2018)</span></a><span> classified widely used models into four categories: substrate conversion-based models, <a href="https://www.sciencedirect.com/topics/engineering/kinetic-model" title="Learn more about kinetic models from ScienceDirect's AI-generated Topic Pages" class="topic-link">kinetic models</a>, blackbox models, and ADM1-based models.</span></p>
<p id="p0150"><span>The <a href="https://www.sciencedirect.com/topics/engineering/substrate-conversion" title="Learn more about substrate conversion from ScienceDirect's AI-generated Topic Pages" class="topic-link">substrate conversion</a> model relates <a href="https://www.sciencedirect.com/topics/immunology-and-microbiology/structural-characteristics" title="Learn more about structural characteristics from ScienceDirect's AI-generated Topic Pages" class="topic-link">structural characteristics</a> and composition of lignocellulosic biomass for the biofuel generation. In a research involving the determination of methane potential from different lignocellulose substrates, first order kinetic model was used to determine the rate of lignocellulose degradation (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0340" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0340"><span class="anchor-text">Li et al., 2013</span></a>,<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0290" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0290"><span class="anchor-text">Kucharska et al., 2018</span></a>). The equation is represented by<span class="display"><span id="e0005" class="formula"><span class="label">(1)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-1-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;" tabindex="0"&gt;<svg xmlns:xlink="http://www.w3.org/1999/xlink" width="22.972ex" height="2.779ex" viewBox="0 -846.5 9890.7 1196.3" role="img" focusable="false" aria-hidden="true"><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"><g is="true"><g is="true"><use xlink:href="#MJMATHI-42"></use></g><g is="true" transform="translate(1037,0)"><use xlink:href="#MJMAIN-3D"></use></g><g is="true" transform="translate(2093,0)"><g is="true"><use xlink:href="#MJMATHI-42"></use></g><g is="true" transform="translate(759,-150)"><use transform="scale(0.707)" xlink:href="#MJMAIN-30"></use></g></g><g is="true" transform="translate(3473,0)"><g is="true"><use xlink:href="#MJMAIN-5B"></use></g><g is="true" transform="translate(278,0)"><use xlink:href="#MJMAIN-31"></use></g><g is="true" transform="translate(1001,0)"><use xlink:href="#MJMAIN-2212"></use></g><g is="true" transform="translate(2001,0)"><use xlink:href="#MJMAIN-65"></use><use xlink:href="#MJMAIN-78" x="444" y="0"></use><use xlink:href="#MJMAIN-70" x="973" y="0"></use></g><g is="true" transform="translate(3698,0)"><g is="true"><use xlink:href="#MJMAIN-28"></use></g><g is="true" transform="translate(389,0)"><use xlink:href="#MJMAIN-2212"></use></g><g is="true" transform="translate(1168,0)"><use xlink:href="#MJMATHI-6B"></use></g><g is="true" transform="translate(1689,0)"><use xlink:href="#MJMATHI-74"></use></g><g is="true" transform="translate(2051,0)"><use xlink:href="#MJMAIN-29"></use></g></g><g is="true" transform="translate(6138,0)"><use xlink:href="#MJMAIN-5D"></use></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi is="true">�</mi><mo linebreak="goodbreak" is="true">=</mo><msub is="true"><mi is="true">�</mi><mn is="true">0</mn></msub><mrow is="true"><mo stretchy="false" is="true">[</mo><mn is="true">1</mn><mo is="true">-</mo><mo is="true">exp</mo><mrow is="true"><mo stretchy="false" is="true">(</mo><mo is="true">-</mo><mi is="true">�</mi><mi is="true">�</mi><mo stretchy="false" is="true">)</mo></mrow><mo stretchy="false" is="true">]</mo></mrow></mrow></math></span></span></span></span></span></p>
<p id="p0155">Where B<sub>0</sub><span> </span>and B represents the ultimate and cumulative methanol yield (mL g<sup>−1</sup><span> </span>VS) and t is the process time (min). This work also included the application of the Buswell formula, which takes into consideration varied substrate compositions.<span> </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0175" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0175"><span class="anchor-text">Fedailaine et al. (2015)</span></a><span> developed a model for substrate degradation and methane production. The model was based on substrate and biomass mass balances with methane production. Sensitivity analysis of the model showed that increase in initial lignocellulose <a href="https://www.sciencedirect.com/topics/engineering/biomass-concentration" title="Learn more about biomass concentration from ScienceDirect's AI-generated Topic Pages" class="topic-link">biomass concentration</a> increased the methane production. Monod model was also employed to determine the <a href="https://www.sciencedirect.com/topics/engineering/substrate-concentration" title="Learn more about substrate concentration from ScienceDirect's AI-generated Topic Pages" class="topic-link">substrate concentration</a> effect on its <a href="https://www.sciencedirect.com/topics/engineering/degradation-process" title="Learn more about degradation process from ScienceDirect's AI-generated Topic Pages" class="topic-link">degradation process</a>.</span></p>
<p id="p0160"><span>Kinetic models may describe several parameters impacting the biofuel process, such as lignocellulose content, pH, temperature, and <a href="https://www.sciencedirect.com/topics/engineering/dilution-rate" title="Learn more about dilution rate from ScienceDirect's AI-generated Topic Pages" class="topic-link">dilution rate</a>. The calculated kinetic constants can be used to forecast the operation and design of biofuel production. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0635" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0635"><span class="anchor-text">Wang et al. (2017)</span></a><span> used two models to calculate the efficiency of <a href="https://www.sciencedirect.com/topics/engineering/biohydrogen" title="Learn more about biohydrogen from ScienceDirect's AI-generated Topic Pages" class="topic-link">biohydrogen</a> generation from raw cassava <a href="https://www.sciencedirect.com/topics/engineering/starch" title="Learn more about starch from ScienceDirect's AI-generated Topic Pages" class="topic-link">starch</a>. The product production and substrate usage kinetics were described using the Gompertz and <a href="https://www.sciencedirect.com/topics/engineering/first-order-equation" title="Learn more about first order equations from ScienceDirect's AI-generated Topic Pages" class="topic-link">first order equations</a>. The Gompertz equation was more adapted to the synthesis of ethanol, <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/volatile-fatty-acid" title="Learn more about volatile fatty acids from ScienceDirect's AI-generated Topic Pages" class="topic-link">volatile fatty acids</a>, and acetate of the two (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0635" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0635"><span class="anchor-text">Wang et al., 2017</span></a>). In the kinetic modelling of biodiesel production, the modified second order (MSO) rate model shown below is recently employed (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0165" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0165"><span class="anchor-text">Ezzati et al., 2021</span></a>).<span class="display"><span id="e0010" class="formula"><span class="label">(2)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-2-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; 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<p id="p0165"><span>Where [T] is the concentration of <a href="https://www.sciencedirect.com/topics/engineering/triglyceride" title="Learn more about triglycerides from ScienceDirect's AI-generated Topic Pages" class="topic-link">triglycerides</a>, [A] means the alcohol concentration and [G] is the glycerol concentration. <a href="https://www.sciencedirect.com/topics/engineering/second-order-model" title="Learn more about MSO models from ScienceDirect's AI-generated Topic Pages" class="topic-link">MSO models</a> are more accurate during initial period of reaction. In the <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-production" title="Learn more about hydrogen production from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen production</a> from lignocellulose, monod model and modified Gompertz model have been used to describe the progress of the reaction. </span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0035" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0035"><span class="anchor-text">Ashah et al. (2020)</span></a><span> </span>applied modified Gompertz equation to study the kinetics of palm based substrates. The equation is represented by (<a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0035" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0035"><span class="anchor-text">Ashah et al., 2020</span></a>):<span class="display"><span id="e0015" class="formula"><span class="label">(3)</span><span class="math"><span class="MathJax_Preview"></span><span class="MathJax_SVG" id="MathJax-Element-3-Frame" data-mathml="&lt;math xmlns=" http:="" www.w3.org="" 1998="" math="" mathml"="">" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; 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height="60" x="0" y="146"></rect><g is="true" transform="translate(60,410)"><g is="true"><g is="true"><use transform="scale(0.5)" xlink:href="#MJMATHI-52"></use></g><g is="true" transform="translate(379,-76)"><use transform="scale(0.5)" xlink:href="#MJMAIN-6D"></use><use transform="scale(0.5)" xlink:href="#MJMAIN-61" x="833" y="0"></use><use transform="scale(0.5)" xlink:href="#MJMAIN-78" x="1334" y="0"></use></g></g><g is="true" transform="translate(1361,0)"><use transform="scale(0.5)" xlink:href="#MJMATHI-65"></use></g></g><g is="true" transform="translate(158,-319)"><g is="true"><use transform="scale(0.5)" xlink:href="#MJMATHI-48"></use></g><g is="true" transform="translate(415,-76)"><use transform="scale(0.5)" xlink:href="#MJMAIN-6D"></use><use transform="scale(0.5)" xlink:href="#MJMAIN-61" x="833" y="0"></use><use transform="scale(0.5)" xlink:href="#MJMAIN-78" x="1334" y="0"></use></g></g></g></g><g is="true" transform="translate(2151,0)"><g is="true"><use transform="scale(0.707)" xlink:href="#MJMAIN-28"></use></g><g is="true" transform="translate(275,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-3BB"></use></g><g is="true" transform="translate(688,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2212"></use></g><g is="true" transform="translate(1238,0)"><use transform="scale(0.707)" xlink:href="#MJMATHI-74"></use></g><g is="true" transform="translate(1494,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-29"></use></g></g><g is="true" transform="translate(3920,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-2B"></use></g><g is="true" transform="translate(4471,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-31"></use></g><g is="true" transform="translate(4825,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-5D"></use></g></g><g is="true" transform="translate(7174,0)"><use transform="scale(0.707)" xlink:href="#MJMAIN-7D"></use></g></g></g><g is="true" transform="translate(4977,-387)"><use transform="scale(0.707)" xlink:href="#MJMATHI-50"></use></g></g></g></g></g></svg><span class="MJX_Assistive_MathML" role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow is="true"><mi is="true">�</mi><mo linebreak="goodbreak" is="true">=</mo><mfrac is="true"><mrow is="true"><msub is="true"><mi is="true">�</mi><mo movablelimits="true" is="true">max</mo></msub><mo is="true">exp</mo><mrow is="true"><mo stretchy="false" is="true">{</mo><mo is="true">-</mo><mo is="true">exp</mo><mrow is="true"><mo stretchy="false" is="true">[</mo><mfrac is="true"><mrow is="true"><msub is="true"><mi is="true">�</mi><mo movablelimits="true" is="true">max</mo></msub><mi is="true">�</mi></mrow><msub is="true"><mi is="true">�</mi><mo movablelimits="true" is="true">max</mo></msub></mfrac><mrow is="true"><mo stretchy="false" is="true">(</mo><mi is="true">�</mi><mo is="true">-</mo><mi is="true">�</mi><mo stretchy="false" is="true">)</mo></mrow><mo is="true">+</mo><mn is="true">1</mn><mo stretchy="false" is="true">]</mo></mrow><mo stretchy="false" is="true">}</mo></mrow></mrow><mi is="true">�</mi></mfrac></mrow></math></span></span></span></span></span></p>
<p id="p0170">Where H and H<sub>max</sub><span> </span>is the cumulative and maximum hydrogen production (mL), e means the Euler’s number, t represents time and R<sub>max</sub><span> </span>denotes maximum production rate of hydrogen (mL h<sup>−1</sup>. Parameters – H<sub>max</sub><span> </span>and R<sub>max</sub><span> </span>has a direct influence on hydrogen production rate and yield.</p>
<p id="p0175"><span>Blackbox models include artificial <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/neural-network" title="Learn more about neural network from ScienceDirect's AI-generated Topic Pages" class="topic-link">neural network</a> (ANN) and <a href="https://www.sciencedirect.com/topics/engineering/response-surface-method" title="Learn more about response surface methodology from ScienceDirect's AI-generated Topic Pages" class="topic-link">response surface methodology</a> (RSM) analysis. RSM is useful in assessing individual factors and determining which component produces the best set of unique results. ANN is a recently created machine learning statistical approach which can be functionalized in wide range of data analysis including optimization for biofuel production. ANN model propose higher efficiency and accuracy on the fitting of modelling of <a href="https://www.sciencedirect.com/topics/engineering/biochemicals" title="Learn more about biochemical from ScienceDirect's AI-generated Topic Pages" class="topic-link">biochemical</a> processes and experimental responses in which the multilayer <a href="https://www.sciencedirect.com/topics/engineering/perceptron" title="Learn more about perceptron from ScienceDirect's AI-generated Topic Pages" class="topic-link">perceptron</a> (PCN) architecture is often employed. ADM1 - <a href="https://www.sciencedirect.com/topics/engineering/anaerobic-digestion" title="Learn more about Anaerobic Digestion from ScienceDirect's AI-generated Topic Pages" class="topic-link">Anaerobic Digestion</a> Model No.1 – is a condensed version of several math models that were utilised in the optimization research. This model takes into account several organic molecules as well as certain <a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/inorganic-substance" title="Learn more about inorganic substances from ScienceDirect's AI-generated Topic Pages" class="topic-link">inorganic substances</a>. ADM1 based model is based on the differential equations of system which signifies the interaction between the microorganisms, substrate and products. The utilization of ADM1 model to develop the production of biofuel/biogas is considered as difficult task because of rapid development of <a href="https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/biogas" title="Learn more about biogas from ScienceDirect's AI-generated Topic Pages" class="topic-link">biogas</a> plant with <a href="https://www.sciencedirect.com/topics/engineering/agro-wastes" title="Learn more about agro waste from ScienceDirect's AI-generated Topic Pages" class="topic-link">agro waste</a> as feedstock material. In optimization research, the regression model has also developed as a necessary model (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0150" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0150"><span class="anchor-text">Dave et al., 2021</span></a><span>). Rao and Basak (2020) RSM-based regression model for dark fermentative <a href="https://www.sciencedirect.com/topics/engineering/hydrogen-generation" title="Learn more about hydrogen generation from ScienceDirect's AI-generated Topic Pages" class="topic-link">hydrogen generation</a> revealed the pH dependency of hydrogen production in their investigation. The benefit of the models is their relative simplicity, but they can only be employed in the range of examined variables, and their application is restricted due to the length of a single experiment. The black box paradigm has the benefit of producing outcomes without requiring an exact reaction mechanism (</span><a class="anchor u-display-inline anchor-paragraph" href="https://www.sciencedirect.com/science/article/pii/S0960852421015455#b0520" data-sd-ui-side-panel-opener="true" data-xocs-content-type="reference" data-xocs-content-id="b0520"><span class="anchor-text">Rao and Basak, 2021</span></a>).</p>
</section>
<section id="s0065">
<h2 id="st085" class="u-h4 u-margin-l-top u-margin-xs-bottom">7.<span> </span>Conclusion</h2>
<p id="p0180"><span>Recent developments in lignocellulose bioconversion mechanisms have demonstrated the potential of efficient biofuel production. It is feasible to generate biofuel feedstock that is not naturally produced using modern <a href="https://www.sciencedirect.com/topics/engineering/synthetic-biology" title="Learn more about synthetic biology from ScienceDirect's AI-generated Topic Pages" class="topic-link">synthetic biology</a> </span><a href="https://www.sciencedirect.com/topics/earth-and-planetary-sciences/science-and-technology" title="Learn more about technologies from ScienceDirect's AI-generated Topic Pages" class="topic-link">technologies</a>. Regardless, genetic and metabolic engineering approach will considered as significant and innovative approach which manipulate and analyse the metabolic pathways for the enhancement of biofuel generation. Low-cost pretreatment and metabolic engineering techniques, modelling for large-scale commercial lignocellulose biofuel production should be the focus of future study. Furthermore, improved techniques must be developed in order to maximise the use of lignocellulose components in fuel generation by fully eliminating the recalcitrant property.</p>
</section>
<section id="s0075"></section>
<p></p>
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<title>Doing More with Less: Ensuring Sustainable Consumption and Production</title>
<link>https://sdgtalks.ai/doing-more-with-less-ensuring-sustainable-consumption-and-production</link>
<guid>https://sdgtalks.ai/doing-more-with-less-ensuring-sustainable-consumption-and-production</guid>
<description><![CDATA[ Delve into the evolving landscape of Sustainable Consumption and Production (SCP) as the United Nations navigates the delicate balance between abundant waste and global hunger. Uncover the transformative journey outlined in SDG 12, aimed at fostering sustainable consumption patterns. Despite the UN&#039;s persistent commitment to SCP, challenges persist, with the SDG Report 2020 revealing escalating global material footprints and hurdles in implementing the 10-Year Framework of Programmes. The COVID-19 pandemic accentuates the pressing need for a paradigm shift, prompting a reassessment of economic priorities towards a well-being-centric model. This exploration encapsulates the UN&#039;s intricate dance with SCP, weaving through history, debates, and the quest for a sustainable future. ]]></description>
<enclosure url="https://www.iisd.org/sites/default/files/styles/banner_desktop/public/2021-08/sustainable-consumption.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 31 Dec 2023 18:29:47 -0500</pubDate>
<dc:creator>Jarret Frank</dc:creator>
<media:keywords>sustainable consumption and production, sdgs, sustainability</media:keywords>
<content:encoded><![CDATA[<article class="o-section o-section--small-margin o-section--wysiwyg paragraph paragraph--type--wysiwyg paragraph--view-mode--default o-section--centred">
<div class="u-container">
<section class="o-section__content o-content-from-editor js-content-from-editor" lang="en">
<p>Every year, about one third of all food produced—about 1.3 billion tonnes—is wasted while 1 billion people remain undernourished and another 1 billion go to bed hungry. Households consume 29% of global energy contributing to 21% of carbon dioxide emissions (UNEP, 2020), pointing to the significant linkage between sustainable consumption and production (SCP) and the climate change challenge of ensuring access to renewable<span> </span><a href="https://www.iisd.org/articles/global-governance-sustainable-energy" rel="noopener" target="_blank">energy</a><span> </span>and the regulation of building standards to reflect best practice in green architecture.</p>
<p>A family in the Global North throws away an average of 30 kg of clothing each year. Only 15% is recycled or donated, and the rest goes directly to the landfill or is incinerated. Every year, 70 million trees in endangered and ancient forests are cut down and replaced by plantations of trees used to make wood-based fabrics, such as rayon, viscose, and modal (Sustain Your Style, 2020).</p>
<blockquote>
<p><em>Sustainable consumption and production: The use of services and related products, which respond to basic needs and bring a better quality of life while minimizing the use of natural resources and toxic materials as well as the emissions of waste and pollutants over the life cycle of the service or product so as not to jeopardise the need of future generations.</em></p>
<div class="author">Norwegian Ministry of Environment, Oslo Symposium on SCP, 1994</div>
</blockquote>
<p>Should the global population reach 9.6 billion by 2050, the equivalent of almost three planets would be required to provide the natural resources needed to sustain current lifestyles (UNEP, 2020). Ensuring SCP has been one of the greatest global challenges over the past fifty years.</p>
</section>
<aside class="o-section__aside"></aside>
</div>
</article>
<article class="o-section o-section--small-margin o-section--wysiwyg paragraph paragraph--type--wysiwyg paragraph--view-mode--default o-section--centred">
<div class="u-container">
<section class="o-section__content o-content-from-editor js-content-from-editor" lang="en">
<h2 id="evolution-sustainable-consumption-and-production-theme-un">Evolution of the “Sustainable Consumption and Production” Theme at the UN</h2>
<p>Declarations and plans to take responsibility for sustainable consumption and production patterns have been part and parcel of the United Nations cycle of sustainable development conferences stretching back to the 1972<span> </span><a href="https://www.iisd.org/articles/stockholm-and-birth-environmental-diplomacy" rel="noopener" target="_blank">UN Conference on the Human Environment</a><span> </span>in Stockholm. The conferences continue trying to respond to scientific and civil society demands to recognize “Spaceship Earth” (Fuller, 1968; Ward, 1966) is a closed system with limited capacity to fuel economic growth and absorb its by-products, including pollution and greenhouse gases.</p>
<p>A ground-breaking initiative came in 1972 with the publication of the report,<span> </span><em>Limits to Growth</em>, by a network of scientists and industrialists known as the Club of Rome (Meadows et. al., 1972). They commissioned the Massachusetts Institute of Technology to use computer simulations to dramatically demonstrate the futility of the human race we cannot win: the race between our capacity to sustain static stocks of resources and satisfy geometric growth rates in population and consumption.</p>
<iframe width="701" height="396" src="https://www.youtube.com/embed/uYNlhjOZ7DU?feature=oembed" frameborder="0" allow="accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share" allowfullscreen="allowfullscreen" title="Interview with Dennis Meadows on " limits="" to="" growth""=""></iframe>
<p>Arguments for restraints in consumption and a steady-state economy followed with Herman Daly’s<span> </span><em>Toward a Steady-State Economy</em><span> </span>(1973). This swell of concern had little impact on mainstream debates until 1987 and the publication of the World Commission on Sustainable Development’s report,<span> </span><a href="https://sustainabledevelopment.un.org/content/documents/5987our-common-future.pdf" rel="noopener" target="_blank"><em>Our Common Future</em></a><span> </span>(Brundtland Commission report). This report stressed that meeting essential human needs requires not only a new era of economic growth for nations where the majority remain in poverty, but an assurance that those living in poverty get their fair share of the resources. Equally, the report called on the affluent to adopt lifestyles within the planet’s ecological means. It has become increasingly well understood that economic growth as an ideology has been used to disguise and defer tackling the persistent problem of inequality.</p>
<blockquote>
<p><em>Sustainable global development requires that those who are more affluent adopt life-styles within the planet's ecological means—in their use of energy, for example... sustainable development can only be pursued if population size and growth are in harmony with the changing productive potential of the ecosystem.</em></p>
<div class="author"><em>Our Common Future</em>, Paragraph 29</div>
</blockquote>
<p>Five years later, the 1992 United Nations Conference on Environment and Development (Earth Summit) adopted the<span> </span><a href="https://www.un.org/en/development/desa/population/migration/generalassembly/docs/globalcompact/A_CONF.151_26_Vol.I_Declaration.pdf" rel="noopener" target="_blank">Rio Declaration</a><span> </span>on Environment and Development, which called on states to reduce and eliminate unsustainable patterns of production and consumption. After another ten years, the<span> </span><a href="https://www.un.org/ga/search/view_doc.asp?symbol=A/CONF.199/20/Corr.1&amp;Lang=E" rel="noopener" target="_blank">World Summit on Sustainable Development</a><span> </span>convened in Johannesburg, South Africa, and called for fundamental changes in the way societies produce and consume. This call was accompanied by a mandate for a ten-year framework of programmes (10YFP) to support regional and national initiatives to accelerate the shift toward SCP. This mandate was developed through what was known as the Marrakech Process, launched in 2003, which led to the adoption of the<span> </span><a href="https://www.unenvironment.org/explore-topics/resource-efficiency/what-we-do/one-planet-network/10yfp-10-year-framework-programmes" rel="noopener" target="_blank">Framework</a><span> </span>at the 2012 UN Conference on Sustainable Development (Rio+20).</p>
<p>In 2015, the UN adopted the<span> </span><a href="https://sdgs.un.org/2030agenda" rel="noopener" target="_blank">2030 Agenda for Sustainable Development</a><span> </span>and its 17 Sustainable Development Goals (SDGs), which aim to end poverty and set the world on a path to peace, prosperity, and opportunity on a healthy planet.<span> </span><a href="https://sdgs.un.org/goals/goal12" rel="noopener" target="_blank">SDG 12</a>, “Ensure sustainable consumption and production patterns,” links worldwide consumption and production—a driving force of the global economy—to the use of the natural environment and resources in a way that has destructive impacts on the planet.</p>
<p>Yet with all this attention, the<span> </span><a href="https://unstats.un.org/sdgs/report/2020/" rel="noopener" target="_blank"><em>Sustainable Development Goals Report 2020</em></a><span> </span>warned the global material footprint is increasing faster than population growth and economic output. It also notes how improvements in resource efficiency in some countries are offset by increases in intensity in others. Fossil fuel subsidies are also cited as a serious concern, as is the high proportion of food waste lost in long supply chains.</p>
<iframe width="701" height="396" src="https://www.youtube.com/embed/SmhEhqLAn8A?feature=oembed" frameborder="0" allow="accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share" allowfullscreen="allowfullscreen" title="How COVID-19 Will Affect the Sustainable Development Goals | Global Citizen Explains"></iframe>
<p>Despite decades of multilateral commitments, the world’s reliance on natural resources has accelerated. The<span> </span><em>SDG Report 2020</em> observes the material footprint (primary materials required to meet basic needs for food, clothing, water, shelter, infrastructure and other aspects of life) grew from 73.2 billion metric tons in 2010 to 85.9 billion metric tons in 2017, a 17.4% increase in just seven years. In addition, while 79 countries and the European Union reported on at least one national policy instrument contributing to the implementation of the 10YFP between 2017 and 2019, only 10% of all policies reported in 2019 related to<span> </span><em>economic and financial</em><span> </span>instruments, reflecting a limited operationalization of the 10YFP vision.</p>
<p>A shift has taken place in the UN discourse on SCP. While the Brundtland Commission focused on inter-generational equity, consumption volumes, and norms, and made an important distinction between addressing justified universal human “needs” and the “felt wants” of elite consuming classes, the language has changed. Now there is a different and more business-friendly focus on innovation and design in methods of production. This has steered the conversation away from norms and new regulations, enshrining the belief that economic growth can be decoupled from environmental degradation and resource depletion (Gasper et al., 2019, p.84) and created a significant blind spot around the role of corporate power to manufacture desire and elite consumer demands using ever more refined tools in the service of the attention economy.</p>
</section>
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<section class="o-section__content o-content-from-editor js-content-from-editor" lang="en">
<h2 id="sustainable-consumption-and-production-timeline">Sustainable Consumption and Production Timeline</h2>
<div class="c-responsive-table">
<table border="1" cellpadding="2" cellspacing="2" class="c-responsive-table__table">
<tbody>
<tr>
<td>
<p>1972</p>
</td>
<td>The Club of Rome report,<span> </span><em>Limits to Growth</em></td>
<td>Highlights the contradiction between static stocks of resources and growth in population and consumption</td>
</tr>
<tr>
<td>
<p>1972</p>
</td>
<td>UN Conference on the Human Environment (Stockholm, Sweden)</td>
<td>Recognizes the Earth's resources are finite and its capacity to re-absorb the by-products of production processes is limited.</td>
</tr>
<tr>
<td>
<p>1973</p>
</td>
<td>Herman Daly,<span> </span><em>Toward a Steady-State Economy</em></td>
<td>Calls for a steady-state economy, entailing stabilized population and per capita consumption.</td>
</tr>
<tr>
<td>
<p>1987</p>
</td>
<td>World Commission on Environment and Development report,<span> </span><em>Our Common Future</em></td>
<td>Distinguishes between human needs and felt wants; highlights an imbalance between the consumption patterns of the wealthy and the poor.</td>
</tr>
<tr>
<td>
<p>1992</p>
</td>
<td>UN Conference on Environment and Development (Rio de Janeiro, Brazil)</td>
<td>Recognizes unsustainable patterns of consumption and production as a major cause of continued deterioration of the global environment.</td>
</tr>
<tr>
<td>
<p>1994</p>
</td>
<td>Oslo Symposium on Sustainable Consumption (Oslo, Norway)</td>
<td>Provides what would become an authoritative definition of SCP.</td>
</tr>
<tr>
<td>
<p>2002</p>
</td>
<td>World Summit on Sustainable Development (Johannesburg, South Africa)</td>
<td>Calls for the development of a 10YFP to accelerate the shift towards SCP and promote social and economic development within the carrying capacity of ecosystems by de-linking growth from environmental degradation.</td>
</tr>
<tr>
<td>
<p>2003</p>
</td>
<td>First meeting of the Marrakech Process, a global multi-stakeholder platform to develop the 10YFP (Marrakech, Morocco)</td>
<td>The United Nations Environment Programme (UNEP) and the UN Department of Economic and Social Affairs (DESA) lead the development of the 10YFP.</td>
</tr>
<tr>
<td>
<p>2012</p>
</td>
<td>World Summit on Sustainable Development (Rio de Janeiro, Brazil)</td>
<td>Calls for a set of SDGs. The Summit also adopted the 10YFP as part of a global commitment to accelerate the shift towards SCP in developed and developing countries.</td>
</tr>
<tr>
<td>
<p>2015</p>
</td>
<td>UN Sustainable Development Summit (New York, US)</td>
<td>Adopts “Transforming Our World: The 2030 Agenda for Sustainable Development” and its 17 SDGs, including SDG 12 “Ensuring sustainable consumption and production.”</td>
</tr>
</tbody>
</table>
</div>
<p> </p>
</section>
<aside class="o-section__aside"></aside>
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<section class="o-section__content o-content-from-editor js-content-from-editor" lang="en">
<h2 id="key-debates-about-un-approach-and-conceptual-developments">Key Debates about the UN Approach and Conceptual Developments</h2>
<p>The fundamental terms of reference for the institutional debates on SCP can be traced back to a challenge to dominant assumptions in neo-classical economic theories that depend on notions of infinite growth and a planet without ecological boundaries. These early debates are populated by a colourful cast of pioneering thinkers and campaigners, notably Andre Gorz, Herman Daly, and Serge Latouche. They have their counterparts today in figures such as<span> </span><a href="https://www.kateraworth.com/doughnut/" rel="noopener" target="_blank">Kate Raworth</a>, the author of<span> </span><em>Doughnut Economics</em>, and the thought leaders on sustainable prosperity and growth,<span> </span><a href="https://www.cusp.ac.uk/themes/s2/paper-tj-pv-lowgrowsfc/" rel="noopener" target="_blank">Tim Jackson and Peter Victor</a>. None issued a more formative challenge than Nicholas Georgescu-Roegen, the intellectual pioneer of ecological economics and bioeconomics. In his<span> </span><em>Entropy Law and the Economic Process</em><span> </span>(1971), Georgescu-Roegen performed for economics the intellectual equivalent of<span> </span><a href="https://home.cern/science/accelerators/large-hadron-collider" rel="noopener" target="_blank">colliding two high-energy particle beams at the speed of light</a>. He did this by bringing physics and the natural sciences into a conversation (or collision) with conventional economics. His writing exposed how the fundamental aim of economic activity—the unlimited growth of production and consumption based on finite sources of matter/energy—is incompatible with the laws of nature. His key contributions to the laws of energy conversion, including the concept of “entropy,” explain the degradation of those vital qualities of matter/energy that make them valuable for production and consumption, namely concentration and organization. Matter and energy degradation is countered by a constant inflow of solar energy and other renewable sources of heat and tidal momentum, which explains the current global transition to new sources of energy infrastructure.</p>
<iframe width="703" height="397" src="https://www.youtube.com/embed/kxQeb2PDz9M?feature=oembed" frameborder="0" allow="accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share" allowfullscreen="allowfullscreen" title="What is Doughnut Economics? - with Kate Raworth"></iframe>
<p>Georgescu-Roegen’s ideas helped give rise to the degrowth movement—at first focused in the 1970s on resource limits, then re-emerging in the 2000s as a fundamental assault on what<span> </span><a href="http://rsesymposia.org/themedia/File/1151679499-Plenary2_Latouche.pdf" rel="noopener" target="_blank">Serge Latouche</a><span> </span>and others have described as the “oxymoron” concept of “sustainable development.” The degrowth movement is also associated with the birth of political ecology and attempts to re-locate our environmental challenges within dominant institutional and cultural ideas, including capitalism. Advocates call for the decolonization of public debate and the abolition of economic growth as a primary social objective. Instead, they support alternative social practices of sharing, simplicity, conviviality, care, and commoning that are consistent with equitable downscaling of production and consumption, leading to a reduced societal throughput of energy and raw materials. These practices are pursued in new forms of collaborative consumption and ecovillage communities.</p>
<iframe width="701" height="396" src="https://www.youtube.com/embed/0MXP2E09dJQ?feature=oembed" frameborder="0" allow="accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share" allowfullscreen="allowfullscreen" title="Degrowth, explained"></iframe></section>
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<h2 id="sdg-12-toward-systems-approach">SDG 12–Toward a Systems Approach?</h2>
<p>The SCP concept is prominently recognized in the 2030 Agenda. SDG 12 recognizes production and consumption habits are at the root of the planet’s sustainability problems and places them at the centre of the sustainable development agenda. Implementation of SDG 12 is linked to the achievement of overall development plans, the reduction of future economic, environmental, and social costs, strengthening economic competitiveness, and the reduction of poverty. </p>
<p>The SDG 12 targets cover a full range of issues, including:</p>
<ul>
<li>12.1: Implement the 10YFP </li>
<li>12.2: Sustainable management and use of natural resources</li>
<li>12.3: Halve global per capita food waste</li>
<li>12.4: Responsible management of chemicals and waste</li>
<li>12.5: Substantially reduce waste generation</li>
<li>12.6: Encourage companies to adopt sustainable practices and sustainability reporting</li>
<li>12.7: Promote sustainable public procurement practices</li>
<li>12.8: Promote universal understanding of sustainable lifestyles</li>
<li>12.A: Support developing countries’ scientific and technological capacity for SCP</li>
<li>12.B: Develop and implement tools to monitor sustainable tourism</li>
<li>12.C: Remove market distortions that encourage wasteful consumption</li>
</ul>
<p>At the second session of the United Nations Environment Assembly in 2016, the International Resource Panel was mandated to prepare a report,<span> </span><a href="https://www.resourcepanel.org/reports/assessing-global-resource-use" rel="noopener" target="_blank"><em>Assessing Global Resource Use: A systems approach to resource efficiency and pollution reduction</em></a><span> </span>(2017). The Panel identified decoupling economic activity and human well-being from resource use as an imperative. The report highlighted the complex linkages between human well-being, economic prosperity, and environmental resilience and the need for policy makers to act across all three domains to bring about transformative outcomes.</p>
<p>Adopting a systems approach, the Panel asserted that improving the well-being of people while minimizing resource use and environmental impacts, in particular through enhanced resource efficiency, is necessary to deliver SDG 12 as well as the other SDGs. To achieve this, the Panel supported the transformation of today’s “linear” material flows—from extraction to use and disposal—to become “circular” through intelligent design of products that incorporates standardization, reuse, recycling, remanufacturing, the development of efficient and inclusive infrastructure, and a new focus on the delivery of services rather than the sale of material products.</p>
</section>
<aside class="o-section__aside"></aside>
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<h2 id="sustainable-consumption-and-covid-19">Sustainable Consumption and COVID-19</h2>
<p>In his introduction to the<span> </span><a href="https://unstats.un.org/sdgs/report/2020/" rel="noopener" target="_blank"><em>SDG Report 2020</em></a>, UN Secretary-General António Guterres observed the root causes and uneven impacts of COVID-19 have demonstrated why we need the 2030 Agenda. He noted the pandemic has underscored the urgency of implementation and has called for an international response and recovery effort guided by the SDGs. The pandemic has prompted similar responses across the world, notably among advocates of a transformation of economic priorities so that public health and well-being are placed more centrally at the heart of government priorities.</p>
<blockquote>
<p>Far from undermining the case for the SDGs, the root causes and uneven impacts of COVID-19 demonstrate precisely why we need the 2030 Agenda…</p>
<div class="author">UN Secretary-General António Guterres, SDG Report 2020</div>
</blockquote>
<p>A European research and advocacy initiative, the<span> </span><a href="https://foundationaleconomy.com/introduction/" rel="noopener" target="_blank">Foundational Economy</a>, is developing new ways to think about economic policy, placing a focus on healthcare, education, housing, and the food supply. In their manifesto, the organization explains that the well-being of citizens in current and future generations depends less on individual [private] consumption and more on their social consumption of essential goods and services. The distinctive, primary role of public policy should therefore be to secure the supply of basic goods and services in a socially responsible way, and not boost private consumption to deliver economic growth. </p>
<p>Similar arguments have been advanced by a<span> </span><a href="https://weall.org/" rel="noopener" target="_blank">worldwide movement</a><span> </span>advocating government prioritization of well-being and well-being indicators to help steer qualitative and inclusive economic growth, as a replacement or complement to gross domestic product (GDP).</p>
<iframe width="701" height="396" src="https://www.youtube.com/embed/3ZtGK9tYX44?feature=oembed" frameborder="0" allow="accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share" allowfullscreen="allowfullscreen" title="What is a Wellbeing Economy v2"></iframe></section>
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<h2 id="what-future-do-we-want">What Future Do We Want?</h2>
<p>Both the<span> </span><a href="https://www.iisd.org/articles/global-climate-change-governance-search-effectiveness-and-universality" rel="noopener" target="_blank">climate</a><span> </span>emergency and the COVID-19 pandemic have accelerated public and governmental understanding of the need to shift our economic paradigm, with calls for “building back better” acknowledging there can be no wholesale retreat to the old economic order. Inspired by Franklin D. Roosevelt’s “New Deal” in response to the Great Depression in the United States in the early 1930s, proposals for<span> </span><a href="https://neweconomics.org/2019/04/a-green-new-deal" rel="noopener" target="_blank">green new deals</a><span> </span>have proliferated in response to climate change and the COVID-19 pandemic.</p>
<p>The most useful measures of progress toward SCP, however, will not be found in the indicator set used to monitor the progress of the SDGs. The key indicator to look for is a shift from a downstream focus on the re-design of private or corporate production and consumption to an upstream focus on the fundamental drivers of national and international economic priorities. Rather than treating markets, for example, as free-standing entities subject to occasional regulatory intrusions, markets must be regarded once again as outcomes of a social process amenable to democratic decision-making. This must accompany a wholesale shift in how society approaches the core question of what it values and whether we are prepared to continue to allow market exchange and pricing mechanisms a privileged status in determining what is to be valued, produced, and consumed. Until this macro-level economic debate on value is resolved in favour of equality and socio-ecological regeneration it will be difficult to see how market and pricing mechanisms applied to biodiversity, forests, and land can produce long-term shifts in consumption practices.</p>
<p>The economist<span> </span><a href="https://marianamazzucato.com/" rel="noopener" target="_blank">Mariana Mazzucato</a><span> </span>is making waves with her powerful calls for a green revolution founded on deliberate and conscious changes in social values: a redirection of the entire economy, transforming production, distribution, and consumption in all sectors in favour of the common good. She has called for the concept of “value” to find its rightful place at the centre of economic reasoning if we are to meaningfully respond to the question: “What future do we want?” To paraphrase Oscar Wilde, the future cannot be left in the hands of cynics—or economists—who know the price of everything and the value of nothing.</p>
</section>
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<title>A &amp;apos;concrete&amp;apos; solution to climate change</title>
<link>https://sdgtalks.ai/a-concrete-solution-to-climate-change</link>
<guid>https://sdgtalks.ai/a-concrete-solution-to-climate-change</guid>
<description><![CDATA[ This article discusses the recent achievement of the United States&#039; first commercial-scale direct-air capture (DAC) facility in Tracy, California, developed by Heirloom. Using limestone to absorb carbon dioxide from the air, the DAC plant aims to sequester 1,000 tons of CO2 annually, with support from the federal government, major technology companies, and an investment from Microsoft. Despite the promising milestone, critics argue that DAC technology, costing over $1,000 per ton of CO2 removal, perpetuates fossil fuel use and increases emissions. Heirloom promises permanent sequestration of captured carbon, particularly in concrete, partnering with CarbonCure Technologies to inject CO2 into concrete for environmental benefits. While some see DAC as a necessary tool to combat climate change and create economic opportunities, others, like Stanford University&#039;s Mark Jacobson, consider it a wasteful distraction from investing in more effective renewable energy solutions. The article underscores the importance of a multifaceted approach to address climate change, combining renewable energy deployment with innovative technologies to reduce existing atmospheric carbon. ]]></description>
<enclosure url="https://media.wbur.org/wp/2023/12/DAC_1-1.jpg" length="49398" type="image/jpeg"/>
<pubDate>Thu, 07 Dec 2023 16:57:31 -0500</pubDate>
<dc:creator>Ava Brennan</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p dir="ltr"><span>Many of the new solutions to flight climate change sound almost impossible. What if a machine could suck planet-warming carbon dioxide out of the air and store the gas forever inside concrete bridges and buildings?</span></p>
<p dir="ltr"><span>Well, that’s happening. Last month, in the city of Tracy, California, the U.S. energy secretary joined a group of very excited scientists and corporate executives to celebrate a milestone: the country’s </span><a href="https://www.heirloomcarbon.com/news/heirloom-unveils-americas-first-commercial-direct-air-capture-facility"><span>first commercial-scale direct-air capture, or DAC, facility.</span></a></p>
<p dir="ltr"><span>This is a template of what we need to be building across the world,” said Heirloom CEO Shashank Samala. “Just like we have solar farms and wind farms, we want carbon farms sucking up CO2 from the air.”</span></p>
<p dir="ltr"><span>Heirloom is just three years old, but the company has already secured a huge investment from the federal government and a sizable boost from some of the biggest names in technology.</span></p>
<p dir="ltr"><span>The direct-air capture plant in Tracy promises to absorb 1,000 tons of CO2 from the sky every year — it’s</span><a href="https://www.epa.gov/energy/greenhouse-gas-equivalencies-calculator#results"><span> equivalent to taking about 220 cars off the road.</span></a></p>
<h3 dir="ltr"><span>Carbon-hungry limestone</span></h3>
<p dir="ltr"><span>The technology works by taking advantage of limestone’s natural tendency to absorb carbon dioxide. Inside Heirloom’s DAC plant, towers of stacked trays rise 40 feet above the ground.</span></p>
<p dir="ltr"><span>Each one of the trays is covered with a powdery limestone substance. As a breeze moves through the open-air building, the carbon in the atmosphere binds to the limestone. After a few days, robots move the trays into a kiln where a blast of heat separates the carbon from the limestone. All of it is powered by renewable energy.</span></p>
<p dir="ltr"><span>But one plant is nowhere near enough, Samala says.</span></p>
<p dir="ltr"><span>“These facilities need to be a thousand times larger,” he says, “and we need to build thousands of those across the world.”</span></p>
<p dir="ltr"><span>A few big spenders agree. To offset its emissions, Microsoft announced in September that it would buy up to 315,000 metric tons of Heirloom’s captured carbon in a deal that cost the company about $200 million.</span></p>
<p dir="ltr"><span>There’s also a lot of money from the government. The Biden Administration is </span><a href="https://www.energy.gov/articles/biden-harris-administration-announces-12-billion-nations-first-direct-air-capture"><span>investing $1.2 billion dollars in Heirloom and other companies</span></a><span> to build direct-air-capture hubs in Louisiana and Texas.</span></p>
<p dir="ltr"><span>But right now the technology is still prohibitively expensive. It costs more than $1,000 to remove one ton of CO2.</span></p>
<p dir="ltr"><span>“This is like the first iPhone getting out of the assembly line,” Samala says. “If you only produced one iPhone, it would cost billions of dollars. That’s the same here. It costs over $1,000 a ton because it’s early. It's first.”</span></p>
<p dir="ltr"><span>But what do you do with all the carbon once it's removed from the air? Some oil companies use carbon dioxide for something called enhanced oil recovery — a technique that pushes more polluting fossil fuels out of the ground.</span></p>
<p dir="ltr"><span>Samala promises that all of the CO2 Heirloom removes from the air will be permanently sequestered, either underground or in concrete.</span></p>
<h3 dir="ltr"><span>A ‘concrete’ solution</span></h3>
<p dir="ltr"><span>Storing carbon in concrete is already happening, and supporters of the technology say it reduces the environmental footprint of one of the world’s dirtiest industries.</span></p>
<p dir="ltr"><span>Producing concrete for bridges, sidewalks and highways accounts for about </span><a href="https://psci.princeton.edu/tips/2020/11/3/cement-and-concrete-the-environmental-impact"><span>8% of the world’s carbon emissions</span></a><span>. In large part, that’s because making cement — a key binding ingredient in concrete — requires heating limestone to very high temperatures.</span></p>
<p dir="ltr"><span>“Concrete is the second most widely consumed material on earth after water. At the same time concrete is emissions-intensive,” says Reilly O’Hara, of CarbonCure Technologies.</span></p>
<p dir="ltr"><span>The Canadian company says it has sold nearly 800 systems to inject carbon dioxide for storage in concrete across 35 countries. In November, CarbonCure announced </span><a href="https://www.carboncure.com/news/carboncure-and-heirloom-agree-to-store-atmospheric-co2-in-concrete/"><span>a partnership with Heirloom</span></a><span>, ensuring that carbon dioxide removed in Tracy will be used in nearby concrete plants.</span></p>
<p dir="ltr"><span>At the Vulcan Materials Central Concrete plant in San Jose, CarbonCure's technology is already in use. Just before a load of wet concrete gets dumped into the spinning drum of a heavy-duty truck, a stream of CO2 is injected into the mix.</span></p>
<p dir="ltr"><span>Carbon is not necessary to make concrete. But CO2 does give concrete a strength boost when it mineralizes in mixture, says Alana Guzzetta, who runs Vulcans’ national research lab in San Jose.</span></p>
<p dir="ltr"><span>That added strength means less planet-warming cement is required in each batch of concrete, helping the company lower its carbon footprint.</span></p>
<p dir="ltr"><span>“Get to zero carbon ultimately, that’s the goal,” Guzzetta says.</span></p>
<p dir="ltr"><span>The concrete producers that use CarbonCure’s technology also share in the revenue from any carbon credits sold.</span></p>
<p dir="ltr"><span>“Once that CO2 is embedded in the concrete, it’s there forever,” O’Hara says. “Even if the concrete is later crushed or demolished, that CO2 is permanently transformed into a rock and won’t be re-released into the atmosphere”</span></p>
<h3 dir="ltr"><span>A distraction, or worse?</span></h3>
<p dir="ltr"><span>CarbonCure says its technology has already been used to lock away 379,000 metric tons of carbon dioxide in concrete.</span></p>
<p dir="ltr"><span>But critics aren’t sold on the idea of sourcing the carbon from direct-air capture facilities or more traditional sources captured from polluting industrial plants.</span></p>
<p dir="ltr"><span>“It’s a complete and utter waste of money,” says Mark Jacobson, professor of civil and environmental engineering at Stanford University. He argues that </span><a href="https://themessenger.com/opinion/bidens-carbon-capture-funding-incentivizes-emissions-higher-costs-climate-energy"><span>DAC technology “increases carbon dioxide.</span></a><span> It increases air pollution. It increases fossil fuel mining.”</span></p>
<p dir="ltr"><span>That’s because the technology perpetuates the use of fossil fuels. Jacobson says the wind turbines and solar panels needed to run thousands of new large-scale carbon farms around the globe would be much better off replacing coal-fired power plants. Add up the new pipelines or trucks you’d need to get that carbon to places like concrete plants, and it just doesn’t make sense, he says.</span></p>
<p dir="ltr"><span>These direct-air capture companies are “ignoring entirely the opportunity cost, ignoring the fact you could be using that renewable energy for something much more effective,” Jacobson says. “They’re not accounting for that one bit.”</span></p>
<p dir="ltr"><span>Jacobson acknowledges he is a lonely voice against a technology that </span><a href="https://www.iea.org/news/the-path-to-limiting-global-warming-to-1-5-c-has-narrowed-but-clean-energy-growth-is-keeping-it-open"><span>global leaders say is necessary</span></a><span> to limit the worst effects of climate change while the world weans itself off of fossil fuels.</span></p>
<p dir="ltr"><span>“There is not a single silver bullet,” says Pat Sapinsley, managing director at New York University’s Urban Future Lab, a business incubator that has helped climate-conscious entrepreneurs raise $2 billion in private capital since 2009.</span></p>
<p dir="ltr"></p>
<p dir="ltr"><span>Yes, countries must deploy renewable energy “like crazy,” Sapinsley adds. But they should also take advantage of new technologies — and new economic opportunities — to reduce the carbon that’s already in the atmosphere.</span></p>
<p dir="ltr"><span>Companies are already using new supplies of captured carbon to make diamonds, jet fuel, perfume, and yes, concrete.</span></p>
<p dir="ltr"><span>“It’s a little bit like the era of the horse and buggy and somebody looking at a car and saying, ‘Oh that will never work,’” Sapinsley says. “I think it just takes some time to convince people that the future is in developing climate-tech. We need some changes in our economy.”</span></p>
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<title>Big food companies commit to &amp;apos;regenerative agriculture&amp;apos; but skepticism remains</title>
<link>https://sdgtalks.ai/big-food-companies-commit-to-regenerative-agriculture-but-skepticism-remains</link>
<guid>https://sdgtalks.ai/big-food-companies-commit-to-regenerative-agriculture-but-skepticism-remains</guid>
<description><![CDATA[ This article discusses the increasing adoption of regenerative agriculture practices by farmers as a climate change mitigation tool. Will Cannon, a farmer in Iowa, employs climate-friendly farming methods such as planting cover crops and avoiding excessive soil tillage to sequester carbon. Companies like PepsiCo and Unilever are financing such practices in collaboration with farmers, demonstrating a cross-supply chain partnership trend. A consortium of 12 major food companies, including Mars, PepsiCo, and McDonald&#039;s, recently announced plans to scale up regenerative farmland, aligning with commitments to achieve net-zero greenhouse gas emissions. However, challenges exist in converting only 15% of global farmland to regenerative practices, with financial risks for farmers and a lack of standardized definitions and measurements for regenerative agriculture. The article emphasizes the need for companies to incentivize farmers through procurement contracts and various financial strategies to achieve a significant shift toward regenerative practices in global agriculture. ]]></description>
<enclosure url="https://media.npr.org/assets/img/2022/11/02/gettyimages-1236174247_custom-d5bac4cb8ae76c9a473597fa9fa76ca3819cc10b-s800-c85.webp" length="49398" type="image/jpeg"/>
<pubDate>Thu, 07 Dec 2023 16:39:12 -0500</pubDate>
<dc:creator>Ava Brennan</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p dir="ltr"><span>Will Cannon does more to sequester carbon than the average U.S. farmer.</span><b></b></p>
<p dir="ltr"><span>After he harvests his corn and soybeans, he plants cover crops, which sequester carbon all winter long, on his entire 1,000-acre operation in Prairie City, Iowa. He's avoiding tilling, or plowing, his soil as much as possible, which helps keep carbon stored in the ground.</span><b></b></p>
<p dir="ltr"><span>"I've kind of had a passion for conservation all my life," he says. "We've always been pushing the envelope on what we're trying to do."</span><b></b></p>
<p dir="ltr"><span>Cannon is getting help to finance this climate-friendly way of farming, which costs him thousands of dollars for additional machinery and seed, from the kinds of companies that ultimately buy his product. Footing the bill in his case is PepsiCo and Unilever, which own food brands ranging from Lay's and Gatorade to Hellman's and Ben &amp; Jerry's.</span></p>
<p dir="ltr"><span>This kind of cross-supply chain partnership could become increasingly common. A consortium of 12 food companies, including Mars, PepsiCo and McDonald's, announced a plan to scale up the amount of regenerative farmland. The plan was released just days before the 27th Conference of the Parties to the United Nations Framework Convention on Climate Change (COP27) in Egypt.</span><b></b></p>
<p dir="ltr"><span>While the practices regenerative agriculture encompasses are nothing new, it's becoming an increasingly popular climate change mitigation tool, especially among mega food corporations.</span><b></b></p>
<p dir="ltr"><span>"I think [regenerative agriculture] has a tremendous but under-tapped opportunity to have a major impact on climate change," says Jim Andrew, PepsiCo's chief sustainability officer.</span><b></b></p>
<p dir="ltr"><span>The food system accounts for a third of global greenhouse gas emissions and the private sector largely controls that system. Corporations, including Mars and PepsiCo, have made commitments to net zero greenhouse gas emissions. But the industry is inextricably tied to emissions, with an enormous, multi-million ton carbon footprint. Part of that stems from rampant deforestation. The corporate food industry also relies heavily on plastic packaging — another big source of emissions.</span><b></b></p>
<p dir="ltr"><span>"They're invested in the system which generates greenhouse gas emissions, and essentially they are trapped by the need to continue to not only be profitable, but to grow their profits," says Ricardo Salvador with the Union of Concerned Scientists.</span><b></b></p>
<p dir="ltr"><span>This isn't the first regenerative agriculture commitment PepsiCo has made. Last year, the company, which earned $9.7 billion over the past year, committed to converting its entire 7 million acre agricultural footprint to regenerative practices by 2030. The company says that will eliminate at least 3 million tons of greenhouse gas emissions. Most of the farmland in that footprint grows potatoes, whole corn, oats, and oranges</span><b></b></p>
<p dir="ltr"><span>In its first year, PepsiCo inched only 5% of the way through that goal, enrolling 345,000 acres in its various regenerative agriculture programs.</span><b></b></p>
<p dir="ltr"><span>Still, Andrew is optimistic. While he won't reveal 2022 acreage yet, he calls it "a decided step up."</span></p>
<p><b> </b></p>
<p dir="ltr"><strong>The scale-up challenge</strong><b></b></p>
<p dir="ltr"><span>Currently, only 15% of global farmland is cared for using regenerative practices, according to the new action plan and report from the Sustainable Markets Initiative (SMI). The group says that number needs to scale up to 40% by 2030 in order to keep global warming to 1.5 degrees Celsius, as laid out in the 2015 Paris Climate Agreement. And that won't be easy, especially given the current global agriculture market.</span><b></b></p>
<p dir="ltr"><span>"The commodity system tells [farmers]: Yield at all costs," says Sarah Carlson with Practical Farmers of Iowa. "And yield at all costs means that Mother Nature then pays. Climate change is her telling us: No more."</span><b></b></p>
<p dir="ltr"><span>Converting to regenerative agriculture is a financial risk for farmers. It can cost tens of thousands of dollars to buy new equipment and additional seed, fuel and labor. And in its current state, the commodity crop market doesn't provide incentives to incur that cost.</span><b></b></p>
<p dir="ltr"><span>"We need to invest in those farmers to de-risk that transition," she says. "I do think that companies have a huge role to play in making a big shift on the landscape."</span><b></b></p>
<p dir="ltr"><span>That could manifest in a number of ways, but Carlson says one of the most effective would be to bake it into procurement contracts. In other words, the onus would be on the company to buy an ingredient (corn, rice, potatoes, etc.) only if it was grown using sustainable practices.</span><b></b></p>
<p dir="ltr"><span>"That's absolutely an essential part of this plan," says Grant Reid, outgoing CEO of Mars and chair of the SMI taskforce.</span><b></b></p>
<p dir="ltr"><span>The plan, while lacking in specificity, lays out five general strategies to financially incentivize farmers to transition to regenerative agriculture. The strategies range from direct payments to farmers to encouraging governments around the world to commit policy and public money.</span><b></b></p>
<p dir="ltr"><span>Reid, former chief procurement officer for Mars, says another strategy is to change the way companies buy their products.</span><b></b></p>
<p dir="ltr"><span>"We used to buy a spec against the quality and price," he says. "Now I think we need to have our sustainability teams and our procurement teams working closely."</span><b></b></p>
<p dir="ltr"><span>Reid acknowledges prescribing any one fix across twelve of the largest global food companies is unrealistic. What works for a fast food chain might not work for a beverage corporation. And, along the same lines, what works for a rice farmer in India might not work for a corn farmer in Iowa.</span><b></b></p>
<p dir="ltr"><span>"There's no one size fits all, right?" he says. "There's not one crop, one company, one country that's identical. So you can't be too prescriptive."</span><b></b></p>
<p dir="ltr"><span>But that lack of precision could make it difficult to track the coalition's climate progress. Especially because there's no standardized definition of regenerative agriculture. There's no step-by-step guide or menu dictating what constitutes a regenerative farm.</span><b></b></p>
<p dir="ltr"><span>"We're satisfied so far when somebody tells us that they're using a regenerative practice, say, reduced tillage or cover crops, without then asking the question: How do you know that? What is the actual, quantifiable, verifiable result?" says Salvador with the Union of Concerned Scientists.</span><b></b></p>
<p dir="ltr"><span>In other words, there's no standard for how much carbon is sequestered on one acre of cover crops, for instance. That number will vary by region, crop and farmer.</span><b></b></p>
<p dir="ltr"><span>"In addition to being verifiable, it needs to be permanent," says Salvador. "Because if it's not permanent, then in essence it's not really helping us with climate change."</span><b></b></p>
<p dir="ltr"><span>Despite his cautionary notes, Salvador acknowledges the important role of private industry in scaling up regenerative agriculture across the food system.</span><b></b></p>
<p dir="ltr"><span>Ultimately, if the world wants more farmers to farm like Will Cannon, food companies need to send those market signals. While most of his farming neighbors still look at him and his untilled ground funny, Cannon thinks that could change if the private industry keeps putting their money where their mouth is.</span><b></b></p>
<p dir="ltr"><span>"As farmers, we've got to offer a bountiful crop again in the future, and I'm hopeful for the seeds that a lot of these companies are trying to plant right now," says Cannon.</span></p>]]> </content:encoded>
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<title>Discover the Untold Story of The Mare Pasture &#45; A Sustainable Tiny Home Oasis</title>
<link>https://sdgtalks.ai/discover-the-untold-story-of-the-mare-pasture-a-sustainable-tiny-home-oasis</link>
<guid>https://sdgtalks.ai/discover-the-untold-story-of-the-mare-pasture-a-sustainable-tiny-home-oasis</guid>
<description><![CDATA[ Nestled in the heart of Sulphur Springs Valley, AZ &quot;The Mare Pasture&quot; is redefining modern living with a sustainable twist. Our tiny home village is a testament to the harmony between nature, community, and conscientious living. ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202312/image_430x256_656cb35903d06.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 03 Dec 2023 12:00:38 -0500</pubDate>
<dc:creator>Holly Lee</dc:creator>
<media:keywords>sustainable, tiny home village, nature, community, conscientious living</media:keywords>
<content:encoded><![CDATA[<p class="MsoNormal">Nestled in the heart of Sulphur Springs Valley, AZ "The Mare Pasture" is redefining modern living with a sustainable twist. Our tiny home village is a testament to the harmony between nature, community, and conscientious living. We believe that our story could inspire, engage, and resonate with a large audience.</p>
<p class="MsoNormal"></p>
<p class="MsoNormal">Sustainable Living: The Mare Pasture is dedicated to eco-friendly living. Our tiny homes are ingeniously designed for minimal environmental impact, utilizing renewable energy, water conservation, and waste reduction to create a truly sustainable community.</p>
<p class="MsoNormal"> </p>
<p class="MsoNormal">Community and Togetherness: In a world that sometimes feels disconnected, our village fosters a close-knit, supportive community where neighbors become friends, and shared values of sustainability and eco-conscious living are celebrated.</p>
<p class="MsoNormal"> </p>
<p class="MsoNormal">Tiny Home Lifestyle: With the tiny home movement gaining momentum, The Mare Pasture offers a living experience that focuses on quality over quantity, simplicity over excess, and a life free from the burden of unnecessary possessions.</p>
<p class="MsoNormal"> </p>
<p class="MsoNormal">Saving this Rangeland: The Mare Pasture is designed by renowned Tucson architect John Riggs. John grew up on Red Wing Ranch, which includes The Mare Pasture, and is a descendant of Brannick Riggs, founder of the original Riggs Settlement and family ranches in Cochise County. John is passionate about preserving his family's heritage and the beautiful open rangelands of Southeastern Arizona.<span> </span></p>
<p class="MsoNormal"> </p>
<p class="MsoNormal">We believe that these aspects of The Mare Pasture offer a fresh perspective on modern living and eco-conscious choices. We envision our village as a blueprint for sustainable communities.</p>]]> </content:encoded>
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<title>Creating Resilient and Sustainable Technologies – COP28 UAE TechSprint by Selva Ozelli</title>
<link>https://sdgtalks.ai/creating-resilient-and-sustainable-technologies-cop28-uae-techsprint-by-selva-ozelli</link>
<guid>https://sdgtalks.ai/creating-resilient-and-sustainable-technologies-cop28-uae-techsprint-by-selva-ozelli</guid>
<description><![CDATA[ The Bank for International Settlements (BIS), COP28 and Central Bank of United Arab Emirates launched TechSprint to develop technological solutions for sustainable finance and combating climate change. This technology initiative fosters innovation in scaling sustainable finance and combating climate change.  ]]></description>
<enclosure url="https://www.tiredearth.com/images/720/6558c13d87b68.jpg" length="49398" type="image/jpeg"/>
<pubDate>Tue, 28 Nov 2023 18:35:47 -0500</pubDate>
<dc:creator>Selva Ozelli</dc:creator>
<media:keywords>tech, blockchain, cop28, art</media:keywords>
<content:encoded><![CDATA[<p><em>“Combating climate change is more urgent than ever. It calls for a profound change in the way economies operate and grow. To finance the needed transformation, investors need certainty that their funds are channeled to their intended uses. Technologies that promote the timely measurement and disclosure of climate-related information are part of the solution. The BIS Innovation Hub has explored how to apply technologies such as AI, blockchain and internet-of-things to green finance instruments and climate-related disclosure. This TechSprint in collaboration with the COP28 UAE, the CBUAE and EIF will complement these efforts to address remaining gaps in the green finance market”,</em><span> </span>explained Agustín Carstens, General Manager of the BIS.</p>
<p><em><strong>Future of Power Art Show by Global Resilience Partnership</strong></em></p>
<p><iframe width="620" height="349" allow="accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share" allowfullscreen="allowfullscreen" frameborder="0" src="https://www.youtube.com/embed/NIeCKwbeYp0" title="" future="" of="" power="" "="" art="" show"=""></iframe></p>
<p></p>
<div class="field field-name-body field-type-text-with-summary field-label-hidden">
<div class="field-items">
<div class="field-item even" property="content:encoded">
<p>This Techsprint at COP28 is being developed jointly by the Central Bank of the United Arab Emirates (CBUAE), alongside the COP28 Presidency, the Emirates Institute of Finance (EIF) and the BIS.</p>
<p><em>“In line with the vision of the UAE's leadership, and its endeavours to address the challenges of climate change; we value the partnership with COP28 UAE and the BIS in launching this international initiative aimed at encouraging innovators across the globe to leverage financial technology in developing new green and sustainable finance solutions”,</em><span> </span>said Khaled Mohamed Balama, Governor of the CBUAE and Chairman of EIF.</p>
<p>The campaign calls for technology solutions to address data verification gaps in sustainable finance in three problem statements:</p>
<ul>
<li>AI solutions for sustainable finance reporting, verification, and disclosure in the financial services industry. </li>
<li>Blockchain solutions for auditing and enhancing transparency, traceability, and accountability in sustainable finance.</li>
<li>Internet-of-Things and sensor technology solutions for sustainable finance to ensure informed assessments of impact, risk, or compliance. </li>
</ul>
<p><em>“COP28 looks forward to working with its partners to drive real solutions to scale up climate action and fast-track sustainable finance initiatives around the world”</em>, said Dr Sultan Al Jaber, COP28 President Designate.</p>
<p></p>
<p><strong>Blockchain solutions for sustainable finance</strong></p>
<p>Parallel to the COP28 Tech initiative, in Singapore, with a similar theme, the BSN Foundation announced its founding members, its role in sustainable blockchain-as-a-service.</p>
<p>BSN Foundation is the governing body of the BSN Spartan Networks made up of:<span> </span><a href="https://www.reddatetech.com/">Red Date Technology</a>,<span> </span><a href="https://www.blockdaemon.com/">Blockdaemon</a>,<span> </span><a href="https://www.gft.com/">GFT Technologies</a>,<span> </span><a href="https://toko.network/">TOKO</a>,<span> </span><a href="https://www.zeeve.io/">Zeeve</a>. These organizations originating from a diverse range of countries and regions, such as the U.S.A., Germany, and Hong Kong, will bring a wide range of expertise dedicated to building the next-generation global Public IT System infrastructures for internet communications, digital economies, metaverses, digital payments and NFTs based on non-cryptocurrency public chain technologies, designed to serve IT systems around the world to advance fundamental technologies that benefit all humankind.  </p>
<p>Tim Bailey, the VP of Global Business &amp; Operations of for Red Date Technology explained<span> </span><em>“on November 16, we announced the founding members of the BSN Foundation that governs the BSN Spartan Network. The network launched late last year with three non-cryptocurrency public chains, including non-crypto versions of sustainable, proof of stake blockchain platforms Ethereum, Cosmos and PolygonEdge. The BSN Spartan Network provides an infrastructure that integrates non-cryptocurrency public blockchains that can be used by any traditional IT system to leverage the capabilities of the underlying blockchain technology in an easier and more cost-effective way. The service will be offered with fixed fees based in fiat currency or USD backed stable coin and is only available outside Mainland China. The cost of using our public chain technology is significantly lower and more predictable than using cryptocurrency based public chains."</em></p>
<p><em></em></p>
<p><em><img src="https://www.tiredearth.com/storage/files/shares/6558c51ed07a4.jpg" width="680" height="509" alt=""></em></p>
<p>The BSN Foundation will start with five members, with the goal of eventually growing to 40 members. Collectively, these organizations will contribute to the BSN Foundation’s mission to pioneer public IT system development at a global level to bring a portfolio of expertise ranging from blockchain-as-a-service and real-world asset tokenization to financial services and consulting.</p>
<p>Looking toward the future, the BSN Foundation aims to expand its membership to at least 40 members, operating as a decentralized governance body.<span> </span><em>“When 40 leading international companies govern the Spartan Network as Foundation members with equal voting rights, the network will become one of the most decentralized IT infrastructures in the world”</em>, said Yifan He, CEO of Red Date Technology. </p>
<p>Together, they aim to promote the concept of public IT systems that complements the existing centralized IT architectures, revolutionizing traditional business operations and data communication in a sustainable way.</p>
<p> </p>
<p><em><strong>Selva Ozelli</strong>, Author of Sustainably Investing in Digital Assets Globally</em></p>
</div>
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<title>New type of recyclable plastic could help reduce single&#45;use plastic waste</title>
<link>https://sdgtalks.ai/new-type-of-recyclable-plastic-could-help-reduce-single-use-plastic-waste</link>
<guid>https://sdgtalks.ai/new-type-of-recyclable-plastic-could-help-reduce-single-use-plastic-waste</guid>
<description><![CDATA[ Hundreds of millions of tons of single-use plastic ends up in landfills every year, and even the small percentage of plastic that gets recycled can’t last forever. A group of materials scientists has developed a new method for creating and deconstructing polymers that could lead to more easily recycled plastics – ones that don’t require you to carefully sort out all your recycling on trash day. ]]></description>
<enclosure url="https://encrypted-tbn1.gstatic.com/images" length="49398" type="image/jpeg"/>
<pubDate>Mon, 20 Nov 2023 23:37:15 -0500</pubDate>
<dc:creator>judelowe</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p><a href="https://www.unep.org/interactives/beat-plastic-pollution/">Hundreds of millions of tons</a><span> </span>of single-use plastic ends up in landfills every year, and even the small percentage of plastic that gets recycled can’t last forever. But our group of materials scientists has developed a new method for creating and deconstructing polymers that could lead to more easily recycled plastics – ones that don’t require you to carefully sort out all your recycling on trash day.</p>
<p>In the century since their conception, people have come to understand the enormous impacts – beneficial as well as detrimental – plastics have on human lives and the environment. As a<span> </span><a href="https://miyakelab.colostate.edu/">group of polymer scientists</a><span> </span>dedicated to inventing sustainable solutions for real-world problems, we set out to tackle this issue by rethinking the way polymers are designed and making plastics with recyclability built right in.</p>
<h2>Why use plastics, anyway?</h2>
<p>Everyday items including milk jugs, grocery bags, takeout containers and even ropes are made from a class of<span> </span><a href="https://www.polymersolutions.com/blog/top-types-of-polyolefins-the-most-common-kind-of-plastics/">polymers called polyolefins</a>. Polyolefins make up around<span> </span><a href="https://ourworldindata.org/grapher/plastic-waste-polymer">half of the plastics</a><span> </span>produced and disposed of every year.</p>
<p>These polymers are used in plastics commonly labeled as HDPE, LLDPE or PP, or by their recycling codes #2, #4 and #5, respectively. These plastics are incredibly durable because the<span> </span><a href="https://doi.org/10.1021/acssuschemeng.9b06635">chemical bonds</a><span> </span>that make them up are extremely stable. But in a world set up for single-use consumption, this is no longer a design feature but rather a design flaw.</p>
<p><iframe width="100%" height="400px" id="2k7dQ" class="tc-infographic-datawrapper" src="https://datawrapper.dwcdn.net/2k7dQ/1/" frameborder="0"></iframe></p>
<p>Imagine if half of the plastics used today were recyclable by twice as many processes as they are now. While that wouldn’t get the recycling rate to 100%, a jump from single digits –<span> </span><a href="https://www.energy.gov/articles/department-energy-releases-plastics-innovation-challenge-draft-roadmap-and-request">currently around 9%</a><span> </span>– to double digits would make a big dent in the plastics produced, the plastics accumulated in the environment and their capacity for recycling and reuse.</p>
<h2>Recycling methods we already have</h2>
<p>Even the plastics that make it to a recycling facility<span> </span><a href="https://ellenmacarthurfoundation.org/plastics-and-the-circular-economy-deep-dive">can’t be reused</a><span> </span>in exactly the same way they were used before – the recycling process degrades the material, so it loses utility and value. Instead of making a plastic cup that is downgraded each time it gets recycled, manufacturers could potentially make plastics once, collect them and reuse them on and on.</p>
<p>Conventional recycling requires careful sorting of all the collected materials, which can be hard with so many different plastics. Here in the U.S., collection happens mainly through<span> </span><a href="https://www.container-recycling.org/index.php/issues/single-stream-recycling">single stream recycling</a><span> </span>– everything from metal cans, glass bottles, cardboard boxes and plastic cups end up in the same bin. Separating paper from metal doesn’t require complex technology, but sorting a polypropylene container from a polyethylene milk jug is hard to do without the occasional mistake.</p>
<figure class="align-center zoomable">
<div class="placeholder-container"><img alt="Two workers, in bright yellow, stand at a conveyor belt covered in plastics in a recycling facility." class=" lazyloaded" data-src="https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;fit=clip" data-srcset="https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=600&amp;h=400&amp;fit=crop&amp;dpr=1 600w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=600&amp;h=400&amp;fit=crop&amp;dpr=2 1200w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=600&amp;h=400&amp;fit=crop&amp;dpr=3 1800w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;h=503&amp;fit=crop&amp;dpr=1 754w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=754&amp;h=503&amp;fit=crop&amp;dpr=2 1508w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=754&amp;h=503&amp;fit=crop&amp;dpr=3 2262w" sizes="(min-width: 1466px) 754px, (max-width: 599px) 100vw, (min-width: 600px) 600px, 237px" srcset="https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=600&amp;h=400&amp;fit=crop&amp;dpr=1 600w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=600&amp;h=400&amp;fit=crop&amp;dpr=2 1200w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=600&amp;h=400&amp;fit=crop&amp;dpr=3 1800w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;h=503&amp;fit=crop&amp;dpr=1 754w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=754&amp;h=503&amp;fit=crop&amp;dpr=2 1508w, https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=754&amp;h=503&amp;fit=crop&amp;dpr=3 2262w" src="https://images.theconversation.com/files/554113/original/file-20231016-20-hwyi6k.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;fit=clip"></div>
<figcaption><span class="caption">Recycling workers sort through materials.</span><span> </span><span class="attribution"><a class="source" href="https://newsroom.ap.org/detail/OhioRecycling/d1c2014b8c194d55b9f06a328b2dd4a5/photo?Query=recycling%20plant&amp;mediaType=photo&amp;sortBy=&amp;dateRange=Anytime&amp;totalCount=181&amp;currentItemNo=22&amp;vs=true">AP Photo/Mark Gillispie</a></span></figcaption>
</figure>
<p>When two different plastics are mixed together during recycling, their useful properties are hugely reduced – to the point of<span> </span><a href="https://www.scientificamerican.com/article/why-its-so-hard-to-recycle-plastic/">making them useless</a>.</p>
<p>But say you can recycle one of these plastics by a different method, so it doesn’t end up contaminating the recycling stream. When we mixed samples of polypropylene with a polymer we made, we were<span> </span><a href="https://doi.org/10.1126/science.adh3353">still able to depolymerize</a><span> </span>– or break down the material – and regain our building blocks without chemically affecting the polypropylene. This indicated that a contaminated waste stream could still recover its value, and the material in it could go on to be recycled, either mechanically or chemically.</p>
<h2>Plastics we need − but more recyclable</h2>
<p>In<span> </span><a href="https://doi.org/10.1126/science.adh3353">a study published in October 2023</a>, our team developed a series of polymers with only two simple building blocks – one soft polymer and one hard polymer – that mimicked polyolefins but could also be chemically recycled.</p>
<p>Connecting two different polymers together multiple times until they form a single, long molecule creates what’s called a<span> </span><a href="https://doi.org/10.1021/jacsau.1c00500">multiblock polymer</a>. Just by adjusting how much of each polymer type goes into the multiblock polymer, our team created a wide range of materials with properties that spanned across polyolefin types. But creating these multiblock polymers is easier said than done.</p>
<p>To link these hard and soft polymers, we<span> </span><a href="https://doi.org/10.1126/science.adh3353">adapted a technique</a><span> </span>that had previously been used only on very small molecules. This method is improved relative to traditional methods of making polymers in a step-by-step fashion, developed in the 1920s, where the reactive groups on the end of the molecules need to be exactly matched.</p>
<p>In our method, the reactive groups are now the same as each other, meaning we didn’t have to worry about pairing the ends of each building block to make polymers that can compete with the polyolefins we already use. Using the same strategy, applied in reverse by adding hydrogen, we could disconnect the polymers back into their building blocks and easily separate them to use again.</p>
<figure class="align-center zoomable">
<div class="placeholder-container"><img alt="A graph showing a steady increase in single-use plastic use across all plastic types shown, from X to projected in 2050." class=" lazyloaded" data-src="https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;fit=clip" data-srcset="https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=600&amp;h=302&amp;fit=crop&amp;dpr=1 600w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=600&amp;h=302&amp;fit=crop&amp;dpr=2 1200w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=600&amp;h=302&amp;fit=crop&amp;dpr=3 1800w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;h=380&amp;fit=crop&amp;dpr=1 754w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=754&amp;h=380&amp;fit=crop&amp;dpr=2 1508w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=754&amp;h=380&amp;fit=crop&amp;dpr=3 2262w" sizes="(min-width: 1466px) 754px, (max-width: 599px) 100vw, (min-width: 600px) 600px, 237px" srcset="https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=600&amp;h=302&amp;fit=crop&amp;dpr=1 600w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=600&amp;h=302&amp;fit=crop&amp;dpr=2 1200w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=600&amp;h=302&amp;fit=crop&amp;dpr=3 1800w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;h=380&amp;fit=crop&amp;dpr=1 754w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=754&amp;h=380&amp;fit=crop&amp;dpr=2 1508w, https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=754&amp;h=380&amp;fit=crop&amp;dpr=3 2262w" src="https://images.theconversation.com/files/554857/original/file-20231019-21-9enk8w.png?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;fit=clip"></div>
<figcaption><span class="caption">Realized and predicted production of commodity plastics through 2050.</span><span> </span><span class="attribution"><a class="source" href="https://www.energy.gov/sites/default/files/2021/01/f82/Plastics%20Innovation%20Challenge%20Draft%20Roadmap.pdf">International Energy Agency</a></span></figcaption>
</figure>
<p>With an almost<span> </span><a href="https://www.reuters.com/business/environment/plastic-consumption-course-nearly-double-by-2050-research-2023-02-27/">twofold increase in annual plastic use</a><span> </span>projected through 2050, the complexity and quantity of plastic recycling will only increase. It’s an important consideration when designing new materials and products.</p>
<p>Using just two building blocks to make plastics that have a huge variety of properties can go a long way toward reducing and streamlining the number of different plastics used to make the products we need. Instead of needing one plastic to make something pliable, another for something stiff, and a third, fourth and fifth for properties in between, we could control the behavior of plastics by just changing how much of each building block is there.</p>
<p>Although we’re still in the process of answering some big questions about these polymers, we believe this work is a step in the right direction toward more sustainable plastics.</p>
<p>We were<span> </span><a href="https://doi.org/10.1126/science.adh3353">able to create materials</a><span> </span>that mimic the properties of plastics the world relies on, and our sights are now set on creating plastic compositions that you couldn’t with existing methods.</p>]]> </content:encoded>
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<title>Unleashing the Power of Geospatial Imagery Analytics: Transforming Data into Insights</title>
<link>https://sdgtalks.ai/unleashing-the-power-of-geospatial-imagery-analytics-transforming-data-into-insights</link>
<guid>https://sdgtalks.ai/unleashing-the-power-of-geospatial-imagery-analytics-transforming-data-into-insights</guid>
<description><![CDATA[ In today&#039;s era of rapid technological advancements, the availability of vast amounts of geospatial data has opened up new possibilities for analysis and decision-making. ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202311/image_430x256_6542288c1fedd.jpg" length="49398" type="image/jpeg"/>
<pubDate>Wed, 01 Nov 2023 05:29:58 -0500</pubDate>
<dc:creator>Shraddha Nevase</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p class="MsoNormal"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Introduction:<o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">In today's era of rapid technological advancements, the availability of vast amounts of geospatial data has opened up new possibilities for analysis and decision-making. <a href="https://www.marketresearchfuture.com/reports/geospatial-imagery-analytics-market-7700">Geospatial Imagery Analytics</a>, a cutting-edge field, harnesses the power of satellite imagery, aerial photography, and other geospatial data sources to derive valuable insights. This article explores the concept of Geospatial Imagery Analytics, its applications across various industries, and the transformative impact it has on the way we understand our world.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Understanding Geospatial Imagery Analytics:<o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Geospatial Imagery Analytics involves the extraction and analysis of information from geospatial imagery. It combines advanced techniques such as remote sensing, machine learning, and data mining to uncover patterns, trends, and relationships hidden within the vast amounts of data captured from satellites, drones, and other sources. By leveraging this data, organizations can make informed decisions, optimize operations, and gain a competitive edge.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Applications across Industries:<o:p></o:p></span></b></p>
<p class="MsoNormal"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">1. Agriculture: <o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Geospatial Imagery Analytics enables farmers to monitor crop health, detect diseases, optimize irrigation, and predict yields. By analyzing satellite imagery and other geospatial data, farmers can make data-driven decisions to increase productivity and reduce environmental impact.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">2. Urban Planning:<o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">City planners can use Geospatial Imagery Analytics to analyze land use patterns, assess infrastructure needs, and identify areas prone to natural disasters. By visualizing and understanding these patterns, urban planners can make informed decisions to create more sustainable and resilient cities.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">3. Environmental Monitoring: <o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Geospatial Imagery Analytics plays a crucial role in monitoring and managing our natural resources. It helps track deforestation, monitor wildlife habitats, assess water quality, and detect changes in climate patterns. This information is vital for conservation efforts and sustainable resource management.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">4. Transportation and Logistics: <o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Geospatial Imagery Analytics is used to optimize transportation routes, track assets, and improve supply chain efficiency. By analyzing geospatial data, companies can reduce fuel consumption, minimize delivery times, and enhance overall operational performance.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Transformative Impact:<o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Geospatial Imagery Analytics has the potential to revolutionize decision-making and problem-solving across industries. By unlocking the insights hidden within geospatial data, organizations can make informed decisions, mitigate risks, and streamline operations. The ability to analyze vast amounts of data quickly and accurately opens up new possibilities for innovation and growth.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Challenges and Future Trends:<o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">While Geospatial Imagery Analytics holds immense potential, it also presents challenges. The sheer volume and complexity of geospatial data require advanced algorithms and high-performance computing capabilities. Additionally, ensuring data accuracy, privacy, and security remains crucial.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Looking ahead, the future of Geospatial Imagery Analytics is promising. Advancements in artificial intelligence, cloud computing, and sensor technology will continue to enhance the capabilities of this field. We can expect increased automation, real-time analytics, and improved integration with other emerging technologies like Internet of Things (IoT) and Blockchain.<o:p></o:p></span></p>
<p class="MsoNormal" style="font-variant-ligatures: normal; font-variant-caps: normal; orphans: 2; text-align: start; widows: 2; -webkit-text-stroke-width: 0px; text-decoration-thickness: initial; text-decoration-style: initial; text-decoration-color: initial; word-spacing: 0px;"><b><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Conclusion:<o:p></o:p></span></b></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Geospatial Imagery Analytics is transforming the way we understand and interact with our world. By harnessing the power of geospatial data, organizations can gain valuable insights and make data-driven decisions. From agriculture to urban planning, environmental monitoring to transportation, the applications of Geospatial Imagery Analytics are vast and diverse. As technology continues to advance, we can anticipate even more exciting developments in this field, paving the way for a smarter and more sustainable future.<o:p></o:p></span></p>
<p class="MsoNormal"><span style="mso-bidi-font-family: Calibri; mso-bidi-theme-font: minor-latin;">Source: <a href="https://www.marketresearchfuture.com/reports/geospatial-imagery-analytics-market-7700">https://www.marketresearchfuture.com/reports/geospatial-imagery-analytics-market-7700</a><o:p></o:p></span></p>]]> </content:encoded>
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<title>Farmers in New England must adapt to unpredictable temperature changes</title>
<link>https://sdgtalks.ai/farmers-in-new-england-must-adapt-to-unpredictable-temperature-changes</link>
<guid>https://sdgtalks.ai/farmers-in-new-england-must-adapt-to-unpredictable-temperature-changes</guid>
<description><![CDATA[ Climate change is changing fruit growing patterns in New England. Farmers are trying to change with it. ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202310/image_430x256_653551093070d.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 22 Oct 2023 12:06:56 -0500</pubDate>
<dc:creator>lellens</dc:creator>
<media:keywords></media:keywords>
<content:encoded><![CDATA[<p>This year, a cold snap in February destroyed much of New Hampsire's peach crop. Three months later, another cold snap took out most of the state's apple crop.</p>
<p>Unlucky year? Freak accident? Farmers in New England aren't so sure.</p>
<p>They say that the seasonal patterns they've observed for decades are shifting. While some farmers are hesitant to pin blame, others attribute these shifts directly to climate change.</p>
<p>Science indicates climate change could indeed be responsible for the large crop failures in New Hampshire this year and that such failures are likely to become more common in the future. This is because as the planet warms, average temperatures increase. This means that fruit trees receive signals to start growing earlier in the year. However, acute cold snaps and freezing temperatures remain possible until their normal times, leaving fruit trees vulnerable. There's growing evidence that cold snaps are becoming more unpredictable with climate change, further compounding the problem.</p>
<p>How are farmers responding? There are variety of methods. Some farmers are simply switching to crops that are less susceptible to cold snaps. Some are transitioning breeds of fruit, swapping a more tempermental apple for a more durable one. Still others are investigating the use of sprays or pulps that can be applied to trees to insulate flowers and young fruits.</p>
<p>For farmers that lost their crop this year, it's a little trickier. Many of them are supplementing their income by selling farmstand products, such as berries, zucchinis, and other fruits unharmed by the cold snaps. Others are renting their property for weddings or hosting other events such as apple cider tastings. </p>
<p>Though no clear path forward exists yet, New England farmers remain optimistic, and many of them are already working on ways to adjust to farming in a warmer climate.</p>]]> </content:encoded>
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<title>Sustainable Aviation Fuel shows promise in reducing CO2 emissions from jet fuel</title>
<link>https://sdgtalks.ai/sustainable-aviation-fuel-shows-promise-in-reducing-co2-emissions-from-jet-fuel</link>
<guid>https://sdgtalks.ai/sustainable-aviation-fuel-shows-promise-in-reducing-co2-emissions-from-jet-fuel</guid>
<description><![CDATA[ Aviation, specifically jet fuel, is a huge contributor to global CO2 emissions. With public and governmental pressure on the rise, airlines are looking for environmental fuel options. ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202310/image_430x256_653547056ba4e.jpg" length="49398" type="image/jpeg"/>
<pubDate>Sun, 22 Oct 2023 11:23:00 -0500</pubDate>
<dc:creator>lellens</dc:creator>
<media:keywords>Climate, Energy</media:keywords>
<content:encoded><![CDATA[<p>Aviation accounts for 2.5% of global carbon dioxide emissions, and this number is only expected to grow in the coming years. Recognizing their disporportionate impact on global warming, most major airlines have made commitments to reach net-zero emissions by 2050. How are they hoping to achieve this?</p>
<p>By using Sustainable Aviation Fuel, or SAF.</p>
<p>Made from bioproducts such as lumber, agricultural waste, and algae, SAF has the potential to revolutionize the aviation industry. Bioproducts absorb carbon dioxide during their lives. When burned, they emit this same CO2, creating a net-zero emissions process. </p>
<p>One of the major advantages of SAF is that it can be directly swapped for conventional fuel. Airlines can continue using their existing planes, and they can gradually increase the percentage of SAF in the jet fuel blend as SAF becomes more widely available.</p>
<p>While this creates a rosy picture of sustainable flight, the reality is much more complicated. SAF fuels sources are currently limited, and production options are nowhere near market-scale. As airlines clamor to meet to government regulations, the limited quanities of SAF have caused prices to soar. SAF is currently 4x as expensive as conventional fuel, meaning many airlines simply cannot afford it. Additionally, changing land use to dramatically scale up bioproduct growth would have huge effects on climate change that could negate many of the benefits SAF provides. As such, it will take serious and dedicated investment on the part of governments, airlines, environmental startups, and oil companies for SAF to become industry standard.</p>]]> </content:encoded>
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<title>Humans are Shifting the Planet: The Shocking Truth About Groundwater Pumping</title>
<link>https://sdgtalks.ai/humans-are-shifting-the-planet-the-shocking-truth-about-groundwater-pumping</link>
<guid>https://sdgtalks.ai/humans-are-shifting-the-planet-the-shocking-truth-about-groundwater-pumping</guid>
<description><![CDATA[ A quiet but frightening transition is taking place on our planet, one that is upending the entire fabric of who we are. The overpumping of groundwater is a hidden catastrophe that is gradually altering our society while climate change frequently dominates the news. This concerning issue is supported by scientific data and poses a threat to drastically alter the Earth’s surface. Here, we summarize the key points of each article regarding how groundwater depletion could potentially change the course of history. ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202310/image_430x256_6530b452d5028.jpg" length="49398" type="image/jpeg"/>
<pubDate>Thu, 19 Oct 2023 07:20:00 -0500</pubDate>
<dc:creator>Joshua</dc:creator>
<media:keywords>groundwater, pumping, shifting, earth, planet</media:keywords>
<content:encoded><![CDATA[<p class="has-large-font-size">For drinking water, agriculture, and industrial use, groundwater is an essential resource. However, groundwater pumping by humans is out of control, leading to a host of issues like land subsidence, saltwater intrusion, and even a tilting of the planet’s axis.</p>
<div class="wordads-ad-wrapper">
<div id="atatags-26942-952203"></div>
</div>
<p class="has-large-font-size">According to a recent study in the journal Geophysical Research Letters, the Earth’s poles drifted by around 2.6 feet between 1993 and 2010 as a result of groundwater extraction and sea level rise. Although it might appear insignificant, this quantity has a big enough impact on the planet’s rotation and climate.</p>
<p class="has-large-font-size">The authors of the study, who were led by Ki-Weon Seo of Seoul National University, utilized a computer model to estimate how groundwater pumping would affect Earth’s rotation. The researchers discovered that the planet’s axis is moving eastward as a result of the redistribution of water mass from the continents to the oceans.</p>
<blockquote class="wp-block-quote">
<p class="has-medium-font-size">The study:</p>
<p class="has-medium-font-size">As we know it, the Earth is tilted 23.5 degrees on its axis. This tilt causes some parts or countries of the world to experience different climatic conditions; worth mentioning are the changes in seasons experienced by countries located closer to polar regions and temperate countries. However, based on a recent study conducted by researchers at Seoul National University, they found out that, from 1993 to 2010, the Earth’s tilt wobbled from its original orientation to 31 inches east. Moreover, the team suggested that the alteration of the Earth’s axial orientation significantly alters the distribution of global water, thus affecting the Earth’s total mass distribution. Scientists described this scenario in which the Earth’s mass becomes unbalanced due to a significant loss of groundwater in some parts of the world. Meanwhile, other countries, especially those at the north pole, experience an increase in the water level primarily driven by their increased exposure to sunlight, causing early glacial melting. The unexpected melting of the cryosphere adds weight to some parts of the world and causes an imbalance in the Earth’s total mass.</p>
</blockquote>
<p class="has-large-font-size">This shift in the axis is causing changes in the length of the day and the seasons. It is also making it more difficult for scientists to predict climate change.</p>
<p class="has-large-font-size">The findings are a wake-up call about the dangers of over pumping groundwater. This practice is not only unsustainable, but it is also causing serious problems for the planet.</p>
<p class="has-large-font-size"><strong>Other shocking facts about groundwater pumping:</strong></p>
<ul>
<li class="has-large-font-size">Groundwater pumping is estimated to cause 11% of global sea-level rise.</li>
<li class="has-large-font-size">Groundwater depletion is a major contributor to land subsidence, which has caused billions of dollars in damage to infrastructure around the world.</li>
<li class="has-large-font-size">Groundwater pumping can also lead to saltwater intrusion, which can contaminate drinking water supplies.</li>
</ul>
<p class="has-large-font-size"><strong>What can be done to address the problem?</strong></p>
<p class="has-large-font-size">There are a number of things that can be done to address the problem of over pumping groundwater, including:</p>
<ul>
<li class="has-large-font-size">Conserving water: Individuals and businesses can conserve water by taking simple steps such as fixing leaky faucets, taking shorter showers, and watering lawns less often.</li>
<li class="has-large-font-size">Using alternative water sources: Where possible, alternative water sources such as recycled water and desalinated water should be used instead of groundwater.</li>
<li class="has-large-font-size">Managing groundwater sustainably: Groundwater resources should be managed sustainably to ensure that they are not overused. This includes setting quotas for pumping and monitoring groundwater levels.</li>
</ul>
<p class="has-large-font-size">It is important to take action to address the problem of groundwater over pumping before it is too late. The planet is already shifting because of this practice, and the consequences could be severe.<br><br><br></p>
<p><strong>Sources:</strong></p>
<ol>
<li><a href="https://earth.org/depleted-aquifers-causes-effects-and-solutions/">earth.org – Depleted Aquifers: Causes, Effects, Solutions</a></li>
<li><a href="https://pubs.usgs.gov/publication/fs20133001#:~:text=Wells%20that%20pump%20water%20out,the%20availability%20of%20surface%20water.">USGS – Understanding and managing the effects of groundwater pumping</a></li>
<li><a href="https://www.researchgate.net/publication/318325129_Groundwater_Issues_in_California_A_Tale_of_Shortage_Mismanagement_and_Climate_Change">ResearchGate – Groundwater Issues in California</a></li>
<li><a href="https://unesdoc.unesco.org/ark:/48223/pf0000215644">UNESCO – United Nations World Water Development Report 4</a></li>
<li><a href="https://www.usgs.gov/mission-areas/water-resources/science/saltwater-intrusion">USGS – Saltwater Intrusion</a></li>
<li><a href="https://courses.lumenlearning.com/geo/chapter/reading-groundwater-withdrawal/">Lumen Learning – Reading: Groundwater Withdrawal</a></li>
<li><a href="https://www.smithsonianmag.com/smart-news/humans-have-shifted-earths-axis-by-pumping-lots-of-groundwater-180982403/">Smithsonian Magazine</a></li>
<li><a href="https://news.agu.org/press-release/weve-pumped-so-much-groundwater-that-weve-nudged-the-earths-spin/">AGU Press Release</a></li>
<li><a href="https://www.sciencedaily.com/releases/2023/06/230615183147.htm">Science Daily</a></li>
<li><a href="https://agupubs.onlinelibrary.wiley.com/journal/19448007">https://agupubs.onlinelibrary.wiley.com/journal/19448007</a></li>
<li><a href="https://www.dailymail.co.uk/sciencetech/article-12209737/Earths-tilt-changed-31-5-INCHES-thanks-humans.html?fbclid=IwAR2FY6-ffimKBqFYHvLWJuW_V-esKxBNZGdvQVrG855DTh4asOxz-cM0xbc">Earth’s tilt has changed by 31 INCHES thanks to humans – and it could make climate change even WORSE, study warns</a></li>
<li><a href="https://greenly.earth/en-us/blog/ecology-news/climate-change-in-2022-where-do-we-stand">Climate Change in 2023: Where Do We Stand?</a></li>
</ol>
<p class="has-large-font-size"></p>]]> </content:encoded>
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<title>Transforming Mine Waste into Fertile Soil: A Groundbreaking Innovation</title>
<link>https://sdgtalks.ai/transforming-mine-waste-into-fertile-soil-a-groundbreaking-innovation</link>
<guid>https://sdgtalks.ai/transforming-mine-waste-into-fertile-soil-a-groundbreaking-innovation</guid>
<description><![CDATA[ In a significant breakthrough, researchers from the universities of Queensland and Saskatchewan have developed a method to convert harmful mine waste, known as ‘tailings’, into fertile soil. The team used a synchrotron to accelerate the process of reintroducing microbial life into the tailings. By amending the tailings with plant mulch, they were able to recolonize them with soil microbes, transforming the lifeless rock into a medium capable of supporting plant growth. This innovative solution could potentially save billions in storage costs and mitigate environmental risks associated with tailings storage facilities, while also offering a new avenue for sustainable agriculture. ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202310/image_430x256_65308e47933ed.jpg" length="49398" type="image/jpeg"/>
<pubDate>Wed, 18 Oct 2023 21:03:15 -0500</pubDate>
<dc:creator>Austin Vanderzyden</dc:creator>
<media:keywords>Mine Waste, Soil Fertility, Sustainable Agriculture, Environmental Restoration, Microbial Life, Synchrotron, University of Queensland, University of Saskatchewan, Tailings Transformation</media:keywords>
<content:encoded><![CDATA[<h2>The Problem with Mine Waste</h2>
<p>The mining industry refers to its mineral waste as ‘tailings’.<span> </span>These are the remnants left after the extraction of valuable metals from mined material. Tailings are typically toxic due to the presence of heavy metals and are rendered unusable for any other purpose.<span> </span>To prevent them from contaminating groundwater or farmland, tailings are stored in dedicated facilities.</p>
<p>However, these storage facilities pose their own set of challenges. They are not only expensive to maintain but also pose a significant environmental risk.<span> </span>Disasters can occur when such facilities break down or are abandoned.</p>
<h2>The Innovative Solution</h2>
<p>A team from the universities of Queensland and Saskatchewan embarked on a mission to see if it was possible to breathe life back into this lifeless rock by reintroducing microbial life.</p>
<p>“Tailings have no biologically friendly properties for growing plants.<span> </span>Roots and water cannot penetrate them, and soluble salts and metals in tailings can kill plants and soil microbes,” explained Longbin Huang, a professor at the University of Queensland.</p>
<p>The team found a way to accelerate the process of repopulating the tailings with soil microbes using the Canadian Light Source (CLS), a giant synchrotron.<span> </span>A synchrotron is a type of circular particle accelerator that works by accelerating charged particles (electrons) through sequences of magnets until they reach almost the speed of light.</p>
<h2>The Process</h2>
<p>The scientists were able to visualize the detailed mechanism of how they developed the organic-mineral interfaces and revitalized the tailings using CLS’s synchrotron light.<span> </span>They successfully recolonized mine tailings with soil microbes after amending the tailings with plant mulch.</p>
<p>These soil microbes consume certain residual organics and minerals, aggregating them into what are referred to as soil particles.<span> </span>“You have microbially active surfaces in soil crumbs that develop a porosity in compacted tailings that allows gas, water, roots, and microbes to survive, just like in arable soil,” said Huang. “Therefore, the dead mineral matrix of tailings becomes a soil-like media that will enable plants to grow.”</p>
<h2>The Impact</h2>
<p>This innovative solution could potentially save billions of dollars worldwide in storage fees while eliminating the threat posed by storage facilities.<span> </span>Moreover, it presents an opportunity to restore soils damaged by over-farming, overuse of fertilizers, and climate change.</p>
<p>In conclusion, this groundbreaking research offers a promising solution to a long-standing problem. By transforming harmful mine waste into healthy soil, we can mitigate environmental risks while creating new opportunities for sustainable agriculture.</p>]]> </content:encoded>
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<title>Amazon’s Leap Towards Sustainability: An Innovative Approach to Reducing Packaging Waste</title>
<link>https://sdgtalks.ai/amazons-leap-towards-sustainability-an-innovative-approach-to-reducing-packaging-waste</link>
<guid>https://sdgtalks.ai/amazons-leap-towards-sustainability-an-innovative-approach-to-reducing-packaging-waste</guid>
<description><![CDATA[ Amazon, the retail giant, has taken a significant step towards reducing packaging waste by developing a new automated packaging machine. This innovative technology is designed to cut waste and improve efficiency in the packaging process.  ]]></description>
<enclosure url="https://s3.us-east-1.amazonaws.com/sdgtalks.ai/uploads/images/202310/image_430x256_6530819f37b4c.jpg" length="49398" type="image/jpeg"/>
<pubDate>Wed, 18 Oct 2023 20:09:19 -0500</pubDate>
<dc:creator>Austin Vanderzyden</dc:creator>
<media:keywords>Amazon, Sustainability, Packaging Waste, Automated Packaging Machine, Recyclable Paper, Heat-Sealed, Efficiency, Waste Reduction, Carbon Emissions, Net-Zero Carbon by 2040</media:keywords>
<content:encoded><![CDATA[<div class="OutlineElement Ltr SCXW45606514 BCX0"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0" data-ccp-parastyle="heading 2">A New Era of Packaging</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 134245418":true,"134245529":true,"201341983":0,"335559738":40,"335559739":0,"335559740":259}"=""> </span></div>
<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" xml:lang="EN-US" lang="EN-US" paraid="1363244654" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{42}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">Amazon’s new system uses a weather-resistant paper that can stretch into the shape of a package</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">. </span><span class="NormalTextRun SCXW45606514 BCX0">This paper can be heat-sealed like plastic, </span><span class="NormalTextRun SCXW45606514 BCX0">eliminating</span><span class="NormalTextRun SCXW45606514 BCX0"> the need for glue</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">.</span><span class="NormalTextRun SCXW45606514 BCX0"> </span><span class="NormalTextRun SCXW45606514 BCX0">The machine scans items such as video games, kitchen gadgets, sports gear, and office supplies that were previously sent in boxes and diverts them to the new system</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">.</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 201341983":0,"335551550":0,"335551620":0,"335559739":160,"335559740":259}"=""> </span></p>
</div>
<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" xml:lang="EN-US" lang="EN-US" paraid="340782166" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{47}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">The machine then cuts a paper bag to fit the item perfectly, minimizing the empty space around the contents</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">. </span><span class="NormalTextRun SCXW45606514 BCX0">Each bag is secured using glue-free, heat-sealing technology, enabling the machines to pack quickly and accurately</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">.</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 201341983":0,"335551550":0,"335551620":0,"335559739":160,"335559740":259}"=""> </span></p>
</div>
<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" role="heading" aria-level="2" xml:lang="EN-US" lang="EN-US" paraid="1347606764" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{52}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0" data-ccp-parastyle="heading 2">Sustainability at its Core</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 134245418":true,"134245529":true,"201341983":0,"335559738":40,"335559739":0,"335559740":259}"=""> </span></p>
</div>
<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" xml:lang="EN-US" lang="EN-US" paraid="1818896801" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{61}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">“Our material scientists developed a light but durable paper which can be heat-sealed like plastic – but is all easily recyclable in your household collections,” said Thais Blumer, head of sustainable packaging for Amazon Europe</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">. </span><span class="NormalTextRun SCXW45606514 BCX0">"Our trials already show that this technology is efficient, secure and reliable."</span></span></p>
</div>
<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" xml:lang="EN-US" lang="EN-US" paraid="284168441" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{66}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">The retail giant’s packaging engineers </span><span class="NormalTextRun SCXW45606514 BCX0">came up with</span><span class="NormalTextRun SCXW45606514 BCX0"> this technology by redesigning machines that previously made plastic packages</span></span><a class="Hyperlink SCXW45606514 BCX0" href="https://www.goodnewsnetwork.org/amazon-now-builds-packaging-to-fit-items-and-cut-waste/" target="_blank" rel="noreferrer noopener"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun Underlined SCXW45606514 BCX0"><span class="NormalTextRun Superscript SCXW45606514 BCX0" data-fontsize="11" data-ccp-charstyle="Hyperlink">1</span></span></a><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">. </span><span class="NormalTextRun SCXW45606514 BCX0">The original machines were decommissioned when Amazon stopped packing items in single-use plastic delivery bags at fulfillment centers across Europe</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">.</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 201341983":0,"335551550":0,"335551620":0,"335559739":160,"335559740":259}"=""> </span></p>
</div>
<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" role="heading" aria-level="2" xml:lang="EN-US" lang="EN-US" paraid="778918946" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{71}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun AdvancedProofingIssueV2Themed SCXW45606514 BCX0" data-ccp-parastyle="heading 2">Future Prospects</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 134245418":true,"134245529":true,"201341983":0,"335559738":40,"335559739":0,"335559740":259}"=""> </span></p>
</div>
<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" xml:lang="EN-US" lang="EN-US" paraid="1029649847" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{80}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">In the future, Amazon expects that automated packaging technology will be able to pack multiple items in strong paper or cardboard packaging, </span><span class="NormalTextRun SCXW45606514 BCX0">that’s</span><span class="NormalTextRun SCXW45606514 BCX0"> made to measure with </span><span class="NormalTextRun SCXW45606514 BCX0">very little</span><span class="NormalTextRun SCXW45606514 BCX0"> air space, while protecting items in transit</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">. </span><span class="NormalTextRun SCXW45606514 BCX0">Lighter shipments can lead to reduced delivery emissions per package, driving the company further towards its goal of achieving net-zero carbon by 2040</span></span><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">.</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 201341983":0,"335551550":0,"335551620":0,"335559739":160,"335559740":259}"=""> </span></p>
</div>
<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" xml:lang="EN-US" lang="EN-US" paraid="2051960974" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{85}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">“On average, each shipment packed with this machine helps us avoid 26 grams (almost a pound) of packaging,” says Blumer. </span><span class="NormalTextRun SCXW45606514 BCX0">"Multiply this by millions of packages and you can imagine the impact."</span></span><span data-contrast="auto" xml:lang="EN-US" lang="EN-US" class="TextRun EmptyTextRun SCXW45606514 BCX0"></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 201341983":0,"335551550":0,"335551620":0,"335559739":160,"335559740":259}"=""> </span></p>
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<p class="Paragraph SCXW45606514 BCX0" role="heading" aria-level="2" xml:lang="EN-US" lang="EN-US" paraid="303345486" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{90}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0" data-ccp-parastyle="heading 2">Conclusion</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 134245418":true,"134245529":true,"201341983":0,"335559738":40,"335559739":0,"335559740":259}"=""> </span></p>
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<div class="OutlineElement Ltr SCXW45606514 BCX0">
<p class="Paragraph SCXW45606514 BCX0" xml:lang="EN-US" lang="EN-US" paraid="1990798915" paraeid="{9b0995a1-f0f9-4a9b-9ce3-a21e8b3dc549}{99}"><span data-contrast="none" xml:lang="EN-US" lang="EN-US" class="TextRun SCXW45606514 BCX0"><span class="NormalTextRun SCXW45606514 BCX0">Amazon’s innovative approach to reducing packaging waste </span><span class="NormalTextRun SCXW45606514 BCX0">represents</span><span class="NormalTextRun SCXW45606514 BCX0"> a significant step forward in sustainability. </span><span class="NormalTextRun SCXW45606514 BCX0">By developing a system that minimizes waste and maximizes efficiency, Amazon is leading the way in sustainable packaging solutions.</span><span class="NormalTextRun SCXW45606514 BCX0"> This initiative not only </span><span class="NormalTextRun SCXW45606514 BCX0">benefits</span><span class="NormalTextRun SCXW45606514 BCX0"> the environment but also contributes to Amazon’s goal of achieving net-zero carbon emissions by 2040.</span></span><span class="EOP SCXW45606514 BCX0" data-ccp-props="{" 201341983":0,"335551550":0,"335551620":0,"335559739":160,"335559740":259}"=""> </span></p>
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<title>Human rights experts: Humanity facing ‘unprecedented global toxic emergency’</title>
<link>https://sdgtalks.ai/human-rights-experts-humanity-facing-unprecedented-global-toxic-emergency</link>
<guid>https://sdgtalks.ai/human-rights-experts-humanity-facing-unprecedented-global-toxic-emergency</guid>
<description><![CDATA[ The consequences of poor chemicals and waste management worldwide are fueling an “unprecedented global toxic emergency”, independent UN human rights experts have warned, ahead of a major summit next week. ]]></description>
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<pubDate>Wed, 18 Oct 2023 19:41:52 -0500</pubDate>
<dc:creator>Shayn McHugh</dc:creator>
<media:keywords>Pollution, Climate Change, Human Health, Environmental Health</media:keywords>
<content:encoded><![CDATA[<p>The fifth session of the International Conference on Chemicals Management (ICCM-5), organized by UN environment programme<span> </span><a href="https://www.unep.org/" target="_blank" rel="noopener noreferrer">UNEP</a><span> </span>and hosted by Germany, kicks off in Bonn on Monday.</p>
<p>“ICCM-5 is expected to be a watershed moment for international cooperation on chemicals and wastes”, said a statement released by the group of more than 30 experts.  </p>
<h2>‘Once in a generation’ chance</h2>
<p>“It is a once in a generation opportunity to deliver a robust outcome to confront the global toxic tide.”</p>
<p>They urged those attending the conference to be guided by human rights principles in line with a “post-2020 global policy framework on the sound management of chemicals and wastes.”</p>
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<p>According to the experts, “the threats of infertility, deadly illnesses, neurological and other disabilities resulting from exposure to hazardous chemicals and wastes, reveal the widespread and systematic denial of basic human rights for countless persons and groups in vulnerable situations.”</p>
<p>The experts went on to list people who are mostly exposed to these toxic environments, including workers, women and children, the poor and Indigenous Peoples.</p>
<h2>‘Toxification’ must stop</h2>
<p>“Humanity cannot afford to further aggravate the toxification of the planet,” the experts added.  </p>
<p>“For ICCM-5 to deliver the ambition and strength needed to overcome the global toxic emergency facing humanity, it needs to explicitly embrace a human rights-based approach,” the group of UN experts warned.</p>
<p>Special Rapporteurs and other UN experts are not UN staff and are independent from any government or organisation. They serve in their individual capacity and receive no salary for their work. </p>]]> </content:encoded>
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<title>Lego&amp;apos;s ESG dilemma: Why an abandoned plan to use recycled plastic bottles is a wake&#45;up call for supply chain sustainability</title>
<link>https://sdgtalks.ai/Legos-ESG-dilemma%3A-Why-an-abandoned-plan-to-use-recycled-plastic-bottles-is-a-wake-up-call-for-supply-chain-sustainability</link>
<guid>https://sdgtalks.ai/Legos-ESG-dilemma%3A-Why-an-abandoned-plan-to-use-recycled-plastic-bottles-is-a-wake-up-call-for-supply-chain-sustainability</guid>
<description><![CDATA[ Lego abandoned its &quot;Bottles to Bricks&quot; project to use recycled plastic bottles due to increased carbon emissions. This underscores the significance of assessing scope 3 emissions from supply chains. New EU and California regulations mandate their disclosure, emphasizing the need for genuine sustainability efforts rather than token gestures. ]]></description>
<enclosure url="https://images.theconversation.com/files/551813/original/file-20231003-27-dy1q3j.jpg" length="49398" type="image/jpeg"/>
<pubDate>Mon, 16 Oct 2023 19:41:27 -0500</pubDate>
<dc:creator>jaysonmartinez</dc:creator>
<media:keywords>Sustainable, Lego, Emissions</media:keywords>
<content:encoded><![CDATA[<p>Lego, the world’s<span> </span><a href="https://www.statista.com/statistics/241241/revenue-of-major-toy-companies-worldwide/">largest toy manufacturer</a>, has built a reputation not only for the<span> </span><a href="https://www.smithsonianmag.com/smart-news/how-much-abuse-can-a-single-lego-brick-take-343398/">durability of its bricks</a>, designed to<span> </span><a href="https://www.theguardian.com/sustainable-business/lego-design-sustainability-circular-economy">last for decades</a>, but also for its substantial investment in sustainability. The company has<span> </span><a href="https://www.esgtoday.com/lego-to-invest-over-1-4-billion-to-reduce-emissions-commits-to-net-zero-by-2050/">pledged US$1.4 billion</a><span> </span>to reduce carbon emissions by 2025, despite netting<span> </span><a href="https://apnews.com/article/lego-profit-sales-higher-prices-denmark-daa98df56563de4b9fa02185862b1b3a">annual profits of just over $2 billion</a><span> </span>in 2022.</p>
<p>This commitment isn’t just for show. Lego sees its core customers as children and their parents, and<span> </span><a href="https://www.un.org/en/academic-impact/sustainability">sustainability</a><span> </span>is fundamentally about ensuring that future generations inherit a planet as hospitable as the one we enjoy today.</p>
<p>So it was surprising when the Financial Times reported on<span> </span><a href="https://www.ft.com/content/6cad1883-f87a-471d-9688-c1a3c5a0b7dc">Sept. 25, 2023</a>, that Lego had pulled out of its widely publicized “<a href="https://www.reuters.com/business/sustainable-business/bottles-bricks-lego-finds-right-fit-with-recycled-plastic-2021-06-23/">Bottles to Bricks</a>” initiative.</p>
<p>This ambitious project aimed to replace traditional Lego plastic with a new material made from recycled plastic bottles. However, when Lego assessed the project’s environmental impact throughout its supply chain, it found that producing bricks with the recycled plastic would<span> </span><a href="https://www.theguardian.com/lifeandstyle/2023/sep/24/lego-abandons-effort-to-make-bricks-from-recycled-plastic-bottles">require extra materials and energy</a><span> </span>to make them durable enough. Because this conversion process would result in higher carbon emissions, the company decided to stick with its current fossil fuel-based materials while<span> </span><a href="https://www.lego.com/en-us/aboutus/news/2023/september/the-lego-group-remains-committed-to-make-lego-bricks-from-sustainable-materials">continuing to search</a><span> </span>for more sustainable alternatives.</p>
<p>As<span> </span><a href="https://tinglongdai.com/">experts</a><span> </span>in<span> </span><a href="https://www.gsb.stanford.edu/faculty-research/faculty/hau-l-lee">global supply chains</a><span> </span>and<span> </span><a href="https://scholar.google.com/citations?user=Kk-QbksAAAAJ&amp;hl=en">sustainability</a>, we believe Lego’s pivot is the beginning of a larger trend toward developing sustainable solutions for entire supply chains in a circular economy. New regulations<span> </span><a href="https://www.isscorporatesolutions.com/library/are-european-companies-ready-for-scope-3-disclosures/">in the European Union</a><span> </span>– and<span> </span><a href="https://www.reuters.com/world/us/california-climate-bill-clears-senate-governor-newsom-have-final-say-2023-09-12/">expected in California</a><span> </span>– are about to speed things up.</p>
<h2>Examining all the emissions, cradle to grave</h2>
<p>Business leaders are increasingly<span> </span><a href="https://doi.org/10.1287/serv.2021.0295">integrating environmental, social and governance factors</a>, commonly known as ESG, into their operational and strategic frameworks. But the pursuit of sustainability requires attention to the entire life cycle of a product, from its materials and manufacturing processes to its use and ultimate disposal.</p>
<p>The results can lead to counterintuitive outcomes, as Lego discovered.</p>
<p>Understanding a company’s entire carbon footprint requires looking at<span> </span><a href="https://www.epa.gov/climateleadership/scope-1-and-scope-2-inventory-guidance">three types of emissions</a>: Scope 1 emissions are generated directly by a company’s internal operations. Scope 2 emissions are caused by generating the electricity, steam, heat or cooling a company consumes. And<span> </span><a href="https://www.epa.gov/climateleadership/scope-3-inventory-guidance">scope 3</a><span> </span>emissions are generated by a company’s supply chain, from upstream suppliers to downstream distributors and end customers.</p>
<p></p>
<p><img src="https://images.theconversation.com/files/450130/original/file-20220304-13-727hza.png?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;fit=clip" alt="Lists of examples of sope 1, 2, 3 emissions sources with an illustration of a factory in the center"></p>
<p></p>
<p>Currently,<span> </span><a href="https://www.isscorporatesolutions.com/library/are-european-companies-ready-for-scope-3-disclosures">fewer than 30%</a><span> </span>of companies report meaningful scope 3 emissions, in part because these emissions are difficult to track. Yet, companies’ scope 3 emissions are on average<span> </span><a href="https://www.cdp.net/en/research/global-reports/transparency-to-transformation">11.4 times greater</a><span> </span>than their<span> </span><a href="https://www.epa.gov/climateleadership/scope-1-and-scope-2-inventory-guidance">scope 1</a><span> </span>emissions, data from corporate disclosures reported to the nonprofit CDP show.</p>
<p>Lego is a case study of this lopsided distribution and the importance of tracking scope 3 emissions. A staggering<span> </span><a href="https://www.lego.com/en-us/sustainability/environment/our-co2-footprint">98% of Lego’s carbon emissions</a><span> </span>are categorized as scope 3.</p>
<p>From 2020 to 2021, the company’s total emissions increased by 30%, amid surging demand for Lego sets during the COVID-19 lockdowns – even though the company’s scope 2 emissions related to purchased energy such as electricity decreased by 40%. The increase was almost entirely in its scope 3 emissions.</p>
<p><iframe width="620" height="348" src="https://www.youtube.com/embed/C3oiy9eekzk?si=2qC0c80mNIhzOmg2" allowfullscreen="allowfullscreen"></iframe><span style="font-size: 8pt;">Lego’s tour of how its toy bricks are made doesn’t address the supply chain, where most of Lego’s greenhouse gas emissions originate.</span></p>
<p>As more companies follow in Lego’s footsteps and begin reporting scope 3 emissions, they will likely find themselves in the same position, realizing that efforts to reduce carbon emissions often boil down to supply chain and consumer-use emissions. And the results may force them to make some tough choices.</p>
<h2>Policy and disclosure: The next frontier</h2>
<p>New regulations in the European Union and pending in California are designed to increase corporate emissions transparency by including supply chain emissions.</p>
<p>The EU in June 2023 adopted the first set of European Sustainability Reporting Standards, which will require publicly traded companies in the EU to<span> </span><a href="https://www.isscorporatesolutions.com/library/are-european-companies-ready-for-scope-3-disclosures/%22%22">disclose their scope 3 emissions</a>, starting in their reports for fiscal year 2024.</p>
<p>California’s legislature<span> </span><a href="https://www.reuters.com/world/us/california-climate-bill-clears-senate-governor-newsom-have-final-say-2023-09-12/#:%7E:text=Sept%2012%20(Reuters)%20%2D%20California's,in%20setting%20corporate%20climate%20rules.%22%22">passed similar legislation</a><span> </span>requiring companies with revenues of more than $1 billion to disclose their scope 3 emissions. California’s governor has until Oct. 14, 2023, to consider the bill and<span> </span><a href="https://apnews.com/article/california-governor-gavin-newsom-climate-bills-global-warming-2c5adbb29e67b753e396169195430ffb">is expected to sign it</a>.</p>
<p>At the federal level, the U.S. Securities and Exchange Commission released a proposal in March 2022 that, if finalized,<span> </span><a href="https://www.wsj.com/articles/secs-climate-disclosure-rule-isnt-here-but-it-may-as-well-be-many-businesses-say-854789bd/">would require</a><span> </span>all public companies to report climate-related risk and emissions data, including scope 3 emissions. After<span> </span><a href="https://news.bloomberglaw.com/securities-law/sec-climate-rules-pushed-back-amid-bureaucratic-legal-woes%22%22">receiving significant pushback</a>, the SEC began reconsidering the scope 3 reporting rule. But SEC Chairman Gary Gensler suggested during a congressional hearing in late September 2023 that California’s move<span> </span><a href="https://www.reuters.com/sustainability/sec-chief-says-new-california-law-could-change-baseline-coming-sec-climate-rule-2023-09-27/">could influence federal regulators’ decision</a>.</p>
<p></p>
<p><iframe width="626" height="351" src="https://www.youtube.com/embed/MacoRZSLzTc" allowfullscreen="allowfullscreen"></iframe><span style="font-size: 8pt;">SEC Chairman Gary Gensler explains the importance of climate-related risk disclosures.</span></p>
<p>This increased focus on disclosure of scope 3 emissions will undoubtedly increase pressure on companies.</p>
<p>Because scope 3 emissions are significant, yet often not measured or reported,<span> </span><a href="https://doi.org/10.1007/s10551-022-05151-9">consumers are rightly concerned</a><span> </span>that companies that claim to have low emissions<span> </span><a href="https://makersite.io/insights/whitepaper-the-cost-of-greenwashing/">may be greenwashing</a><span> </span>without taking action to reduce emissions in their supply chains to combat climate change.</p>
<p>At the same time, we suspect that as more investors support sustainable investing, they may prefer to invest in companies that are transparent in disclosing all areas of emissions. Ultimately, we believe consumers, investors and governments will demand more than lip service from companies. Instead, they’ll expect companies to take actionable steps to reduce the most significant part of a company’s carbon footprint – scope 3 emissions.</p>
<h2>A journey, not a destination</h2>
<p>The Lego example serves as a cautionary tale in the complex ESG landscape for which<span> </span><a href="https://www.reuters.com/sustainability/three-quarters-firms-globally-are-not-ready-new-esg-rules-kpmg-finds-2023-09-26/">most companies are not well prepared</a>. As more companies come under scrutiny for their entire carbon footprint, we may see more instances where well-intentioned sustainability efforts run into uncomfortable truths.</p>
<p>This calls for a nuanced understanding of sustainability, not as a checklist of good deeds, but as a complex, ongoing process that requires vigilance,<span> </span><a href="https://theconversation.com/esg-investing-has-a-blind-spot-that-puts-the-35-trillion-industrys-sustainability-promises-in-doubt-supply-chains-170199">transparency</a><span> </span>and, above all, a commitment to the benefit of future generations.</p>]]> </content:encoded>
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<title>Climate change &#45; &amp;quot;Taking Action Against Plastic Waste’’</title>
<link>https://sdgtalks.ai/climate-change-taking-action-against-plastic-waste</link>
<guid>https://sdgtalks.ai/climate-change-taking-action-against-plastic-waste</guid>
<description><![CDATA[ Rethinking plastic is essential for controlling climate change. By adopting eco-friendly alternatives, supporting recycling efforts, and advocating for change, we can use plastic as a force for good rather than harm. It will help to reshape the future of plastic in a way that benefits our planet and combats climate change. ]]></description>
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<pubDate>Wed, 11 Oct 2023 12:54:56 -0500</pubDate>
<dc:creator>Nibin Joseph</dc:creator>
<media:keywords>Bio Plastics, Climate Change, Rethink Plastics</media:keywords>
<content:encoded><![CDATA[<p><strong>Introduction </strong></p>
<p><strong>Plastic pollution is a global crisis</strong></p>
<p>It's found everywhere, from the deepest oceans to the highest mountains. It harms wildlife, marine life, contaminates our ecosystems, and releases harmful greenhouse gases during its production and disposal. This is where the rethinking begins.</p>
<p><strong>Recycle and Reuse </strong></p>
<p>When we recycle, we reduce the need to produce new plastic, which saves energy and reduces greenhouse gas emissions. But we can take this a step further by actively seeking out products made from recycled plastic. Supporting businesses that use recycled materials can help create a demand for it.</p>
<p> <strong>1. Recycle Properly </strong></p>
<ul>
<li>Familiarize yourself with your local recycling program. Learn which types of plastics are accepted and how to prepare them for recycling.</li>
<li>Rinse and clean your plastic containers before recycling to prevent contamination. • Set up a designated recycling area in your home, so it's easy for everyone to separate recyclables from other waste.</li>
</ul>
<p><strong>2. Use Reusable Water Bottles</strong></p>
<ul>
<li>Instead of buying single-use plastic water bottles, invest in a reusable water bottle. Carry it with you to school, sports events, and other activities.</li>
</ul>
<p><strong>3. Bring Your Own Bag</strong></p>
<ul>
<li>Carry a reusable shopping bag when you go grocery shopping or to the mall. Say no to plastic bags offered at stores.</li>
</ul>
<p><strong>4. Lunchbox Makeover </strong></p>
<ul>
<li>Use a reusable lunchbox or container for your meals instead of disposable plastic bags or containers.</li>
<li>Go for reusable utensils and cloth napkins to reduce single-use plastic waste.</li>
</ul>
<p><strong>5. Avoid Straws </strong></p>
<ul>
<li>Skip plastic straws at restaurants and use metal, bamboo, or paper alternatives.</li>
<li>If you need a straw for a drink, carry a reusable one with you.</li>
</ul>
<p><strong>6. Buy in Bulk </strong></p>
<ul>
<li>Purchase items like cereal, pasta, and snacks in bulk and store them in reusable containers. This reduces the need for individually packaged items.</li>
</ul>
<p><strong>7. Upcycling </strong></p>
<ul>
<li>Get creative and turn plastic containers, like yogurt cups, into plant pots, pencil holders, or organizers.</li>
<li>Use plastic bottles for DIY projects, such as making bird feeders or self-watering planters.</li>
</ul>
<p><strong>8. Support Recycling Initiatives </strong></p>
<ul>
<li>Participate in school or community recycling programs and encourage your peers to get involved.</li>
<li>Organize or join recycling drives and collection events at your school.</li>
</ul>
<p></p>
<p><strong>9. Electronics Recycling </strong></p>
<ul>
<li>Old electronic devices often contain plastics. Make sure to recycle them through proper ewaste recycling programs when they are no longer usable.</li>
</ul>
<p><strong>10. Environmental Clubs </strong></p>
<ul>
<li>Join or create an environmental club at your school. This provides a platform to raise awareness and initiate recycling and plastic reduction efforts.</li>
</ul>
<p><strong>11. Education and Advocacy </strong></p>
<ul>
<li>Share your knowledge with friends and family about the importance of recycling and reusing plastics. Encourage them to do the same.We must spread awareness about the link between plastic and climate change.</li>
<li>By educating ourselves and advocating for sustainable practices, we can influence government policies and corporate practices. </li>
</ul>
<p><strong>12. Reduce Plastic in Arts and Crafts</strong></p>
<ul>
<li>Choose alternative materials for art projects when possible. Reuse paper and cardboard instead of plastic in your creative endeavors.</li>
</ul>
<p><strong>13. Learn About Eco-friendly Alternatives </strong></p>
<ul>
<li>Research and experiment with eco-friendly, biodegradable alternatives for everyday plastic items, like toothbrushes, food storage containers, and personal care products</li>
</ul>
<p><strong>14. Choose Reusable Hygiene Products </strong></p>
<p>Consider using reusable items like cloth diapers or menstrual cups instead of disposable diapers and pads. Bioplastics Traditional plastics are made from fossil fuels. Bioplastics, on the other hand, are made from renewable sources like cornstarch or sugarcane. They can reduce our reliance on fossil fuels, which are a major contributor to climate change.</p>
<p><strong>Circular Economy</strong></p>
<p>Imagine a world where plastic isn't "waste" but a valuable resource. The circular economy model encourages us to keep plastics in use for as long as possible. Instead of discarding items, we repair, reuse, and recycle them.</p>
<p><strong>Innovative Technologies </strong></p>
<p>Scientists are working on exciting new technologies that can turn plastic waste into clean energy. These technologies can help us manage plastic waste while generating power without adding more greenhouse gases to the atmosphere.</p>
<p><strong>Conclusion</strong></p>
<p>Rethinking plastic is essential for controlling climate change. By adopting eco-friendly alternatives, supporting recycling efforts, and advocating for change, we can use plastic as a force for good rather than harm. Let's be part of the solution and help reshape the future of plastic in a way that benefits our planet and combats climate change.</p>
<div class="ts-fab-content"></div>
<p> </p>
<div class="at-below-post addthis_tool" data-url="https://www.plt.org/educator-tips/reduce-single-use-plastic"></div>
<p><a href="file:///C:/Users/ACER/Downloads/AARON/ACTIVITIES/Climate%20change%20rethink%20plastic%20article%20Aaron%20Nibin.pdf" title="Climate change - " taking="" action="" against="" plastic="" waste"=""></a></p>]]> </content:encoded>
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<title>Next Generation Experimental Aircraft Becomes NASA’s Newest X&#45;Plane</title>
<link>https://sdgtalks.ai/next-generation-experimental-aircraft-becomes-nasas-newest-x-plane</link>
<guid>https://sdgtalks.ai/next-generation-experimental-aircraft-becomes-nasas-newest-x-plane</guid>
<description><![CDATA[ NASA and Boeing have introduced the X-66A, an experimental aircraft developed as part of NASA&#039;s Sustainable Flight Demonstrator project. It seeks to advance sustainable single-aisle aircraft technology, potentially reducing emissions by up to 30%. The project aligns with the goal of achieving net-zero aviation greenhouse gas emissions by 2050, as outlined in the U.S. Aviation Climate Action Plan. NASA and Boeing are jointly investing in this project, with NASA providing $425 million and Boeing and its partners contributing approximately $725 million over a seven-year period. ]]></description>
<enclosure url="https://www.nasa.gov/wp-content/uploads/2023/06/sustainable-aviation-v2-16x9-2.jpg" length="49398" type="image/jpeg"/>
<pubDate>Mon, 02 Oct 2023 20:04:47 -0500</pubDate>
<dc:creator>Naomi Carleo</dc:creator>
<media:keywords>SDG Related Articles, Aviation, Air Pollution</media:keywords>
<content:encoded><![CDATA[<p>Author: Claire A. O'Shea</p>
<p>NASA and Boeing said Monday the aircraft produced through the agency’s Sustainable Flight Demonstrator project has been designated by the U.S. Air Force as the X-66A.</p>
<p>The new X-plane seeks to inform a potential new generation of more sustainable single-aisle aircraft – the workhorse of passenger airlines around the world. Working with NASA, Boeing will build, test, and fly a full-scale demonstrator aircraft with extra-long, thin wings stabilized by diagonal struts, known as a Transonic Truss-Braced Wing concept.</p>
<p>“At NASA, our eyes are not just focused on stars but also fixated on the sky. The Sustainable Flight Demonstrator builds on NASA’s world-leading efforts in aeronautics as well climate,” said NASA Administrator Bill Nelson. “The X-66A will help shape the future of aviation, a new era where aircraft are greener, cleaner, and quieter, and create new possibilities for the flying public and American industry alike.”</p>
<p>The X-66A is the first X-plane specifically focused on helping the United States achieve the goal of net-zero aviation greenhouse gas emissions, which was articulated in the White House’s<span> </span><a href="https://www.faa.gov/sites/faa.gov/files/2021-11/Aviation_Climate_Action_Plan.pdf" rel="noopener">U.S. Aviation Climate Action Plan</a>.</p>
<p>“To reach our goal of net zero aviation emissions by 2050, we need transformative aircraft concepts like the ones we’re flying on the X-66A,” said Bob Pearce, associate administrator for NASA’s Aeronautics Research Mission Directorate, who announced the designation at the American Institute of Aeronautics and Astronautics Aviation Forum in San Diego. “With this experimental aircraft, we’re aiming high to demonstrate the kinds of energy-saving, emissions-reducing technologies the aviation industry needs.”</p>
<p>NASA and Boeing sought the X-plane designation shortly after the agency<span> </span><a href="https://www.nasa.gov/press-release/nasa-issues-award-for-greener-more-fuel-efficient-airliner-of-future" rel="noopener">announced</a><span> </span>the Sustainable Flight Demonstrator project award earlier this year. The Air Force confers X-plane status for development programs that set out to create revolutionary experimental aircraft configurations. The designation is for research aircraft. With few exceptions, X-planes are intended to test designs and technologies that can be adopted into other aircraft designs, not serve as prototypes for full production.</p>
<p>“We’re incredibly proud of this designation, because it means that the X-66A will be the next in a long line of experimental aircraft used to validate breakthrough designs that have transformed aviation,” said Todd Citron, Boeing chief technology officer. “With the learnings gained from design, construction, and flight-testing, we’ll have an opportunity to shape the future of flight and contribute to the decarbonization of aerospace.”</p>
<p>For the X-66A, the Air Force provided the designation for an aircraft that validates technologies for a Transonic Truss-Braced Wing configuration that, when combined with other advancements in propulsion systems, materials, and systems architecture, could result in up to 30% less fuel consumption and reduced emissions when compared with today’s best-in-class aircraft.</p>
<p>Due to their heavy usage, single-aisle aircraft today account for nearly half of worldwide aviation emissions. Creating designs and technologies for a more sustainable version of this type of aircraft has the potential for profound impact on emissions.</p>
<p>NASA’s history with the X-plane designation dates to the 1940s, when its predecessor agency, the National Advisory Committee for Aeronautics (NACA) jointly created an experimental aircraft program with the Air Force and the U.S. Navy. The X-66A is the latest in a<span> </span><a href="https://www.nasa.gov/centers/armstrong/aircraft/x-planes/index.html" rel="noopener">long line</a><span> </span>of NASA X-planes. Additionally, NASA’s Armstrong Flight Research Center in Edwards, California, has provided technical expertise and support for several additional X-planes.</p>
<p>For the Sustainable Flight Demonstrator, NASA has a Funded Space Act Agreement with Boeing through which the agency will invest $425 million over seven years, while the company and its partners will contribute the remainder of the funding, estimated at about $725 million. NASA also will contribute technical expertise and facilities.</p>
<p>The Sustainable Flight Demonstrator project is an activity under<span> </span><a href="https://www.nasa.gov/aeroresearch/programs/iasp/sfd/description/" rel="noopener">NASA’s Integrated Aviation Systems Program</a><span> </span>and a key element of the agency’s<span> </span><a href="https://www.nasa.gov/sfnp/" rel="noopener">Sustainable Flight National Partnership</a>, which focuses on developing new sustainable aviation technologies.</p>]]> </content:encoded>
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<title>California&amp;apos;s Groundwater Sustainability Overhaul Begins Implementation</title>
<link>https://sdgtalks.ai/californias-groundwater-sustainability-overhaul-begins-implementation</link>
<guid>https://sdgtalks.ai/californias-groundwater-sustainability-overhaul-begins-implementation</guid>
<description><![CDATA[ California&#039;s Sustainable Groundwater Management Act (SGMA), enacted in 2014, is moving from planning to implementation as it seeks to address overuse of underground aquifers by 2042. A recent conference organized by the Public Policy Institute of California (PPIC) in Fresno revealed this shift in approach. Farmers are increasingly embracing SGMA, with initial resistance giving way to participation in initiatives aimed at curbing groundwater use. Implementation efforts center on both reducing groundwater consumption and replenishing water sources, including diverting floodwater and creating recharge basins. Ensuring collaboration between groundwater sustainability agencies and rural communities is emphasized for inclusive representation, especially for disadvantaged communities often left out of discussions. However, skepticism persists among growers about repurposing irrigated farmland for alternatives such as solar farms or dryland farming, posing challenges for sustaining agricultural production in the face of SGMA&#039;s changes. ]]></description>
<enclosure url="https://images.nationalgeographic.org/image/upload/t_edhub_resource_key_image/v1638892082/EducationHub/photos/well.jpg" length="49398" type="image/jpeg"/>
<pubDate>Fri, 29 Sep 2023 17:09:55 -0500</pubDate>
<dc:creator>Marin Ward</dc:creator>
<media:keywords>Agriculture, Farming, sustainable agriculture</media:keywords>
<content:encoded><![CDATA[<h2 class="ArtP-subheadline">In 2014, the mammoth groundwater management law known as SGMA promised to overhaul water use in the state. A recent conference showed how the rubber is hitting the road.</h2>
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<div class="ArtP-articleBody">
<p>FRESNO, Calif. – For years, conversations about the Sustainable Groundwater Management Act – known commonly as SGMA – have largely taken a tone of speculation and even apprehension.</p>
<p>The 2014 law, which aims to slow California’s unlimited tapping of underground aquifers, gives locally organized groundwater sustainability agencies until 2042 to overhaul pumping practices for the spectrum of groundwater users — from cities and rural communities to dairies, small farms and agricultural conglomerates.</p>
<p>Ultimately, the consequences could be dire: the non-profit Public Policy Institute of California predicted<span> </span><a href="https://www.ppic.org/publication/policy-brief-the-future-of-agriculture-in-the-san-joaquin-valley/" class="Link" target="_blank" data-cms-ai="0" rel="noopener">even in the best-case scenario, as much as 500,000 acres of farmland may need to be fallowed in order to adequately reduce groundwater pumping</a>.</p>
<p>Now, nine years into SGMA’s rollout, public conversations are evolving from planning water-saving projects to implementing them.</p>
<p>This was evident last week, when water leaders from across the state gathered for a conference at Fresno State. The convening, organized by the PPIC,<a href="https://www.ppic.org/publication/policy-brief-the-future-of-agriculture-in-the-san-joaquin-valley/" class="Link" target="_blank" data-cms-ai="0" rel="noopener">presented a SGMA progress report</a><span> </span>and included panels of government officials as well as farmers, elected leaders and community advocates.</p>
<p>Karla Nemeth, director of the state Department of Water Resources, noted attitudes are changing and more people are willingly coming to the table to discuss SGMA.</p>
<p>“It just opens up conversations we weren't really able to have in a serious way,” she said. “It’s not to say that it’s not going to continue to be quite difficult, but to give ourselves a chance to be optimistic for certain reasons…I think that’s terrific.”</p>
<h2 class="">Farmers are getting on board</h2>
<p></p>
<p>Aaron Fukuda, general manager of the Tulare Irrigation District and interim general manager of the Mid-Kaweah Groundwater Sustainability Agency, agreed. He said he spends a lot of time on the phone talking about SGMA with farmers and other water users.</p>
<p>“I tell everybody it's a two-hour conversation,” he said. “The first hour they're yelling at you, and the second hour they're going, ‘OK, we’re going to do it, how can I be a part of it?’”</p>
<p>For all involved, being a part of SGMA’s implementation means not only finding ways to cut back on groundwater use, but also bringing water back into the system. Many groundwater sustainability agencies have plans to divert or store floodwater and build recharge basins for water to percolate back into the subsurface.</p>
<p>Don Cameron, general manager of Terranova Ranch and chairman of the McMullin Area Groundwater Sustainability Agency in Fresno County, shared that last spring, a series of pumps and canals successfully diverted flood flows into on-farm groundwater recharge.</p>
<p>“We're somewhere between 16 and 18, almost 19,000 acre-feet of water that we took and put on the land and put into the ground,” he said, noting that his agency plans to expand the project in the coming years. “When you've got farmers involved that have their livelihood at stake, they get pretty creative.”</p>
<h2 class="">Room for improvement remains</h2>
<p></p>
<p>Self-Help Enterprises community development specialist Sonia Sanchez emphasized the importance of collaboration between groundwater sustainability agencies and the rural, sometimes disadvantaged, communities within their districts to ensure many voices are heard.</p>
<p>“It does vary, but some themes that we're seeing are that communities are not being engaged overall,” Sanchez said, noting that many of these agencies do not have any rural residents on their governing boards.</p>
<p>“That could be a space where residents could be more involved and have their voices heard.”</p>
<p>Meanwhile, many growers remain skeptical about repurposing their land. As a water cost-saving measure, many agencies are transitioning irrigated farmland into less water-intensive uses like solar farms, habitat restoration, or even dryland farming, which uses no irrigation.</p>
<p>Ralph Pistoresi, a Madera County farmer who attended the SGMA convening, shared his skepticism following a discussion of these options. He pointed to the breakfast buffet at the side of the room.</p>
<p>“All that fruit you ate over there today? You'd be eating oat hay, because that’s the only thing you can grow [by] dryland farming, on a wet year,” he said. “Most people eat three times a day, and unless they're going to eat oat hay or chew on a solar panel, you're not going to be happy.”</p>
<p>Caitlin Peterson, associate director of the PPIC and a research fellow, responded: “I don't think it's anybody's first choice to plant dryland oats or wheat instead of our wonderful diversity of fruits, vegetables, watermelons, almonds…This is more of a conversation about, ‘What can we do with the lands for which there are no other options?’”</p>
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